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Atomic Structure

1. The energies of three conservative energy levels L 3 , L 2 and L 1 of hydrogen atom are

respectively. A photon of wavelength λ is emitted for a transition

4 E

, 9

E 0

E

0

0

and

4

L 3 to L 1 . What will be the wavelength of emission for transition L 2 to L 1 ?

(a)

16

λ

31

(b

)

27

λ

7

( c )

19

20 λ

(d) λ

[Concept Evaluator-III]

2. The time of revolution of an electron around a nucleus of charge Ze in nth

Bohr orbit is directly proportional to :

(

a) n

(b ) n 3 / Z 2

( c )

n 2 /Z

[Concept Builder-1]

( d) Z/ n

3. The ratio of minimum to maximum wavelength in Balmer series is :

(

a)

5 : 9

( b ) 5 : 36

( c )

1

: 4

( d)

[Concept Builder-1] 3 : 4

4. The product of angular speed and tangential speed of electron in n th orbit of

hydrogen atom is

( a) Directly proportional to n 2

(c ) Inversely proportional to n 4

[Concept Builder-1]

( b ) Directly proportional to n 3

( d) Independent of n

5. If the binding energy of the electron in a hydrogen atom is 13.6 eV, the energy required to remove the electron from the first excited state of Li ++ is

(

a) 122.4 eV

( b ) 30.6 eV

( c )

13.6 eV

( d)

[Concept Builder-1] 3.4 eV

6. The wavelength of the first line of the Lyman series of a ten-times ionised

sodium atom (i.e., Z = 11) is nearly :

(

a)

1216 Å

( b ) 1216

11

Å

(c ) 1216

(

11

)

2

Å

[Final Shoot-1]

( d) 1216

(

11

)

3

Å

7. Electrons in a certain energy level n = n 1 , can emit 3 spectral lines. When they

are in another energy level, n = n 2 . They can emit 6 spectral lines. The orbital

speed of the electrons in two orbits are in the ratio : [Final Shoot-1]

(a)

4 : 3

( b ) 3 : 4

( c )

2

:

1

( d)

1

: 2

8. The ionisation potential of hydrogen atom is -13.6 eV. An electron in the ground state of a hydrogen atom absorbs a photon of energy 12.75 eV. How many different spectral lines can one expect when the electron makes a downward

transition

[Final Shoot-1]

(a) 1

( b ) 4

( c )

2

( d)

6

9. A hydrogen like atom of atomic number Z is in an excited state of quantum number 2n. It can emit a maximum energy photon of 204 eV. If it makes a

transition to quantum state n, a photon of energy 40.8 eV is emitted. The

value of n will be

(

a)

1

( b ) 2

( c )

3

[Final Shoot-1]

( d)

4

10. A Hydrogen atom and a Li ++ ion are both in the second excited state. If l H and l Li are their respective electronic angular momenta and E H and E Li their

respective energies, then

( a)

(c )

l H > l Li and |E H | > |E Li |

l H = l Li and |E H | > |E Li |

[Final Shoot-1]

( b ) l H = l Li and |E H | < |E Li |

( d) l H < l Li and |E H | < |E Li |