Академический Документы
Профессиональный Документы
Культура Документы
HANDOUT 7.1
Table 7-1. Four Stages of Solid Liquid Separations
PRETREATMENT To increase particle size, reduce viscosity.
CHEMICAL PHYSICAL
coagulation crystallization freezing/heating
flocculation aging filteraid admix
SOLIDS To reduce the volume of material to process.
CONCENTRATION
CLARIFICATION THICKENING
gravity sedimentation gravity sedimentation cyclones
cross flow filtration periodic pressure filters
SOLIDS To separate the solids from the liquid; to form cakes of dry solids or to produce
SEPARATION particulate free liquid.
1
SOLIDS PROCESSING HANDOUTS, George G. Chase, The University of Akron
HANDOUT 7.2
Thickener 10 1 9 90 90/99 = 10
90.9
Filter 25 1 3 6 6/99 = 4
6.1
Deliquoring 50 1 1 2 2/99 = 2
2.0
Hence, you can see that even though the thickener only concentrated the solids from 1 to 10%, 91% of the
liquid was removed and the mixture yet to be treated was only 10% of the volume of the original feed.
Filter
Costs
Thickener
Size
Figure 7-1. Relative costs of filters and thickeners as related to size.
2
SOLIDS PROCESSING HANDOUTS, George G. Chase, The University of Akron
HANDOUT 7.4
Table 7-3. Comparison of Forces Used in SLS.
Gravity Simple
Low Operating Cost
Very Bulky
Still High Volume of Liquid After Separation
3
SOLIDS PROCESSING HANDOUTS, George G. Chase, The University of Akron
HANDOUT 7.5
High Concentration
Mixture (Low
Porosity)
With Significant
Particle-Particle
Contact
Figure 7-2. Particle contact as a function of concentration. Surface charges and electrostatic
forces can keep particles separated, requiring compressive forces to push particles together.
4
SOLIDS PROCESSING HANDOUTS, George G. Chase, The University of Akron
HANDOUT 7.6
10
5 loose-unglued sand run 1
loose-unglued sand run 2
0
loose-unglued sand run 3
-5 0 5 10 15
ZP (mV)
10.0
0.0
-10.0
Zeta Potential [mV]
-20.0
-30.0
-40.0
-50.0
-60.0
2 3 4 5 6 7 8 9 10 11 12
pH
Figure 7-4. Zeta potential measurements for Kaolinite, Halloysite and Illite Clayes in 0
M and 0.14 M NaCl solution. (E. A. Stephan, Examination of Deep Bed Filtration,
Dissertation, The University of Akron, 1999).
5
SOLIDS PROCESSING HANDOUTS, George G. Chase, The University of Akron
HANDOUT 7.7
1
0.9
0.8
Grade E Carbonyl Iron
Kaolin
0.7
Porosity
Latex
Talc
0.6
Supercel
Fine Silica
0.5
0.4
0.3
1 10 100 1000 10000
Applied Compressive Stress, kPa
Figure 7-3. Compressibility of packed beds of selected materials (H.P. Grace, “Resistance and
Compressibility of Filter Cakes (Part I and II), Chem. Eng. Prog., 49, 303-318, 367-377, 1953).
THICKENER
0.8
GRAVITY FILTER
PRESSURE FILTER
0.4
CENTRIFUGE
EXPRESSION
0.2
PARTICLE
DEFORMATION
0
0.01 0.1 1 10 100 1000
Compressive Stress, ATM
Figure 7-6. Compressive Stress relation to separation operation. (F. Tiller and W. Li, Theory and
Practice of Solid/Liquid Separation, 4th ed., University of Houston, 2002.
6
SOLIDS PROCESSING HANDOUTS, George G. Chase, The University of Akron
HANDOUT 7.8
Table 7-5. Filter Selection Chart. (data from D.B. Purchas, Solid/Liquid Separation Technology, Uplands
Press, Croydon, 1981).
TYPICAL OPERATING RANGE PERFORMANCE
Filter SCORE 0 TO 9
(9 IS BEST)
% (mass) OF PARTICLE SIZE
CAKE DRYNESS
PERFORMANCE
WASH
CLARITY
FILTRATE
BREAKAGE
CRYSTAL
SOLIDS IN OF SOLIDS,
THE FEED MICRONS
7
SOLIDS PROCESSING HANDOUTS, George G. Chase, The University of Akron
HANDOUT 7.9
Table 7-6. Centrifuge Selection Chart (data from D.B. Purchas, Solid/Liquid Separation Technology,
Uplands Press, Croydon, 1981).
CAKE DRYNESS
PERFORMANCE
WASH
CLARITY
FILTRATE
BREAKAGE
CRYSTAL
SOLIDS IN OF SOLIDS,
THE FEED MICRONS
PUSHER 8 – 90 50 – 80,000 9 5 4 4
PEELER/SCRAPER 5 – 80 2 – 20,000 9 6 5 5
DECANTER 2 – 70 1 – 20,000 4 3 4 -
8
SOLIDS PROCESSING HANDOUTS, George G. Chase, The University of Akron
HANDOUT 7.10
Table 7-7. Selection based on cake formation rate (F. Tiller, Chem. Eng. Progr. Oct. 1977, 65-76).
Cake Formation Rate (rate at Separation type Equipment
which cake height grows in a
gravity filter).
0.1 to 10 cm/sec Rapid Filtering Gravity pans; screens; horizontal
belt or top-feed drum filter;
continuous feed pusher centrifuge
0.1 to 10 cm/min Medium Filtering Vacuum drum, disc, horizontal
belt, pan filters, peeler centrifuge
0.1 to 10 cm/hr Slow Filtering Pressure filters, disc and tubular
centrifuges, sedimenting
centrifuges
Negligible cake Clarification Cartridges, granular beds, precoat
drums, filter aid admix