JEE Main 2019 Chemistry January Attempt Shift - 1 (10th January, 2019)

PAPER-1 (B.E./B. TECH.
JEE (Main) 2019

COMPUTER BASED TEST (CBT)
Date: 10 January, 2019 (SHIFT-1) | TIME : (9.30 a.m. to 12.30 p.m)
Duration: 3 Hours | Max. Marks: 360

SUBJECT : CHEMISTRY
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Tel.No.: 0744-6607777, 3012100, 3012222, 6635555 | Toll Free: 1800 258 5555 | Fax: +91-022-39167222 | 08003 444 888
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| JEE MAIN-2019 | DATE : 10-01-2019 (SHIFT-1) | CHEMISTRY
PART : CHEMISTRY
Straight Objective Type (lh/ks oLrqfu"B izdkj)

This section contains 30 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which Only One is correct.
bl [k.M esa 30 cgq&fodYih iz'u gSaA izR;sd iz'u ds 4 fodYi (1), (2), (3) rFkk (4) gSa] ftuesa ls flQZ ,d lgh gSA
1. The correct structure of product ‘P’ in the following reaction is :

NEt
Asn–Ser + (CH3 CO) 2 O 
3
P
(Excess)
fuEu vfHkfØ;k esa mRikn ‘P’ dh lgh lajpuk gS&
NEt3
Asn–Ser + (CH3CO)2 O   P
( vkf/kD;)
O
OCOCH3 O NH2 O
O H N
N N H OH
(1) OH (2) H3C
H3C N H O
H O NH2 OCOCH3
O
OCOCH3
NHCOCH3
O O O O
N N
OH H OH
(3) H3C N H (4) H3C N
H H O NHCOCH3
O
OCOCH3
O
Ans. (2)
O O
Sol. NH2–CH—CO–NH—CH–COOH + Ac2O   CH3–C–NH–CH–C–NH—CH–COOH

Et3N
CH2–C–NH2 CH2–OH O CH2–C–NH2 CH2–O–C–CH3
O O O
2. Consider the given plots for a reaction obeying Arrhenius equation (0°C < T < 300°C) : (k and E a are
rate constant and activation energy, respectively)
Ea
(I)
Choose the correct option :
(1)  is right but II is wrong (2) Both  and  are wrong
(3)  is wrong but  is right (4) Both  and  are correct

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This solution was download from Resonance JEE MAIN 2019 Solution portal PAGE # 1
vkgsZfu;l lehdj.k dks ekuus okyh ,d vfHkfØ;k ds fy, vkjs[kksa ij fopkj dhft, (0°C < T < 300°C), (k rFkk Ea
Øe'k% nj fu;rkad rFkk laØe.k ÅtkZ gSa)
Ea
(I)
lgh fodYi pqfu;s :
(1)  lgh gS ijUrq II xyr gS (2)  rFkk  nksuksa xyr gSa
(3)  xyr gS ijUrq  lgh gS (4)  rFkk  nksuksa lgh gSa
Ans. (4)
Sol. k  Ae–Ea / RT
k decreases exponentially with Ea
 First graph is correct.
But temperature is given in °C So, k  0 at 0°C.

 For temperature between 0°C and 300°C, graph will come like (II)
–Ea / RT
gy K  Ae
K, Ea ds lkFk pj?kkrkadh :i ls ?kVrk gSA
 (I) vkjs[k lgh gSA
ijUrq rkieku °C esa fn;k x;k gS vr% 0° ij k  0

 rki 0°C rFkk 300°C ds e/; vkjs[k (II) tSlk gksxkA

3. Consider the following reduction processes :

fuEu vip;u izØeksa ij fopkj dhft,&
Zn2+ + 2e–  Zn(s) ; E0 = –0.76 V
Ca2+ + 2e–  Ca(s) ; E0 = –2.86 V
Mg2+ + 2e–  Mg(s) ; E0 = –2.36 V
Ni2+ + 2e–  Ni(s); E0 = –0.25 V
The reducing power of the metals increases in the order :
/kkrqvksa dh vipk;d lkeF;Z bl Øe esa c<s+xh&
(1) Ca < Mg < Zn < Ni (2) Ni < Zn < Mg < Ca
(3) Ca < Zn < Mg < Ni (4) Zn < Mg < Ni < Ca
Ans. (2)
Sol. Higher the SOP, higher will be reducing power.
mPp SOP, eku gksus ij] vipk;d {kerk vf/kd gksrh gSA
4. Which hydrogen in compound (E) is easily replaceable during bromination reaction in presence of light?
CH3–CH2–CH=CH2
 
(E)
(1) –hydrogen (2) –hydrogen (3) –hydrogen (4) –hydrogen
;kSfxd (E) esa izdk'k dh mifLFkfr esa czksehus'ku vfHkfØ;k ds chp dkSu gkbMªkstu vklkuh ls foLFkkfir fd;k tk
ldrk gS ?
CH3–CH2–CH=CH2
 
(E)
(1) –gkbMªkstu (2) –gkbMªkstu (3) –gkbMªkstu (4) –gkbMªkstu
Ans. (2)
Sol. Allylic radical is more stable.
,ykbfyd ewyd vf/kd LFkk;h gksrk gSA
5. Wilkinson catalyst is :
foyfdUlu mRizsjd gS&
(1) [(Et3P)3rCl] (Et = C2H5) (2) [(Et3P)3RhCl]
(3) [(Ph3P)3RhCl] (4) [(Ph3P)3rCl]
Ans. (3)
Sol. Refer Notes uksV~l nsa[ksA

6. Which of the graphs shown below does not represent the relationship between incident light and the
electron ejected from metal surface ?
K.E. of No. of Electrons

Electron
(1) (2)
0 0 Frequency
Energy of Light
of Light
K.E. of K.E. of
Electron Electron
(3) (4)
0 0
Frequency of Light Intensity of Light
uhps iznf'kZr xzkQ esa ls dkSu&lk vkifrr izdk'k rFkk /kkrq i`"B ls fu"dkflr bysDVªkWu ds chp dk lEcU/k lgh <ax ls
ugha vfHkO;Dr djrk gS \
bysDVªkWu dh bysDVªkWu dh
xfrt ÅtkZ la[;k
(1) (2)
0 0
izdk'k dh ÅtkZ izdk'k dh vko`fr
bysDVªkWu dh
bysDVªkWu dh xfrt ÅtkZ
xfrt ÅtkZ
(3) (4)
0
0 izdk'k dh rhozrk
izdk'k dh vko`fr
Ans. (3)
K.E. of KEmax = h–h0

Electron tan= h
Sol.
Intercept = –h0
Frequency of Light

bysDVªkWu dh
xfrt ÅtkZ KEmax = h–h0
tan= h
Sol.
Intercept = –h0
izdk'k dh vko`fr
7. Which dicarboxylic acid in presence of a dehydrating agent is least reactive to give an anhydride ?
fuEu esa ls dkSu MkbdkckZfDlfyd vEy futZyhdkjd dh mifLFkfr esa ,d ,ugkbMªkbM nsus ds fy, lcls de
vfHkfØ;k’'khy gS \
CH2 O
CO2H
H2 C COOH COOH
H2C OH
(1) (2) COOH (3) (4)
CO2H H2C COOH
CH2 H2C OH
O
Ans. (2)
O
CH2—CH2—COOH CH2—CH2—C
H O
Sol. 2 O
CH2—CH2—COOH  CH2—CH2—C
O
7 member cyclic anhydride is less stable.
7 lnL; pØh; ,ugkbMªkbM de LFkk;h gSA
8. The type of hybridisation and number of lone pair(s) of electrons of Xe in XeOF 4, respectively, are :
(1) sp3d2 and 1 (2) sp3d2 and 2 (3) sp3d and 1 (4) sp3d and 2
XeOF4 esa Xe ds ladj.k rFkk ,dkdh bysDVªkWu ;qXeksa dh la[;k Øe'k% gSa&
(1) sp3d2 rFkk 1 (2) sp3d2 rFkk 2 (3) sp3d rFkk 1 (4) sp3d rFkk 2
Ans. (1)
O
F F
Sol. Xe
..
F F
9. The decreasing order of ease of alkaline hydrolysis for the following esters is
fuEu ,LVjksa ds fy, {kkjh; ty vi?kVu ds vklkuh ls gksus dk ?kVrk Øe gS]
COOC2H5 Cl COOC2H5
() ()
O2N COOC2H5 CH3O COOC2H5

() (V)
(1) III > II > IV > I (2) II > III > I > IV (3) IV > II > III > I (4) III > II > I > IV
Ans. (4)
Sol. Electron withdrawing group increases rate of reaction and Electron releasing group decreases rate of
reaction
bysDVªkWu xzkgh lewg vfHkfØ;k ds nj dks c<+krk gS vkSj bysDVªkWu nkrk lewg vfHkfØ;k dh nj dks de djrk gSA

10. Which of the following is not an example of heterogeneous catalytic reaction ?

(1) Ostwald’s process (2) Haber’s process
(3) Combustion of coal (4) Hydrogenation of vegetable oils
fuEu esa ls dkSu fo”"kekaxh mRizsjdh; vfHkfØ;k dk mnkgj.k ugha gS \
(1) vksLVokYM izØe (2) gScj izØe
(3) dks;ys dk ngu (4) ouLifr rsyksa dk gkbMªkstuhdj.k
Ans. (3)
Sol. Catalyst
(1) Ostwald process Pt
(2) Haber process Oxide of Fe, K, Al
(3) Combustion of coal no heterogeneous catalytic
(4) Hydrogenation Ni
mRizsjd
(1) vkWLVokYM izØe Pt
(2) gscj izØe Fe, K, Al ds vkWDlkbM
(3) dks;ys dk ngu fo"kekaxh mRizsj.k ugha
(4) gkbMªkstuhdj.k Ni
11. Liquids A and B form an ideal solution in the entire composition range. At 350 K, the vapor pressures of
pure A and pure B are 7 × 103 Pa and 12 × 103 Pa, respectively. The composition of the vapor in
equilibrium with a solution containing 40 mole percent of A at this temperature is :
nzo A rFkk B iwjs la?kVu ds ijkl esa ,d vkn'kZ foy;u cukrs gSaA 350 K ij 'kq) A dk ok”"i nkc rFkk 'kq) B dk
ok"i nkc Øe'k% 7 × 103 Pa rFkk 12 × 103 Pa gSA bl rki ij] ml ok"i dk la?kVu D;k gksxk tks A ds 40 eksy
izfr'kr foy;u ds lkFk lkE; esa gS&
(1) xA = 0.28 ; xB = 0.72 (2) xA = 0.76 ; xB = 0.24
(3) xA = 0.37 ; xB = 0.63 (4) xA = 0.4 ; xB = 0.6
Ans. (1)
xA PA 0 x 'A 7  103 0.4  28 7
Sol. = = = =
xB 0
PB x 'B 12  10 0.6  72 18
3
x’A & x’B are mole fraction in liquid state

x’A o x’B nzo voLFkk esa eksy fHkUu gSA
7 18
xA = = 0.28 ; xB = = 0.72
25 25
12. The effect of lanthanoid contraction in the lanthanoid series of elements by an and large means :
(1) increase in atomic radii and decrease in ionic radii
(2) decrease in both atomic and ionic radii
(3) increase in both atomic and ionic radii
(4) decrease in atomic radii and increase in ionic radii
rRoksa ds ySUFksukbM J`a[kyk esa ySUFksukbM ladqpu lkekU;r;k n'kkZrk gS&
(1) ijekf.od f=kT;k esa o`f) rFkk vk;fud f=kT;k es deh
(2) ijkek.kqd f=kT;kvksa rFkk vk;fud f=kT;kvksa nksuksa dk ?kVuk
(3) ijek.kqd f=kT;kvksa rFkk vk;fud f=kT;kvksa nksuksa dk c<+rk
(4) ijekf.od f=kT;k esa deh rFkk vk;fud f=kT;k es o`f)
Ans. (2)
Sol. Decrease in both atomic and ionic radii
ijekf.od f=kT;k ,oa vk;fud f=kT;k nksuksa es deh

13. The increasing order of the pKa values of the following compounds is :
fuEu ;kSfxdksa ds pKa dk c<+rk gqvk Øe gS]
OH OH OH OH
NO2
NO2 OMe
A B C D
(1) C < B < A < D (2) B < C < D < A (3) B < C < A < D (4) D < A < C < B
Ans. (3)
Sol. Electron withdrawing group increases acidic strength and Electron releasing group decreases acidic
strength.
bysDVªkWu xzkgh lewg vEyh;rk c<+krk gS vkSj bysDVªkWu nkrk lewg vEyh;rk de djrk gSA
14. The total number of isomers for a square planar complex [M(F) (Cl) (SCN) (NO 2)] is :
oxZ leryh ladqy [M(F) (Cl) (SCN) (NO2)] ds fy;s leko;fo;ksa (vkblksejksa) dh dqy la[;k gksxh&
(1) 16 (2) 4 (3) 12 (4) 8
Ans. (3)
Sol. No. of Isomers lekofo;ksa dh la[;k
[M(F) (Cl) (SCN) (NO2)]  3
[M(F) (Cl) (NCS) (NO2)]  3
[M(F) (Cl) (SCN) (ONO)]  3
[M(F) (Cl) (NCS) (ONO)]  3
dqy Total = 12
15. Which premitive unit cell has unequal edge lengths (a  b c) and all axial angles different from 90º ?
(1) Monoclinic (2) Triclinic (3) Hexagonal (4) Tetragonal
fdl vHkkT; ,dd dksf"Bdk esa vleku dksj yEckbZ (a  b c) gksrh gS rFkk lHkh v{kh; dks.k 90º ls fHkUu gksrs gS?
(1) f}leyEck{k (2) f=kurk{k (3) "kVdks.kh; (4) ,durk{k
Ans. (2)
Sol. Factual rF;kRedA
16. The values of KP/KC for the following reactions at 300 K are, respectively : (At 300 K, RT = 24.62 dm 3
atm mol–1)
300 K ij] fuEu vfHkfØ;kvksa ds fy, KP/KC ds eku Øe'k% gksaxs (300 K ij RT = 24.62 dm3 atm mol–1)
N2(g) + O2(g) 2NO(g)
N2O4(g) 2NO2(g)
N2(g) + 3H2(g) 2NH3(g)
(1) 1,4.1 × 10–2 dm–3 atm–1 mol, 606 dm6 atm2mol–2
(2) 1,24.62 dm3 atm–1 mol–1, 1.65 × 10–3 dm–6 atm2mol–2
(3) 24.62 dm3 atm mol–1 606.0 dm6 atm2 mol–2, 1.65 × 10–3 dm–6 atm–2 mol2
(4) 1,24.62 dm3 atm mol–1, 606.0 dm6 atm2mol–2
Ans. (2)
ng
Sol. kP /k c = (RT)
kp
(1) ng = 0 ; =1
kc
kp
(2) ng = 2 – 1 = 1 ; = (RT)1 = (24.62)1
kc
kp
(3) ng = 2 – 4 = –2 ; = (RT)–2 = (24.62)–2 = 1.65 × 10–3
kc

17. The major product of the following reaction is :

CH3O
CH2Cl (i) AlCl3 ( anhyd.)
  
(ii) H2O
fuEu vfHkfØ;k dk eq[; mRikn gS&

CH3O
CH2Cl (i) AlCl3 ( futZy.)
  
(ii) H2O
CH3O CH3O
(1) (2)
OCH3
CH3O
CH3
(3) (4)
CH3
Ans. (1)
MeO MeO
CH2–Cl 
AlCl3 
Sol.  
MeO
MeO 

18. The electronegativity of aluminium is similar to :

(1) Lithium (2) Carbon (3) Boron (4) Beryllium
,Y;wfefu;e dh fo|qr _.kkRedrk fuEu esa ls ftlds leku gS og gS&
(1) yhfFk;e (2) dkcZu (3) cksjkWu (4) csjhfy;e
Ans. (4)
Sol. Be (diagonal relationship).
Be ¼fod.kZ lEcU/k½
19. The chemical nature of hydrogen peroxide is :

(1) Oxidising agent in acidic medium, but not in basic medium.
(2) Oxidising and reducing agent in both acidic and basic medium.
(3) Reducing agent in basic medium, but not in acidic medium.
(4) Oxidising and reducing agent in acidic medium, but not in basic medium.
gkbMªkstu ijkDlkbM dh jklk;fud izd`fr gS&
(1) vEyh; ek/;e esa vkDlhdkjd :i esa] ijUrq {kkjh; ek/;e esa ugha
(2) vEyh; rFkk {kkjh; nksuksa ek/;eksa esa vkDlhdkjd rFkk vipk;d ds :i esa
(3) {kkjh; ek/;e esa vipk;d ds :i esa] vEyh; ek/;e esa ugha
(4) vEyh; ek/;e esa vkDlhdkjd rFkk vipk;d ds :i esa] ijUrq {kkjh; ek/;e esa ugha
Ans. (2)
Sol. H2O2 is Oxidizing agent as well as reducing agent in both acidic & basic medium. Although its oxidizing
or reducing power may vary according to the medium.
H2O2 vEyh; rFkk {kkjh; nksuksa ek/;e esa vkWDlhdkjd rFkk vipk;d nksuksa ds leku O;ogkj djrk gSA ;|fi ek/;e
ds vuqlkj vkWDlhdkjd vipk;d {kerk esa ifjorZu gksrk gSA

20. A process has H = 200 J mol–1 and S = 40 JK–1 mol–1. Out of the values given below, choose the
minimum temperature above which the process will be spontaneous :
,d izØe esa H = 200 J mol–1 rFkk S = 40 JK–1 mol–1 gSA uhps fn;s x;s vk¡dM+ksa esa ls ml fuEure rki dk
pquko dfj;s ftlds Åij izØe Lor% gksxk&
(1) 5 K (2) 12 K (3) 4 K (4) 20 K
Ans. (1)
Sol. G = H – TS = 0
H 200
T= = = 5 K.
S 40
21. Water filled in two glasses A and B have BOD values of 10 and 20, respectively. The correct statement
regarding them, is :
(1) A is more polluted than B. (2) Both A and B are suitable for drinking.
(3) A is suitable for drinking, whereas B is not. (4) B is more polluted than A
nks fxyklksa A rFkk B, esa Hkjs gq, ikuh ds BOD dk eku Øe'k% 10 rFkk 20 gSA lgh dFku dks igpkfu;s&
(1) A, B dh rqyuk esa T;knk iznwf"kr gSA (2) A rFkk B, nksuksa gh ihus ds fy, mi;qDr gSaA
(3) A ihus ds fy, mi;qDr gS tcfd B ugha gSA (4) B, A dh rqyuk esa T;knk iznwf"kr gSA
Ans. (4)
Sol. Clean water would have BOD value of less than 5 ppm whereas highly polluted water could have a
BOD value of 17 ppm or more.
LoPN ty esa BOD dk eku 5 ppm ls de gksxk tcfd vR;f/kd iznwf"kr ty esa BOD dk eku 17 ppm ;k mlls
vf/kd gks ldrk gSA
22. The major product formed in the reaction given below will be :
uhps nh xbZ vfHkfØ;k esa cuus okyk eq[; mRikn gksxk&
NH2
NaNO2
  
Aq. HCl, 0 – 5 ºC
OH
(1) (2) OH
NO2
(3) (4) NO2
Ans. (BONUS)
23. The total number of isotopes of hydrogen and number of radioactive isotopes among, them,
respectively, are :
(1) 3 and 2 (2) 2 and 0 (3) 3 and 1 (4) 2 and 1
gkbMªkstu ds leLFkkfudksa dh dqy la[;k rFkk muesa jsfM;ks/kehZ leLFkkfudksa dh la[;k Øe'k% gSa :
(1) 3 rFkk 2 (2) 2 rFkk 0 (3) 3 rFkk 1 (4) 2 rFkk 1
Ans. (3)
Sol. Protium, Deuterium, Tritium are three isotopes of hydrogen out of which tritium is radioactive.
izksfV;e] M~;wVsfj;e rFkk VªkbfV;e gkbMªkstu ds rhu leko;oh gSaA buesa ls VªkbfV;e jsfM;ks lfØ; gSA

24. Hall-Heroult’s process is given by :

(1) 2Al2O3 + 3C  4Al + 3CO2 (2) Cu+2 (aq) + H2(g)  Cu(s) + 2H+(aq)
Coke , 1673 K
(3) ZnO + C 
 Zn + CO (4) Cr2O3 + 2Al  Al2O3 + 2Cr
gky&gsjkWYV izØe fuEu gS%
(1) 2Al2O3 + 3C  4Al + 3CO2 (2) Cu+2 (aq) + H2(g)  Cu(s) + 2H+(aq)
(3) ZnO + C  dksd
, 1673
 K
 Zn + CO (4) Cr2O3 + 2Al  Al2O3 + 2Cr
Ans. (1)
Sol. Al2O3 (molten) + C (anode)  Al + CO + CO2
Al2O3 (xfyr) + C (,uksM)  Al + CO + CO2
25. If dicxhloromethane (DCM) and water (H2O) are used for differential extraction, which one of the
following statements is correct ?
(1) DCM and H2O will make turbid/colloidal mixture
(2) DCM and H2O will be miscible clearly
(3) DCM and H2O would stay as lower and upper layer respectively in the S.F.
(4) DCM and H2O would stay as upper and lower layer respectively in the separating funnel (S.F.)
;fn MkbDyksjksesFksu (DCM) rFkk ty (H2O) dks vody fu"d"kZ.k esa iz;ksx fd;k tkrk gS rks fuEu esa ls dkSu lk
dFku lgh gS \
(1) DCM rFkk H2O ,d vkfoy@dksykbMh foy;u cuk;saxs
(2) DCM rFkk H2O Li"V :i ls feJ.kh; gksaxs
(3) DCM rFkk H2O i`FkDdkjh Qusy esa Øe'k% fuEu rFkk mPp lrgksa esa :dsaxs
(4) DCM rFkk H2O i`FkDdkjh Qusy esa Øe'k% Åijh rFkk fupys Hkkx esa :dsaxs
Ans. (3)
26. The major product of the following reaction is :

Br
Ph KOH alc ( excess)

 

Br
fuEu vfHkfØ;k dk eq[; mRikn gS %
Br
Ph KOH alc ( vkf/kD; es)a

 

Br
(1) (2)
Ph Ph
(3) (4)
Ph Ph
Ans. (1)
Br
Alc. KOHexcess
Sol. Ph    Ph Ph
Br Conjugated diene la;qfXer MkbbZu

27. The metal used for making X-ray tube window is :

X-fdj.k uyh ds okrk;u dks cukus ds fy, iz;qDr
(1) Na (2) Ca (3) Mg (4) Be
Ans. (4)
Sol. Informative lwpukRedA
28. A mixture of 100 m mol of Ca(OH)2 and 2 g of sodium sulphate was dissolved in water and the volume
was made up to 100 mL. The mass of calcium sulphate formed and the concentration of OH– in
resulting solution, respectively, are : (Molar mass of Ca(OH) 2, Na2SO4 and CaSO4 are 74, 143 and 136
g mol–1, respectively; Ksp of Ca(OH)2 is 5.5 × 10–6)
100 m mol Ca(OH)2 rFkk 2 g lksfM;e lYQsV ds ,d feJ.k dks ty esa ?kksydj mldk vk;ru 100 mL rd fd;k
x;kA cus gq, foy;u esa dSfY'k;e lYQsV dk nzO;eku rFkk OH– dh lkUnzrk Øe'k% gSa] (Ca(OH)2, Na2SO4 rFkk
CaSO4 ds eksyj nzO;eku gSa Øe'k% 74, 143 rFkk 136 g mol–1, Ca(OH)2 dk Ksp = 5.5 × 10–6)
(1) 13.6 g, 0.14 mol L–1 (2) 13.6 g, 0.28 mol L–1
(3) 1.9 g, 0.28 mol L–1 (4) 1.9 g, 0.14 mol L–1
Ans. (3)
Sol. Ca(OH)2 + Na2SO4  CaSO4 + 2 OH–
2000
100 mmol
142
= 13.986  14 milimol 14 mmol 28 mmol
14  136
mass of CaSO4= = 1.9 g
1000
14  136
CaSO4 dk nzzO;eku = = 1.9 g
1000
28
[OH–] = = 0.28 M
100
29. Two pi and half sigma bonds are present in :

nks ikbZ rFkk vk/kk flXek vkcU/k fuEu esa ls fdlesa mifLFkr gSa \
(1) N2+ (2) O2 (3) O2+ (4) N2
Ans. (1)
Sol. N2+ = kk 2s2 *2s2  2p2x p2x 2p2y  2p1z
1
BO = 2.5 = 2  & 
2
30. The major product ‘X’ formed in the following reaction is :
fuEu vfHkfØ;k esa cuusokyk eq[; mRikn ‘X’ gS
O
O
CH2–C–OCH3
NaBH

4
 X
MeOH
OH OH
CH2CH2OH CH2CH2OH
(1) (2)
O O
OH O
CH2–C–OCH3 CH2–C–H
(3) (4)
Ans. (3)
Sol. Ester and alkene are not reduced by NaBH4.
NaBH4 ,LVj rFkk ,Ydhu dk vip;u ugha djrk gSA


JEE Main 2019 Chemistry January Attempt Shift - 1 (10th January, 2019)

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JEE Main 2019 Chemistry January Attempt Shift - 1 (10th January, 2019)

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PAPER-1 (B.E./B. TECH.

JEE (Main) 2019

Duration: 3 Hours | Max. Marks: 360

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Straight Objective Type (lh/ks oLrqfu"B izdkj)

1. The correct structure of product ‘P’ in the following reaction is :

Sol. NH2–CH—CO–NH—CH–COOH + Ac2O   CH3–C–NH–CH–C–NH—CH–COOH

CH2–C–NH2 CH2–OH O CH2–C–NH2 CH2–O–C–CH3

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But temperature is given in °C So, k  0 at 0°C.

ijUrq rkieku °C esa fn;k x;k gS vr% 0° ij k  0

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3. Consider the following reduction processes :

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K.E. of No. of Electrons

K.E. of KEmax = h–h0

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O2N COOC2H5 CH3O COOC2H5

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10. Which of the following is not an example of heterogeneous catalytic reaction ?

x’A & x’B are mole fraction in liquid state

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17. The major product of the following reaction is :

fuEu vfHkfØ;k dk eq[; mRikn gS&

18. The electronegativity of aluminium is similar to :

19. The chemical nature of hydrogen peroxide is :

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24. Hall-Heroult’s process is given by :

26. The major product of the following reaction is :

Ph KOH alc ( excess)

Ph KOH alc ( vkf/kD; es)a

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27. The metal used for making X-ray tube window is :

29. Two pi and half sigma bonds are present in :

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