5.

What is the more powerful reducing agent that is used in the reduction of
QUICE REVIEW CENTER carboxylic acids ans esters?
6th floor room 608-610 Doňa Amparo Bldg. a. NaBH4
G. Tolentino St., Sampaloc Manila b. LiAlH4
c. NaoH
GENERAL INSTRUCTION. Please select the best answer and submit on time. d. H2SO4
6. in Fischer esterification, the common products are the ester and what other
1. Glutathione removes potentially harmful oxidants in human body and is a compound?
common whitening agent among Filipinos. How many carbon atoms does a. Alcohol
glutathione have? b. Acid
a. 10 c. Water
b. 12 d. Ketone
c. 7 7. A sample of nitrogenous material weighing 1.00g is digested with concentrated
d. 15 sulfuric acid and a catalyst. The resulting solution is made alkaline with excess
2. Which of the following is an aldohexose? sodium hydroxide and the liberated NH3 is caught in 25 ml of 0.2520 N
a. Glucose Hydrochloric acid. The excess HCl then requires 2.75mL of 0.2340 N NaOH for
b. Fructose neutralization. What is the percentage of nitrogen in the original sample.
c. Ribose a. 12.34 %
d. Sedoheptulose b. 7.923 %
3. Which functional group will cause an IR absorption of 3500 cm-1? c. 19.00%
a. Alkyne d. 33.12%
b. Alkane 8. The solubility of calcium phosphate in water is 2.5 x 10 -5 g per mL. how many
c. Ketone moles per liter does a saturated solution of calcium phosphate contain?
d. Alcohol a. 2.5 x 10 -5
4. Which of the following is the most acidic? b. 5 x 10 -5
a. Ethanol c. 8.1 x 10 -5
b. Methanol d. 3.1 exp -5
c. Butanol 9. A diluted acetic acid solution at 25 deg C has a hydrogen ion concentration of 2.5
d. Phenol x 10 -4 mole per liter. What color would be given to the solution by a drop of
thymol blue?
 a. Colorless a. 27.2 mL
b. Pink b. 21.14 mL
c. Blue c. 11.35 mL
d. Yellow d. 0.9 mL
10. How many milliliters of 0.2 N Hydrochloric acid can be neutralized by 20 mL of 15. What is the percentage of Cr in a sample of chromite if a 0.50 g sample after
0.15 N Sodium Hydroxide? fusion in the regular way is treated with 50.0 mL of 0.12 N ferrous ammonium
a. 20 mL sulfate and the excess requires 15.05 mL of K2Cr2O7 ( 1.0 mL = 0.0060 g Fe)
b. 25 mL a. 12 %
c. 10 mL b. 16%
d. 15 mL c. 15%
11. What is the normality of a solution containing 0.008282 g of potassium carbonate d. 9%
per milliliter? 16. It states that different samples of the same compound always contain its
a. 0.11N constituent elements in the same proportion by mass.
b. 0.12N a. Dalton’s Law
c. 0.13N b. Boyle’s Law
d. 0.14N c. Proust’ Law
12. To what volume must 1600mL of a 0.2050 N solution be diluted in order that the d. Charle’s Law
resulting solution will be 0.2 N? 17. Who coined the word “atomos”
a. 1640 mL a. Plato
b. 1330 mL b. Aristotle
c. 1670mL c. Democritus
d. 1780mL d. Archimedes
13. Which of the following is not used as a primary standard for sodium hydroxide 18. In 1932, James Chadwick bombarded a thin sheet of beryllium with alpha
solutions? particles, and paved way for his discovery of this very small particles. What is this
a. KHP small particle?
b. Benzoic acid a. Electron
c. Sulfuric Acid b. Proton
d. Potassium biiodate c. Neutron
14. How many milliliters of 0.010 N barium hydroxide are theoretically required to d. Atom
titrate 0.030 g of arsenic acid to the formation of Ba(H2AsO4)2 19. Which of the following is not true about acids?
 a. Sour taste a. 12 g/mol
b. Changes litmus from blue to red b. 16 g/mol
c. Reacts with metal to produce gas c. 18 g/mol
d. Aqueous solutions do not conduct electricity d. 24 g/mol
20. A small bubble rises from the bottom of a lake, where temperature and pressure 24. A certain gas expands in volume from 2.0L to 6.0L at constant temperature.
are 8 deg C and 6.4 atm, to the water’s surface, where the temperature is 25 deg Calculate the work done by the gas if it expands against a vacuum.
C and pressure is 1 atm. Calculate the final volume of the bubble if its initial a. 400 J
volume was 2.1 mL. b. 200 J
a. 10 mL c. 0 J
b. 12mL d. 12 J
c. 14mL 25. A 394g sample of water is heated from 10.75 deg C to 83.20 deg C. calculate the
d. 16mL amount of heat absorbed by the water.
21. Sodium azide is used in some automobile air bags. The impact of collision a. 119 J
decomposes the sodium azide to sodium and nitrogen gas. Calculate the volume b. 119 kJ
of the nitrogen gas generated during impact at 85 deg C and 812 mmHg from a c. 19 J
50.0 g sample of sodium azide d. 19 kJ
a. 12 L 26. It is the distance between identical points on successive waves
b. 32 L a. Wavelength
c. 43L b. Amplitude
d. 16L c. Frequency
22. Robert Boyle became famous due to his studies in gas collisions. What is the d. Wave
nationality of Robert Boyle 27. The wavelength of the green light from a traffic signal is centered at 522 nm.
a. Polish What is the frequency of this radiation?
b. Irish a. 5.75 x 10 14 Hz
c. English b. 3.45 x 10 14 Hz
d. American c. 10.89 x 10 14 Hz
23. A flammable gas made up only of carbon and hydrogen is found to effuse through d. 23.5 x 10 14 Hz
a porous barrier in 3.50 min. Under the same conditions of temperature and 28. The smallest quantity of energy that can be emitted or absorbed in the form of
pressure, it takes an equal volume of chlorine gas 7.34 mins to effuse through the electromagnetic radiation
same barrier. Calculate the molar mass of the unknown gas. a. Joule
 b. Planck 34. Which has the lowest ionization energy?
c. Quantum a. He
d. Calorie b. Ne
29. It is impossible to know simultaneously both the momentum and the position of a c. Ar
particle d. Kr
a. Plancks theory 35. Which of the following has the lowest viscosity at 20 deg C?
b. Schrodinger theory a. Blood
c. Heisenberg principle b. Water
d. Bohr’s principle c. Mercury
30. Describes the orientation of the orbital in space. d. Acetone
a. Principal quantum number 36. Calculate the freezing point of a solution containing 724 g Ethylene glycol (MW =
b. Angular quantum number 62.07) in 2603 g of water.
c. Magnetic quantum number a. 8.35 deg C
d. Spin quantum number b. -8.35 deg C
31. The most stable arrangement of electron in subshells is the one with the greatest c. 2.3 deg C
number of parallel spins. d. -2.3 deg C
a. Hund’s rule 37. The osmotic pressure of a 0.01 M KI solution at 25 deg C is 0.465 atm. Calculate
b. Pauli’s rule the van’t hoff factor for KI at this concentration.
c. Magnetic rule a. 2.9
d. Arrangement rule b. 1.9
32. The outer most electrons of an atom which are involed in chemical bonding c. 3.9
a. Valence electron d. 4.9
b. Special electron 38. Which atom should have the smallest first ionization energy?
c. Alpha electron a. F
d. Beta electron b. K
33. Which of the following has the biggest atomic radius? c. O
a. Sr d. C
b. Pb 39. It is found in nature mainly as stibnite. It was first isolated by Vannoccio
c. B Biringuccioand described in 1540.
d. Rb a. Lead
 b. Antimony 45. Ecological Solid Waste Act of 2000
c. Bismuth a. RA 9003
d. Tin b. RA 8749
40. Which of the following amino acids is the smallest of all amino acids? c. RA 8550
a. Alanine d. RA 3931
b. Methionine 46. Toxic Substances and Hazardous and Nuclear Waste control Act of 1990
c. Cysteine a. RA 8749
d. Glycine b. RA 6969
41. The three letter abbreviation "asn" corresponds to which amino acid? c. RA 9003
a. Aspartic acid d. RA 3931
b. Asparagine 47. How much money was appropriated for the initial implementation of the
c. Arginine Philippine Clean Air Act of 1999?
d. Astatine a. 500 Million pesos
42. Which of the following amino acid(s) are polar? b. 600 Million pesos
a. Arginine c. 750 Million pesos
b. Serine d. 1 Billion pesos
c. Tyrosine 48. Which of the following is the weakest acid in the group?
d. All of these a. Perchloric acid
43. Which interesting sounding scientist came up with the name "vitamin"? b. Hydroiodic acid
a. Emil Fischer c. Nitric acid
b. Kazimierz Funk d. Formic acid
c. J. B. S. Haldane 49. Calculate the pH of a 0.045M Barium Hydroxide
d. Friedrich Miescher a. 10
44. Deducing the structures of vitamins is important in understanding their b. 11
biochemical function. Which woman was responsible for solving the structure of c. 12
vitamin B12, the most chemically complex vitamin? d. 13
a. Marie Curie 50. Calculate the pH of a 0.036 M nitrous acid solution (Ka = 4.5 x 10 -4)
b. Dorothy Hodgkin a. 3.56
c. Mary Somerville b. 2.42
d. Barbara McClintock c. 4.11
 d. 3.11 b. Bluish purple
51. The pH of a 0.10M solution of formic acid is 2.39. what is the Ka of the acid? c. Orange
a. 2.5 x 10 -4 d. Red
b. 3.5 x 10 -4 57. Calculate the solubility of silver chloride in a 8.3 x 10 -3 M silver nitrate solution.
c. 1.8 x 10 -4 (Ksp = 1.6 x 10 -10)
d. 5.7 x 10 -4 a. 2.7 x 10 -6 g/L
52. What is the pH of a 0.40M ammonia solution? (Kb = 1.8 x 10 -5) b. 3.2 x 10 -6 g/L
a. 10.4 c. 7.88 x 10 -6 g/L
b. 11.4 d. 9.0 x 10 -6 g/L
c. 12.2 58. A 0.22-mole quantity of CuSO4 is added to a liter od 1.35M NH3. What is the
d. 13 concentration of Cu2+ ions at equilibrium. (Kf = 5 x10 13)
53. Which of the following is a weak acid? a. 9.0 x 10 -14 M
a. HF b. 12.0 x 10 -14 M
b. HCl c. 5.44 x 10 -14 M
c. HBr d. 2.11 x 10 -14 M
d. HI 59. What is the percentage of total acid expressed as acetic acid in a sample of
54. The pH of a 0.25M solution of potassium fluoride is 8.28. what is the percent vinegar if 3.00 g of vinegar require 20.5mL of 0.115 N KOH solution for an
hydrolysis? (kb = 1.4 x 10 -11) endpoint with phenolphthalein indicator?
a. 1% a. 3%
b. 0.00076% b. 4.7%
c. 0.005% c. 4.3%
d. 0.000003% d. 5.11%
55. Calculate the pH of a buffer system containing 1.0M CH3COOH and 1.0M 60. What wait of sample of impure oxalic acid should be taken for titration by 0.50 N
CH3COONa (Ka = 1.8 x 10 -5) NaOH so that the percentage of H2C2O4 2H2O will be twice the buret reading?
a. 4.74 a. 1.57 g
b. 5.67 b. 2.33g
c. 3.11 c. 2.11g
d. 4.5 d. 1.02g
56. What is the color of Chlorophenol blue in basic solutions? 61. A 1.20g sample of a mixture of sodium hydroxide and sodium carbonate with
a. Yellow inert impurity is dissolved and titrated cold with 0.50 N HCl. With phenolphthalein
 as the indicator, the solution turns colorless after the addition of 30.0mL of the b. Citric acid cycle is also called carboxylic acid cycle.
acid. Methyl orange is then added, and 5.0mL more of the acid are required for c. Cardiolipids are a group of lipids found in heart muscles.
the color to change to pink. What is the percentage of NaOH in the sample? d. Sanger dideoxy method uses carbon reactions.
a. 22.08% 67. Which of the following is the most important progestin?
b. 32.11% a. Androsterone b. estrone c. progesterone d.
c. 45.67% testosterone
d. 41.67% 68. Which of the following does not belong to the group?
62. A 1.20g sample of a mixture of sodium hydroxide and sodium carbonate with a. Aspirin b. naprosyn c. tylenol d. kremil-s
inert impurity is dissolved and titrated cold with 0.50 N HCl. With phenolphthalein 69. Benzyl penicillinic acid is also known as
as the indicator, the solution turns colorless after the addition of 30.0mL of the a. Penicillin A b. Penicillin G c. Penicillin B d. Penicillin H
acid. Methyl orange is then added, and 5.0mL more of the acid are required for 70. The most general method for prepaing alcohols is
the color to change to pink. What is the percentage of sodium carbonate in the a. Reduction of a carbonyl group c. oxidation of a carbonyl group
sample? b. Separation of a carbonyl group d. hydrogenation of a carbonyl
a. 22.08% group
b. 32.11% 71. Which of the following compounds can undergo the aldol reaction?
c. 45.67% a. Benzaldehyde c. formaldehyde
d. 41.67% b. c. 2,2,6,6-tetramethylcyclohexanone d. 2,2-dimethylcyclohexanone
63. What is the normality of a solution of potassium permanganate if 40.0mL will 72. Two grams of O2 are confined in a 2-liter vessel by a pressure of 1.21 atm. What is
oxidize 0.30g of sodium oxalate? the temperature of the gas in OC?
a. 0.22 a. 200OC b. 210 OC c. 220 OC d. 230 OC
b. 0.06 73. What weight of 225Ra, for which t ½ = 14.8 days, is required to yield 1 millicurie
c. 0.34 of radiation?
d. 0.56 a. 0.360(g) b. 0.361(g) c. 0.362(g) d. 0.363(g)
64. The process by which the genetic information encoded in DNA is read and used to 74. A weight of 1000g falls freely to a platform from a height of 10 m. What amount
synthesize RNA in the nucleus of the cell. of heat will be evolved when the weight strikes the platform?
a. Transfer RNA b. transcription c. transamination d. Translation a. 23.44cal b. 26.78cal c. 24.90 cal d. 26.66cal
65. How many products might be formed on chlorination of m-xylene? 75. A liquid is observed to boil at 120 OC under a pressure of 725mm at 70 OC. its
a. One b. two c. three d. four molar heat of vaporization is 8200cal/mole. Calculate the normal boiling point of
66. Which of the following is a TRUE statement? the liquid.
a. A carbon atom is larger than a hydrogen atom. a. 100.8 OC b. 110.8 OC c. 120 OC d. 130 OC
76. The standard free energy of formation of H2O(1) at 25OC is -56,690 cal. Find the a. True b. falsec. true and false d. no answer
free energy of formation of H2O at 25OC from H2 at a partial pressure of 0.01 atm 84. The decomposition of ethane to methyl radicals is a 1st order reaction with a rate
and O2 at a partial pressure of 0.25 atm. constant of 5.36x10-4s-1 at 700 OC. Calculate the half life of the reaction in minutes.
a. 12240cal b. 11490cal c. 12420cal d. 11380cal a. 15mins b. 20mins c. 30mins d. 133mins
77. How many protons and neutrons are present in a Pb nucleus of atomic mass of 85. Minimum amount of energy required to initiate chemical reaction.
206? a. Ionization energy b. first energy c. activation energy d. chemical energy
a. 65 b. 37 c. 34 d. 124 86. Methanol is manufactured industrially by reacting Carbon Monoxide with
hydrogen gas. The equilibrium constant (Kc) for the reaction is 10.5 at 220OC.
78. Marijuana is the most commonly used illegal drug in the United States and in the
What is the value of Kp at this temperature?
world, and was a well-established medicine until it was federally criminized in
1937. What is the chemical responsible for most of marijuana’s psychological a. 6.41 x 10-3 b. 7.13x10-3 c. 3.11x10-4 d. 4.0x10-2
effects? 87. Which is NOT true?
a. Octanitrocubane b. Tetrahydrocannabinol c. Cisplatin d. Terapthalic acid a. No two electrons in the same atom can have the same four quantum
79. This type of spectroscopy is mainly used to tell functional groups within a numbers.
compound. Older versions require special salt plates, but newer technology has b. The most stable arrangement of electrons in a subshell is the one that has
made them obsolete. The "fingerprint region" in the readout is only useful for the greatest number of parallel spins.
those who have studied this method extensively, and isn't very useful for c. Each orbital can be occupied by a maximum of 2 electrons
beginners. d. Atoms in which all the electron spins are paired are paragmagnetic.
a. Nuclear Magnetic Resonance c. Infrared Spectroscopy 88. Isomers can be further classified into
b. X-Ray Fluorescence d. Gas Chromatography-Mass Spectroscopy a. Enantiomers and diastereomers c. constitutional and sterioisomers
80. What happens to the protons in a sample when an external magnetic field is
b. Configurational and cis-trans d. all of these
applied?
89. Molecule that does not contain a plane of symmetry
a. All protons align with the field. C. All protons align opposite to
the field. a. Isomer b. enantiomer c. chiral d. achiral
b. Some protons align with the field and some align opposite to it. D. All 90. Which is TRUE about alkyl-halides?
protons assume a random orientation a. They are usually prepared from alcohols.
81. A solution contains 50% of water, 35% of ethyl alcohol, and 15 % of acetic acid by b. They react with magnesium metal to form organomagnesium halides
weight. Calculate the mol fraction of each component in the mixture. c. Treatment of alkyl halide with nucleophile results either in substitution or
a. ½ b. ¾ c. 0.6 d. 1 elimination.
82. Which of the following is not a colligative property? d. All of these
a. Vapor pressure lowering c. freezing point depression 91. Which of the following is TRUE?
b. Boiling point elevation d. reverse osmosis a. A carbon-oxygen double bond is structurally similar to carbon-carbon double
83. Boiling point elevation is proportional to molality. bond
 b. Carbonyl groups are strongly polarized because of the electronegativity of c. The octet rule predicts that atoms form enough covalent bonds.
oxygen d. None of these.
c. Aldehydes and ketones undergo nucleophilic addition reactions 100. Select the CORRECT statement.
d. All of these a. Rise in temperature is proportional with solubility of gases.
92. A 2-mm layer of pyrex glass will transmit 10% of incident radiation of 3000A. b. Rise in temperature is proportional with solubility of liquids.
What percentage of light of the same wave length will be absorbed by 1-mm layer c. Solubility of gas in a liquid is inversely proportional to the partial pressure of
of the glass? gas
a. 3% b. 4% c. 5% d. 6% d. No answer
93. A certain substance in a cell of length l absorbs 10% of the incident light. What
fraction of the incident light will be absorbed in a cell 5 times as long?
a. 45% b. 92% c. 89% d. 90%
94. The radius of the given capillary is 0.105mm. A liquid whose density is 0.800g/cc
rises in this capillary to a height of 6.25cm. calculate the given tension of the
liquid.
a. 167 b. 185 c. 145 d. 900
95. Select the wrong pair
a. Substitution by water-hydrolysis c. substitution by alcohol- alcoholysis
b. Substitution by an organometallic reagent-Grignard reaction d. no
answer
96. Which is true about amines?
a. Aryl amines are generally stronger bases than alkylamines
b. Alkylation of ammonia yields secondary amine
c. Amines can be prepared from amides by oxidation
d. Amines are organic derivatives of ammonia
97. Select the WRONG pair
a. Transferases-catalyze tranfers of groups c. hydrolases-catalyze hydrolysis
b. Ligases-catalyze bond formations d. lyases-catalyze redox reactions
98. Which of the following is the sweetest?
a. Lactose b. glucose c. fructose d. sucralose
99. Which of the following is INCORRECT?
a. A lewis dot symbol shows the number of valence electron.
b. In a covalent bond, two electrons are shared by two atoms.