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JEE (Advanced)-2019
PAPER – 1
1. A, B
Sol. Q PEsin37 y
3
2R2 R E0
5
6 5 53
R3E0 mR2
5 3
O
18 RE0
25 m
x
Q
2. A, B, D
Sol. When the vessel starts accelerating then 2V00g
the sphere gets completely immersed in
the liquid of density 20.
So,
5 V00a 2V00a
T V0 20 0 a2 g2 V0 0 g .
3
H 53
53
(3/5)H T
V00g
3. A, C, D
Sol. PV = nRT
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AITS-FT-V (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 2
3
nRT nR(T0 V )
P
V V
1/ 3
dP T
0, V 0
dV 2
R(T0 T0 / 2) 3
Pmin 1/3
RT02/3 21/3 .
T0 2
2
4. B, C, D
1 1 1 90 cm
Sol.
v u f
v = 100 cm
100 cm
110 cm
5. A, B, C, D
Sol. On increasing frequency stopping potential and maximum kinetic energy of photoelectrons
increases.
Kmax = hf = eV0
If is decreased, Kmax and V0 both will increases.
With increases in distance between cathode and anode ‘f’ remains unchanged.
6. A, B, C, D
Sol. Equivalent resistance between P and Q = 100 6 amp 2 amp
400 A 4 amp
So current towards P = 4 ampere
100
10
Current through R = 6 4 = 2 ampere
400
So, R = 200
2 100
R
100
180
100 160
120
100 25
7. A
8. B
Sol. (for Q. 7 to Q. 8)
By the conservation of angular momentum about ‘O’
I1 I2 I0
Induced emf in the loop
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3 AITS-FT-V (Paper-1)-PCM(Sol.)-JEE(Advanced)/19
1
B 1 2 2
2
Torque on the rod OM about ‘O’
N
B 2 (1 2 ) B2 4 1
dr B r = = 0 22 M
0 4R
8R P
O 2 Q
B 2 4 0
I 2
4R 2 ‘B’
3B2 2
0
2 t
d2 3B 2 2 t
= dt 2 = 1 e 4mR
0 0 4mR 0 2
2
2
1 1 1
Heat produced = I02 I02 m 2 20
2 4 12
9. B
10. A
Sol. (for Q. 9 to Q. 10)
Let P2 is the initial pressure in upper chamber
mg
P2 P0 2P0
A
V2 = A 12 102 m3
Let P2 and V2 are final pressure and volume of upper chamber and lower piston moved by cm.
3
V2 A(28 )102 m
P2 V2 P2 V2
24P0
P2
28
Let P1 is initial pressure in lower chamber
2mg
P1 P0 3P0
A
3
V1 A 8 102 m
Let lower piston moved by ‘’ cm and P1 and V1 are final pressure and volume of lower chamber
mg 24P0 52
P1 P2 P0 P0
A 28 28
3
V1 A(8 )102 m
P1V1 P1V1
52
3P0 A 8 102 P0 A(8 )10
2
28
Solving this = 4 cm
52 4 5 2
P1 P0 2P0 2 10 N/m
28 4
24P0
P2 P0
28
V2 28 24
2
V1 8 12
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AITS-FT-V (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 4
SECTION – D
11. 04645.76
Sol. equation of parabola N
2
y = kx
y = h = ka2 v
h x
k 2 mg h
a
h 2
y 2 x a
a
3/ 2
dy 2
1 y
dx
R
d2 y
dx 2
1
R(x 0)
2k
mv 2
mg N
R
mv 2
N mg m(g v 2 2k) 4645.76 N
R
12. 00002.35
Sol. Flux passing through the loop ABCD
(8/5)
I I 8
0 dr 0 n (C, D)
2 r 2 5 (8/5)
D
0.47 10 37
0 2.35 0
2 37 74
I (A, B)
13. 00000.16
Sol. When DC source is connected resistance of inductor
15
R 6
2.5
When AC source connected
20
Z 10
2
Z2 R2 XL2
XL 8
2fL = 8
8 0.16
L
2 25
14. 00058.40
Sol. E2 E1 43.8
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5 AITS-FT-V (Paper-1)-PCM(Sol.)-JEE(Advanced)/19
E1
E1 43.8
(2)2
43.8 4
E1 58.40 eV
3
15. 00001.35
400 0 13.5 m
Sol. Qice = KA t
13.5 x Ice Water
Q KA(400 0)t (0C) x (100C)
So ice melt, m ice = ice …(i) 400C
LF 80(13.5 x)
(400 100)
Qwater = KA t
x
Q KA(400 100)
msteam water t …(ii)
Lv 540x
mice msteam
400 300
80(13.5 x) 540x
6(13.5 x) 54x
6 13.5 (54x 6x)
6 13.5
x 1.35 m
60
16. 00138.24
T / 2 O
x 2
Sol. dT 1 dx x
0 2
2 2 2 2
T 4 (3.6)2 (2)2 138.24
3 3 x dx
O
T + dT T
17. 00006.08
mR2
Sol. Idisc = I0 = kR4
4
mR2
I0
4
4
R
IPQ k (3 2)R I0 I0 2 I0 m( 2R)2
320 4mR2 320I0 16I0 304I0
18. 00002.16
2G
Sol. I 2 sin
R 2
Putting all values
I = 2.16 G newton/kilogram
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AITS-FT-V (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 6
Chemistry PART – II
SECTION – A
(One or More than one correct type)
This section contains 6 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four options is(are) correct.
19. B
Sol. 2Na2CrO 4 H2O 2CO 2 Na2Cr2O7 2NaHCO3
3K 2MnO4 2H2O 4CO2 2KMnO 4 MnO2 4KHCO3
20. A, B, D
21. A, B, C, D
22. A, B, C, D
23. B
24. C, D
25. B
26. A
Sol. (for Q. 25 to Q. 26)
H O Zn
H
Dehydration
I K
2
Aldol condensation
3o Alcohol O
H3C CH3
Ph CH2 OH L
Ph M H
OH OH 2 Ph CH3
H
OH2
CH3 Dehydration CH3
Ph Ph H Ph
Ph Ph
Ph H3C Ph
H3C O
O3 /Zn
Ph H
O O Ph I H
O O KOH
Ph C H H3C C Ph Aldol condensation
J K
O
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7 AITS-FT-V (Paper-1)-PCM(Sol.)-JEE(Advanced)/19
27. B
28. D
Sol. 2AgClO3 Cl2
90o C
2AgCl 2ClO2 O2
x
2ClO2 2O3 Cl2O6 2O2
y
Cl2 O6 2NaOH NaClO3 NaClO4 H2 O
4HClO 4 P4O10 2Cl2O7 4HPO3
SECTION – D
29. 00007.50
Sol. This is a buffer solution where H2PO 4 acts as the acid and NaH2PO4 is the salt.
HPO 4
pH pK 2 log
H2PO4
7.2 + log 2
7.50
30. 00009.00
Sol. (a) 5
O
O O
|| ||
(Except C2H5 C CH3 , CH3 C H, ,
(b) 4
31. 00003.50
Sol. a = 1; butan-2-ol
b = 3 (ethers)
c = 3 (1o alcohols)
32. 00001.60
Sol. pH = 12, pOH = 2
OH 10 2
33. 00002.25
Sol. 6 compounds has 1 mole each
NH4NO3 do not give O2
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AITS-FT-V (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 8
1
2LiNO3
Li2 O 2NO2 O2
1 mole 2 0.25 mole
2Ca NO3 2 2CaO 4NO2 O2
1 mole 0.5 mole
2AgNO3
2Ag 2NO2 O2
1 mole 0.5 mole
2NaNO3
Na2 O O2 NO NO2
1 mole 0.5 mole
Total number of moles of O2 evolved = 2.25
34. 00001.20
Sol. x = 6; (except H2CO3; CH3CO2H; H3BO3)
y=5
35. 00035.00
Sol. Co 2 6NH3 Co NH3 6
2
K 1 105
3
Co 3 6NH3 Co NH3 6 K 2 10 x
Co3 e
Co2 Eo 1.9 V
2 3
Co NH3 6 Co NH3 6 e E o 0.1 V
2 3
Co 3 Co NH3 6 Co 2 Co NH3 6 Eo 1.8 V
0.06 K
Eo log 2 (at equilibrium)
1 K1
K2
1.8 0.06log
105
K2
30 log
105
K 2 1035
36. 00900.00
k 2 30.8 298 4.606 308 208
Sol. log
k1 2.303 2 308 298
k
log 2 1
k1
k2
10
k1
k 2 10k1
10k1 k1
% increased (x) 100
k1
= 900.00
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9 AITS-FT-V (Paper-1)-PCM(Sol.)-JEE(Advanced)/19
37. A, B, D
Sol. Let An denotes number of codes which ends with 0 or 4, Bn denotes number of codes which ends
with 1 or 3 and Cn denotes number of codes which ends with 2
An + 1 = Bn = Cn + 1, Bn + 1 = An + 2Cn, N = 23·39
38. B, C
8
C4 1
Sol. For same number probability is 9
8
C4 C4
39. A, C
dy y 5t
Sol. Let (x, y) be the point on the path followed by dog, then
dx x
xy – y = –5t ..... (1)
On differentiating equation (1), w.r.t. x
dt 1 y 2
xy = –5 =
dx 2
40. B
Sol. Use IVT
Let h(x) = x11 – f(x)
h(0) < 0 and h(1) > 0
41. A, B
x2 y2
Sol. Locus of the mid-point is 1
a4e4 a4 e4
2 2
4a 4b
42. A, B
Sol. Let P, Q be (2, 0) and (6, 0) respectively
43. D
x 1 y 1 z 1
Sol. Equation of L is
4 3 1
44. D
x y z
Sol. Required line passes through (1, 1, 1) and parallel to
1 2 3
45. C
/2
sin1 x
3
Sol. f x x sin t x sin t ..... dt
0 1 x2
46. D
/2
sin1 x
x sin t x sin t
3
Sol. f x ..... dt
0 1 x2
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AITS-FT-V (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 10
SECTION – D
47. 00000.00
2r 1
n
cos 2
Sol. lim ncot
n
r 1 2r 1
48. 00001.00
Sol. Expanding (ex + 1)n – (ex – 1)n in two ways
49. 00001.00
Sol. (ae–iB + beiA)3 = (c + i(b sin A – a sin B))3 = c3
50. 00002.00
Sol. Use integration by parts, then use expansion
51. 00006.00
n
d2 8 d 8 nd 8 d
Sol. lim 1 2 lim
n ar n 8 8 n 1 d 8
r 1
52. 00023.00
Sol. P(x) = Q(x)(x – 1)(x – 2) + 2x + 3
P(10) = 72n + 23
53. 00001.00
Sol. From similar AEM and APE
AE AM
AP AE
AE2 = AM·AP = (AD – r)AP ..... (1)
AB both circles touches each other (R – r)2 = r2 + OD2 = r2 + (AD – R)2
AE = AD
54. 00351.00
7
Sol. C7 7C1 10 2 2 7C4 2
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