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Development of Lutensol® XL
and Lutensol® XP based on
C10 Guerbet alcohol type by
BASF
Residual alcohol
25
Lutensol® XL 40 - XL 140
20 Lutensol® XP 30 - XP 140
residual alcohol in %
C9C11 ethoxylates
15 APEO
ES 94017
10 ES 94018
ES 94019
5
approx. 1% residual alcohol
0
2 4 6 8 10 12 14
EO content in mol
Wetting
Wetting on cotton (EN 1772: 23°C, 1g/l )
200
Lutensol® XL 40 - 140
180
Lutensol® XP 30 - 140
160
C9C11 ethoxylates
140 APEO
wetting time in s
120
100
80
60
40
20
0
2 4 6 8 10 12 14 16
EO content in mol
70 Lutensol® XP 80
C9C11 + 8 EO
60 AP 8
50
40
30
20
0,001 0,01 0,1 1 10
bubble lifetime in s
44 ms 12 s
40
35
30
contact angle
25
20
water
15 Lutensol® XL 80
10 Lutensol® XP 80
C9C11 + 8 EO
5
APEO + 8 EO
0
0,1 1 10
time in s
10
Contact angle on
60 glass (23°C; 0,5g/l)
Dr. Roland
E-EVD/GT,
Dr. Böhn / BASF
02/2004
Roland Böhn AGAG
/ BASF
Performance Chemicals
Adding value for the detergent and formulating industries
Soil removal
Nozzle
Testing Apparatus
pump
thermostat
cleaning
solution
80
70
60
50 Lutensol® XL 40-140
Lutensol® XP 30-140
40
C9C11 ethoxylates
30 APEO
20
0 2 4 6 8 10 12 14 16
EO-content [mol]
Mechanical energy
Fast-acting emulsifier e.g. C13+ 3 EO
Continuous
phase Coalescence
g
tin
-ac er
w ifi
Emulsifier Slo uls Phase
em
Fa separation
st
em -acti
uls ng
ifie Coalescence
r No
Disperse phase
coalescence
Phase
Emulsification Emulsification Stabilisation separation
Deformation & Emulsion Short-term stability
Breakup
Emulsifier/coemulsifier principle
Mechanical energy
Continuous
phase
Emulsifier
Coemulsifier
Molecular weight
GPC of an emulsifier/coemulsifier system GPC of an Lutensol® XL 70
Dr. Roland Böhn / BASF AG
Performance Chemicals
Adding value for the detergent and formulating industries
100% 100%
Emulsifier Coemulsifier
e.g. C13+ 10 EO e.g. C13 + 3 EO
Emulsifier/Coemulsifier
e.g. Lutensol® XL 70
Dr. Roland Böhn / BASF AG
Performance Chemicals
Adding value for the detergent and formulating industries
C9C11 -
Lutensol® XP Lutensol® XL APEO
ethoxylates
Wetting +/- + ++ -
Dynamic surface
tension
+/- + ++ +/-
Spreading on a
surface
+/- +/- + ++
Summary
Spreading Soil removal
Ecology
Lutensol® XP
and
Lutensol® XL
Emulsification
Performance Chemicals
Adding value for the detergent and formulating industries
Backup
Cleaning conditions:
• concentration of cleaner solution: 0.5 %
• duration of cleaning process: 1 min
• room temperature