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PAPER-1 (B.E./B. TECH.

JEE (Main) 2019


COMPUTER BASED TEST (CBT)
Date: 12 January, 2019 (SHIFT-2) | TIME : (2.30 p.m. to 5.30 p.m)

Duration: 3 Hours | Max. Marks: 360


SUBJECT : CHEMISTRY

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| JEE (Main) 2019 | DATE : 12-01-2019 (SHIFT-2) | CHEMISTRY

PART : CHEMISTRY

Straight Objective Type (lh/ks oLrqfu"B izdkj)


This section contains 30 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which Only One is correct.
bl [k.M esa 30 cgq&fodYih iz'u gSaA izR;sd iz'u ds 4 fodYi (1), (2), (3) rFkk (4) gSa] ftuesa ls flQZ ,d lgh gSA

1. The major product of the following reaction is :


fuEufyf[kr vfHkfØ;k dk eq[; mRikn gS %
(i) KOH alc.
CH3CH2 CH–CH2
(ii) NaNH2
Br Br in liq.NH3

(1) CH3CH=C=CH2 (2) CH3CH=CHCH2NH2

(3) CH3CH2CCH (4) CH3CH2CH–CH2


NH2 NH2
Ans. (3)
EtOH NaNH H
Sol. Br 
 Br 
2
 CH3–CH2–C C Na 
 CH3–CH2–CCH

EtO
Br

2. The major product of the following reaction is:


fuEufyf[kr vfHkfØ;k dk eq[; mRikn gS %
CH2CH3
NaOEt
H3C Cl 

COOCH2CH3
OCH2CH3 CO2CH2CH3

(1) H3C–H2C CO2CH2CH3 (2) CH3C=CHCH3

CH3
CH2CH3

(3) CH3CH2C=CH2 (4) H3C OCH2CH3

CO2CH2CH3 COOCH2CH3
Ans. (2)
CH2–CH3
CH3
EtO 
Sol. CH3 Cl  C=CH
(E2 ) EtOOC CH3
COOEt
(Cis & Trans) ¼lei{k ,oa foi{k½

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3. Among the following, the false statement is :


(1) It is possible to cause artificial rain by throwing electrified sand carrying charge opposite to the one
on clouds from an aeroplane.
(2) Lyophilic solution can be coagulated by adding an electrolyte
(3) Latex is a colloidal solution of rubber particles which are positively charged
(4) Tyndall effect can be used to distinguish between a colloidal solution and a true solution
fuEufyf[kr esa ls] vlR; dFku gS %
(1) ok;q;ku dh lgk;rk ls cknyksa ij mifLFkr vkos'k ls foijhr vkosf'kr jsr ds d.kksa dks Qsad dj d`f=ke o’"kkZ
djokuk lEHko gSA
(2) nzojkxh] lkWy dk LdUnu ,d fo|qr vi?kV; feykdj fd;k tk ldrk gSA
(3) ysVsDl] jcj ds d.kksa dk ,d dksykWbMh foy;u gS] tks /kukosf'kr gksrs gSaA
(4) fVUMy izHkko dk mi;ksx ,d dksykWbMh foy;u rFkk okLrfod foy;u esa vUrj djus ds fy, fd;k tk ldrk
gSA
Ans. (3)
Sol. Theory based lS)kfUrd

4. An open vessel at 27°C is heated until two fifth of the air (assumed as an ideal gas) in it has escaped
from the vessel. Assuming that the volume of the vessel remains constant, the temperature at which the
vessel has been heated is:
27°C ij fLFkr ,d [kqys ik=k dks rc rd xeZ fd;k tkrk gS tc rd blesa mifLFkr ok;q (vkn'kZ xSl ekurs gq,) ds
nks ik¡posa Hkkx (2/5) ik=k ls fudy ugha tkrkA ;g ekudj fd ik=k dk vk;ru fLFkj gS] rki ftl ij ik=k dks xeZ
fd;k x;k gS] og gS %
(1) 750 K (2) 750°C (3) 500 ºC (4) 500 K
Ans. (4)
Sol. n1T1 = n2T2
 2n 
 n × 300 =  n –  T2
 5 
3
 300 = T2
5
 T2 = 500 K

5. Chlorine on reaction with hot and concentrated sodium hydroxide gives:


(1) ClO3– and ClO2– (2) Cl– and ClO– (3) Cl– and ClO3– (4) Cl– and ClO2–
xeZ rFkk lkUnz lksfM;e gkbMªkWDlkbM ds Dyksjhu dh vfHkfØ;k nsrh gS %
(1) ClO3– rFkk ClO2– (2) Cl– rFkk ClO– (3) Cl– rFkk ClO3– (4) Cl– rFkk ClO2–
Ans. (3)
Sol. NaOH + Cl2  NaCl + NaClO3
Hot & conc. xeZ rFkk lkUnz

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6. If Ksp of Ag2CO3 is 8 × 10–12, the molar solubility of Ag2CO3 in 0.1 M AgNO3 is :


;fn Ag2CO3 dk Ksp 8 × 10–12 gS] rks Ag2CO3 dh 0.1 M AgNO3 esa eksyj foys;rk gS %
(1) 8 × 10–10
M (2) 8 × 10–12 M (3) 8 × 10–13 M (4) 8 × 10–11 M
Ans. (1)
Sol. 8 × 10–12 = (2S' + 0.1)2S'
or S' = 8 × 10–10 M

7. Given :
(i) C(graphite) + O2(g)  CO2(g); rH– = xkJ mol–1
1
(ii) C(graphite) + O2(g)  CO2(g); rH– = ykJ mol–1
2
1
(iii) CO(g) + O2(g)  CO2(g); rH– = zkJ mol–1
2
Based on the above thermochemical equations, find out which one of the following algebraic
relationship is correct?
fn;k x;k gS %
(i) C(xzsQkbV) + O2(g)  CO2(g); rH– = xkJ mol–1
1
(ii) C(xzsQkbV) + O2(g)  CO2(g); rH– = ykJ mol–1
2
1
(iii) CO(g) + O2(g)  CO2(g); rH– = zkJ mol–1
2
mi;qZDr Å’"ekjklk;fud lehdj.kksa ds vk/kkj ij crkb;s fd uhps fn, x;s chtxf.krh; laca/kksa esa ls dkSulk lgh gS \
(1) x = y – z (2) y = 2z – x (3) x = y + z (4) z = x + y
Ans. (3)
Sol. Bonus can be claimed because question is incorrect due to misprint in second reaction ie CO 2 in palce
of CO(g).
cksul vad dk nkok dj ldrs gS D;ksafd f}rh; vfHkfØ;k esa CO(g) ds LFkku ij CO2 dh xyr NikbZ ds dkj.k iz'u
xyr gSA
8. The major product of the following reaction is:
fuEufyf[kr vfHkfØ;k dk eq[; mRikn gS %
H3C O (i) NaNO2/H
NH2
O (ii) CrO3/H
(iii) H2SO4(Conc.),
HO O
(1) (2) CH3 O
O O

O
CH3 O
(3) (4) O
O
O
Ans. (1)

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O
O
O O
O
Sol. O
(1) NaNO2/H
NH2 CrO3/H
OH
OH

O
OH

H

9. The pair that does NOT require calcination is :


(1) ZnO and MgO (2) ZnCO3 and CaO
(3) Fe2O3 and CaCO3.MgCO3 (4) ZnO and Fe2O3.xH2O
;qXe ftlds fy, fuLrkiu dh vko';drk ugha gksrh gS] og gS %
(1) ZnO rFkk MgO (2) ZnCO3 rFkk CaO
(3) Fe2O3 rFkk CaCO3.MgCO3 (4) ZnO rFkk Fe2O3.xH2O
Ans. (1)
Sol. Calcination is required for hydroxide, carbonate and hydrated oxide ores.
fuLrkiu gkbMªkWDlkbM] dkcksZusV rFkk ty;ksftr vkWDlkbM v;Ldks ds fy, vko';d gSA

10. The major product of the following reaction is :


fuEufyf[kr vfHkfØ;k dk eq[; mRikn gS %
O

NaBH

4

EtOH

O O OH OH

(1) (2) (3) (4)

OEt OEt
Ans. (3)
O OH

NaBH
Sol. 
4

EtOH

NaBH4 does not reduce C=C

C=C dks NaBH4 vipf;r ugha djrk gSA

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11. The major product of the following reaction is:


fuEufyf[kr vfHkfØ;k dk eq[; mRikn gS %
H3C
HCl
CH2  

H
H3C CH2–Cl CH3
CH3
(1) (2)
H H
Cl
H3C CH3
CH2–Cl
(3) CH3 (4) Cl
H H
Ans. (4)
H3C CH3
CH3 CH3
HCl
Sol. C=CH2 
 C–CH3  Cl

H

12. Molecules of benzoic acid (C6H5COOH) dimerise in benzene. ‘w’ g of the acid dissolved in 30 g of
benzene shows a depression in freezing point equal to 2 K. If the percentage association of the acid to
form dimer in the solution is 80, then w is :
(Given that Kf = 5 kg mol–1, Molar mass of benzoic acid = 122 g mol–1)
csUtksbd vEy (C6H5COOH) ds v.kq csUthu esa f}rf;d gksrs gSaA 30 g csUthu esa ?kqfyr ‘w’ g vEy 2 K ds cjkcj
fgekad esa voueu iznf'kZr djrk gSA ;fn foy;u esa vEy ds laxq.ku dk izfr'kr 80 gS rks w dk eku gS %
(fn;k x;k gS] Kf = 5 kg mol–1, csUtksbd ,flM dk eksyj nzO;eku = 122 g mol–1)
(1) 2.4 g (2) 1.8 g (3) 1.0 g (4) 1.5 g
Ans. (1)
Sol. 2A – (A)2
1 –
0.8
1–0.8
2
Tf = Kf × i × m
w 1000
2 = 5 × 0.6 × ×  w = 2.44 g
122 30

13. 8 g of NaOH is dissolved in 18 g of H2O. Mole fraction of NaOH in solution and molality (in mol kg –1) of
the solution respectively are :
8 g NaOH dks 18 g H2O esa ?kksyk x;k gSA foy;u esa NaOH dk eksyka'k rFkk foy;u dh eksykfyVh (eksy izfr
fdyksxzke) Øe'k% gS %
(1) 0.2, 11.11 (2) 0.167, 11.11 (3) 0.167, 22.20 (4) 0.2, 22.20

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Ans. (2)
8
Sol. n1 =  0.2
40
18
n2 = 1
18
0.2
mole fraction of NaOH =  0.167
1.2
0.2
NaOH dk eksy izHkkt =  0.167
1.2
8 1000
molality eksyyrk =   11.11
40 18


14. m for NaCl, HCl and NaA are 126.4, 425.9 and 100.5 S cm 2mol–1, respectively. If the conductivity of
0.001 M HA is 5 × 10–5 S cm–1, degree of dissociation of HA is:

NaCl, HCl rFkk NaA ds fy, m Øe'k% 126.4, 425.9 rFkk 100.5 S cm2mol–1 gSaA ;fn 0.001 M HA dh
pkydrk 5 × 10–5 S cm–1 gks rks HA dh fo;kstu ek=kk gS %
(1) 0.125 (2) 0.50 (3) 0.75 (4) 0.25
Ans. (1)
Sol. °m(HA) = °m(HCl) + °m(NaA) – °(NaCl)
= 425.9 + 100.5 – 126.4
= 400
 K  1000 5  10 –5  103
m   = 50
M 10 –3
50
  0.125
400

15. The volume strength of 1M H2O is: (Molar mass of H2O2 = 34 g mol–1)
1M H2O dk vk;ru lkeF;Z gS (H2O2 dk eksyj nzO;eku = 34 xzk- eksy–1)
(1) 11.35 (2) 22.4 (3) 16. 8 (4) 5.6
Ans. (1)
Sol. Volume strength vk;ru lkeF;Z = 11.35 × M = 11.35 (STP)

16. The correct order of atomic radii is :


ijek.kq f=kT;kvksa dk lgh Øe gS %
(1) Eu > Ce > Ho > N (2) N > Ce > Eu > Ho (3) Ce > Eu > Ho > N (4) Ho > N > Eu > Ce
Ans. (1)
Sol.
Element Eu Ce Ho N
Atomic radius (in pm) 199 183 176 70

17. The element that shows greater ability to form p-p multiple bonds, is:
p-p cgqca/k cukus dh izcy ;ksX;rk j[kus okyk rRo gS %
(1) Ge (2) Sn (3) C (4) Si
Ans. (3)
Sol. C form most stable p-p bonds.
C lokZf/kd LFkk;h p-pcU/k cukrk gSA

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18. The compound that is NOT a common component of photochemical smog is:
izdk'k jklk;fud /kwedqgk dk tks lkekU; la?kVd ugha gS] og ;kSfxd gS %
(1) H3C–C–OONO2 (2) O3 (3) CF2Cl2 (4) CH2=CHCHO
O
Ans. (3)
Sol. Fact rF;kRed

19. The two monomers for the synthesis of Nylon-6, 6 are:


(1) HOOC(CH2)4COOH & H2N–(CH2)6–NH2 (2) HOOC(CH2)6COOH & H2N(CH2)4NH2
(3) HOOC(CH2)6COOH & H2N(CH2)6 NH2 (4) HOOC(CH2)4COOH, H2N–(CH2)4NH2
Ans. (1)
Sol. It is Fact ;g rF; gSA

20. The correct structure of histidine in a strongly acidic solution (pH = 2) is:
,d lkUnz vEyh; foy;u (pH = 2) esa] fgLVhMhu dh lgh lajpuk gS %

H3N–CH–COOH 
H3N–CH–COOH
(1) NH (2) 
NH2

N 
H N
 

H3N–CH–COO

H3N–CH–COO

NH2
(3) (4)
NH2
N 
N H
Ans. (1)
Sol. Only the basic "N" get pronated.
dsoy {kkjh; "N" dk izksVksuhdj.k gksrk gSA

21. If the de Broglie wavelength of the electron in nth Bohr orbit in a hydrogenic atom is equal to 1.5 a0
(a0 is Bohr radius), then the value of n/z is:
;fn ,d gkbMªkstu ijek.kq esa] nosa (nth) cksj d{kd esa fLFkr bysDVªkWu dk ns czkXyh rjaxnS/;Z 1.5 a0 ds cjkcj gS] rks
n/z dk eku gS % (a0 cksj f=kT;k gS)
(1) 0.75 (2) 0.40 (3) 1.0 (4) 1. 50
Ans. (1)
Sol. 2r = n
n2
 2a0  n
Z
n2
2a0  n1.5 a0
Z
n 1.5 3
  = 0.75
Z 2 4

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22. The correct statement(s) among, I to III with respect to potassium ions that are abundant within the cell
fluids is/are:
I. They activate many enzymes.
II. They participate in the oxidation of glucose to produce ATP
III. Along with sodium ions, they are responsible for the transmission of nerve signals
(1) I and III only (2) III only (3) I and II only (4) I, II and III
dksf'”kdk rjy esa ckgqY; :i esa ik;s tkus okys iksVsf'k;e vk;uksa ds laca/k esa I ls III esa ls lgh dFku gS@gSa\
I. os dbZ ,atkbeksa dks lfØ; djrs gSaA
II. os Xywdksl ds vkDlhdj.k }kjk ATP ds cukus esa Hkkxhnkjh djrs gSaA
III. lksfM;e vk;u ds lkFk] raf=kdkvksa ds ladsrksa ds lapj.k ds fy, ftEesnkj gksrs gS\
(1) dsoy I rFkk III (2) dsoy III (3) dsoy I rFkk II (4) I, II rFkk III
Ans. (4)
Sol. Fact rF;A

23. The upper stratosphere consisting of the ozone layer protects us from the sun’s radiation that falls in
the wavelength region of :
Åijh lerkieaMy ftlesa mifLFkr vkstksu ijr gesa lw;Z ds fofdj.k ls cpkrh gS] mldk rjaxnS/;Z {ks=k gS %
(1) 0.8 – 1.5 nm (2) 400 – 550 nm (3) 200 – 315 nm (4) 600 – 750 nm
Ans. (3)
Sol. Fact rF;A

24. The element that does NOT show catenation is:


J`a[kyu ugha iznf'kZr djus okyk gS %
(1) Sn (2) Si (3) Ge (4) Pb
Ans. (4)
Sol. Concentration tendency order lkUnzrk izo`fr Øe: C >> Si > Ge ~ Sn > Pb

25. The combination of plots which does not represents isothermal expansion of an ideal gas is:

P
P
(A) (B)

O 1/Vm O
Vm

PVm
(C) (D) U

O O
P Vm
(1) (B) and (C) (2) (A) and (C) (3) (A) and (D) (4) (B) and (D)

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,d vkn'kZ xSl ds lerkih; izlj.k dks ugha fu:fir djus okys IykVksa dk la;kstu gS %

P
P
(A) (B)

O 1/Vm O
Vm

PVm
(C) (D) U

O O
P Vm
(1) (B) rFkk (C) (2) (A) rFkk (C) (3) (A) rFkk (D) (4) (B) rFkk (D)
Ans. (4)

26. The increasing order of the reactivity of the following with LiAlH 4 is:
fuEufyf[kr dh LiAlH4 ds lkFk vfHkfØ;k'khyrk dk c<+rk Øe gS %
O O
(A) (B)
C2H5 NH2 C2H5 OCH3
O O O
(C) (D)
C2H5 Cl C2H5 O C2H5
(1) (A) < (B) < (C) < (D) (2) (A) < (B) < (D) < (C)
(3) (B) < (A) < (D) < (C) (4) (B) < (A) < (C) < (D)
Ans. (2)
O

Sol. —C—NH2 will do acid base reaction with Grignard reagent.


O

—C—NH2 lewg fxzxukMZ vfHkdeZd ds lkFk vEy {kkj vfHkfØ;k nsxkA


O O O
O
C C C—OEt
R—C—Cl > O CH3
>
(SNAC)

Rate is dependent on + on carbon of C=O group.

vfHkfØ;’k dh nj C=O lewg ds dkcZu ij + ij fuHkZj djrh gSA

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27. For a reaction, consider the plot of ln k versus 1/T given in the figure. If the rate constant of this reaction
at 400 K is 10–5 s–1, then the rate constant at 500 K is:
,d vfHkfØ;k ds fy, fn;s x;s fp=k esas ln k vs 1/T ds IykV ij fopkj dhft,A ;fn bl vfHkfØ;k dk nj fu;rkad
400 K ij 10–5 s–1 gS] rks 500 K ij mldk nj fu;rkad gS %

nk
Slope = –4606 K

1/T
(1) 10–4 s–1 (2) 4 × 10–4 s–1 (3) 2 × 10–4 s–1 (4) 10–6 s–1
Ans. (1)
Ea 4606  E A 
Sol. nk = nA –  nA –  R  4606 
RT T  
 k   E  500 – 400
n  –5    a  
 10   R  500  400
 k  1
n  –5   4606   2.303
 10  2000
 k 
n  –5   n10
 10 
k  10–4 s–1

28. The aldehydes which will not form Grignard product with the equivalent Grignard reagents are:
,d lerqY; fxzxukMZ vfHkfØ;k ds lkFk fxzxukMZ mRikn ugha nsus okys ,sfYMgkbM gSa %
CHO CHO CHO CHO

(A) (B) (C) (D)


HO2C H3CO HOH2C
(1) (B), (D) (2) (B), (C) (3) (C), (D) (4) (B), (C), (D)
Ans. (1)
Sol. B and D gives acid-base reaction with Grignard reagent.
B rFkk D fxzxukMZ vfHkdeZd ds lkFk vEy {kkj vfHkfØ;k nsrk gSA

29. The magnetic moment of an octahedral homoleptic Mn(II) complex is 5.9 BM. The suitable ligand for
this complex is:
(1) Ethylenediamine (2) CN– (3) NCS– (4) CO
,d v"VQyd gkseksysfIVd Mn(II) ds ladqy dk pqEcdh; vk?kw.kZ 5.9 BM gSA bl ladqy ds fy, mi;qDr layXuh gS %
(1) Ethylenediamine (2) CN– (3) NCS– (4) CO
Ans. (3)

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| JEE (Main) 2019 | DATE : 12-01-2019 (SHIFT-2) | CHEMISTRY

30. The major product in the following conversion is:


fuEufyf[kr :ikUrj.k esa lgh mRikn gS %
HBr (excess)
CH3O CH–CH–CH3 ?
Heat

(1) HO CH–CH2–CH3 (2) CH3O CH–CH2–CH3


Br Br

(3) CH3O CH2–CH–CH3 (4) HO CH2–CH–CH3


Br Br
Ans. (1)
HBr excess
Sol. CH3O CH=CH–CH3   HO CH–CH2–CH3
Heat

Br

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