SECTION A (1 MARK)

Q1. Write the formula of any two Oxacials of sulphur?

Q2. Name lanthanoid which show +2 Oxidation state?

Q3. Write the IUPAC name of compound.

Q4. Write the foumula for the compound:

Potossiumhexacyaniferrate (ii)

Q5. Predict the product in the following reaction

Q6. Which type of detergent used in hair conditinor?

SECTION – B (2 MARKS )

Q7. (i) What is lanthanoid contraction?

(ii) Name lanthanoid which show +4 Oxidation state.

Or

Explain the observation giving an appropriate reason for each.

(a) These occurs much more frequent metal-metal bonding in

compound of heavy transition metal (i.e. 3rd series)

(b) Mn +2 is much more resistant than Fe+2 towards Oxidation.

Q8. How do you prepare

(i) KNno4 from K2Mno4

(ii) NaCro4 from FeCr2o4

Q9. (a) Name a Vitamin which help in coagulation of blood.

(b) Name a heterocyclic base which present in RAN but not in DNA.
Q10. Write the following reactions:

(a) Diazotization

(b) Sandmeyer Reaction

Q11. Give Reason

(a) Aniline is weaker base than Cyclohexylamine.

(b) Ammonplysis of alkye halide does not give corresponding amine

in pere state.

SECTION –C ( 3 MARKS)

Q12. (a) Name two allotrupes of sulphur which of them is more state at room

temperature? Which of them formed at 369K?

(b) Why sulphur is paramagnetic in Vapur state?

Q13. (a) Name one narcotic used as Analgesic

(b) Give one example of Artificial sweether which can be used in cold
food and drink.

(c) What are cationic detergents.

Or

What are detergents? How are they classified? Why are detergents
preferred over Soaps?

Q14. (a) Write structure of monomer of Teflon?

(b) What are thermoplastic? Give on example?

(c) Which of following is elastomer nylon ,Neoprene , PVC , Bakelite

Q15. Cecl3, 6H2o gives 2 moles of Agcl when treated with excess of AgNO3
Solution. Write structure and formula of Complex.

(b) Write Hybridization, shape and magnetic property of [Fe (CN6] 3

(Atomic no of Fe =26)
Q.16 (a) Which of following is antiseptic:

o.2% phenol , 2% phenol , aspirin , Ervine

(b) Give one difference between

Analgesic and Antipyretics

(c) Name the drug used for reducing anxiety , tension stress and
depression

Q17. Identify the Compounds A , B , C Write major product only

Q18. How would you account for the following

i) The chemistry of Actinoids is more Complicate as Compared to

lanthanides
ii) Transition metals show variable Oxidation state

Q19. writes the names and structure of monomer of the following polymer.
i) Nylon-6
ii) Novala c
iii) Buna – N
Q20. a) what is difference between amyl use and amylopectin

b) What is difference between natine protein and denaturated protein

c) Write the name of Vitamin whose deficiency leads to Scurvy?

Q.21 a) Fluorine is more reactine than chlorine why?

b) What happen H3po4 is heated

c) Complete the equation

pbs+o3
Q22. a) [ni(c1)4] is paramagnetic , whereas [Ni(co)4] is diamagnetic though
both are tetrahedral why?

b) Explain [ co(NH)6]3+ is inner Orbital Complex , whereas [Ni(NH3)6]

2+ is Outer Orbital Complex (atomic number of Co=27, Ni=28)

Q23. arrange the following ;

i) C2H5NH2 , (C2H5) 3N , (c2H502NH in increasing order of their

boiling point

ii) Aniline , p-nitroaniline , p-methylaniline in increasing order of their

basic strength

Q24. Compound ‘A’ having molecular formula ( c7H7on) on treatment with

br2 and KOh gives ‘B’ (C6H7N) which on Diazotization gives ‘C’ C react
with Aqueous Solution of H3Po2 and from ‘ D’ C on reaction with KI
gives ‘E’ Identify a and E and write reaction involved

Q25. (a) Give two difference between white and red phosphorous?

(b) Complete the following equation:

a) Name One allotrope of Oxygen?

b) Why is Ozone more reactive than Oxygn?
c) Why pH3 is less basis than NH3 ?
d) Why loniazation enthalpy of N More thean O?
e) What are Interhalogen Compounss?

Q26. (a) Complete the following reaction.

(b) Why always have higher boiling points than aldehyde?

(c) Why carboxylic more acidic than phennor?

(a) Write short note on the following:

i. Cannizzaor’s Reaction.
ii. Aldol Condensation.
iii. Wolf- Kishner Reducation.
 (b) Conversion

(i) Acetone to tert Butyl Alcohol

(ii) Butal -2- of to Butane -2- one

Q27. (a) Write electronic configuration of Cr+3 I on? Calculate its magnetic
moment

(b) Complete the following reaction:-

a) Why does cerium show +4 Oxidation state.

b) Why do transition metals from olloy?
c) Which of bivalent ions in 3d series is the most paramagnetic and why?
d) Why do transition metal have higher ionistion enthalpy than 5 block
elemet?
e) Whyb so trasition metal from complex comouns?