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Answer keys : Online Mock Test Series for NSEC-2018-19_Test-02

You scored -1 of 3
Question : 1

In a given sequence of reaction.

(CD3)3C⊕ + (CH3)3CH (CH3)3C⊕ + (CD3)3CH

K298 = 1.97

Where K298 equilibrium constant at 298 K temperature

Which of the following is correct statements?

Options:

(CH3)3C⊕ is more stable than (CD3)3C⊕

(CD3)3C⊕ is more stable than (CH3)3C⊕

(CH3)3C⊕ have same stability as (CD3)3C⊕

Number of hyperconjugating structure of (CH3)3 is different from ⊕C(CD3)3

Solution :

Answer (1)

Stability of (CH3)3C⊕ can be explained by the polar effect and by better hyperconjugation.
You scored 3 of 3
Question : 2

In the given compound

The correct order of stability of carbocation in

Options:

I > II > III

II > I > III

III > II > I

III > I > II

Solution :

Answer (3)

In cyclopropylmethyl carbocation vacant P orbital lie parallel to C2 – C3 of cyclopropane ring.

You scored 0 of 3
Question : 3 (skipped)

Which of following product is formed when aqueous solutions of Na2S2O3 on reaction with Cl2 gives?

Options:

Na2S4O6

NaHSO4

NaOH

NaCl

Solution :

Answer (2)

Na2S2O3 + 4Cl2 + 5H2O 2NaHSO4 + 8HCl


You scored -1 of 3
Question : 4

Statement-I : For every chemical reaction at equilibrium standard Gibbs free energy of reaction is zero.

Statement-II : At constant temperature and pressure, chemical reactions are spontaneous in the direction of decreasing Gibbs
free energy.

Options:

Statement-I is true, statement-II is correct explanation for statement-I

Statement-I is true, statement-II is true statement-II is not a correct explanation for statement-I

Statement-I is true, statement-II is false

Statement-I is false, Statement-II is true

Solution :

Answer (4)

At equilibrium ΔG = 0, ΔG° of a reaction may or may not be zero.

For a spontaneous process ΔG < 0

You scored 0 of 3
Question : 5 (skipped)

Statement-I : Pb4+ compounds are stronger oxidizing agents than Sn4+ compounds.

Statement-II : The higher oxidation state for the group 14 elements are more stable for the heavier members of the group due to
'inert pair effect'.

Options:

Statement-I is true, statement-II is true, Statement-II is correct explanation for statement-I

Statement-I is true, statement-II is true statement-II is not a correct explanation for statement-I

Statement-I is true, statement-II is false

Statement-I is false, Statement-II is true

Solution :

Answer (3)

The lower oxidation states for the group 14 elements are more stable for the heavier member of the group due to inert pain effect.
You scored 3 of 3
Question : 6

Which of following compound have linear geometry.

Options:

XeF4

SF4

Solution :

Answer (4)

Based on VSEPR theory

You scored 3 of 3
Question : 7

The methods chiefly used for the extraction of lead and tin from their ores are respectively.

Options:

Self reduction and carbon reduction

Self reduction and electrolytic reduction

Carbon reduction and self reduction

Cyanide process and carbon reduction

Solution :

Answer (1)

Fact based.
You scored -1 of 3
Question : 8

On heating (NH4)2Cr2O7 gives a gas, which is also given by.

Options:

Mg3N2 + H2O

Na + H2O2

Heating NH4NO3

Heating NH4NO2

Solution :

Answer (4)

(NH4)2Cr2O7 N2 + Cr2O3 + 4H2O

NH4NO2 N2 + 2 H2O

You scored -1 of 3
Question : 9

Spin magnetic moment of the compound Hg[Co(SCN)4] is

Options:

Solution :

Answer (2)

Hg[Co(SCN)4]

Co ⇒ [Ar]3d7 4s2

Co ⇒ [Ar]3d7 4s°

n=3
You scored 0 of 3
Question : 10 (skipped)

The sodium salt of an unknown anion when treated with MgCl2 gives white precipitate only on boiling. The anion is.

Options:

SO4–

NO3–

HCO3–

CO32–

Solution :

Answer (3)

MgCl2 + 2NaHCO3 + 2NaCl

Mg (HCO3)2 + H2O + CO2

You scored -1 of 3
Question : 11

Number of lone pair on central atom of compound I and II are.

Options:

3 and 1

1 and 3

2 and 1

1 and 2

Solution :

Answer (1)
You scored 0 of 3
Question : 12 (skipped)

In the given reaction sequence, the end product (D) is.

Options:

Solution :

Answer (1)
You scored 0 of 3
Question : 13 (skipped)

For a monatomic gas kinetic energy = E, the relation with root mean square (RMS) velocity is.

U RMS velocity and M Molecular weight of gas

Options:

Solution :

Answer (3)

2KE = 3KT
You scored 3 of 3
Question : 14

Which of following is not correctly matched.

(1) Siderite FeCO3


(2) Malachite CuCO3 × Cu(OH)2
(3) Calamine Ag2S
(4) Philosopher's wool ZnO
Options:

(1)

(2)

(3)

(4)

Solution :

Answer (3)

Factual.

You scored 3 of 3
Question : 15

Number of sp3 hybridised atoms are present in one molecule of CuSO4 · 5H2O is.

Options:

Solution :

Answer (4)
You scored -1 of 3
Question : 16

The coordination number of Fe in [Fe(η5 – C5H5)2 is X, then value of X is.

Options:

10

12

Solution :

Answer (3)
You scored 0 of 3
Question : 17 (skipped)

In the given reactions

Product formed is

Options:

Solution :

Answer (3)

Benzoin condensation.
You scored 0 of 3
Question : 18 (skipped)

Carbylamine reaction is given by which of following compound

Options:

I, II and IV

I, II, III and IV

Only I and II

Only I

Solution :

Answer (1)

Test of 1° amine

R – NH2 + CHCl3 + alc.KOH R – NC + KCl + H2O

1° amine Isocyanide
You scored 3 of 3
Question : 19

In the given reaction sequence

C is :-

Options:

Solution :

Answer (3)
You scored 3 of 3
Question : 20

Which of the following is not correctly matched; (catalyst name with its molecular formula)

Options:

Zeigler Natta catalyst TiCl3 + (C2H5)3Al

Wilkinson's catalyst [Ph3P]3 RhCl

Lindlar's catalyst Na;Liq NH3

Adam's catalyst Pt/PtO used for reduction

Solution :

Answer (3)

Lindlars catalyst is : H2; Pd, BaSO4 in quinoline

You scored 0 of 3
Question : 21 (skipped)

The preferred protonation site in the given compounds are.

Options:

X and X

X and Y

Y and Y

Y and X

Solution :

Answer (1)

Due to resonance structure [X] site have high

electron density.
You scored 3 of 3
Question : 22

In the given reaction sequence.

In this nitration experiment if 20 gm of benzene produces 26.4 gm of nitrobenzene. Then yield % is.

Options:

83.5%

43.5%

90%

75%

Solution :

Answer (1)

78 gm of benzene produces 123 gm of nitro

20 ––––––––

% yield =
You scored -1 of 3
Question : 23

In the following oxyacid of phosphorus

H3PO2 H3PO3 H4P2O6


(I) (II) (III)

Oxidation state of P-atom in I, II, III are respectively.

Options:

+1 , +3 , +4

+1, +1, +3

+1, +4, +3

+1, +4, +4

Solution :

Answer (1)

You scored 3 of 3
Question : 24

Which of following is not correctly matched?

Options:

SO2 Acidic oxide

MgO Basic oxide

Al2O3 Amphoteric oxide

CO Basic oxide

Solution :

Answer (4)

CO is neutral oxide.
You scored 3 of 3
Question : 25

In peroxodisulfuric acid and Caro's acid oxidation state of sulphur atom is.

Options:

+5 and +5

+5 and +6

+6 and +6

+1 and +1

Solution :

Answer (3)

Caro's acid; H2SO5

Peroxo disulphuric acid H2S2O8

You scored 0 of 3
Question : 26 (skipped)

In a given sequence of reaction

Na2S2O3 × 5H2O A [X] + NaNO3 X is

Options:

Ag2S

AgNO3

Ag2S2O3

NO

Solution :

Answer (3)

Na2S2O3 + 2AgNO3 Ag2S2O3↓

Silver thiosulphate (White ppt)


You scored 3 of 3
Question : 27

In fcc arrangement, the corner atoms are A type and those at the face centres are B type. The simplest formula of the
compound is.

Options:

AB

AB2

AB3

AB4

Solution :

Answer (3)

Factual

You scored 3 of 3
Question : 28

Which of following is not correctly matched (type of lattice vs number of atoms in unit cell)?

  Type of lattice Number of atoms in the unit cell


(1) Primitive 1
(2) Face centered 4
(3) Body centered 2
(4) Edge centered 2

Options:

(1)

(2)

(3)

(4)

Solution :

Answer (4)

In edge centered ; number of atom in a unit cell = 4


You scored 3 of 3
Question : 29

Silver crystallizes in the cubic lattice. The density is found to be 10.7g cm–3. If the unit cell length is 0.406 nm, then number of
atom per unit cell is.

Options:

Solution :

Answer (4)

Density =

z=4

You scored 0 of 3
Question : 30 (skipped)

An aqueous solution contains 2.0 × 10–2 kg of glucose per dm3. Assuming the solution to be ideal its osmotic pressure at 298K
is.

Options:

5 atm

5.7 atm

2.7 atm

10 atm s

Solution :

Answer (3)

= icRT

= cRT
You scored 3 of 3
Question : 31

A 5.13% solution of cane sugar is isotonic with a 0.9% solution of an unknown solute. The molar mass of solute is.

Options:

40

50

60

70

Solution :

Answer (3)

W = 5.13 g, M = 342 g/mol–1 and V = 0.1 dm3

For unknown solute

W = 0.9 g, M = ? and V = 0.1 dm3

Since solution are isotonic


You scored 3 of 3
Question : 32

In a cell containing a solution of silvernitrate, a certain amount of current was passed for 3 hours. The amount of silver
deposited was found to be 60.8 g. The current strength is.

Options:

5.036 ampere

10.072 ampere

1.015 ampere

15.036 ampere

Solution :

Answer (1)

W = ItZ

= 5.036 ampere

You scored 3 of 3
Question : 33

Hybridisation of Cl and I in ClOF3 and IOF4+ are

Options:

sp3 and sp3d

sp3d and sp3d

sp3d2 and sp3d

sp3d and sp3

Solution :

Answer (2)
You scored 3 of 3
Question : 34

Which of following statement is not correct about I and II?

Options:

Melting point of maleic acid is greater than fumaric acid

Melting point of fumaric acid is greater than maleic acid

Ka(I) of maleic acid is greater than Ka(I) of fumaric acid

Maleic acid is more soluble in water than fumaric acid

Solution :

Answer (1)
You scored 3 of 3
Question : 35

Which of following is correct regarding A and B

Options:

A contain more acidic hydrogen than B

B contain more acidic hydrogen than A

Both A and B contain same acidic strength hydrogen

A and B are isomers

Solution :

Answer (2)
You scored 3 of 3
Question : 36

Which of following is not true about following conversion?

Options:

Dehydration

Nucleophilic addition

Carbanion as intermediate is formed

Nucleophilic substitution reaction

Solution :

Answer (4)

Factual

You scored -1 of 3
Question : 37

Among the following, the intensive property is/are

Options:

Electromotive force

Resistance

Heat capacity

Volume

Solution :

Answer (1)

EMF is not mass dependent.


You scored 3 of 3
Question : 38

Product formed in this reaction is.

Options:

Solution :

Answer (3)

Oxidation reaction at benzylic (C – H).


You scored 3 of 3
Question : 39

Arrange the increasing order of bond order in the following compound.

O2, O2+, O22–

Options:

O2 < O2+ < O22–

O22– < O2 < O2+

O22– < O2+ < O2

O2+ < O22– < O2

Solution :

Answer (2)

Bond order

O22– (18e–) O2(16e–) O2+ (15e–)


1 2 2.5

You scored 3 of 3
Question : 40

Number of radial node and angular node of 5P are respectively.

Options:

1 and 1

3 and 1

4 and 2

2 and 1

Solution :

Answer (2)

Number of radial node:- n – l – 1

Number of angular node: l

Where n = principal quantum number

l = Azimuthal quantum number


You scored 3 of 3
Question : 41

Which element is not found in common amino acids?

Options:

Hydrogen

Nitrogen

Oxygen

Phosphorus

Solution :
Answer (4)

You scored 3 of 3
Question : 42

Which of the following is not classified as a carbohydrate?

Options:

Glucose

Glycine

Lactose

Starch

Solution :

Answer (2)

Glucose, lactose and starch are carbohydrates

You scored 3 of 3
Question : 43

Oxygen gas can be produced by the decomposition of all of the following substances, except

Options:

Calcium oxide

Hydrogen peroxide

Mercury(II) oxide

Ozone

Solution :
Answer (1)
You scored 3 of 3
Question : 44

A sample of gas occupies a volume of 9.23 L at 345 K and 1.40 atm. What is its volume at 525 K and 3.20 atm?

Options:

2.65 L

6.14 L

13.9 L

32.1 L

Solution :
Answer (2)

You scored -1 of 3
Question : 45

Which substance has the strongest London dispersion forces?

Options:

H2O

H2S

H2Se

H2Te

Solution :
Answer (4)
You scored -1 of 3
Question : 46

When the substances KCl, CH3OH and C2H6 are arranged in order of increasing melting point, what is the correct order?

Options:

KCl, CH3OH, C2H6

CH3OH, C2H6, KCl

KCl, C2H6, CH3OH

C2H6, CH3OH, KCl

Solution :

Answer (4)

KCl being ionic has maximum melting point.

You scored -1 of 3
Question : 47

The energies of the bonds broken in a certain reaction are greater than the energies of the bonds formed. Which one of the
following statements about this reaction must be true?

Options:

The reaction is endothermic

The reaction is exothermic

The reaction is spontaneous

The reaction is non-spontaneous

Solution :
Answer (1)
You scored 3 of 3
Question : 48

What is the standard enthalpy of formation of ethylene, C2H4, if its standard enthalpy of combustion is –1411 kJ . mol–1?

Options:

1411 kJ . mol–1

51 kJ . mol–1

–337 kJ . mol–1

–445 kJ . mol–1

Solution :
Answer (2)

You scored -1 of 3
Question : 49

Which of the following is not aromatic?

Options:

Solution :
Answer (1)
You scored 3 of 3
Question : 50

"A perfect crystalline substance has an entropy of zero at absolute zero" is a statement of

Options:

Hess's law

The first law of thermodynamics

The second law of thermodynamics

The third law of thermodynamics

Solution :
Answer (4)

You scored 3 of 3
Question : 51

Which one of the following sets of conditions would result in a reaction that is spontaneous at high temperatures but non-
spontaneous at low temperatures?

Options:

ΔH > 0, ΔS > 0

ΔH > 0, ΔS < 0

ΔH < 0, ΔS < 0

ΔH < 0, ΔS > 0

Solution :
Answer (1)
You scored -1 of 3
Question : 52

Change in which factors affect both the rate and the rate constant of a first order reaction?

I. Temperature

II. Concentration

Options:

I only

II only

Both I and II

Neither I nor II

Solution :
Answer (1)

You scored 3 of 3
Question : 53

Consider the hypothetical reaction :

A + 2B C

The rate remains constant when the concentration of A is doubled and the concentration of B is held constant. The reaction rate
doubles when the concentration of B is doubled and the concentration of A is held constant. What are the order of A and B in
this reaction?

Options:

A = 0, B = 1

A = 0, B = 2

A = 1, B = 2

A = 1, B = 0

Solution :
Answer (1)
You scored 3 of 3
Question : 54

Which statement is true about a reactant that appears in the balanced equation for a reaction but does not appear in the rate
equation?

Options:

It is an inhibitor

It is not part of the reaction

Its concentration is too low to be important

It may take part in the reaction after the rate determining step

Solution :
Answer (4)

You scored 3 of 3
Question : 55

Introduction of two drops of concentrated sulfuric acid H2SO4, speeds up an esterification reaction. Introduction of a piece of
platinum metal, Pt, speeds up the reaction of H2 and O2 gas. Which of the following statement is true?

Options:

Pt is a homogeneous catalyst; H2SO4 is a heterogeneous catalyst

Pt is a heterogeneous catalyst; H2SO4 is a homogeneous catalyst

Pt and H2SO4 are both heterogeneous catalysts

Pt and H2SO4 are both homogeneous catalysts

Solution :
Answer (2)

You scored 3 of 3
Question : 56

Which change will decrease the rate of the reaction between I2(s) and H2(g)?

Options:

Increasing the partial pressure of H2(g)

Adding the I2(s) as one piece rather than as several small ones

Heating the reaction mixture

Adding a catalyst for the reaction

Solution :
Answer (2)
You scored 3 of 3
Question : 57

For the equilibrium system

CO(g) + 2H2(g) CH3OH(l) What is KC?

Options:

Solution :
Answer (4)

You scored -1 of 3
Question : 58

Consider the system at equilibrium

2SO2(g) + O2(g) 2SO3(g), ΔH < 0

Which change(s) will increase the yield of SO3(g)?

I. Increasing the temperature.

II. Increasing the volume of the container.

Options:

I only

II only

Both I and II

Neither I nor II

Solution :
Answer (4)
You scored -1 of 3
Question : 59

CH3CH2CH2CH2 CONH2 .

Product X is

Options:

CH3CH2CH2CH2 COBr

CH3CH2CH2CH2 CH2NH2

CH3CH2CH2CH2 COOH

CH3CH2CH2CH2 NH2

Solution :
Answer (4)

You scored -1 of 3
Question : 60

Which one of the following mixtures creates a buffer solution?

Options:

10.0 mL 0.10 M NaOH, 10.0 mL 0.10 M HF

20.0 mL 0.10 M NaOH, 15.0 mL 0.10 M HF

15.0 mL 0.10 M NaOH, 20.0 mL 0.10 M HF

10.0 mL 0.10 M NaOH, 5.0 mL 0.20 M HF

Solution :
Answer (3)
You scored 0 of 3
Question : 61 (skipped)

The solubility of AgBrO3 in aqueous solution depends on the presence of other substances in solution. Relative to its solubility
in H2O the solubility of AgBrO3 is higher in 0.10 M ______ and lower in 0.10 M ______.

Options:

NH3, KBrO3

KBrO3, NH3

HNO3, NH3

NH3, HNO3

Solution :

Answer (1)

Presence of common ion decreases solubility.

You scored 3 of 3
Question : 62

Which of the following is most basic in benzene?

Options:

CH3NH2

(CH3)3N

(C2H5)2NH

C6H5NH2

Solution :
Answer (2)
You scored -1 of 3
Question : 63

All of the reactions below represent oxidation-reduction processes except the

Options:

Combustion of tin in chlorine gas

Decomposition of potassium chlorate

Neutralization of sodium hydroxide

Reaction of magnesium with hydrochloric acid

Solution :
Answer (3)

You scored -1 of 3
Question : 64

Which expression gives the correct value for the standard potential for a gold-rhodium voltaic cell?

Options:

1.69 + 0.76

1.69 – 0.76

3(1.69) + 0.76

3(1.69) – 0.76

Solution :
Answer (2)
You scored 0 of 3
Question : 65 (skipped)

When potassium permanganate, KMnO4, is added to an acidified solution of oxalic acid, H2C2O4, the products are CO2 gas and

Mn2+ ions. What is the reducing agent in this reaction?

Options:

KMnO4

H2C2O4

H3O+

CO2

Solution :
Answer (2)

You scored -1 of 3
Question : 66

Consider a voltaic cell in which the reaction below occurs in two half-cells connected by a salt bridge and an external circuit.

2Cr(s) + 3Sn2+(aq) 3Sn(s) + 2Cr3+(aq), E° = 0.603 V

Which change will cause the voltage to increase?

Options:

Increasing the amount of Sn(s) in its half-cell

Increasing the amount of Cr(s) in its half-cell

Diluting the solution in the anode compartment

Diluting the solution in the cathode compartment

Solution :
Answer (3)
You scored 3 of 3
Question : 67

How long must a current of 4.00 A be applied to a solution of Cu2+(aq) to produce 2.0 grams of copper metal?

Options:

2.4 × 104 s

1.5 × 103 s

7.6 × 102 s

3.8 × 102 s

Solution :
Answer (2)

You scored 3 of 3
Question : 68

Which element has atoms with exactly four valence electrons in its ground state?

Options:

Ca

Cr

Si

Solution :
Answer (3)

You scored 3 of 3
Question : 69

Which term represents the charge on one mole of electrons?

Options:

One Ampere

One Coulomb

One Faraday

One Volt

Solution :
Answer (3)
You scored 3 of 3
Question : 70

What is the oxidation number of rhenium in Ca(ReO4)2?

Options:

+1

+3

+6

+7

Solution :

Answer (4)

+2 + 2x – 16 = 0

x = +7

You scored -1 of 3
Question : 71

Which species has the largest bond angle?

Options:

NO2+

NO2

NO2–

NO3–

Solution :

Answer (1)

NO2+ is sp hybridised others are sp2 hybridised.


You scored 3 of 3
Question : 72

Which gas-phase atom in its ground state could have an electron with the quantum numbers :
n = 3, l = 2, ml = 0, ms = –1/2?

Options:

Na

Mg

Ti

Solution :
Answer (4)

You scored 3 of 3
Question : 73

Properties of the alkaline earth metals that increase from Be to Ba include which of the following?

I. Atomic radius

II. Ionization energy

III. Nuclear charge

Options:

I and II only

I and III only

II and III only

I, II and III

Solution :

Answer (2)

Down the group ionisation energy decreases.


You scored -1 of 3
Question : 74

In which list are the ions arranged in order of decreasing size?

Options:

S2–, Br–, K+, Ca2+

Br–, S2–, K+, Ca2+

K+, Ca2+, S2–, Br–

Ca2+, K+, S2–, Br–

Solution :
Answer (2)

You scored 3 of 3
Question : 75

Which species is planar?

Options:

CO32–

SO32–

ClO3–

BF4–

Solution :

Answer (1)

CO32– : sp2 hybridisation triangular planar.


You scored 3 of 3
Question : 76

How many resonance forms can be written for the nitrate ion, NO3–?

Options:

Solution :
Answer (3)

You scored -1 of 3
Question : 77

The boiling points of CH3COCH3, CH3COC2H5 and CH3COC3H7 are 56°C, 80°C, and 102°C, respectively. This increase is best
attributed to an increase in which of the following?

I. Dipole-dipole interactions.

II. Dispersion forces.

III. Hydrogen bonding.

Options:

I only

II only

III only

II and III only

Solution :
Answer (2)
You scored 0 of 3
Question : 78 (skipped)

How many isomeric compounds have the formula C3H8O?

Options:

Solution :

Answer (3)

CH3CH2CH2OH, CH3CH(OH)CH3, CH3OC2H5

You scored 3 of 3
Question : 79

How many sigma bonds does propyne, C3H4, have?

Options:

Solution :

Answer (3)
You scored 3 of 3
Question : 80

Which of the compounds below will react readily with chlorine by addition?

I. C2H2 (ethyne) II. C2H4 (ethene)

III. C6H6 (benzene)

Options:

I only

I and II only

II and III only

I, II and III

Solution :

Answer (2)

Benzene is stable so do not undergo addition of chlorine.

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