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ii. Choose from column (B) the suitable characteristics for the
gases produced from the anion reactions listed in column (A)
:
Column (A) Column (B)
(a) CO32- + HCI(aq) 1. Colourless gas forms white fumes with
(b) SO32- + HCl(aq) wetted glass rod of ammonia solution.
(c ) S2- + HCl (aq) 2. Violet fumes tum a wetted paper of starch
(d) NO2- + HCI(aq) solution blue.
3. Colourless gas turns limewater turbid.
4. Pungent ga turns an acidified potassium
dichromate paper green.
5. Colourless gas has bad odour and turns a
paper wetted with lead acetate black.
6. Colourless gas which turned reddish-brown
iii. Show by balanced chemical
at the mouth of thewhat
reactions test tube.
happens in each of
the following :
(1) Passing carbon dioxide in limewater.
(2) Adding hydrochloric acid to the white precipitate which is formed by
reacting the salt solution of carbonate with magnesium sulphate.
(3) Decomposing magnesium bicarbonate.
(4) Exposing filter paper moistened with acidified potassium dichromate
solution to the gas which is evolved when the solid salt of sulphite
reacts with dil. HCl
(5) Exposing filter paper moistened with lead acetate (II) solution to the
gas which is evolved when the solid salt of sulphide reacts with dil.
HCl
(6) Adding iodine solution to sodium thiosulphate.
(7) Decomposing isolated acid from the reaction of sodium nitrite with dil.
HCl
(8) Exposing nitric oxide to the oxygen.
(9) Adding acidified potassium permanganate solution to sodium nitrite.
iv. How to differentiate practically between each of the following
(with chemical equation as possible.)
(1) Sodium chloride salt and sodium iodide "by using cone. Sulphuric
acid".
(2) Sodium nitrite and sodium nitrate salts.
(3) Sodium bromide and sodium iodide "by using silver nitrate sol."
(4) Sodium carbonate and sodium sulphite salts.
(5) Sodium bromide and sodium chloride salts.
(6) Sodium carbonate and sodium bicarbonate solutions "by using
magnesium sulphate solution".
(7) Calcium chloride and calcium bicarbonate salts.
(8) Sodium sulphite and sodium thiosulphate salts.
(9) Sodium sulphide and sodium bromide solutions.
v. Choose the correct answer for each of the following :
(1) The gas which turns limewater milky .
(a) CO2 (b) SO2 (c)NO2 (d) none of the previous.
(2) The salt which gives vapours with cone. H2SO4 and if a copper
felling is added, dense fumes will evolve, this salt may be
(a) nitrate. (b) chloride. (c) bromide. (d) iodide.
(3) Barium sulphate is insoluble in .
(a) cone. HNO3 (b) cone. HCl (c) conc. H2SO4 (d) dil. HCl
(4) Sulphur dioxide may be detected by its………………..
a. greenish-yellow colour.
b. reddish-brown colour.
c. turns acidified potassium dichromate paper green.
d. ability to decolorize acidified KMnO4 solution
(5) when dil. HCl is added to NaNO2 ……………. .
a. A deep red vapour is evolved.
b. A colourless gas is evolved which turned into violet fumes by
the action of cone. H2SO4
c. A colourless gas is evolved which has irritating smell.
d. A colourless gas is evolved which turned reddish-brown at the
mouth of the test tube.
vi. Mention an example of the importance of analytical chemistry
in :
a. Agriculture.
b. Studying environmental pollutants.
c. Pharmaceutical industries.
d. Checking the validity of industrial products.
vii. Write the name and the chemical formula of the acidic or basic
radicals which give the following product during confirmatory
test
a. A salt reacts with dil. hydrochloric acid and gives a gas with a bad
smell which turns a paper wetted with acidified potassium
dichromate solution into green.
b. A salt solution removes the colour of the acidified solution of
potassium permanganate with cone. Sulphuric acid.
c. A salt reacts with dil. hydrochloric acid and gives a gas which turns
a paper wetted with lead (II) acetate solution into black.
d. A salt gives with dil. hydrochloric acid, a colourless gas which
turns at the mouth of the tube into reddish-brown
viii. Write name of the evolved gas (or vapour) from the reaction of
each of the following and how to detect it :
(1) Dil. hydrochloric acid with sodium carbonate salt.
(2) Dil. hydrochloric acid with sodium sulphite salt.
(3) Dil. hydrochloric acid with sodium sulphate salt.
(4) Dil. hydrochloric acid with sodium thiosulphate salt.
(5) Dil. hydrochloric acid with sodium nitrite salt.
ix. Mention one confirmatory test for each of the following :
(1) Carbonate anion.
(2) Bicarbonate anion.
(3) Sulphite anion.
(4) Sulphide anion
(5) Thiosulphate anion