MATERIAL SAFETY DATA SHEET

PRODUCT: GTS-PP-100 SLEEVE, CRP-PP-100 REPAIR PATCH

REVISION DATE: APRIL 26, 2013 Page 1 of 11

SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

MANUFACTURER/SUPPLIER: CANUSA-CPS, A DIVISION OF SHAWCOR LTD.

ADDRESS:
CITY, PROVINCE/STATE:
POSTAL CODE:
EMERGENCY PHONE NUMBER:
INFORMATION NUMBER:
25 BETHRIDGE ROAD
TORONTO, ONTARIO
M9W 1M7
(613) 996-6666 (CANUTEC)
(416) 743-7111

PRODUCT IDENTITY GTS-PP-100 SLEEVE, CRP-PP-100 REPAIR PATCH

(AS USED ON LABEL AND LIST):
PRODUCT USE: HEAT SHRINKABLE CORROSION PROTECTION SLEEVE
PRODUCT I.D. NUMBER (PIN): NOT AVAILABLE

SECTION 2 - HAZARDS IDENTIFICATION

ADVERSE HEALTH EFFECTS:

MAY CAUSE IRRITATION TO EYES, SKIN AND LUNGS

ENVIRONMENTAL EFFECTS:
NOT AVAILABLE

PHYSICAL AND CHEMICAL HAZARDS:

MAY EMIT DECOMPOSITION PRODUCTS AT TEMPERATURES ABOVE 150°C (302 F)

SPECIFIC HAZARDS:
HOT MATERIAL MAY CAUSE BURNS

CARCINOGENICITY INFORMATION:
CONTAINS A SMALL AMOUNT OF CARBON BLACK; CARBON BLACK IS LISTED AS A
POSSIBLE HUMAN CARCINOGEN BY IARC

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 MATERIAL SAFETY DATA SHEET
PRODUCT: GTS-PP-100 SLEEVE, CRP-PP-100 REPAIR PATCH
REVISION DATE: APRIL 26, 2013 Page 2 of 11

SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS

INGREDIENT CAS # % HAZARD SYMBOLS RISK PHRASES

HYDROCARBON RESIN 69430-35-9 10-30 - -

LIMESTONE (CALCIUM 1317-65-3 1-5 - R36, R37, R38

CARBONATE)

CARBON BLACK 1333-86-4 1-5 Xn, Xi R36, R37, R38,

R40

POLYPROPYLENE 9003-07-0 1-5 - -

VINYLTRIETHOXYSILANE 78-08-0 0.1-1 Xi R10, R36, R37,

R38

DIBUTYLTIN DILAURATE 77-58-7 0.1-1 N, T R25, R26, R36,

R38, R50, R53

SECTION 4 - FIRST-AID MEASURES

EYE CONTACT:
FLUSH WITH WATER FOR 15 MINUTES; SEEK MEDICAL ATTENTION

SKIN CONTACT:
WASH WITH SOAP AND WATER; DO NOT REMOVE MOLTEN MATERIAL FROM SKIN;
SEEK MEDICAL ATTENTION

INHALATION:
IF EXPOSED TO FUMES OR GASES FROM OVERHEATING SEEK MEDICAL ATTENTION

INGESTION:
SEEK MEDICAL ATTENTION

NOTE TO PHYSICIAN:
NOT AVAILABLE

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 MATERIAL SAFETY DATA SHEET
PRODUCT: GTS-PP-100 SLEEVE, CRP-PP-100 REPAIR PATCH
REVISION DATE: APRIL 26, 2013 Page 3 of 11

SECTION 5 - FIRE-FIGHTING MEASURES

SUITABLE EXTINGUISHING MEDIA:

WATER SPRAY; DRY CHEMICAL; FOAM; CARBON DIOXIDE

FIRE-FIGHTING HAZARDS:
HARMFUL VAPOURS

FIRE-FIGHTING PERSONAL PROTECTIVE EQUIPMENT:

USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING

FIRE-FIGHTING PROCEDURES:
FIGHT FIRE FROM A PROTECTED LOCATION; AVOID HIGH PRESSURE, DIRECT WATER
STREAM THAT MAY SPREAD MOLTEN OR BURNING RESINS

THERMAL DECOMPOSITION BY-PRODUCTS:

OXIDES OF CARBON, NITROGEN AND SULPHUR; ORGANIC ACIDS; ALDEHYDES;
ALCOHOLS

SECTION 6 - ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS:
WEAR PERSONAL PROTECTIVE EQUIPMENT

ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW MATERIAL TO ENTER SEWERS, DRAINS OR WATERWAYS

METHODS FOR CLEANING UP:

LET MATERIAL COOL BEFORE SWEEPING OR SHOVELING INTO A CONTAINER FOR
REUSE OR DISPOSAL

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 MATERIAL SAFETY DATA SHEET
PRODUCT: GTS-PP-100 SLEEVE, CRP-PP-100 REPAIR PATCH
REVISION DATE: APRIL 26, 2013 Page 4 of 11

SECTION 7 - HANDLING AND STORAGE

HANDLING REQUIREMENTS:
AVOID OVERHEATING; DO NOT BREATHE FUMES PRODUCED DURING OVERHEATING
OR BURNING

STORAGE REQUIREMENTS:
COOL, DRY ENVIRONMENT

INCOMPATIBLE MATERIALS:
STRONG ACIDS AND OXIDIZERS

VENTILATION:
GENERAL VENTILATION; LOCAL VENTILATION IF OVERHEATING IS EXPECTED

SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS:
GENERAL VENTILATION; LOCAL VENTILATION IF OVERHEATING IS EXPECTED

PERSONAL PROTECTIVE EQUIPMENT (PPE):

GLOVES/TYPE: PROTECTIVE GLOVES WHEN HANDLING HOT MATERIAL
RESPIRATORY/TYPE: NOT REQUIRED WITH ADEQUATE VENTILATION; WHERE
OVERHEATING IS EXPECTED A NIOSH APPROVED
RESPIRATOR IS NECESSARY
EYE/TYPE: SAFETY GLASSES OR A FACE SHIELD DURING FLAME
HEATING
FOOTWEAR: PROTECTIVE FOOTWEAR
CLOTHING: LONG SLEEVES AND PANTS

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 MATERIAL SAFETY DATA SHEET
PRODUCT: GTS-PP-100 SLEEVE, CRP-PP-100 REPAIR PATCH
REVISION DATE: APRIL 26, 2013 Page 5 of 11

INGREDIENT EXPOSURE DATA:

INGREDIENT CAS # LD50 (species LC50 (species OSHA (PEL) ACGIH (TLV)
and route) and route) TWA TWA

3
HYDROCARBON RESIN 69430-35-9 >5000mg/kg - 5mg/m
(RAT, ORAL)

3 3
LIMESTONE (CALCIUM 1317-65-3 - - 5mg/m 10mg/m
CARBONATE)

3 3
CARBON BLACK 1333-86-4 15400mg/kg 3.5mg/m 3.5mg/m
(RAT, ORAL)

3
POLYPROPYLENE 9003-07-0 - - - 10mg/m

VINYLTRIETHOXYSILANE 78-08-0 9100mg/kg - - -

(RABBIT,
DERMAL)

3 3 3
DIBUTYLTIN 77-58-7 175mg/kg 150mg/m 0.10mg/m 0.10mg/m
DILAURATE (RAT, ORAL) 2H (MOUSE,
INHALATION)

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL DATA:
PHYSICAL STATE: SOLID
FORM: ADHESIVE COATED PLASTIC BACKING
COLOUR: BLACK
ODOUR: NO DISTINCT ODOUR
ODOUR THRESHOLD (PPM): NOT AVAILABLE
BOILING POINT: >160°C (320 F)
FREEZING POINT: NOT AVAILABLE
MELTING POINT: NOT AVAILABLE
EVAPORATION RATE: NOT AVAILABLE
VAPOUR PRESSURE (mmHg): NOT AVAILABLE
VAPOUR DENSITY (AIR = 1): NOT AVAILABLE
pH: NOT AVAILABLE
SPECIFIC GRAVITY (WATER = 1): 0.90-1.10
COEFFICIENT OF WATER/OIL DISTRIBUTION: NOT AVAILABLE
SOLUBILITY IN WATER: INSOLUBLE

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 MATERIAL SAFETY DATA SHEET
PRODUCT: GTS-PP-100 SLEEVE, CRP-PP-100 REPAIR PATCH
REVISION DATE: APRIL 26, 2013 Page 6 of 11

SECTION 10 - STABILITY AND REACTIVITY

CONDITIONS TO AVOID:
TEMPERATURES ABOVE 150°C (302 F)

MATERIALS TO AVOID:
STRONG ACIDS AND OXIDIZERS

STABILITY AND REACTIVITY DATA:

STABILITY: UNSTABLE: STABLE: X
HAZARDOUS POLYMERIZATION: WILL OCCUR: WILL NOT OCCUR: X

FLAMMABILITY DATA:
DECOMPOSITION TEMPERATURE: >150°C (302 F)
FLASHPOINT: >200°C (392 F)
AUTOIGNITION TEMPERATURE: NOT AVAILABLE

HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS:

OXIDES OF CARBON, NITROGEN AND SULPHUR; ORGANIC ACIDS; ALDEHYDES;
ALCOHOLS

EXPLOSION DATA:
STATIC DISCHARGE: NOT AVAILABLE
MECHANICAL IMPACT: NOT AVAILABLE
LOWER EXPLOSIVE LIMIT, LEL (%): NOT AVAILABLE
UPPER EXPLOSIVE LIMIT, UEL (%): NOT AVAILABLE

SECTION 11 - TOXICOLOGY INFORMATION

EFFECTS FROM EYE CONTACT:

MAY CAUSE MECHANICAL IRRITATION; CONTACT WITH HOT MATERIAL MAY CAUSE
BURNS

EFFECTS FROM SKIN CONTACT:

MAY CAUSE DERMATITIS; CONTACT WITH HOT MATERIAL MAY CAUSE BURNS

EFFECTS FROM INHALATION:

VAPOURS FROM OVERHEATING MAY CAUSE IRRITATION

EFFECTS FROM INGESTION:

MAY CAUSE IRRITATION

F-SGU-204-2
 MATERIAL SAFETY DATA SHEET
PRODUCT: GTS-PP-100 SLEEVE, CRP-PP-100 REPAIR PATCH
REVISION DATE: APRIL 26, 2013 Page 7 of 11

TOXICOLOGICAL DATA:
EFFECTS OF ACUTE EXPOSURE: SEE ABOVE
EFFECTS OF CHRONIC EXPOSURE: SKIN DEFATTING MAY OCCUR WITH CHRONIC
EXPOSURE
IRRITANCY OF MATERIAL: MILD
SENSITIZING CAPABILITY: NONE KNOWN
CARCINOGENICITY OF MATERIAL: CARBON BLACK IS LISTED AS A POSSIBLE
CARCINOGEN BY IARC
REPRODUCTIVE TOXICITY: NONE KNOWN
TERATOGENICITY: NONE KNOWN
MUTAGENICITY: NONE KNOWN
SYNERGISTIC MATERIALS: NONE KNOWN

SECTION 12 - ECOLOGICAL INFORMATION

ECOTOXICITY DATA:
NOT AVAILABLE

OTHER EFFECTS AND INFORMATION:

NOT AVAILABLE

SECTION 13 - DISPOSAL CONSIDERATIONS

PRODUCT AS SOLD:
DISPOSE OF IN COMPLIANCE WITH ALL FEDERAL, STATE, PROVINCIAL AND
MUNICIPAL LEGISLATION

PRODUCT PACKAGING:
DISPOSE OF IN COMPLIANCE WITH ALL FEDERAL, STATE, PROVINCIAL AND
MUNICIPAL LEGISLATION

SPECIAL INSTRUCTIONS:
NOT AVAILABLE

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 MATERIAL SAFETY DATA SHEET
PRODUCT: GTS-PP-100 SLEEVE, CRP-PP-100 REPAIR PATCH
REVISION DATE: APRIL 26, 2013 Page 8 of 11

SECTION 14 - TRANSPORT INFORMATION

SHIPPING INFORMATION:
SHIPPING NAME: FLAMMABLE LIQUID, N.O.S
PIN/UN NUMBER: UN1993
PACKING GROUP: III
TDG REGULATED: YES
DOT REGULATED: YES
IATA REGULATED: YES
IMDG REGULATED: YES

SPECIAL SHIPPING INSTRUCTIONS:

NOT AVAILABLE

SECTION 15 - REGULATORY INFORMATION

NOTE:
THE REGULATORY INFORMATION PROVIDED IS NOT INTENDED TO BE
COMPREHENSIVE. OTHER LOCAL, STATE, PROVINCIAL, FEDERAL, INTERNATIONAL
OR COUNTRY SPECIFIC REGULATIONS MAY APPLY TO THIS MATERIAL.
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA
OF THE CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE MSDS CONTAINS
ALL THE INFORMATION REQUIRED BY THE CPR.

GENERAL MATERIAL INFORMATION:

WHMIS CLASSIFICATION:

B2 D2A, D2B

EUROPEAN CLASSIFICATION:

T N Xi Xn

RISK PHRASES: R10, R25, R26, R36, R37, R38, R40, R50, R53

SAFETY PHRASES: S9, S16, S24, S25, S26, S28A, S29, S33, S36, S37, S45, S61

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 MATERIAL SAFETY DATA SHEET
PRODUCT: GTS-PP-100 SLEEVE, CRP-PP-100 REPAIR PATCH
REVISION DATE: APRIL 26, 2013 Page 9 of 11

COMPONENT ANALYSIS – LIST STATUS:

INGREDIENT CAS # CANADA US

WHMIS IDL CERCLA PRIORITY LIST

HYDROCARBON 69430-35-9 NO NO
RESIN

1317-65-3 1317-65-3 NO NO

CARBON BLACK 1333-86-4 D2 NO

POLYPROPYLENE 9003-07-0 NO NO

VINYLTRIETHOXYSILAN 78-08-0 B2, D2 NO

E

DIBUTYLTIN 77-58-7 NO NO
DILAURATE

COMPONENT ANALYSIS – INVENTORY STATUS:

INGREDIENT CAS # CANADA- US- EU- AUSTRALIA

DSL TSCA EINECS -AICS

HYDROCARBON RESIN 69430-35-9 YES YES NO YES

LIMESTONE (CALCIUM 1317-65-3 YES YES 215-279-6 YES

CARBONATE)

CARBON BLACK 1333-86-4 YES YES 215-609-9 YES

POLYPROPYLENE 9003-07-0 YES YES NO YES

VINYLTRIETHOXYSILANE 78-08-0 YES YES 201-081-7 YES

DIBUTYLTIN 77-58-7 YES YES 201-039-8 YES

DILAURATE

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 MATERIAL SAFETY DATA SHEET
PRODUCT: GTS-PP-100 SLEEVE, CRP-PP-100 REPAIR PATCH
REVISION DATE: APRIL 26, 2013 Page 10 of 11

SECTION 16 - OTHER INFORMATION

PREPARED BY: SHAWCOR LTD.

TELEPHONE NUMBER: (416) 743-7111
DATE PREPARED: APRIL 27, 2004

ADDITIONAL INFORMATION:

WHMIS CLASSIFICATION:
B2 FLAMMABLE LIQUIDS – FLASHPOINT OF <37.8°C (100 F)
D2 POISINOUS AND INFECTIOUS MATERIAL (MATERIALS CAUSING OTHER TOXIC EFFECTS)

HAZARD SYMBOLS:
N DANGEROUS TO THE ENVIRONMENT
T TOXIC
Xi IRRITANT
Xn HARMFUL

RISK PHRASES:
R10 FLAMMABLE
R25 TOXIC IF SWALLOWED
R26 VERY TOXIC BY INHALATION
R36 IRRITATING TO EYES
R37 IRRITATING TO RESPIRATORY SYSTEM
R38 IRRITATING TO SKIN
R40 LIMITED EVIDENCE OF A CARCINOGENIC EFFECT
R50 VERY TOXIC TO AQUATIC ORGANISMS
R53 MAY CAUSE LONG TERM ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT

SAFETY PHRASES:
S9 KEEP CONTAINER IN A WELL-VENTILATED PLACE
S16 KEEP AWAY FROM SOURCES OF IGNITION- NO SMOKING
S24 AVOID CONTACT WITH SKIN
S25 AVOID CONTACT WITH EYES
S26 IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND
SEEK MEDICAL ADVICE
S28 AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH PLENTY OF WATER
S29 DO NOT EMPTY INTO DRAINS
S33 TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES
S36 WEAR SUITABLE PROTECTIVE CLOTHING
S37 WEAR SUITABLE GLOVES
S45 IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY
(SHOW THE LABEL WHERE POSSIBLE)
S61 AVOID RELEASE TO THE ENVIRONMENT

F-SGU-204-2
 MATERIAL SAFETY DATA SHEET
PRODUCT: GTS-PP-100 SLEEVE, CRP-PP-100 REPAIR PATCH
REVISION DATE: APRIL 26, 2013 Page 11 of 11

IARC INTERNATIONAL AGENCY FOR RESEARCH ON CANCER

DISCLAIMER: THIS INFORMATION IS ACCURATE AND RELIABLE TO THE BEST OF OUR

KNOWLEDGE. IT IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED. CANUSA-CPS,
A DIVISION OF SHAWCOR LTD. ASSUMES NO LEGAL RESPONSIBILITY FOR THE USE OF, OR
RELIANCE UPON, THIS DATA FOR HAZARDS WHICH MIGHT BE ASSOCIATED WITH THE USE OF
THESE MATERIALS OR FOR RESULTS OBTAINED. IT IS THE RESPONSIBILITY OF THE USER TO
COMPLY WITH ALL APPLICABLE LAWS AND REGULATIONS. THIS MSDS WAS CREATED IN
COMPLIANCE WITH APPLICABLE HAZARDOUS MATERIAL REGULATIONS, AND IS NOT INTENDED
TO BE USED FOR ANY OTHER PURPOSE.

F-SGU-204-2