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PAPER-1 (B.E./B. TECH.

JEE (Main) 2019


COMPUTER BASED TEST (CBT)
Date: 11 January, 2019 (SHIFT-1) | TIME : (9.30 a.m. to 12.30 p.m)

Duration: 3 Hours | Max. Marks: 360


SUBJECT : CHEMISTRY

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| JEE MAIN-2019 | DATE : 11-01-2019 (SHIFT-1) | CHEMISTRY

PART : CHEMISTRY

Straight Objective Type (lh/ks oLrqfu"B izdkj)


This section contains 30 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which Only One is correct.
bl [k.M esa 30 cgq&fodYih iz'u gSaA izR;sd iz'u ds 4 fodYi (1), (2), (3) rFkk (4) gSa] ftuesa ls flQZ ,d lgh gSA

1. An example of solid sol is:


(1) Butter (2) Hair cream (3) Paint (4) Gem stones
Bksl lkWy fdldk ,d mnkgj.k gS &
(1) eD[ku (2) gs;j Øhe (3) isUV (4) tse LVksu
Ans. (4)
Sol. Factual rF;kRedA

2. An organic compound is estimated through Dumus method and was found to evolve 6 moles of CO 2, 4
moles of H2O and 1 mole of nitrogen gas. The formula of the compound is:
,d dkcZfud ;kSfxd dk M;wek fof/k ls vkdyu djus ij ik;k x;k fd 6 eksy CO2, 4 eksy H2O rFkk 1 eksy
ukbVªkstu mRlftZr gksrs gSaA bl ;kSfxd dk lw=k gS %
(1) C6H8N (2) C6H8N2 (3) C12H8N2 (4) C12H8N
Ans. (2)
6CO2

Combustion
Sol. CxHyNz 1N2
by Dumas method
1 mole

4H2O
on applying POAC
we get the formula C6H8N2
6CO2

Sol. CxHyNz 1N2


1 mole
M~;wek fof/k }kjk ngu

4H2O
POAC ykxw djus ij
izkIRk lw=k C6H8N2

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3. Two blocks of the same metal having same mass and at temperature T 1 and T2, respectively, are
brought in contact with each other and allowed to attain thermal equilibrium at constant pressure. The
change in entropy, S, for this process is:
,d gh /kkrq ds leku lagfr okys nks Cykdksa dks Øe'k% rki T1 rFkk T2 ij ijLij ,d nwljs ds lEidZ esa yk;k x;k
fu;r nkc ij Å"eh; lkE; izkIr djus fn;k x;kA bl izØe esa ,UVªkih ifjorZu S gS %
 1 
 T  T2   (T1  T2 ) 2 
(1) 2CP In  1  (2) 2CP In  
 4T1T2   T1T2 
 
 (T  T2 )2   T  T2 
(3) CP In  1  (4) 2CP In  1 
 4T1T2   2T1T2 
Ans. (3)
T1  T2
Sol. TFinal =
2
T 
SI  CP n  f 
 T1 
T 
SII  CP n  f 
 T2 
S  SI  SII
  T  T 2 
 1 2

 T2    2  
= CP n  f   CP n 
 T1T2  T1T2
   
 

4. For the cell Zn(s) |Zn2+ (aq)||Mx+ (aq) |M(s), different half cells and their standard electrode potentials
are given below :
Mx+(aq)/M(s) Au3+(aq)/ Au(s) Ag+(aq)/Ag(s) Fe3+(aq)/Fe2+(aq) Fe2+(aq)/Fe(s)
EMx  / M/( V ) 1.40 0.80 0.77 –0.44

If EZn2 / Zn = –0.76 V, which cathode will give a maximum value of Ecell per electron transferred ?
(1) Au3+ / Au (2) Fe3+ / Fe2+ (3) Fe2+ / Fe (4) Ag+ / Ag

lsy Zn(s) |Zn2+ (aq)||Mx+ (aq) |M(s) ds fy, fofHkUu v)Z&lsy rFkk ekud bysDVªksM foHko uhps fn;s x;s gSa
Mx+(aq)/M(s) Au3+(aq)/ Au(s) Ag+(aq)/Ag(s) Fe3+(aq)/Fe2+(aq) Fe2+(aq)/Fe(s)
EMx  / M/( V ) 1.40 0.80 0.77 –0.44

;fn EZn2 / Zn = –0.76 V, rks izfr bysDVªkWu LFkkukarj.k ds fy, dkSu ls dSFkksM dk Ecell lokZf/kd gksxk %
(1) Au3+ / Au (2) Fe3+ / Fe2+ (3) Fe2+ / Fe (4) Ag+ / Ag
Ans. (1)

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Sol. Ecell  EZn(s)|Zn2  EAu3 / Au(s)


= SOPanode + SRPcathode
= 0.76 V + 1.4 V = 2.16V
E°cell is maximum with EAu3 |Au(s) and Ecell is intensive property so does not depend on number of
electron transferred in cell reaction.
EAu3 |Au(s) ds lkFk E°lsy mPPkre gksxk rFkk ek=kk LorU=ka jk'kh gSA ;g lsy vfHkfØ;k esa LFkkUrjrfjr bysDVªksuksa dh
la[;k ij fuHkZj ugh djrk gSA

5. The correct match between item (I) and item (ii) is:
Item - I Item – II
(A) Norethindrone (P) Anti-biotic
(B) Ofloxacin (Q) Anti-Fertility
(C) Equanil (R) Hypertension
(S) Analgesics
enksa (I) rFkk (ii) ds chp lgh lqesy gS %
en - I en – II
(A) ukWj,fFkuMªku (P) izfrtSfod
(B) vk¶yksDlkflu (Q) izfrtuu {kerk
(C) ,DoSfuy (R) vfrruko
(S) ihM+kgkjh
(1) (A)  (Q); (B)  (R); (C)  (S) (2) (A)  (R); (B) (P); (C)  (S)
(3) (A)  (Q); (B)  (P); (C)  (R) (4) (A)  (R); (B) (P); (C)  (R)
Ans. (3)
Sol. Fact and information based.

Sol. rF; rFkk lwpuk vk/kkfjrA

ukWjfFkUMªksu bDosfuy

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6. Match the metals (column I) with the coordination compound(s)/ emzyme (s) (column II):
(column I) (column II)
Metal Coordination compound(s)/enzyme(s)
(A) Co (i) Wilkinson catalyst
(B) Zn (ii) ChlorophyII
(C) Rh (iii) Vitamin B12
(D) Mg (iv) Carbonic anhydrase
èkkrqvksa (dkWye I) dks milgla;kstu ;kSfxdksa@,Utkbe (dkWye II) ds lkFk lqesfyr dhft,&
(dkWye I) (dkWye II)
èkkrq milgla;kstu ;kSfxd@,Utkbe
(A) Co (i) fofYdlau mRizsjd
(B) Zn (ii) DyksjksfQy
(C) Rh (iii) foVkfeu B12
(D) Mg (iv) dkcksZfud ,UgkbMªst
(1) (A)-(i);(B)-(ii);(C)-(iii);(D)-(iv) (2) (A)-(iv);(B)-(iii);(C)-(i);(D)-(ii)
(3) (A)-(iii);(B)-(iv);(C)-(i);(D)-(ii) (4) (A)-(ii);(B)-(i);(C)-(iv);(D)-(iii)
Ans. (3)
Sol. Based on Fact rF; ij vk/kkfjrA

7. The correct order of the atomic radii of C, Cs, Al, and S is:
C, Cs, Al, rFkk S ds ijek.oh; f=kT;kvksa dk lgh vuqØe gS %
(1) C < S < Al <Cs (2) S < C < Al < Cs
(3) S < C < Cs < Al (4) C < S < Cs < Al
Ans. (1)
Sol. On going down the group size increases. From left to right in a period size decreases.
oxZ es uhps tkus ij vkdkj c<+rk gS vko`rZ esa cka;s ls nka;s tkus ij vkdkj ?kVRkk gSA

8. The polymer obtained from the following reactions is:


(i)NaNO / H O 
NH2 2 3

HOOC (ii)polymerisa tion

fuEufyf[kr vfHkfØ;kvksa ls izkIr gksus okyk cgqyd gS %


(i )NaNO / H O 
NH2 2 3 
HOOC (ii) cg qy dhdj.k

O O O
H
O–(CH2)4–C HNC(CH2)4–C–N
(1) (2)
n n

O O
H
C–(CH2)4–N OC–(CH2)4O
(3) (4)
n n
Ans. (1)

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O
(1) NaNO2,H3O
Sol. H2N–(CH2)4–C–OH

O
HO–(CH2)4–C–OH
O
(O–(CH2)4–C)n Polymerisation
Polymer

9. The correct match between items I and II is:


Item – I Item – II
(Mixture) (Seperation method)
(A) H2O : Sugar (P) Sublimation
(B) H2O : Aniline (Q) Recrystallization
(C) H2O : Toluene (R) Steam distillation
(S) Differential extraction
enksa I rFkk II ds chp lgh lqesy gS %
en – I en – II
(feJ.k) (i`FkDdj.k fof/k)
(A) H2O : 'kdZjk (P) Å/oZikru
(B) H2O : ,fuyhu (Q) iqu% fØLVyu
(C) H2O : VkWywbZu (R) Hkki vklou
(S) izHkkth vklou
(1) (A) (Q);(B)  (R); (C) (P) (2) (A)(R);(B) (P); (C) (S)
(3) (A) (S);(B)  (R); (C) (P) (4) (A)(Q);(B) (R); (C) (S)
Ans. (4)

10. The major product of the following reaction is


fuEufyf[kr vfHkfØ;k
Cl
i HBr


 2 alc.KOH
O
Cl OH Cl
(1) (2) (3) (4)

O O O OH
Ans. (4)
Cl Cl
+ 
Sol. HBr Alco. KOH Tautomerism
HO
O O Br O

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11. If a reaction follows the Arrhenius equation the plot lnk vs 1/(RT) gives straight line with a gradient (–y)
unit . The energy required to activate the reactant is :
(1) –y unit (2) y unit (3) y/R unit (4) yR unit
;fn ,d vfHkfØ;k vkgsZfuvl lehdj.k dk vuqlj.k djrh gS] rks IykV lnk vs 1/(RT), rks izo.krk (–y) ek=kd ds
lkFk ,d lh/kh js[kk nsrk gSA vfHkdkjdksa dks lfØ; djus ds fy, vko';d ÅtkZ gS %
(1) –y ek=kd (2) y ek=kd (3) y/R ek=kd (4) yR ek=kd
Ans. (2)
1
Sol. Slope of nk v/s  –y  –Ea
RT
1
nk rFkk ds e/; vkjs[k dk <+ky = – Y = –Ea
RT
 Ea  y

12. The major product of the following reaction is:


fuEu vfHkfØ;k ls izkIr gksus okyk eq[; mRikn gS %

H
OH O N NH
(1) (2) (3) (4)
CHO
NH2
Ans. (3)
O O
C–OC2H5 H2 + Ni C–OC2H5
Sol.
CN NH2

DIBAL-H

N CH=O
NH2

13 Consider the reaction, N2(g) + 3H2(g) 2NH3(g). The equilibrium constant of the above reaction is
KP. If pure ammonia is left to dissociate, the partial pressure of ammonia at equilibrium is given by
(Assume that pNH3  ptotal at equilibrium)

fuEufyf[kr vfHkfØ;k ij fopkj dhft,% N2(g) + 3H2(g) 2NH3(g)


mi;qZDr vfHkfØ;k dk lkE; fLFkjkad KP gSA ;fn fo'kq) veksfu;k dks fo;ksftr gksus fn;k tkrk gS] rks lkE;koLFkk ij
veksfu;k dk vkaf'kd nkc gS % (eku yhft, lkE;koLFkk ij pNH3  ptotal )

33 / 2 K1/
p P
2 2
33 / 2 K1/
p P
2 2
K1/
p P
2 2
K1/
p P
2 2
(1) (2) (3) (4)
16 4 4 16

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Ans. (1)
1
Sol. 2NH3 N2 + 3H2 K'P =
kP
PTotal = P = PN2  PH2  PNH3 PN2  PH2

P
PN2 
4
3P
PH2 
4
3
 P  3P 
1  4 
 4 


 
kP 2
PNH3
3
3 2 P2
PNH3  kP 1/ 2
16

14. The element that usually does NOT show variable oxidation states is :
lkekU; :i ls ifjorZuh; vkDlhdj.k voLFkk ugha iznf'kZr djus okyk rRo gS %
(1) Cu (2) Ti (3) Sc (4) V
Ans. (3)
Sol. Sc shows only +3 oxidation state.
Sc dsoy +3 vkDlhdj.k voLFkk n'kkZrk gSA

15. Peroxyacetyl nitrate (PAN), an eye irritant is produced by :


(1) Classical smog (2) Organic waste
(3) Photochemical smog (4) Acid rain
ijkDlh,lhVkby ukbVªsV (PAN), ,d us=k mÙkstd] fuEufyf[kr esa ls fdlesa mRiUu gksrk gS \
(1) fpjlEer /kwedqgk (2) dkcZfud vif'k"V
(3) izdk'k jklk;fud /kwedqgk (4) vEy o"kkZ
Ans. (3)
Sol. Based on Fact.

16. NaH is an example of :


(1) Electron-rich hydride (2) Saline hydride
(3) Molecular hydride (4) Metallic hydride
NaH ,d mnkgj.k gS
(1) bysDVªkWu&/kuh
gkbMªkbM dk (2) yo.k gkbMªkbM dk
(3) vkf.od gkbMªkbM dk (4) /kkfRod gkbMªkbM dk
Ans. (2)
Sol. Saline hydrides react violently with water producing dihydrogen gas.
{kkjh; gkbMªkbM] ty esa rhozrk ls fØ;k dj MkbZgkbMªkstu xSl nssrs gSA
NaH(s) + H2O (aq)  NaOH(aq) + H2 (g)

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17. Heat treatment of muscular pain involves radiation of wavelength of about 900 nm. Which spectral line
of H-atom is suitable for this purpose ?
[RH = 1 × 105 cm–1, h = 6.6 × 10–34 Js, c = 3 × 108 ms–1 ]
(1) Paschen,  3 (2) Paschen, 5  3 (3) Balmer,  2 (4) Lyman,  1
ekalis'kh; nnZ ds Å"ek mipkj ds fy, yxHkx 900 nm ds rjaxnS/;Z ds fofdj.k dk mi;ksx gksrk gSA blds fy,
H-ijek.kq dh dkSulh LisDVªy ykbu mi;qDr gS \
[RH = 1 × 105 cm–1, h = 6.6 × 10–34 Js, c = 3 × 108 ms–1 ]
(1) ik'u,  3 (2) ik'ku, 5  3 (3) ckej,  2 (4) ykbZeSu,  1
Ans. (1)
1  1 1 
Sol.  R 2  2 
 n
 1 n2 
1  1 1
 107  2  
  (3) 
= 9 × 10–7 m
= 900 nm

18. The major product of the following reaction is:


fuEufyf[kr vfHkfØ;k dk eq[; mRikn gS %
COCH3
(i) KMnO / KOH, (i) KMnO / KOH,

4
 
4

(ii) H2SO4 (dil) (ii) H2SO4 ( ruq )
CH3
COCH3 COOH
(1) (2)
HOOC OHC
COOH COCOOH
(3) (4)
HOOC HOOC
Ans. (3)
COCH3 COOK
KMnO4/KOH COOH
H SO
Sol. H3C
2

4

KOOC HOOC

19. The correct statement among (a) to (d) regarding H2 as a fuel are :
(a) It produces less pollutants that petrol.
(b) A cylinder of compressed dihydrogen weighs ~30 times more than a petrol tank producing the same
amount of energy.
(c) Dihydrogen is stored in tanks of metal alloys like NaNi5 .
(d) On combustion, values of energy released per gram of liquid dihydrogen and LPG are 50 and 142
kJ, respectively.
(1) (a) and (c) only (2) (b) and (d) only
(3) (a), (b) and (c) only (4) (b), (c) and (d) only

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bZa/ku ds :i esa H2 ds ckjs esa] (a) ls (d) esa ls lgh dFku gSa %
(a) ;g isVªksy dh vis{kk de iznw"kdksa dks cukrk gS
(b) mlh ek=kk dh ÅtkZ mRiUu djus ds fy, ,d isVªksy VSad dh rqyuk esa ,d laihfMr gkbMªkstu dk flfyUMj ~30
xquk vf/kd Hkkjh gksrk gSA
(c) MkbgkbMªkstu dks NaNi5 dh rjg ds /kkrq feJ/kkrq ds VSad esa j[kk tkrk gSA
(d) ngu ds mijkar] izfr xzke nzfor MkbgkbMªkstu rFkk LPG ls mRlftZr ÅtkZ ds eku Øe'k% 50 rFkk 142 kJ gSa
(1) (a) rFkk (c) ek=k (2) (b) rFkk (d) ek=k (3) (a), (b) rFkk (c) ek=k (4) (b), (c) rFkk (d) ek=k
Ans. (3)
Sol. Factual

20. Match the ores (column A) with the metals (column B) :


(Column A) (Column B)
Ores Metals
(I) Siderite (a) Zinc
(II) Kaolinite (b) Copper
(III) Malachite (c) Iron
(IV) Calamine (d) Aluminium
v;Ldksa (dkWye A) dks /kkrqvksa (dkWye B) ds lkFk lqesfyr dhft,%
(dkWye A) (dkWye B)
v;Ld /kkrq
(I) flMsjkbV (a) ftad
(II) dsvksfyukbV (b) dkWij
(III) eSysdkbV (c) vk;ju
(IV) dSykekbu (d) ,Y;qfefu;e
(1) (I)  (c); (II)  (d); (III)  (b); (IV)  (a) (2) (I)  (b); (II)  (c); (III)  (d); (IV)  (a)
(3) (I)  (c); (II)  (d); (III)  (a); (IV)  (b) (4) (I)  (a); (II)  (b); (III)  (c); (IV)  (d)
Ans. (1)
Sol. Malachite esysdkbV - CuCO3.Cu(OH)2
Calamine dsykekbu - ZnCO3
Kaolin dsvksfyu - Al2Si2O5(OH)4
Siderite flMsjkbV - FeCO3

21. Among the following compounds, which one is found in RNA?


fuEufyf[kr ;kSfxdksa esa ls dkSu lk ,d RNA esa ik;k tkrk gS \
NH2 O O O
H3 C
N NH N Me NH
(1) (2) (3) (4)
N O N O N O N O
H
H H Me
Ans. (4)

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O

NH
Sol. Uracil is present in RNA.
N O
H
O

NH
Sol. ;wjsfly RNA es mifLFkr gSA
N O
H
22. The amphoteric hydroxide is:
mHk;/kehZ gkbMªkDlkbM gS &
(1) Sr(OH)2 (2) Mg(OH)2 (3) Ca(OH)2 (4) Be(OH)2
Ans. (4)
Sol. Be forms amphoteric hydroxide.
Be mHk;/kehZ gkbMksDlkbM cukrk gSA

23. The freezing point of a diluted milk sample is found to be –0.2°C, while it should have been –0.5°C for
pure milk. How much water has been added to pure milk to make the diluted sample ?
(1) 1 cup of water to 3 cups of pure milk
(2) 1 cup of water of 2 cups of pure milk
(3) 2 cups of water to 3 cups of pure milk
(4) 3 cups of water to 2 cups of pure milk
,d ruqd`r nqXèk izfrn'kZ dk fgekad –0.2°C ik;k x;k] tcfd fo'kq+) nqXèk dk fgekad –0.5°C gksuk pkfg,A ruqd`r
nqXèk izfrn'kZ dks cukus ds fy, fo’'kq) nqXèk esa fdruk ty feyk;k x;k gS\
(1) 3 di fo’”'kq) nqXèk esa 1 di ty
(2) 2 di fo’”'kq) nqXèk esa 1 di ty
(3) 3 di fo’”'kq) nqXèk esa 2 di ty
(4) 2 di fo’”'kq) nqXèk esa 3 di ty
Ans. (4)
Sol. Freezing point of milk = –0.5ºC  Tf = 0.5ºC
Freezing point of diluted milk = –0.2ºC  Tf = 0.2ºC
 Tf i 0.5 K f m
 
 Tf ii 0.2 k f m
Both has same amount of solute. Let that is x mole.
0.5 x mole  W2

0.2 W1  x mole
5 W2

2 W1
5
W2 = W1
2

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Sol. nqX/k dk fgekad –0.5ºC  Tf = 0.5ºC


ruq nqX/k dk fgekad = –0.2ºC  Tf = 0.2ºC
 Tf i 0.5 K f m
 
 Tf ii 0.2 k f m
nksukas esa leku ek=kk esa foy; ik;k tkrk gSA ekuk dh ;g x eksy gSA
0.5 x mole  W2

0.2 W1  x mole
5 W2

2 W1
5
W2 = W1
2

24. The major product of the following reaction is:


fuEufyf[kr vfHkfØ;k dk eq[; mRikn gS &
OH

Br2 ( vkf/kD;)
Br (excess)

2
  

SO3H
OH OH OH OH
Br Br Br Br Br
(1) (2) (3) (4)
Br Br
SO3H Br Br SO3H
Ans. (2)
OH OH
Br Br
Br
Sol.  2

excess 
SO3H Br
It is EAS activated ring.
;g EAS lfØ;r oy; gSA

25. The chloride that CANNOT get hydrolysed is :


DyksjkbM ftldk ty&vi/kVu ugha gks ldrk gS] og gS %
(1) PbCl4 (2) SiCl4 (3) CCl4 (4) SnCl4
Ans. (3)
Sol. ''C'' in CCl4 does not have vacant orbital required for hydrolysis.
ty vi?kVu ds fy, CCl4 esa ''C'' esa fjDr d{kd ugha gksrs gSaA

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26. For the chemical reaction X Y, the standard reaction Gibbs energy depends on temperature T (in
3
K) as rG°(in kJ mol–1) = 120 – T . The major component of the reaction mixture at T is :
8
(1) Y is T = 280 K (2) Y is T = 300 K (3) X if T = 315 K (4) X if T = 350 K
jklk;fud vfHkfØ;k X Y ds fy,] ekud vfHkfØ;k fxCl ÅtkZ rki (K esa) ij fuEufyf[kr dh rjg vkfJr
gksrh gS%
3
rG°(kJ mol–1 esa) = 120 – T
8
vfHkfØ;k feJ.k dk eq[; la?kVd T ij gS %
(1) Y ;fn T = 280 K (2) Y ;fn T = 300 K (3) X ;fn T = 315 K (4) X ;fn T = 350 K
Ans. (3)
3
Sol. At 315 K G° = 120 –  315
8
Gº = 1.875
Amount of Y will be greater than its equilibrium amount at 315 K.
Y dh ek=kk] bldh lkE; ek=kk ls vf/kd gSA

27. A solid having density of 9 × 103 kg m–3 forms face centred cubic crystals of edge length 200 2 pm.
What is the molar mass of the solid? [Avogadro constant  6 × 1023 mol–1,   3]
,d Bksl] ftldk ?kuRo 9 × 103 kg m–3 gS] Qyd dsfUnzr ?kuh; fØLVy cukrk gS ftlds dksj dh yEckbZ
200 2 pm gSA Bksl dk eksyj nzO;eku D;k gS \ [vokxknzks fu;rkad  6 × 1023 mol–1,   3]
(1) 0.0432 kg mol–1 (2) 0.0305 kg mol–1 (3) 0.4320 kg mol–1 (4) 0.0216 kg mol–1
Ans. (2)
ZM
Sol. d=
NA  a3
M0
4
9 × 103 = 6  1023
(200  2  10–12 )3
M0
4
9 × 103 = 3 6  1023
2  2  2  10 –30
9  103  6  1023  24  2  10–30
M0 =
4
= 9 × 6 × 10–4 × 4 × 2 = 0.03 kg

28. The concentration of dissolved oxygen (DO) in cold water can go upto:
BaMs ty esa ?kqfyr vkWDlhtu (DO) ds lkUnzrk dh Åijh lhek gks ldrh gS %
(1) 8 ppm (2) 16 ppm (3) 14 ppm (4) 10 ppm
Ans. (4)

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29. A 10 mg effervescent tablet containing sodium bicarbonate and oxalic acid releases 0.25 ml of CO 2 at
T = 298.15 K and p = 1 bar. If molar volume of CO 2 is 25.0 L under such condition, what is the
percentage of sodium bicarbonate in each tablet ?
[Molar mass of NaHCO3 = 84 g mol–1]
lksfM;e ckbdkcksZusV rFkk vkDlSfyd vEy ;qDr ,d 10 mg dk cqncqnkus okyk VScysV T = 298.15 K rFkk p = 1 bar
ij 0.25 ml CO2 mRlftZr djrk gSA ,slh n'kk esa] ;fn CO2 dk eksyj vk;ru 25.0 L gS] rks izR;sd VScysV esa
lksfM;e ckbdkcksZusV dk D;k izfr'kr gS \
[NaHCO3 dk eksyj nzO;eku = 84 g mol–1]
(1) 0.84 (2) 33.6 (3) 8.4 (4) 16.8
Ans. (3)
Sol. 2NaHCO3  H2C2O4  Na2C2O4  2CO2  2H2O
Let mass of NaHCO3 be x mg
ekuk dh NaHCO3 dk nzO;eku x mg gSA
0.25
n=  10–5
25000
w = 84  10–5 g
84  10 –5
%  100 = 8.4%
10 –2

30. Which compound(s) out of the following is/are not aromatic?


fuEufyf[kr esa ls dkSu lk@ls ;kSfxd ,sjkseSfVd ugha gS@gSa \

(A) (B) (C) (D)



 
(1) (B) (2) (B), (C) and rFkk (D)
(3) (C) & rFkk (D) (4) (A) & rFkk (C)
Ans. (2)
Sol. Neither of B, or C, nor D, follow the Huckel's rule of 4n + 2e– for aromaticity.
u rks B ;k C vkSj u gh D ,sjksesfVdrk ds fy, 4n + 2e– ds gdy fu;e dk ikyu djrsa gSA

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