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MATERIAL SAFETY DATA SHEET

PRODUCT: LIQUID EPOXY TYPE P - BASE


REVISION DATE: FEBRUARY 20, 2014 Page 1 of 10

SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

MANUFACTURER/SUPPLIER: CANUSA-CPS, A DIVISION OF SHAWCOR LTD.


ADDRESS: 25 BETHRIDGE ROAD
CITY, PROVINCE/STATE: TORONTO, ONTARIO
POSTAL CODE: M9W 1M7
EMERGENCY PHONE NUMBER: 1-(613) 996-6666 (CANUTEC)
INFORMATION NUMBER: 1-(416) 743-7111

PRODUCT IDENTITY LIQUID EPOXY TYPE P - BASE


(AS USED ON LABEL AND LIST):
PRODUCT USE: PIPELINE CORROSION PROTECTION
PRODUCT I.D. NUMBER (PIN): NOT AVAILABLE

SECTION 2 - HAZARDS IDENTIFICATION

ADVERSE HEALTH EFFECTS:


MAY CAUSE IRRITATION TO EYES, SKIN AND RESPIRATORY SYSTEM; MAY CAUSE
SKIN SENSITIZATION WITH PROLONGED AND REPEATED EXPOSURE

ENVIRONMENTAL EFFECTS:
MAY BE TOXIC TO AQUATIC ORGANISMS

PHYSICAL AND CHEMICAL HAZARDS:


NOT AVAILABLE

SPECIFIC HAZARDS:
NOT AVAILABLE

CARCINOGENICITY INFORMATION:
THIS PRODUCT CONTAINS QUARTZ (CRYSTALLINE SILICA) CLASSIFIED AS
CARCINOGENIC TO HUMANS AND CARBON BLACK CLASSIFIED AS POSSIBLY
CARCINOGENIC TO HUMANS BY IARC

99440-040
MATERIAL SAFETY DATA SHEET
PRODUCT: LIQUID EPOXY TYPE P - BASE
REVISION DATE: FEBRUARY 20, 2014 Page 2 of 10

SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS

INGREDIENT CAS # % HAZARD SYMBOLS RISK PHRASES

EPOXY PHENOL NOVOLAC 28064-14-4 30-60 N, Xi R36, R38, R43,


R51, R53

QUARTZ (CRYSTALLINE 14808-60-7 10-40 Xn R20, R48


SILICA)

SEVERELY HYDROTREATED 64742-52-5 5-10 T R45


HEAVY NAPHTHENIC
DISTILLATE

MICA 12001-26-2 1-5 - -

HYDROPHOBIC SILICA 67762-90-7 1-5 - -

CARBON BLACK 1333-86-4 0.1-1 Xn R40

SECTION 4 - FIRST-AID MEASURES

EYE CONTACT:
IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES; SEEK MEDICAL ATTENTION

SKIN CONTACT:
WASH WITH SOAP AND WATER; REMOVE CONTAMINATED CLOTHING; IF IRRITATION
PERSISTS SEEK MEDICAL ATTENTION

INHALATION:
REMOVE TO FRESH AIR; IF SYMPTOMS PERSIST SEEK MEDICAL ATTENTION

INGESTION:
DO NOT INDUCE VOMITING; SEEK IMMEDIATE MEDICAL ATTENTION

NOTE TO PHYSICIAN:
NOT AVAILABLE

99440-040
MATERIAL SAFETY DATA SHEET
PRODUCT: LIQUID EPOXY TYPE P - BASE
REVISION DATE: FEBRUARY 20, 2014 Page 3 of 10

SECTION 5 - FIRE-FIGHTING MEASURES

SUITABLE EXTINGUISHING MEDIA:


CARBON DIOXIDE; DRY CHEMICAL; FOAM; WATER SPRAY

FIRE-FIGHTING HAZARDS:
IRRITATING VAPOURS MAY BE RELEASED DURING DECOMPOSITION

FIRE-FIGHTING PERSONAL PROTECTIVE EQUIPMENT:


USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING

FIRE-FIGHTING PROCEDURES:
FIGHT FIRE FROM A PROTECTED LOCATION; AVOID HIGH PRESSURE, DIRECT WATER
STREAM THAT MAY SPREAD MOLTEN OR BURNING RESINS

THERMAL DECOMPOSITION BY-PRODUCTS:


OXIDES OF CARBON; ALDEHYDES; HYDROCARBONS

SECTION 6 - ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS:
WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT

ENVIRONMENTAL PRECAUTIONS:
PREVENT RUN-OFF FROM ENTERING DRAINS OR OTHER WATERWAYS

METHODS FOR CLEANING UP:


SOAK UP SPILL WITH INERT ABSORBENT MATERIAL AND PLACE IN A CLOSED
CONTAINER; DISPOSE OF IN COMPLIANCE WITH APPLICABLE LEGISLATION

SECTION 7 - HANDLING AND STORAGE

HANDLING REQUIREMENTS:
WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT

STORAGE REQUIREMENTS:
COOL, DRY ENVIRONMENT

INCOMPATIBLE MATERIALS:
STRONG OXIDIZERS

VENTILATION:
ADEQUATE GENERAL VENTILATION IS RECOMMENDED; LOCAL VENTILATION IN A
CONFINED OR RESTRICTED AREA

99440-040
MATERIAL SAFETY DATA SHEET
PRODUCT: LIQUID EPOXY TYPE P - BASE
REVISION DATE: FEBRUARY 20, 2014 Page 4 of 10

SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS:
ADEQUATE GENERAL VENTILATION IS RECOMMENDED; LOCAL VENTILATION IN A
CONFINED OR RESTRICTED AREA

PERSONAL PROTECTIVE EQUIPMENT (PPE):


GLOVES/TYPE: CHEMICAL-RESISTANT GLOVES WHEN HANDLING MATERIAL
RESPIRATORY/TYPE: WEAR A NIOSH APPROVED RESPIRATOR DURING
APPLICATION AND HANDLING WHERE VAPOUR/MIST IS
ENCOUNTERED IN THE BREATHING ZONE; AFTER
APPLICATION AND DRYING, WEAR A DUST RESPIRATOR FOR
ANY SANDING OR GRINDING TYPE ACTIVITIES
EYE/TYPE: CHEMICAL GOGGLES
FOOTWEAR: PROTECTIVE FOOTWEAR
CLOTHING: CHEMICAL-RESISTANT APRON; LONG SLEEVES AND PANTS
TO COVER EXPOSED SKIN

INGREDIENT EXPOSURE DATA:

INGREDIENT CAS # LD50 (species and LC50 (species OSHA (PEL) ACGIH (TLV)
route) and route) TWA TWA

EPOXY PHENOL NOVOLAC 28064-14-4 2000mg/kg - - -


RAT, ORAL

3 3
QUARTZ (CRYSTALLINE 14808-60-7 - - 0.3mg/m 0.025mg/m
SILICA)

SEVERELY 64742-52-5 - - - -
HYDROTREATED HEAVY
NAPHTHENIC DISTILLATE

3 3
MICA (MUSCOVITE) 12001-26-2 - - 3mg/m 3mg/m

HYDROPHOBIC SILICA 67762-90-7 1000mg/kg - - -


RAT, ORAL

3 3
CARBON BLACK 1333-86-4 8000mg/kg - 3.5mg/m 3mg/m
RAT, ORAL

99440-040
MATERIAL SAFETY DATA SHEET
PRODUCT: LIQUID EPOXY TYPE P - BASE
REVISION DATE: FEBRUARY 20, 2014 Page 5 of 10

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL DATA:
PHYSICAL STATE: LIQUID
FORM: VISCOUS
COLOUR: BLACK
ODOUR: SLIGHT HYDROCARBON ODOUR
ODOUR THRESHOLD (PPM): NOT AVAILABLE
BOILING POINT: 115°C (239 F)
FREEZING POINT: 0°C (32 F)
MELTING POINT: 0°C (32 F)
EVAPORATION RATE: NOT APPLICABLE
VAPOUR PRESSURE (mmHg): NOT APPLICABLE
VAPOUR DENSITY (AIR = 1): NOT APPLICABLE
pH: NOT AVAILABLE
SPECIFIC GRAVITY (WATER = 1): 1.5
COEFFICIENT OF WATER/OIL DISTRIBUTION: NOT AVAILABLE
SOLUBILITY IN WATER: SLIGHT

SECTION 10 - STABILITY AND REACTIVITY

CONDITIONS TO AVOID:
ELEVATED TEMPERATURES

MATERIALS TO AVOID:
STRONG OXIDIZERS, ACIDS, BASES AND AMINES

STABILITY AND REACTIVITY DATA:


STABILITY: UNSTABLE: STABLE: X
HAZARDOUS POLYMERIZATION: WILL OCCUR: WILL NOT OCCUR: X

FLAMMABILITY DATA:
DECOMPOSITION TEMPERATURE: 150ºC (302 F)
FLASHPOINT: 120°C (248 F)
AUTOIGNITION TEMPERATURE: NOT AVAILABLE

HAZARDOUS COMBUSTION PRODUCTS:


OXIDES OF CARBON; ALDEHYDES; HYDROCARBONS

EXPLOSION DATA:
STATIC DISCHARGE: NOT AVAILABLE
MECHANICAL IMPACT: NOT AVAILABLE
LOWER EXPLOSIVE LIMIT, LEL (%): NOT AVAILABLE
UPPER EXPLOSIVE LIMIT, UEL (%): NOT AVAILABLE

99440-040
MATERIAL SAFETY DATA SHEET
PRODUCT: LIQUID EPOXY TYPE P - BASE
REVISION DATE: FEBRUARY 20, 2014 Page 6 of 10

SECTION 11 - TOXICOLOGY INFORMATION

EFFECTS FROM EYE CONTACT:


MAY CAUSE IRRITATION

EFFECTS FROM SKIN CONTACT:


MAY CAUSE IRRITATION

EFFECTS FROM INHALATION:


MAY CAUSE IRRITATION; HOWEVER, UNDER NORMAL CONDITIONS OF USE,
EXPOSURE TO RESPIRABLE SILICA VIA INHALATION IS NOT EXPECTED TO OCCUR

EFFECTS FROM INGESTION:


MAY CAUSE IRRITATION

TOXICOLOGICAL DATA:
EFFECTS OF ACUTE EXPOSURE: SEE ABOVE
EFFECTS OF CHRONIC EXPOSURE: ALLERGY, ECZEMA OR SKIN CONDITIONS MAY
OCCUR
IRRITANCY OF MATERIAL: MODERATE
SENSITIZING CAPABILITY: MAY CAUSE SKIN SENSITIZATION WITH
PROLONGED AND REPEATED EXPOSURE
CARCINOGENICITY OF MATERIAL: THIS PRODUCT CONTAINS QUARTZ
(CRYSTALLINE SILICA) CLASSIFIED AS
CARCINOGENIC TO HUMANS AND CARBON
BLACK CLASSIFIED AS POSSIBLY
CARCINOGENIC TO HUMANS BY IARC
REPRODUCTIVE TOXICITY: NONE KNOWN
TERATOGENICITY: NONE KNOWN
MUTAGENICITY: NONE KNOWN
SYNERGISTIC MATERIALS: NONE KNOWN

SECTION 12 - ECOLOGICAL INFORMATION

ECOTOXICITY DATA:
NOT AVAILABLE

OTHER EFFECTS AND INFORMATION:


MAY BE TOXIC TO AQUATIC ORGANISMS

99440-040
MATERIAL SAFETY DATA SHEET
PRODUCT: LIQUID EPOXY TYPE P - BASE
REVISION DATE: FEBRUARY 20, 2014 Page 7 of 10

SECTION 13 - DISPOSAL CONSIDERATIONS

PRODUCT AS SOLD:
DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, PROVINCIAL, MUNICIPAL AND
LOCAL REGULATIONS

PRODUCT PACKAGING:
DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, PROVINCIAL, MUNICIPAL AND
LOCAL REGULATIONS

SPECIAL INSTRUCTIONS:
NONE

SECTION 14 - TRANSPORT INFORMATION

SHIPPING INFORMATION:
SHIPPING NAME: LIQUID EPOXY TYPE P - BASE
PIN/UN NUMBER: UN3082
PACKING GROUP: III
TDG REGULATED: NOT REGULATED AS A HAZARDOUS MATERIAL
DOT REGULATED: NOT REGULATED AS A HAZARDOUS MATERIAL
IATA REGULATED: NOT REGULATED AS A HAZARDOUS MATERIAL

SPECIAL SHIPPING INSTRUCTIONS:


NOT AVAILABLE

SECTION 15 - REGULATORY INFORMATION

NOTE:
THE REGULATORY INFORMATION PROVIDED IS NOT INTENDED TO BE
COMPREHENSIVE. OTHER LOCAL, STATE, PROVINCIAL, FEDERAL, INTERNATIONAL
OR COUNTRY SPECIFIC REGULATIONS MAY APPLY TO THIS MATERIAL.
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA
OF THE CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE MSDS CONTAINS
ALL THE INFORMATION REQUIRED BY THE CPR.

99440-040
MATERIAL SAFETY DATA SHEET
PRODUCT: LIQUID EPOXY TYPE P - BASE
REVISION DATE: FEBRUARY 20, 2014 Page 8 of 10

GENERAL MATERIAL INFORMATION:


WHMIS CLASSIFICATION:

D2A, D2B

EUROPEAN CLASSIFICATION:

N T Xi, Xn

RISK PHRASES: R20, R36, R38, R40, R43, R45, R48, R51, R53
SAFETY PHRASES: S23, S26, S28, S36, S37, S39, S45, S53

COMPONENT ANALYSIS – LIST STATUS:

INGREDIENT CAS # CANADA US CERCLA


WHMIS IDL PRIORITY LIST

EPOXY PHENOL NOVOLAC 28064-14-4 NO NO

QUARTZ (CRYSTALLINE SILICA) 14808-60-7 D2A NO

SEVERELY HYDROTREATED 64742-52-5 NO NO


HEAVY NAPHTHENIC DISTILLATE

MICA 12001-26-2 NO NO

HYDROPHOBIC SILICA 67762-90-7 NO NO

CARBON BLACK 1333-86-4 D2A, D2B NO

99440-040
MATERIAL SAFETY DATA SHEET
PRODUCT: LIQUID EPOXY TYPE P - BASE
REVISION DATE: FEBRUARY 20, 2014 Page 9 of 10

COMPONENT ANALYSIS – INVENTORY STATUS:

INGREDIENT CAS # CANADA- US- EU- AUSTRALIA


DSL TSCA EINECS -AICS

EPOXY PHENOL NOVOLAC 28064-14-4 YES YES NO YES

QUARTZ (CRYSTALLINE 14808-60-7 YES YES 238-878-4 YES


SILICA)

SEVERELY HYDROTREATED 64742-52-5 YES YES 265-155-0 YES


HEAVY NAPHTHENIC
DISTILLATE

MICA 12001-26-2 YES NO NO YES

HYDROPHOBIC SILICA 67762-90-7 YES YES NO YES

CARBON BLACK 1333-86-4 YES YES 215-609-9 YES

SECTION 16 - OTHER INFORMATION

PREPARED BY: SHAWCOR LTD.


TELEPHONE NUMBER: (416) 743-7111
DATE PREPARED: AUGUST 14, 2012

ADDITIONAL INFORMATION:

WHMIS CLASSIFICATION:
D2A POISONOUS AND INFECTIOUS MATERIAL – MATERIALS CAUSING OTHER TOXIC EFFECTS
– VERY TOXIC MATERIAL
D2B POISONOUS AND INFECTIOUS MATERIAL – MATERIALS CAUSING OTHER TOXIC EFFECTS
– TOXIC MATERIAL

EUROPEAN/INTERNATIONAL HAZARD SYMBOLS AND RISK AND SAFETY PHRASES

HAZARD SYMBOLS:
N DANGEROUS FOR THE ENVIRONMENT
T TOXIC
Xi IRRITANT
Xn HARMFUL

99440-040
MATERIAL SAFETY DATA SHEET
PRODUCT: LIQUID EPOXY TYPE P - BASE
REVISION DATE: FEBRUARY 20, 2014 Page 10 of 10

RISK PHRASES:
R20 HARMFUL BY INHALATION
R36 IRRITATING TO EYES
R38 IRRITATING TO SKIN
R40 LIMITED EVIDENCE OF A CARCINOGENIC EFFECT
R43 MAY CAUSE SENSITISATION BY SKIN CONTACT
R45 MAY CAUSE CANCER
R48 DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE
R51 TOXIC TO AQUATIC ORGANISMS
R53 MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT

SAFETY PHRASES:
S23 DO NOT BREATH GAS/FUMES/VAPOURS
S26 IN CASE OF CONTACT WITH EYES, RINSE IMMEADIATELY WITH PLENTY OF WATER AND
SEEK MEDICAL ADVICE.
S28 AFTER CONTACT WITH SKIN, WASH WITH PLENTY OF WATER
S36 WEAR SUITABLE PROTECTIVE CLOTHING
S37 WEAR SUITABLE PROTECTIVE GLOVES
S39 WEAR SUITABLE EYE/FACE PROTECTION
S45 IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL SEEK MEDICAL ADVICE IMMEADIATELY
(SHOW THE CONTAINER OR LABLE WHERE POSSIBLE)
S53 AVOID EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE

DISCLAIMER: THIS INFORMATION IS ACCURATE AND RELIABLE TO THE BEST OF OUR


KNOWLEDGE. IT IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED. CANUSA-CPS,
A DIVISION OF SHAWCOR LTD. ASSUMES NO LEGAL RESPONSIBILITY FOR THE USE OF, OR
RELIANCE UPON, THIS DATA FOR HAZARDS WHICH MIGHT BE ASSOCIATED WITH THE USE OF
THESE MATERIALS OR FOR RESULTS OBTAINED. IT IS THE RESPONSIBILITY OF THE USER TO
COMPLY WITH ALL APPLICABLE LAWS AND REGULATIONS. THIS MSDS WAS CREATED IN
COMPLIANCE WITH APPLICABLE HAZARDOUS MATERIAL REGULATIONS, AND IS NOT INTENDED
TO BE USED FOR ANY OTHER PURPOSE.

99440-040