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SECTION–I
This section contains 05 Multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D) for its answer, out which ONLY ONE is correct.
(+4, - 1)
21. The density of a pure substance ‘A’ whose atoms are in cubic close packing arrangement is 1 g/cc. If
all the tetrahedral voids are occupied by ‘B’ atom, what is the density of resulting solid in g/cc.
[Atomic mass (A) = 30 g/mol, and atomic mass of (B) = 50 g/mol]
(A) 3.33 (B) 4.33 (C) 2.33 (D) 5.33
22. The distance between an octahedral and a tetrahedral void in fcc lattice would be:
3𝑎
(A) √ 3a (B) √2
3𝑎 3𝑎
(C) √3 (D) √4
23. A crystal is made of particles X and Y. X forms fcc packing and Y occupies all the octahedral voids.
If all the particles along one body diagonal are removed then the formula of the crystal would be:
(A) X4 Y3 (B) X5 Y4 (C) X4 Y5 (D) none of theses
24. When heated above 916OC, iron changes its bcc crystalline form to fcc without the change in the
radius of atom. The ratio of density of the crystal before heating ad after heating is:
(A) 1.0609 (B) 0.918 (C) 0.725 (D) 1.231
25. Which of the crystal systems contains the maximum number of Bravis lattices?
(A) Cubic (B) hexagonal (C) triclinic (D) Orthorhombic
SECTION–II
This section contains 10 Multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D) for its answer, out which ONE OR MORE is/are correct.
(+4, –2)
26. The hcp and ccp structure for a given element would be expected to have:
(A) The same co-ordination number (B) The effective number of atoms
(C) The same packing fraction (D) The same percentage void
29. In diamond, carbon atom occupy fcc lattice points as well as alternate tetrahedral voids. If edge
length of the unit cell is 356 pm, then diameter of carbon atom is:
(A) 77.07 pm (B) 154.14 pm (C) 251.7 pm (D) 89pm
34. The shortest distance between 1st and Vth layer of HCP arrangement is:
2 3 2 3
(A) 8�3 𝑟 (B) 4�2 𝑟 (C) 16√3 𝑟 (D) 8�2 𝑟
40. A solid has a structure in which X atoms are located at cubic corners of unit cell, O atoms are at the
edge centres and Y atoms at cube centre.
Then the formula compound is XaYbOc.
If two atoms of O are missing from any of two edge centres per unit cell, then the molecular formula
is Xx Yy Oz.
Then, find the value of (x + y + z) – (a + b + c).