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¤ Latent heats
n Latent heat of fusion
n Latent heat of vaporization
n Latent heat of sublimation
Phase equilibrium & vapor-pressure curve
3
¨ A fusion curve indicates where the solid and liquid phases are in
equilibrium.
¨ A sublimation curve indicates where the solid and gas phases
are in equilibrium.
¨ A plot showing a vapor-pressure curve, a fusion curve, and a
sublimation curve is called a phase diagram.
¨ The vapor-pressure curve comes to an end at the critical point.
Beyond the critical point, there is no distinction between liquid
and gas.
¨ At triple point, all three phases, solid, liquid, and gas, are in
equilibrium.
¤ In water, the triple point occur at T = 273.16 K and
P = 611.2 Pa.
Quiz: 1
5
¨ Negative
¨ In most substances, the fusion line has a positive slope. As the pressure increases, the
melting temperature of the substance also increases because a solid is denser than
the corresponding liquid.
¨ In water, the slope is negative because ice is less dense.
¨ CO2 sublimation
¤ Demonstration of sublimation of CO2
Latent heats
10
𝑄 = 𝑚𝐿
¨ A heat transfer of
Q = 9.5 × 105 J is required
to convert a block of ice at
Ti = -12 °C to Tf = 12 °C.
What was the mass of the
block of ice?
Quiz: 2
12
¨ Steam
¨ The hot steam first has to undergo a phase change into water
at 100 °C before cooling down. This releases additional
energy causing more severe burns.
Example: 3
14
¨ Phoenix
¨ In Phoenix, where the air is dry, more of the water will evaporate from your
skin because there is not much water vapor in the air.
¨ Evaporation is a phase change, where the water must absorb the heat of
vaporization from your skin.
¨ That is why you feel cool as the water evaporates.
¨ You may also feel colder when you are taking a shower with a bathroom
door open compared to when the door is closed.
Quiz: 4
17
¨ 50 cal/g
¨ The coefficient of latent heat of fusion is
the energy required to convert a substance
of unit mass from one phase to another.
Q
Q 50 cal
L= =
m 1.0 g
Quiz: 5
19
()*
¨ 0.25
+,-°
¨ The specific heat is the energy required to
raise the temperature of a substance of
unit mass by 1C°.
Q
0 45
()* ()*
¨ 𝑐= = = 0.25
1,23 4.5
+ 85
°- +,-°
ΔT
Water protects buds from cold weather
21
¨ When temperature falls a few degrees below 0 °C, fruit crop is in danger of being ruined.
¨ To protect the buds, farmers spray the trees with water.
¨ Water has large latent heat of fusion.
¨ Before the buds can freeze, the water must be cooled to 0 °C and then freeze.
¨ In this process, the water gives up heat and keeps the temperature of the buds from going
below 0 °C.
¨ The layer of ice over the buds acts like insulation because ice is not a good conductor of heat.