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Processing of cocoa beans is done usually to produce two main products: cocoa butter
and powder (Asselstine, Et.al 2016). The production is a multistep process that starts with the
cacao beans being fermented, dried, roasted, winnowed, grinded, and refined (Giacometti, 2015).
First, the cacao pods are harvested from the tree then cracked open to harvest the beans. The
beans are then fermented in aseptic conditions in order to prevent the cacao beans from
germinating. After fermenting, the beans are left to dry (Owen, 2013). Once dried, the beans are
roasted for the purpose of developing the notable chocolate flavor, sterilize, and to puff up the
beans (Beckett,2008). The roasting step is the most influential when it comes to developing the
flavor of the chocolate product (Afoakwa,2010). After roasting, winnowing is done to remove
the shell from the beans. After the shell stripping process, what is left is the nib. The cacao nibs
are grinded into slurry and refined to produce the cocoa value added products (Beckett,2008).
However, when the beans are left dried under the sun which may jeopardize the food
safety of the product. Such conditions would promulgate mold growth and insect infestation
(Afoakwa,2010). This will directly cause the deprecation of product quality and price. The
components of the said cacao beans (insert scientific name) and its composition, along with its
desired product composition, are listed in (Table).
It is also important to take note the important characteristics of the cacao products in
terms of taste, color and odor. Alkalization and roasting process greatly affects the taste, color
and odor of cocoa powder. Alkalization process increases the pH of the cocoa cake (wherein the
natural cocoa bean has a pH of 5.0-6.0) to 7.0 - 7.6. This results in improving the cocoa powder's
color and flavor but lowering the antioxidant activity, total polyphenols and flavanols (Miller,
Hurst, & Payne, 2008). Roasting is a heat treatment that brings changes in the chemical
composition and physical structure of cacao beans and develops the characteristic chocolate
flavor and aroma of the beans (Philippine National Standard, 2017), by removing undesired
compounds with low boiling points, such as acetic acid, kill any microbiological contaminants,
such as salmonellae, and form the typical roasty, sweet odorants of cocoa (Beckett, 2008;
Frauendorfer & Schieberle, 2008; Żyżelewicz et al., 2016).
In the selection of process options, these concerns were taken into account, and included
processes which would be suited to the needs of effectively producing high quality cocoa
products. The list of advantages and disadvantages of these processes are listed in Table 2-1.
Cracking with wooden to remove cocoa beans no energy requirement causes damage to the
from the pods (e.g. electricity)
club cocoa beans; requires
more manpower; not
efficient
Fermentation
Insufficient literature
with regards to
design efficient
mixing, no scale-up
was done from pilot
scale design, and
high rpm can damage
to the substrate
(Panday, 2008).
Coarse/Pre-grinding
Process Purpose Advantage Disadvantage
Hammer mills used for pre- Aside from grinding Needs higher energy
grinding cocoa by stirring and requirement; must
beans mixing, the cocoa operate at around 60
nibs will turn into a to 80 degrees Celsius
coarse viscous mass (NIIR Board of
of cocoa; has sieves Consultants and
that restricts particle Engineers, 2005)
size of produced
cocoa mass (NIIR
Board of Consultants
and Engineers, 2005)
Disc mills used for pre- speed of grinding and requires extruders
grinding cocoa throughput can be that are expensive
beans adjusted (NIIR Board of
independently from Consultants and
one another; can Engineers, 2005)
operated with several
stages (NIIR Board
of Consultants and
Engineers, 2005)
Blade mills used for pre- grinds cocoa nibs of efficiency depends
grinding cocoa up to 150-250 on the concentration
beans micrometers; can of coarse particles
remove moisture and (NIIR Board of
unpleasant flavors by Consultants and
evaporation when Engineers, 2005)
operated in vacuum
(NIIR Board of
Consultants and
Engineers, 2005)
Fluted rollers An initial step in Carry out process at Is not efficient will
pre-grinding the low temperature low throughput
cocoa beans (NIIR (NIIR Board of (NIIR Board of
Board of Consultants and Consultants and
Consultants and Engineers, 2005) Engineers, 2005)
Engineers, 2005)
Thermal Pre-treatment
Introduced moisture
significantly
increases the lethality
of the process
(Winkler, 2013)
Infra-red Radiation Loosen the shell Particles of dust, Could not be used as
Treatment from the cotyledons remains of fruit pulp, a control step for
and decrease rodent hair, insect microbial hazards
bacteria count and fragments, and other (Winkler, 2013)
major contaminants foreign matter
originating from incinerates (Beckett
the shell (Beckett (Ed.), 1994; Elvers
(Ed.), 1994; Martin, (Ed.), 2017)
1987)
Resulting water
vapour accumulates
on the surface of the
cotyledons and
detaches the
cotyledons from the
shells without
significantly reducing
its moisture content
(Beckett (Ed.), 1994;
Elvers (Ed.), 2017)
High surface
temperature only on
the surface of the
bean and brings
about a drop in the
amount of
microbiological
contamination
(Beckett (Ed.), 1994;
Elvers (Ed.), 2017)
Roasting
Whole Bean Roasting To roast the whole Loosens the shell Heat causes some of
beans after the from the nib which the fat to migrate into
drying process makes winnowing the shells where it
relatively easy remains and is
(Beckett (Ed.), 1994; thrown away, thus
Beckett, 2008) resulting in a loss of
some cocoa butter
and can result in
losses of as much as
0.5% (Afoakwa,
2010; Beckett (Ed.),
1994; Beckett, 2008;
Beckett (Ed.), 2009;
Elvers (Ed.), 2017;
Gutiérrez, 2017)
Requires a greater
expenditure of
energy to heat the nib
through the shell.
Estimated of up to
44% extra energy is
needed compared to
the other 2 methods
of roasting (Beckett
(Ed.), 1994; Beckett,
2008; Beckett (Ed.),
2009; Gutiérrez,
2017)
Nib Roasting To roast the nibs Problems of fat Needs thermal pre-
after undergoing migration and extra treatment in order to
pretreatment & energy use are loosen the husks that
winnowing process overcome (Beckett are firmly attached to
(Ed.), 1994) the cotyledons
(Afoakwa, 2010;
Increase of output for
Elvers (Ed.), 2017;
the same amount of
Gutiérrez, 2017)
energy input (Martin,
1987)
Uniformity of heat
treatment (Beckett
(Ed.), 1994; Martin,
2017)
Liquor Roasting (Mass To roast the cacao Problems of fat Mass still has
Roasting) liquor after migration and extra relatively high
grinding process energy use are moisture content and
overcome (Beckett is difficult to pump
(Ed.), 1994) (Beckett (Ed.), 1994)
Uniformity of heat Nib is very difficult
treatment (Beckett to grind due to
(Ed.), 1994) having relatively
Big surface area is high moisture content
good for removing (Beckett (Ed.), 1994)
volatile substances
Requires very careful
(Beckett (Ed.), 1994)
moisture control
Process can be able
(Beckett, 2008)
to moderate flavors
Needs thermal pre-
(Beckett (Ed.), 1994)
treatment in order to
loosen the husks that
are firmly attached to
the cotyledons
(Afoakwa, 2010;
Gutiérrez, 2017)
Fine Grinding
Agitator Ball Mills final step in the capacity is also has broader particle
grinding process; around low size spectrum and
must meet required investment cost (NIIR requires higher
fineness of cocoa Board of Consultants grinding energy
powder and Engineers, 2005) compared to roller
refiners with high
maintenance cost;
might cause fine
metal contaminant
(NIIR Board of
Consultants and
Engineers, 2005)
Fine Double Roll final step in the reduces grinding cost; relatively unhygienic
Refiner before the grinding process; roller refiners due to open mode
Agitator Ball Mill must meet required produces plate- operation of the roller
fineness of cocoa shaped agglomerates refiners thus requiring
powder that can be easily more supervision
ground in the agitator (NIIR Board of
ball mill (NIIR Board of Consultants and
Consultants and Engineers, 2005)
Engineers, 2005)
Extraction
Hydraulic Press Extract cacao butter Typically, about 40g Hydraulic Fluid can
(Cacao Liquor) and cacao cake of cocoa butter can cause corrosion if the
from cacao liquor. be extracted from pistol is not properly
100g of cacao beans. coated. (Clerq,2011)
(Clercq,2011) Low
maintenance,
minimum downtime,
minimum cost-
efficiency and
optimum
performance due to
standardization.
(DuvyisWiener,2017)
Cacao Nibs Press Extract cacao butter Overcomes Lower yields about
and cacao cake entrainment of solid 80% compared to the
from cacao nibs particles into cocoa pressing of cacao
butter, clogging of mass/liquor which is
the filter medium. If about 89%. (Venter
the press chambers et al.,2007)
and the malfunction
of the sealing ring
used in the press
chambers may occur
during the pressing of
cacao mass. (Venter
et al.,2007)
Screw Press Cacao Extraction of cacao Cheap capital cost Small scale and low
Beans butter and cacao and wide variety of yield of oil recovery.
cake from cacao application. (Venter (Venter et al.,2007)
beans et al.,2007)
Alkalization
Process Purpose Advantages Disadvantages
Nib Alkalization the nibs are then the prevalent it also alkalizes the
soaked in an alkali alkalization process cocoa butter, thus
solution, possibly in United States and affecting its flavor
as high as 50 Europe, the alkali and more treatment
percent, the solution has a better processes and
strength of the time with the nibs; methods are needed
solution is pre- the pH is raised from for pre-treatment and
determined by the 5.2 to 5.6 to nearly deodorization of the
desired pH and neutrality at 6.8- 7.5 cocoa butter; results
color of the end (Afoakwa, 2010) to yield loss and
product Deeper and more because of this yield
intense reds are loss, the method is
possible, as well as, more costly than the
offering a cleaner other two.
flavor and the time
and temperature of
the process can be
controlled.
Cocoa Cake is performed after only the cocoa is flavor is undesirable
Alkalization the separation of alkalized, thus the because the already
the cocoa butter quality of the cocoa roasted cocoa cake is
and cocoa cake butter is unaffected to be reprocessed
from filter pressing. and it is more again. The varying
The cocoa cake is economical and leads particle size of the
treated with the to a lower price cocoa cake affect
alkali solution to how the alkali
raise its pH value solution contacts the
cake.
Chocolate Liquor is done after the non- cocoa bean the addition of water
Alkalization cocoa beans are processors can be makes the resulting
roasted, winnowed, able to perform solution more
and grinded to liquor alkalization viscous, thus making
chocolate liquor. can be done with less it difficult to work
equipment used. with. After
alkalization,
- additional steps are
needed in order to
reduce the water
content and
additional steps and
expenses to re-
process the cocoa
butter
Addition of dry alkali is done after the a higher pH value little effect on color
to cocoa cake separation of cocoa after pulverizing with less contact time
butter and cocoa with the alkali
cake the cocoa cake powder
is treated with dry
alkali power
(Beckett, 2009)
No Alkalization the cacao beans are the production the resulting products
Process processed as is/ proceeds as it is will be acidic and
proceed towards astringent
the separation of
cocoa butter and
cocoa solids -
Solvent Extraction by to dissolve oil by 31.32 ± 0.78 yield difficult to carry out
Supercritical CO2 supercritical CO2 (Roiaini M., 2004) the extraction with
simple and effective CO2 alone at T=40-
(Roiaini M., 2004) 90°C and P=80-300
Solvent can be easily bar. (Roiaini M.,
re-used with 2004) high capital
immobilization costs for batch
(Zdeněk Wimmer, extraction (J. P.
2010) low toxicity, Friedrich, 1984) lack
low cost, lack of of engineering
flammability, lack of hardware technology
reactivity (J. P. for continuous
Friedrich, 1984) wide operation (J. P.
range of solvent Friedrich, 1984)
properties (J. P. higher product
Friedrich, 1984) oxidation value
improved properties (Roiaini M., 2004)
of separated
components (in
certain cases) (J. P.
Friedrich, 1984)
Solvent Extraction by to extract oil by a 37.05 ± 1.63 yield The presence of
mixture of ethanol makes the
Supercritical CO2 and (Roiaini M., 2004)
supercritical CO2 process less ‘green’
ethanol and ethanol
Further evaluation of these processes was done using a criterion. The criterion was used
to assess the qualitative aspects of the process. The areas being assessed are: (1) Efficiency; (2)
Food Safety; (3) Ease of Operation; (4) Cost; (5) Environmental Impact. The specified
characteristics of a suitable process in these areas of assessment are listed in Table 2-#. A score
of 3 is given in a certain area of assessment to a process if it would satisfy the given conditions
and the given score would decrease if these conditions couldn’t be met up until 1.0 which is the
lowest score that could be given to a process option in a particular area. The score of the process
option for this set of criteria is calculated using equation #. The evaluation of the process options
using this set of criteria are found in Table 2.#.
For example, in the table, the process option, Cake Alkalization is given a score of 2.85
because it is equal to the sum of the scores with their corresponding weights from Table 2-#
equal to: (30% x 3) + (25% x 3) + (15% x 2) + (25% x 3) + (5% x 3).
1 2 3 4 5 Score
Splitting/Peeling
Fermentation
SSF bioreactor without forced aeration (Trays) 2.0 2.0 2.0 3.0 3.0 2.3
Continuously mixed SSF bioreactors 1.0 2.0 2.0 1.0 2.0 1.5
Intermittently mixed bed bioreactor 2.0 3.0 3.0 1.0 3.0 2.1
Thermal Pre-treatment
Liquor Roasting (Mass Roasting) 2.0 2.0 1.0 2.0 3.0 1.9
Extraction
Hydraulic Press (Cacao Liquor) 3.0 3.0 3.0 2.0 3.0 2.7
Screw Press Cacao Beans 1.0 2.0 3.0 3.0 3.0 2.2
Alkalization
Addition of dry alkali to cocoa cake 1.0 2.0 3.0 3.0 2.0 3.0
Pin Mill
Soxhlet extraction
Ultrasonic extraction
The modified process is chosen because it addresses the concern of the Philippines regarding
the problem of post-harvesting facilities (BPI,2017). The disadvantages of this process are compromised
by the advantages. It lessens the lag time of farmers from fermenting the beans on their own. The
process makes a bridge between the harvesting and post-harvest process making it more efficient. The
fermentation part of the modified process is well controlled hence will give consistent cacao bean
product quality. Thus,e products fromin this process canwill be sold at a higher price producing premium
grade quality value added products .