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Introductory Note
This brochure is intended to assist small Other topics treated in this series of
and medium enterprises (SMEs) to identi- brochures organised along the same
fy gas and dust explosion hazards at lines and already published or being pre-
the workplace, evaluate the associated pared are:
risks and recommend possible preventive
and protective measures.
䡵 Hazards arising from
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1. Basic Information – Principles
To create an explosion there has to be the air is established and the concen-
fuel (i.e. gas, such as hydrogen or dust, tration of the fuel is within the explosion
such as flour), an oxidizer (the oxygen limits, the resulting mixture can be ignit-
in air) and an ignition source (i.e. a hot ed if the ignition source has sufficient
surface or an electrical spark). Once strength.
the mechanism of mixing the fuel with
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sion cannot occur. When the concen- It is important to know that less than
tration is higher than the upper explosion 1 mm of dust can already create an
limit, the mixture is «too rich» and explosive atmosphere.
thus there is insufficient oxygen for an
Although an explosion happens at the
explosion.
blink of an eye, there are several phases
Temperature and pressure also influ- which happen at that instant: the original
ence flammability limits. Higher temper- shock wave blast of the explosion; the
ature results in lower LEL and higher flying fragments of the exploding
UEL, while greater pressure increases container; and, depending on the pres-
both values. sure of the blast, parts of walls, roof,
floors, doors, windows and ceilings
The following Table shows some exam- could collapse. Also, the generated heat
ples of explosion limits: may cause secondary fires, burns
and secondary structural collapse/dam-
age. Moreover, shock waves may sever-
Flammable Lower Upper
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1.4 What could trigger an explosion?
The Council Directive 1999/92/EC, usually cordance with the following basic princi-
referred to as ATEX-137, (hereinafter “User ples:
ATEX Directive”), is the legal basis for the ● the prevention of the formation of explo-
necessary measures at the workplace to sive atmospheres, or where the nature
improve the safety and health protection of of the activity does not allow that,
workers potentially at risk from explosive ● the avoidance of the ignition of explo-
atmospheres. sive atmospheres, and
The User ATEX Directive defines the ● the mitigation of the detrimental effects
minimum requirements for the protection of of an explosion so as to ensure the
safety and health of workers at risk from health and safety of workers and other
explosive atmospheres. persons at risk.
With a view to preventing and providing The Council Directive 94/9/EC, usually re-
protection against explosions, the employ- ferred to as ATEX-95, is also relevant since
er shall take technical and/or organisation- it specifies the essential requirements for
al measures appropriate to the nature of equipment and protective systems intend-
the operation, in order of priority and in ac- ed for use in explosive atmospheres.
In the sense of the User ATEX Directive, require special protective measures to
If an explosive atmosphere may occur safeguard the safety and health of the
at a place in such quantities as to workers concerned, then that place is
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described as a hazardous place and For example:
the corresponding atmosphere in that
place as a hazardous explosive atmo-
Zone 0
sphere. A place in which an explosive atmo-
sphere consisting of a mixture with air
At such workplaces, a of flammable substances in the form
special warning sign of gas, vapour or mist is present con-
must be placed. The tinuously or for long periods or frequent-
EX sign warns workers ly.
and other persons of Ex sign
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able vapour is EN 60079-10. This stan- ● Zone 2: Explosive atmosphere for
dard makes a clear link between the less than 0,1 % of the operation time,
amount of flammable vapour that may or 10 h/yr, but still sufficiently likely
be released, the ventilation at that loca- as to require controls over ignition
tion, and the zone number. sources.
Various other sources have tried to The number given in terms of h/yr could
place time limits on to these zones, but be used in cases where the plant is
none have been officially adopted. operational throughout the year.
Where people wish to quantify the zone
Examples of some common values used
definitions, these values are the most
are:
appropriate, but for the majority of situa-
● Zone 0: Explosive atmosphere for tions a purely qualitative approach is
more than 10 % of the operation time adequate.
of the plant, or 1000 h/yr. Zoning can also be used to determine
● Zone 1: Explosive atmosphere for the extent of protective measures with
more than 0,1 % of the operation time respect to the category of the protective
or 10 h/yr, but less than 10 % of systems to be used in the hazardous
the operation time, or 1000 h/yr. place.
Hazard means anything that can cause atmosphere and the potential con-
harm (e.g. chemicals, electricity, work- sequences, following its subsequent
ing from ladders, an open pit, a circular ignition, from an explosion.
saw, etc). Risk Assessment can be carried out
Risk is the chance, high or low, that using the following checklist to identify
someone could be harmed by these and explosion hazards at the workplace
other hazards together with an indication and following an assessment of the
of how serious the harm could be. risk, come up with the proper preventive
To assess the risk it is necessary to and protective measures.
consider the likelihood of an explosive
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Explosion Hazards Measures Remarks
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Explosion Hazards Measures Remarks
Preventive Maintenance
Hot work (e.g. grinding, flame cutting, welding) in areas with potential explosion Eliminate movable flammable substances and remove dust
hazards (general) deposits, if necessary
keep work area clean by regular cleaning by means of
proper cleaning equipment and material
maintain electrical and mechanical equipment regularly following
the manufacturer’s instructions
The selection of the preventive and the Probability Factor and the Severity
protective measures which should be Factor using the risk assessment matrix
implemented may be established from shown below:
Severity Factor
(Likely to
High 4 5 6 7
occur at least
every year
during the
plant lifetime
Propability
Factor
(Likely to
Medium 3 4 5 6
occur more
than once
during the
plant lifetime)
(Unlikely to
Low 2 3 4 5
uccur during
the plant
lifetime)
(Remotely
Very low 1 2 3 4
possible to
occur, if ever)
In the above scenario, the plant lifetime the necessary action and the time frame
is estimated at 20 years. Based on the in which it must be taken is indicated
values established from the table above, from the table below:
risk necessary)
risk urgently mented immediately for work tasks which are already in progress.
necessary) If risk cannot be reduced to an acceptable level, the prohibition of
work activities must remain in effect.
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4. Risk Reduction – Taking Measures
4.1 Introduction
If the risk assessment has indicated that tioned measures could be technical and
there is a risk of explosion at the work-
place, then measures must be devised
organisational.
The purpose of the preventive measures In such a case, the quantity of the flam-
is to eliminate, if possible, the risk of mable material kept at the workplace
explosion by preventing the creation of should be reduced to the absolute mini-
an explosive atmosphere, or by prevent- mum needed. Flammable materials
ing ignition sources. should be stored in suitable fireproof
storage containers, properly labelled and
Such preventive measures include: away from potential ignition sources. It
is important not to store them together
with incompatible materials that may
4.2.1 Prevent or reduce flammable
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achieved by closed installations. These
parts of the installation shall be of suffi-
ciently tight construction to prevent leak-
age. The installations shall be so de-
signed that no leakage can occur under
the foreseeable operating conditions.
This shall also be ensured by regular
maintenance and testing.
If leakage of flammable substances can-
not be eliminated, the formation of explo-
sive atmosphere must be prevented
by suitable measures so that the con-
centration of the flammable material in
the material/air mixture is kept out-
side the explosion limits. Such possible
measures include ventilation and clean- Figure 3: Improper and proper methods
ing. for removing flammable dust
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malfunction or misuse could be prevent- noted that the equipment
ed from becoming active by: must be suitable for the
nature of the hazardous
● electrostatic grounding,
workplace environment,
● avoiding materials and objects of low e.g. gas certified equipment
electrical conductivity, must only be used in areas
with gas explosive atmos-
● reducing the size of non-conductive pheres.
surfaces,
● avoiding the use for dust 4.2.5 Detection of and explosive
conveying and filling operations of atmosphere
conducting pipes and containers Suitable detection systems may be used
with an electrically insulating inner to provide an early warning when an
coating, explosive atmosphere is formed. These
systems typically trigger the alarm when
● selection of low speed mechanical
the concentration of the flammable
equipment,
material/air mixture is around 10 % of
● selection of electrical and mechanical the LEL. Such systems may shut down
equipment as per the requirements of non explosion proof equipment, start
the ATEX 95 Directive. It should be the exhaust fan, etc.
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which should include at least the follow-
ing:
4.3.1 Issue of written operating
instructions
Operating instructions should contain ● The work location.
written rules of conduct issued by the ● A description and
employer to the workers. Also, a list of duration of the work to be
all mobile work equipment permitted undertaken.
for use in the hazardous place con-
cerned. They should also indicate what ● The number and names
personal protective equipment must of workers involved.
be worn by persons entering such a ● The work equipment to
place. be used.
● Identification of the hazards.
● List of the precautionary
4.3.2 Provide training
Employers must provide workers with measures followed by an acknow-
training on the explosion hazards pre- ledgement by the responsible
sent at the workplace and on the re- person that they have been
levant prevention and protection meas- implemented.
ures taken. This training must take
● The personal protective equipment
place before work commencement and
needed.
when job description changes, when
new work equipment is introduced or ● An acknowledgement that
changed and when new technology is the workers involved have received
introduced. adequate training.
The training should explain, for exam- For example, before maintenance work
ple, how the explosion hazard arises commences in a hazardous area a
and in what parts of the workplace it Work Permit must be issued. Experi-
is likely to appear, the measures ence shows that a high accident risk
taken and the correct use and mainte- is associated with maintenance and
nance of the work equipment. Also, servicing work. Before, during and
workers must be instructed on how after completion of the work, it must
to work safely in or near hazardous be ensured that all necessary protec-
areas. The employer should also brief tive measures are taken.
third persons, such as visitors to the
SME as well as subcontractors, on
the risk of explosion.
4.3.4 Inspection
Before a workplace that contains areas
where an explosive atmosphere may
4.3.3 Adopt a Work Permit System occur, is used for the first time, its
Works, which may cause an explosion, overall explosion safety must be as-
in or near a hazardous place must be sessed by a competent person. Inspec-
carried out through a Work Permit Sys- tion should also be carried out when
tem. A Work Permit Form signed by the alterations, with an impact on the
responsible person should be issued safety levels, take place in an area
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and also after the use of the area in
question.
4.3.6 Marking
The points of entry to hazardous place,
must be properly marked using the
4.3.5 Supervision proper warning signs.
Appropriate workers´ supervision must See section 2.6.
be ensured during the presence of
workers in workplaces where an explo-
sive atmosphere may occur.
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Explosion pressure resistant containers sion doors are, for example, such vent-
and vessels withstand the expected ex- ing devices.
plosion overpressure without becoming
permanently deformed. The design is Explosion venting however, may not
based on the expected explosion over- be used if vented substances are haz-
pressure. ardous, e.g. toxic, corrosive, etc.
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sures developed can be much higher
than the maximum explosion pressure
under normal conditions and may de-
stroy unprotected sections of an installa-
tion, or even items of a plant which are
of the explosion pressure resistant, or
explosion pressure shock resistant
type.
It is therefore important to isolate possi-
Figure 8: Explosion isolation with
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National Aspects (respective legal transpositions)
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National contact persons
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The following ISSA International Sections on Prevention elaborated the brochure.
They are also available for further information:
www.issa.int
Click on “Prevention Sections” under “Quick Links”
ISBN 978-3-941441-50-7