31 .What is the total number of sigma bonds found in the following compound?

(a) 8 (b) 10 (c) 11 (d) 15

32. Select the correct IUPAC name for:

(a) 5-methyl-5-ethyloctane
(b) 5-methyl-5-propylheptane
(c) 4-ethyl-4-methyloctane
(d) 3-methyl-3-propyloctane
(e) 3-methyl-3-propylheptane
33 .Select the correct IUPAC name for:

(a) 1,4-dimethylcyclopentane
(b) 1,3-dimethylcyclopentane
(c) 2,5-dimethylcyclopentane
(d) 2,3-dimethylcyclopentane
(e) 2,4-dimethylcyclopentane
34.Select the IUPAC name for the compound below.

(a) 2,4-dimethylpentanoic acid

(b) 1,1,3-trimethylbutanoic acid
(c) 1-hydroxy-2,4-dimethylpentanone
(d) 2-carboxyisohexane
35 .Select the IUPAC name for: (CH3)2CHCH(OH)CH2C(CH3)3.
(a) 2,5,5-trimethyl-3-hexanol
(b) 1,1,4,4-pentamethylbutanol
(c) 1,1-dimethylisopentanol
(d) 2,5-dimethyl-4-hexanol
(e) none of these
36 .The IUPAC name of salicylic acid is

a. p- benzoicacid
b. o-hydroxybenzoic acid
c. o-methoxybenzoic acid
d. p-hydroxybenzoic acid

37.what is the IUPAC name of

a.Bicyclo [2,2,2]hexane

b.Bicyclo[2,2,1]hexane

c. Bicyclo[2,2,1]heptane

d.Bicyclo[2,2,0]heptane

38 .the hybridization of alpha and beta Carbon of propene is

a.SP3

b. SP2

c. SP

d. both a and b

39.Alcohols are isomeric with

a. acids
b. ethers
c. esters
d. aldehydes
 40. Which of following pair s represents only electrophiles

a.Cl+ ,BF3

b.H2O,H+

c.NO2+, -NH2

d.OH- ,R-O-H

41.the molecule in which the distance between two adjacent carbon atom s is longest is

a.Ethane b.Ethene c. Ethyne d. Benzene

42.Select the correct priority for citation as principal group

a. COOH>CO>CHO>OH
b. COOH>CHO>CO
c. CHO>COOH>CO
d. CO>COOH>CHO

43.Total no of isomeric alcohol with formula C4H10O is

a.1 b. 2. C . 3 d.4

44.In carbocation the carbon atom bearing positive charge is

a.SP3 hybridised b. SP hybridized c. dSP2 hybridised d. SP2 hybridised

45.when hemolytic fission occurs in Br2 molecule which type of species is formed

a.carbocation b. carbanion c. free radical d. both a and b

46.Which of the following is the correct IUPAC name?

a.3-Ethyl-4, 4-dimethylheptane b. 4,4-Dimethyl-3-ethylheptane

c. 5-Ethyl-4, 4-dimethylheptane c. 4,4-Bis(methyl)-3-ethylheptane

47.Which of the following structures represents bicyclo [3.2.0] heptane -

a. b. c. d.
48Which of the following is the most stable carbocation (carbonium ion)?
(a) CH3 CH2+ (b) (CH3)2 C+H (c) (CH3)3 C+ (d) C H3+

49Which of the following are isomers -

(a) Ethanol and ethoxy ethane (B) Methanol and methoxy methane
(c) Propanoic acid and ethyl acetate (D) Propionaldehyde and acetone

50The compound which has one isopropyl group is :

(A) 2,2,3,3-tetramethyl pentane (B) 2,2-dimethyl pentane
(C) 2,2,3-trimethyl pentane (D) 2-methyl pentane