05/12/2018 OYM

Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005

MM : 70 Time : 3 Hrs.
BOARD BOOSTER TEST
HINTS AND SOLUTION
(Subjective Test - 01)

SECTION-A

A1. In a rock salt type crystal CN of each type of ions is 6.

OR
In Frenkel defect density does not change.
A2. Molality of solution is independent on temperature.
A3. Electrode reaction in Ni–Cd cell is

Cd  s   2Ni  OH3 s  CdO s  2Ni  OH2 s  H2 Ol

OR
Express mathematically the relation among resistance, specific conductivity and cell constant.
The relation between G*, R and K is G* = R × K
Cell constant = resistance × specific conductivity
A4. Threshold energy is greater in magnitude than activation energy.
A5. Electroosmosis – when electrophoresis is prevented by some means, then the dispersion medium begins to
move in electric field.

SECTION-B

A6. Packing efficiency in simple cube

effective number of atoms = 8 × 1/8 = 1, a = 2r

volume of one atom  100

Packing efficiency = volume of cubic unit cell

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One Year Medical 2018-2019 Subjective Test (OYM_ST01)-Hints & Solution

4 3
r
3 
  100  52.4%
8r 3 6

A7. S.NO. Ideal solution Non ideal solution

Solution which follow Raoult’s
Solution which do not follow
1 law over the entire range of
Raoult’s law
conc

2 Hmix  0 Hmix  0

3 E A-A = EB -B=E A-B EA-A & E B-B  EA- B

OR

w 1000
Osmotic pressure,    R  T i
M Vml

25 1000
   0.0821 298  3  10.54atm
134 1000

A8. Fe  2Ag  Fe 2  2Ag

0.059 Fe 2 
Ecell  Ecell
0
 log  2
2  Ag 

0.059 0.1
=  0.80   0.44    log
 0.1
2
2

= 1.2105 V
A9. Inversion of sugar is bimolecular reaction and first order reaction
OR
–2 –1
K = 10 s (first order reaction)

0 .6 9 3
K 
t1
2

0.693
t1   6.93sec
2 102

A10. Shape selective catalysis: The catalytic reaction that depends on the pore structure of catalyst and size of
reactant and product moleccules.
Zeolites are good shape selective catalyst because they have honey comb like structure.
Zeolites are microporous aluminosilicates.

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Subjective Test (OYM_ST01)-Hints & Solution One Year Medical 2018-2019

A11. Stearate ion is C17H35COO–

It consists of hydrophylic head i.e., – COO– end and hydrophobic tail i.e., hydrocarbon part

–
COO

A12. Matrix – Earthy impurities associated with mineral

Slag – The low fusible substance produced by the reaction of gangue or matrix with flux

Gangue + Flux  slag

Eg: CaO + SiO2  CaSiO3

SECTION-C

A13. a. Crystalline solid Amorphous solid

I Anisotropic, long range i Isotropic, short range
order solid order solid
ii Have 3D regular ii
Have random
geometrical pattern of arrangement of particles
particles

b. Schohky defect Frenkel Defect

I Missing of equal number
of cations and amions
from their regular sites
ii It decreases density
Eg: NaCl, KCl
i Dislocation of certain
ions from their regular
sites to interstitial sites
ii No decrease in density
Eg: AgCl, Zns

c. Ferromagnetic Antiferromagnetic
Lose their magnetic behaviour
Strongly attracted by due to alignment of magnetic
i i
magnetic field moments of domain in
compensatory
Magnetic moments of domains
All magnetic moments of
are aligned in antiparallel
domain are arranged in the i
ii directions to cancel out each
same direction i
other
Eg: Fe, Co, Ni
Eg: MnO, MnO2

OR
Effective number of A per unit cell = 8×1/8 = 1
Effective number of B per unit cell = 1×1 = 1
Effective number of C per unit cell = 12 × 1/4 = 3

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One Year Medical 2018-2019 Subjective Test (OYM_ST01)-Hints & Solution

A occupying corners = 1
B occupying body centre = 1
C occupying edge centres = 3
Formula of compound = ABC3
A14. a. Hypertonic solution – cell will shrink
b. Hypotonic solution – cell will expand

0.059 PH2
A15. E   log 2
H
H2 2 H 

Pt/H2 (1 atm) | H+
–0.30 = – 0.059 PH
PH = 5.08

A16. As T increase, number of collisions increases, number of fruitful collisions increases due to increase in kinetic
energy. As a result rate of reaction increases with increase in temperature.

OR

Reaction rate : The change in concentration of reactants or products per unit time.

dc  dx
r or r 
dt dt

Reaction rate constant: The rate of reaction per unit molar concentration of reactants at given temperature.

r = k[c]n

where k = rate constant

A17. Physical adsorption Chemical adsorption

1. By weak vander waal’s forces 1. By chemical bond formation
2. Low enthalpy of adsorption 2. High
3. Reversible 3. Irreversible
4. Multi molecular layer. 4. Unimolecular layer
5. Not specific in nature 5. Specific in nature
6. Favourable at low temperature 6. Favourable at high temperature
OR

Na3PO4 will be more effective because Cr2O3 XH2O is positively charged sol. According to Hardy Schulze
rule, greater the charge on oppositely charged ion if electrolyte added, more effective is coagulation.

A18. a. The process of conversion of precipitate into colloids by shaking it with the dispersion medium in the
presence of a small amount of electrolyte.

b. A process of removing dissolved substance from a colloidal solution by means of diffusion through a
semipermeable membrane

c. The movement of colloideal particles under the applied electric potential. Positively charged particles move
towards the cathode while negatively changed move towards the anode.

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Subjective Test (OYM_ST01)-Hints & Solution One Year Medical 2018-2019

A19. Based on different wetling properties of ore and gangue particles with water and oil

This method uses

1. Water

2. Pine oiol to produce foam and as collector

3. Cresol to stabilise foam

4. Xanthate to increase wetting of sulphide ore

The powdered ore is put in a tank containing stirrer a device of passing compressed air and all the above
material. Foam product takes the sulphide ore by wetting to the surface + diagram

A20. Functions of roasting and calcination

1. Volatile impurities are removed

2. Reaction surface area of ore increases

3. Final form obtained is oxide form generally

A21. i. Ge doped with In (Group – B) causes P–type (Group–14) semiconductor

ii. B doped with Si (Group – 14) causes n–type (Group–13) semiconductor

A22. Tb  Tbs  Tb0  k b mi

180 1
Tbs  100  0.52   1
180 1

Tbs  100.52C

A23. Kohlrausch law: At infinite dilution, molar conduction of an electrolyte is equal to sum of contributions due
to cation as well as anion.

  
 m0 Na 2 SO 4  2 m0 Na    m0 SO 42 
Application: If helps to calculate  m0 of weak eletrolytes

 m0 CH3 COOH   m0 CH3 COONa   m0 HCl   m0 NaCl

OR

3Sn4  2Cr  3Sn2  2Cr 3 E°cell = 0.89V

G  nFEcell

= – 6 × 96500 × 0.89 = –515.31 KJ

A24. The order is 1 w.r.t Cl2 because rate of reaction becomes double when concentraion of Cl2 is doubled. When
concentration of both NO & Cl2 is double, rate becomes 8 times. It menas that it becomes double due to
Cl2 and 4 times due to NO

order w.r.t Cl2 = 1

NO = 2

Over all order = 1 + 2 = 3

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One Year Medical 2018-2019 Subjective Test (OYM_ST01)-Hints & Solution

SECTION-D

A25. Egg in water will swell because of endosmosis + diagram and explanation

Egg in NaCl will shrink because of exosmosis + diagram and explanation

OR

Boiling occurs when external pressure becomes equal to the vapour pressure. So, the boiling pressure = Vp
of solution

Vp of solution = PA0 x A  PB0 xB

2 1
= 540   402 
3 3

= 494 mm of Hg

Here CH2Cl2 is solute

1
402 
XCH2Cl2  3  134
494 494

2
540 
XCH3 Cl  3  360
494 494

nCH2Cl2 134
  0.372
nCHCl3 360

A26.  m0 CH3 COOH  m0 CH3 COO    m0 H

= 345 + 40 = 385 Scm2mol–1

K  1000 1.62  104  1000

mc    54 Scm2mol1
M 0.003

 mc 54
   0.14
m 0
385

OR

Lead storage battery: Secondary cell, rechargable cell

Anode – lead plate

Cathode grid of lead packed with PbO2

Electrolyte – dil. H2SO4 (38%)

Reactions occuring during discharging:

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Subjective Test (OYM_ST01)-Hints & Solution One Year Medical 2018-2019

Anode: Pb  SO 42  PbSO 4  2e 

Cathode: PbO 2  4H  SO 42  2e   PbSO 4  2H2 O

Net r × n: Pb + PbO2 + 4H+ + 2SO 42  2PbSO 4  2H2 O

H2SO4 is consumed during discharging and when concentration falls to 1.20 g/ml it requires recharging +
diagram

A27. let the rate of reaction

rate = K[A]x [B]y

From the data by doubling the [A] rate also becomes double, when [B] is kept constant reate   A   x  1

When the [A] is kept constant and [B] is doubled the rate does not change

rate  B   y  0

dx
 rate  k  A  B  
1

dt

OR

a. For a first order

0.693 0.693
K   6.93  103 s1
t1 100
2

2.303 a
b. K log
t   x
a

2.303 0.05
t 3
 log
6.93  10 0.0125

t = 2000 s

  

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