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PAPER-1 (B.E./B. TECH.

JEE (Main) 2019


COMPUTER BASED TEST (CBT)
Date: 09 January, 2019 (SHIFT-1) | TIME : (9.30 a.m. to 12.30 p.m)

Duration: 3 Hours | Max. Marks: 360


SUBJECT : CHEMISTRY

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| JEE MAIN-2019 | DATE : 09-01-2019 (SHIFT-1) | CHEMISTRY

PART : CHEMISTRY
Straight Objective Type (lh/ks oLrqfu"B izdkj)
This section contains 30 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which Only One is correct.
bl [k.M esa 30 cgq&fodYih iz'u gSaA izR;sd iz'u ds 4 fodYi (1), (2), (3) rFkk (4) gSa] ftuesa ls flQZ ,d lgh gSA

1. Which one of the following statements regarding Henry's law is not correct ?
(1) Different gases have different KH (Henry' law constant) values at the same temperature.
(2) The value of KH increases with increase of temperature and KH is function of the nature of the gas
(3) The partial pressure of the gas in vapour phase is proportional to the mole fraction of the gas in the
solution.
(4) Higher the value of KH at a given pressure, higher is the solubility of the gas in the liquids.
gsujh fu;e ds laca/k esa fuEufyf[kr dFkuksa esa ls dkSu lk ,d lgh ugha gS \
(1) ,d gh rki ij] fofHkUu xSlksa ds KH (gsujh fu;e fLFkjkad) fHkUu gksrs gSaA
(2) ok"i izkoLFkk esa xSl dk vkaf'kd nkc foy;u esa xSl ds eksyka'k ds lekuqikrh gksrk gSA
(3) KH dk eku rkids c<+us ij c<+rk gS rFkk KH xSl dh izd`fr dk Qyu gSA
(4) ,d fn;s x;s nkc ij] nzo esa xSl dh foys;rk vf/kd gksus ij KH dk eku vf/kd gksrk gSA
Ans. (4)
Sol. Value of KH decrease when solubility of gas increases
KH ds eku esa deh gksus ij xSl dh foys;rk esa o`f) gksrh gSA

2. Which amongst the following is the strongest acid ?


fuEu esa ls dkSulk izcyre vEy gS \
(1) CHBr3 (2) CHCl3 (3) CHI3 (4) CH(CN)3
Ans. (4)
 
Sol. The conjugate base of CH(CN)3 is C ( C 3N and in C(CN)3 the negative charge is extensively
delocalized.

CH(CN)3 dk la;qXeh {kkj C(CN)3 vR;fèkd foLFkkuhdj.k ds dkj.k LFkk;h gSA
3. Correct statements amongst a to d regarding silicones are :
(a) They are polymers with hydrophobic character.
(b) They are biocompatible.
(c) In general, they have high thermal stability and low dielectric strength.
(d) Usually, they are resistant to oxidation and used as greases.
(1) (a), (b) and (c) only (2) (a) and (b) Only
(3) (a), (b) and (d) only (4) (a), (b), (c) and (d)
a ls d esa ls flfydkWu ds laca/k esa lgh dFku gSa%
(a) ;s cgqyd ty&fojkxh izd`fr ds gksrs gSaA
(b) budh tSolaxfrrk gksrh gSA
(c) lk/kkj.kr;k] budk mPp Å"ek LFkkf;Ro rFkk fuEu ijkoS|qr lkeF;Z gksrk gSA
(d) lkekU;r;k] ;s vkWDlhdj.k izfrjks/kh gksrs gSa rFkk xzht dh rjg mi;ksx esa yk;s tkrs gSaA
(1) dsoy (a), (b) rFkk (c)a (2) dsoy (a) rFkk (b)
(3) dsoy (a), (b) rFkk (d) (4) (a), (b), (c) rFkk (d)
Ans. (4)
Sol. Refer notes
uksV~l ns[ksaA

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4. Adsorption of a gas follows Freundlich adsorption isotherm. In the given plot, x is the mass of the gas
x
adsorbed on mass m of the adsorbent at pressure p. is proportional to :
m
,d xSl dk vf/k'kks"k.k ÝkW;UMfyd vf/k'kks"k.k lerki oØ dk vuqlj.k djrk gSA fn;s x;s IykV esa] p nkc ij
x
vf/k'kks"k.k ds m gSA lekuqikfrd gSA
m

x 2 unit
Log
m 4 unit

Log P

(1) p2 ds (2) p ds (3) p1/2 ds (4) p1/4 ds


Ans. (3)
x
Sol.  K(P)1/ n
m
x 1
log  log k  log P
m n
1 1
 Slope    <ky
n n
2 1
From graph, slope vkjs[k ls <ky = 
4 2
x
 n2   (P)1/ 2
m

5. The ore that contains both iron and copper is :


(1) azurite (2) copper pyrites (3) malachite (4) dolomite
vk;ju rFkk dkWij nksuksa ftl v;Ld esa mifLFkr gSa og gS %
(1) ,stqjkbV (2) dkWij ikbjkbV (3) eSysdkbV (4) MksyksekbV
Ans. (2)
Sol. CuCO3 .Cu(OH)2 malachite
2CuCO3 .Cu(OH)2 Azurite
CuFeS2 copper pyrite
Dolomite CaCO3.MgCO3
Sol. CuCO3 .Cu(OH)2 esysdkbV
2CuCO3 .Cu(OH)2 ,T;qjkbV
CuFeS2 dkWij ikbjkbfVt
MksyksekbV CaCO3.MgCO3

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6. The correct match between item–I and item–II


Item–I Item–II
(drug) (test)
(A) Chloroxylenol (P) Carbylamine test
(B) Norethindrone (Q) Sodium hydrogencarbonate test
(C) Sulphapyridine (R) Ferric chloride test
(D) Penicillin (S) Bayer's test
enksa–I rFkk II ds e/; lgh lqesy gS %
enksa–I enksa–II
(vkS"k/k) (ijh{k.k)
(A) Dyksjkstbfyuky (P) dkfcZy,sehu
(B) ukj,fFkuMªku (Q) lksfM;e gkbMªkstu dkcksZusV ijh{k.k
(C) lYQkfifjMhu (R) Qsfjd DyksjkbM ijh{k.k
(D) isfuflfyu (S) csvj ijh{k.k
(1) A Q, B P, C S, D R (2) A Q, B S, C P, D R
(3) A R, B S, C P, D Q (4) A R, B P, C S, D Q
Ans. (3)

Sol.

Penicillin

gy

isfuflyhu DyksjksfDlukWy

lYQkikbjhfMu ukWj,f’FkMªkWu

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7. According to molecular orbital theory, which of the following is true with respect to Li 2+ and Li2– ?
(1) Li2+ is unstable and Li2– is stable (2) Li2+ is stable and Li2– is unstable
(3) Both are stable (4) Both are unstable
vkf.od d{kd fl)kUr ds vuqlkj Li2+ rFkk Li2– ds laca/k esa fuEufyf[kr esa ls dkSu lR; gS ?
(1) Li2+ vLFkk;h gS rFkk Li2– LFkk;h gSA (2) Li2+ LFkk;h gS rFkk Li2– vLFkk;h gSA
(3) nksuksa LFkk;h gaSA (4) nksuksa vLFkk;h gSaA
Ans. (3)
Sol. Li 2  5e – Li2–  7e –

1s2 * 1s22s1 1s2 * 1s22s2 * 2s1


3–2 1 4–3 1
B.O.   B.O.  
2 2 2 2
Li2 & Li2– have same bond order since no. of bonding electrons are more than antibonding electrons
both are stable.
Li2
rFkk Li2– leku ca/k Øe j[krs gS D;ksafd cfU/kr bysDVªkWuksa dh la[;k izfrcfU/kr bysDVªkWuksa dh la[;k ls vf/kd
gksrh gSA nksuksa LFkk;h gSA

8. The major product of the following reaction is :


fuEufyf[kr vfHkfØ;k dk eq[; mRikn gS %

Br (1) KOH (aqueous)


(2) CrO3/H+
Br (3) H2SO4/

O O
(1) (2)

Br HO
O O
(3) (4)

HO Br

Ans. (4)
Br OH OH
CrO3 / H  H 2 SO 4 O
Sol. 
 
O 
KOH

Br Br Br Br

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9. 0.5 moles of gas A and x moles of gas B exert a pressure of 200 Pa in a container of volume 10 m3 at
1000 K. Given R is the gas constant in JK–1 mol–1, x is :
1000 K ij 10 m3 vk;ru ds ,d ik=k esa 0.5 eksy xSl A rFkk x eksy xSl B, 200 Pa dk nkc cukrs gSaA ;fn R xSl
fLFkjkad (JK–1 mol–1 esa) gks rks x gS %
4–R 2R 2R 4R
(1) (2) (3) (4)
2R 4R 4 R 2R
Ans. (1)
Sol. PV = nRT
200 × 10 = (0.5 + x) R × 1000
2
0.5 + x =
R
4–R
x=
2R

10. The anodic half–cell of lead–acid battery is recharged using electricity of 0.05 Faraday. The amount of
PbSO4 electrolyzed in g during the process is : (Molar mass of PbSO 4 = 303 g mol–1)

,d ysM&vEy cSVjh ds ,uksMh v)Z&lsy dks 0.05 QSjkMs fo|qr dk mi;ksx djds iqu% vkosf'kr fd;k tkrk gSA bl
izØe esa fo|qr vi?kfVr PbSO4 dh ek=kk (g esa) (PbSO4 dk eksyj nzO;eku = 303 g mol–1)
(1) 15.2 (2) 22.8 (3) 7.6 (4) 11.6
Ans. (3)
Sol. PbSO4 (s)  2e –  Pb(s)  SO24 –
For 2F current passed, PbSO4 electrolyzed = 303g/mol
0.05  303
For 0.05F; PbSO4 electrolyzed = = 7.6g
2
Sol. PbSO4 (s)  2e –  Pb(s)  SO24 –
2F fo|qr/kkjk izokghr djus ij fo|qr vi?kfVr PbSO4 = 303g/mol
0.05F; fo|qr/kkjk izokghr djus ij fo|qr vi?kfVr PbSO4 = 0.05  303 = 7.6g
2

11. The highest value of the calculated spin–only magnetic moment (in BM) among all the transition metal
complexes is :
lHkh laØe.k /kkrq ladqyksa esa lokZf/kd ifjdfyr izpØ.k ek=k pqEcdh; vk?kw.kZ (BM esa) gS %
(1) 4.90 (2) 6.93 (3) 3.87 (4) 5.92
Ans. (4)
Sol. Maximum number of unpaired electrons possible = 5
Spin only magnetic moment = n(n  2) BM  5(5  2)  5.92B.M.
vf/kdre laHko v;qfXer bysDVªkWu = 5
dsoy izpØ.k pqEcdh; vk?kw.kZ = n(n  2) BM  5(5  2)  5.92B.M.

12. The isotopes of hydrogen are :


(1) Deuterium and tritium only (2) Protium and deuterium only
(3) Protium, deuterium and tritium (4) Tritium and Protium only
gkbMªkstu ds leLFkkfud gSa %
(1) M~;wVhfj;e rFkk VªkbfV;e ek=k (2) izksfV;e rFkk M~;wVhfj;e ek=k
(3) izksfV;e] M~;wVhfj;e rFkk VªkbfV;e (4) VªkbfV;e rFkk izksV;e ek=k
Ans. (3)
Sol. Factual rF;kRedA

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13. Aluminium is usually found in +3 oxidation state. In contrast, thalium exists in +1 and +3 oxidation
states. This is due to :
(1) inert pair effect (2) lanthanoid contraction
(3) diagonal relationship (4) lattice effect
,syqehfu;e lkekU;r;k +3 vkWDlhdj.k voLFkk esa ik;k tkrk gSA blds foijhr] FkSfy;e +1 rFkk +3 vkWDlhdj.k
voLFkkvksa esa jgrk gSA bldk dkj.k gS %
(1) vfØ; ;qXe izHkko (2) ySUFksukW;M vkdaqpu
(3) fod.kZ laca/k (4) ySfVl izHkko
Ans. (1)
Sol. Due to inert pair effect T is stable in +1 state
vfØ; ;qXe izHkko ds dkj.k T , +1 voLFkk esa LFkk;h gSA

14. In general, the properties that decrease and increase down a group in the periodic table, respectively,
are :
(1) atomic radius and electronegativity
(2) electronegativity and atomic radius
(3) electron gain enthalpy and electronegativity
(4) electronegativity and electron gain enthalpy
lkekU;r%] vkorZ lkj.kh ds oxZ esa uhps tkus ij ?kVus rFkk c<+us okys xq.k/keZ Øe'k% gS %
(1) ijek.kq f=kT;k rFkk fo|qr&_.kkRedrk
(2) fo|qr&_.kkRedrk rFkk ijek.kq f=kT;k
(3) bysDVªkWu yfC/k ,aFkSYih rFkk fo|qr&_.kkRedrk
(4) fo|qr&_.kkRedrk rFkk bysDVªkWu yfC/k ,aFkSYih
Ans. (2)
Sol. Down the group electronegativity decreases and atomic radius increases
oxZ esa uhps tkus ij fo|qr_.kkRedrk esa deh rFkk ijek.kq f=kT;k esa o`f) gksrh gSA

15. 20 mL of 0.1 M H2SO4 solution is added to 30 mL of 0.2 M NH4OH solution. The pH of the resultant
mixture is : (pKb of NH4OH = 4.7)
20 mL 0.1 M H2SO4 ds foy;u dks 30 m L 0.2 M NH4OH ds foy;u esa feykus ij izkIr feJ.k ds pH dk eku
gS% (pKb of NH4OH = 4.7) [XI_IEQ_BC_M_205]
(1) 9.0 (2) 5.2 (3) 9.4 (4) 5.0
Ans. (1)
Sol. H2SO4 + 2NH4OH (NH4)2 SO4 + 2H2O
2m.m 6m.m.
– 2mm 2mm
4
pOH = 4.7 + log =5
2
pH = 14 – 5 = 9

16. The alkaline earth metal nitrate that does not crystallise with water molecules, is :
{kkjh; e`nk /kkrq ukbVªsV ftldk ty ds v.kqvksa ds lkFk fØLVyhdj.k ugha gksrk gS] og gS %
(1) Sr(NO3)2 (2) Mg(NO3)2 (3) Ba(NO3)2 (4) Ca(NO3)2
Ans. (3)
Sol. Because of low polarization power of Ba2+ ion
Ba2+ vk;u dh U;wu /kqzohdj.k {kerk ds dkj.k

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17. The major product of the following reaction is :


fuEufyf[kr vfHkfØ;k dk eq[;k mRikn gS %
(i) Br2
(ii) EtOH

OEt OEt

Br
(1) (2)

Br OEt

OEt OEt
(3) (4)

Ans. (1)
Br
Br OEt
Br
Br2 EtOH
Sol.  

Addition SN1

18. A water sample has ppm level concentration of the following metals :
Fe = 0.2; Mn = 5.0; Cu = 3.0 ; Zn = 5.0. The metal that makes the water sample unsuitable for drinking
is :
,d ty ds izfrn'kZ esa fuEufyf[kr /kkrqvksa ds ppm lkUnzrk dk Lrj gS %
Fe = 0.2; Mn = 5.0; Cu = 3.0 ; Zn = 5.0. /kkrq ftlds dkj.k ty izfrn'kZ ihus ;ksX; ugha gS og gS %
(1) Fe (2) Zn (3) Cu (4) Mn
Ans. (4)
Sol. Presence of Mn with Concentration 0.05 ppm and higher makes water unsuitable for drinking.
[Reference -NCERT]
Fe = 0.2 ppm, Mn = 0.05 ppm, Cu = 3.0 ppm, Zn = 5.0 ppm
Mn dk lkUæ.k 0.05 ppm ;k vfèkd gksus ls ty ihus ;ksX; ugh jgrk gSA [Reference -NCERT]
Fe = 0.2 ppm, Mn = 0.05 ppm, Cu = 3.0 ppm, Zn = 5.0 ppm
19. The increasing order of pKa of the following amino acids in aqueous solution is :
tyh; foy;u esa fuEufyf[kr ,sehuksa vEyksa ds pKa dk c<+rk Øe gS %
Gly Asp Lys Arg
(1) Asp < Gly < Lys < Arg (2) Arg < Lys < Gly < Asp
(3) Asp < Gly < Arg < Lys (4) Gly < Asp < Arg < Lys
Ans. (1)
In aqueous solution the amino acid exist in following ionic form.

Sol.
NH3+ C=NH2+
COO–

ykbflu, vkfxZukbu, ,likjfVd vEy, Xykbflu


Pi (9.8) (10.8) (3.0) (6.0)

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20. The correct decreasing order for acid strength is :


vEy lkeF;Z ds fy, lgh ?kVrk Øe gS %
(1) CNCH2COOH > O2NCH2COOH > FCH2COOH > ClCH2COOH
(2) FCH2COOH > NCCH2COOH > NO2CH2COOH > ClCH2COOH
(3) NO2CH2COOH > NCCH2COOH > FCH2COOH > ClCH2COOH
(4) NO2CH2COOH > FCH2COOH > CNCH2COOH > ClCH2COOH
Ans. (3)
Sol. Greater the –I effect, greater will be the acidity.
vfèkd –I izHkko] vfèkd vEyh;A

21. The following results were obtained during kinetic studies of the reaction ;
2A + B  Products
Experiment [A] [B] Initial Rate of reaction
(in mol L–1) (in mol L–1) (in mol L–1 min–1)
I 0.10 0.20 6.93 × 10–3
II 0.10 0.25 6.93 × 10–3
III 0.20 0.30 1.386 × 10–2
Time time (in minutes) required to consume half of A is :

fuEufyf[kr vfHkfØ;k ds xfrd v/;;uksa ds nkSjku


fuEufyf[kr ifj.kke izkIr gq, %
2A + B  mRikn
iz;ksx [A] [B] vkjafHkd vfHkfØ;k nj (mol L–1 min–1 esa)
(mol L–1 esa) (mol L–1 esa)
I 0.10 0.20 6.93 × 10–3
II 0.10 0.25 6.93 × 10–3
III 0.20 0.30 1.386 × 10–2
A ds vk/ks Hkkx dks lekIr djus ds fy, vko';d le; (feuV esa) gksxk %
(1) 1 (2) 5 (3) 10 (4) 100
Ans. (3)
Sol. R = k[A]x [B]y
6.93 ×10–3 = k (0.1)x (0.2)y (i)
6.93 × 10–3 = k (0.1)x (0.25)y (ii)
1.386 × 10–2 = k (0.2)x (0.3)y (iii)
 y = 0 (from (i) & (ii))
x = 1 (from (i) & (iii))
 First order wrt A  6.93 ×10–3 = k (0.1)
n2 0.693
 k = 6.93 × 10–2 min–1  t1/ 2   = 10
k 6.93  10 – 2
Sol. R = k[A]x [B]y
6.93 ×10–3 = k (0.1)x (0.2)y (i)
6.93 × 10–3 = k (0.1)x (0.25)y (ii)
1.386 × 10–2 = k (0.2)x (0.3)y (iii)
 y = 0 ((i) & (ii) ls)
x = 1 ((i) & (iii) ls)
 A ds lkis{k izFke dksfV dh vfHkfØ;k gSA
 6.93 ×10–3 = k (0.1)
 k = 6.93 × 10–2 min–1
n2 0.693
 t1/ 2   = 10
k 6.93  10 – 2

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22. The compound A and B in the following reaction are, respectively :


HCHOHCl
  A 
AgCN
B

(1) A = Benzyl alcohol, B = Benzyl isocyanide


(2) A = Benzyl chloride, B = Benzyl cyanide
(3) A = Benzyl chloride, B = Benzyl isocyanide
(4) A = Benzyl alcohol, B = Benzyl cyanide
fuEufyf[kr vfHkfØ;k esa ;kSfxd A rFkk B Øe'k% gSa %
HCHOHCl
  A 
AgCN
B

(1) A = csfUty ,sYdksgky, B = csfUty vkblkslk;ukbM


(2) A = csfUty DyksjkbM, B = csfUty lk;ukbM
(3) A = csfUty DyksjkbM, B = csfUty vkblkslk;ukbM
(4) A = csfUty ,sYdksgky, B = csfUty lk;ukbM
Ans. (3)
CH2–Cl
HCl
Sol. + CH2=O 
  Ph–CH2–NC
AgCN


23. Arrange the following amines in the decreasing order of basicity :


{kkjdrk ds ?kVrs Øe esa fuEu ,sehuksa dks O;oLFkr dhft, %

N N N
| |
H H
(I) (II) (III)

(1) I > III > II (2) III > I > II (3) III > II > I (4) I > II > III
Ans. (2)

Sol. In the lone pair is localized in sp3 hybrid orbital, in the lone pair is localized in sp2
N N
(P)
H
(R)

hybrid orbital, and in the lone pair electron is delocalized in aromaticity.


N

H
(Q)

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gy v;qfXer ;qXe sp3 ladj d{kd esa LFkkuh; gS] v;qfXer ;qXe sp2 ladj d{kd esa LFkkuh; gS]
N N
(P)
H
(R)

dk v;qfXer ;qXe ,jkSesfVd oy; esa foLFkkuhd`r gSA


N

H
(Q)

24. The major product of following reaction is :


fuEufyf[kr vfHkfØ;k dk eq[; mRikn gS %
(1) AlH(i Bu)2
R–CN  ?
(2)H2O

(1) RCONH2 (2) RCH2NH2 (3) RCHO (4) RCOOH


Ans. (3)
(1) AlH(i Bu)2
Sol. R—CN   R–CHO
(2)H2 O

25. Two complexes [Cr(H2O)6]Cl3 (A) and [Cr(NH3)6]Cl3 (B) are violet and yellow coloured respectively. The
incorrect statement regarding them is :
(1) 0 value for (A) is less than that of (B).
(2) both absorb energies corresponding to their complementary colors.
(3) 0 values of (A) and (B) are calculated from the energies of violet and yellow light, respectively.
(4) both are paramagnetic with three unpaired electrons.
nks ladqy [Cr(H2O)6]Cl3 (A) rFkk [Cr(NH3)6]Cl3 (B) Øe'k% cSaxuh rFkk ihys jax ds gSaA buds laca/k esa xyr dFku gS%
(1) (A) ds fy, 0 dk eku (B) dh rqyuk esa de gSA
(2) nksuksa vius iwjd jaxksa ds vuqdwy ÅtkZ dk vo'kks"k.k djrs gSaA
(3) (A) rFkk (B) ds 0 ekuksa dk ifjdyu Øe'k% cSaxuh rFkk ihys izdk'k dh ÅtkZvksa ds }kjk fd;k tkrk gSA
(4) nksuksa rhu v;qfXer bysDVªkWuksa ds lkFk vuqpqEcdh; gSaA
Ans. (3)
Sol. The crystal field splitting parameter can’t be measured by wavelength of yellow and violet colours for
(A) and (B) respectively
fØLVy {ks=k foikVu ekiØe dk ekiu Øe'k% (A) rFkk (B) ds ihys rFkk cSxuh jax dh rjaxnS/;Z ds ekiu }kjk fd;k
ugha tk ldrk gSA

26. A solution of sodium sulfate contains 92 g of Na+ ions per kilogram of water. The molality of Na+ ions in
that solution in mol kg–1 is :
lksfM;e lYQsV ds ,d foy;u esa izfr fdyksxzke ty esa 92 g Na+ vk;u gSaA Na+ vk;u dh ml foy;u esa
eksykfyVh (mol kg–1 esa) gksxh %
(1) 16 (2) 12 (3) 8 (4) 4
Ans. (4)
92
Sol. m= 4
23

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27. The one that is extensively used as a piezoelectric material is :


(1) tridymite (2) amorphous silica
(3) quartz (4) mica
nkc&fo|qr inkFkZ dh rjg foLrh.kZ mi;ksx esa vkus okyk v;Ld gS %
(1) VªkbMkbekbV (2) vfØLVyh; flfydk
(3) DokV~tZ (4) ekbdk
Ans. (3)
Sol. Piezoelectric material are those that produce an electric current when they are placed under
mechanical stress
ikbtksbysDVªhd inkFkZ og inkFkZ gksrs gS tks dh ;kaf=kd ruko okyh fLFkfr esa j[kus ij] fo+|qr /kkjk mRiUu djrs gSA

 1
28. For emission line of atomic hydrogen from ni = 8 to nf = n, the plot of wave number    against  2  will
n 
be (The Rydberg constant, RH is in wave number unit)
(1) Linear with intercept –RH (2) Linear with slope –RH
(3) Non linear (4) Linear with slope RH

ijek.kq gkbMªkstu ds ni = 8 ls nf = n rd dh mRltZu ykbu ds fy,  2  ds fo:) rjax la[;k    dk IykV


1
n 
gksxk] (fjMcxZ fLFkjkad] RH rjax la[;k ds ek=kd esa)
(1) –RH vUr% [k.M ds lkFk jSf[kd (2) –RH Lyksi ds lkFk jSf[kd
(3) vjSf[kd (4) RH Lyksi ds lkFk jSf[kd
Ans. (4)
Sol.
 1 1 
  RHZ2  –
 n2 n2 
 1 2 

 1 1 
 RH(1)2  –
 n 2 82 
 f 
1
RH RH –RH
 – 64 nf
2

nf 2 64

1
Slope for graph of  & is + RH
nf 2

1
, rFkk ds e/; vkjs[k dk <ky + RH gSA
nf 2

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29. Major product of the following reaction is :


fuEufyf[kr vfHkfØ;k dk eq[; mRikn gS %
Cl
Cl NH2
+ H2N 
(1)Et3N

(1)Et3N
(2)Freeradical (2) eqDr ewyd cgqydu
polymrisation
O O
O Cl
Cl
n n
(1) NH2 (2)
HN
O N NH2
H
O O
Cl O

n Cl
O O
(3) (4)
HN
n NH2
NH2 N
O
H

Ans. (1)

Cl Cl

Cl n
Free Radical Polymerization O=C
Sol. Cl NH2 Et N

3
 O=C 
+
NH2 NH NH
O O
CH2 CH2
O=C
O=C
NH2
NH2
Cl Cl

Cl n
Cl NH2 Et N O=C eqDr ewyd cgqydhdj.k O=C
+ 
3
 
NH2 NH NH
O O
CH2 CH2
O=C
O=C
NH2
NH2

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30. Consider the reversible isothermal expansion of an ideal gas in a closed system at two different
temperatures T1 and T2 (T1 < T2). The correct graphical depiction of the dependence of work done (w)
on the final volume (V) is :
nks fHkUu rkiksa T1 rFkk T2 (T1 < T2) ij ,d can fudk; esa ,d vkn'kZ xSl ds mRØe.kh; lerkih izlkj ij fopkj
dhft,A fd;s x;s dk;Z (w) dh vafre vk;ru (V) ij fuHkZjrk dk lgh vkysf[kd fp=k.k gS %
T2 T2
|w| |w|
T1 T1
(1) (2)

O In V O In V
T2 T2
|w| T1 |w| T1

(3) (4)

O In V O In V
Ans. (4)
v
Sol. |w| = nRT n f
vi
|w| = nRT n v f – nRT vi
Intercept will be – ve
vUr%[k.M – ve gksxkA

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