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1 AITS-CRT-IV (Paper-2)-PCM (Sol.

)-JEE(Advanced)/18

FIITJEE JEE(Advanced)-2018

ANSWERS, HINTS & SOLUTIONS


CONCEPT RECAPITULATION TEST - IV
PAPER-2

Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS


ALL INDIA TEST SERIES

1. A 24. D 47. B

2. A 25. B 48. B
3. A 26. C 49. B

4. BD 27. ABCD 50. AC


5. BC 28. ABCD 51. ABC

6. ACD 29. BCD 52. ABC

7. ABD 30. ABCD 53. ABCD


8. BC 31. AD 54. BCD

9. A 32. B 55. B

10. D 33. C 56. C


11. 3 34. 9 57. 1
12. 3 35. 2 58. 1
13. 3 36. 7 59. 3

14. 1 37. 4 60. 8

15. 7 38. 7 61. 1

16. 2 39. 7 62. 7


17. 4 40. 6 63. 3

18. 1 41. 5 64. 5


19. 2 42. 8 65. 5
20. 9 43. 7 66. 9
21. 00002.99 44. 00145.80 67. 02011.25
22. 00001.66 45. 00002.00 68. 05142.85

23. 00000.25 46. 00070.31 69. 00833.33

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AITS-CRT-IV (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 2

Physics PART – I

SECTION – A
1. A
2

  r  dy 
2
Rate of loss of water  2 gy
0
2. A
3. A
2 k mv 2 2 r
 ,T 
r r v
4. BD
5. BC
For the bubble, PV=const.
dV dP
 
V P
dV 3dr 4T
 , dP   , P  P0  according to the question 
V r R
4Tr
 dr 
3P0 R
6. ACD
7. ABD
8. BC
9. A
10. D
[9-10]
For the charge
   

F  q v  B  bv 
  
dv q  dr   b  dr 
    B  
dt m  dt  m  dt 

 q   b  r 
v 
m

r  B 
m

SECTION – C
11. 3
12. 3
13. 3
14. 1
15. 7
16. 2
17. 4
18. 1
Sol: The change in internal energy of the gas is DU = 1.5 nR (DT)= 1.5 (1 mol) (
253J/mol-K) (2K)
= 25 J.
The heat given to the gas = 42 J
The work done by the gas is DW = DQ – DU= 42 J – 25 J = 17 J.
If the distance moved by the piston is x, the work done is DW = (100 kPa) (8.5 cm2) x.
Thus, (105 N/m2) (8.5 × 10–4 m2) x = 17 J or, x = 0.2m = 20 cm.

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3 AITS-CRT-IV (Paper-2)-PCM (Sol.)-JEE(Advanced)/18

19. 2
t1 = RC; t2 = R/L
LC = t1t2 = 0.1 sec -> T = 2pie

T = 2 sec.
20. 9
SECTION – D
21. 00002.99
22. 00001.66
23. 00000.25

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AITS-CRT-IV (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 4

Chemistry PART – II

SECTION – A

24. D
25. B
26. C
27 ABCD
28. ABCD
29. BCD
30. ABCD
31. AD
32 B
33. C
Solutions
A  B +C C  B + D
1 0 0 α α 0

1-α α α α-β α+β β


1-α α+β α-β
(α-β)(α+β) β(α+β)
Kc1 = Kc 2 =
1-α α-β
[C] α-β 1 α 3
= = =
[B] α-β 5 β 2
Final Press=2[initial Press]
 + =1
3 2
So, α= β=
5 5
1
Kc1 = Kc 2 =2
2
Kc 2
4
Kc1
1000  0.006
m   12
0.5
12
α= =0.06
200
C1α12 =C2 α 22
α 2 =0.135
i=1.135
π=12.72atm
SECTION – C
34. 9
Sol. check structure of glycine amino acid
35. 2
Sol. due to – I effect

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5 AITS-CRT-IV (Paper-2)-PCM (Sol.)-JEE(Advanced)/18

36. 7

+ O

O
(P)
Sol.
37. 4
Sol. 4+6+6+12+12=40
z  4
38. 7
0.0591
Sol. E 0Cl- /AgCl/Ag =E Ag
0
+
/Ag
+ logK sp
1
 K sp  1010 then let x be solubility of AgCl in 0.01M solution of NaCl
 10 10  x ( x  0.01)
x=10-8 moles/L
39. 7
Sol. 4 and 6 particles are emitted.
40. 6
Sol. NaCN, Na 3PO 4 , Na 2CO3 , NaHCO3 , Na 2 C2O 4 , Na 2 HPO 4 these are basic.
41. 5
Sol. m=3 and n=2
42. 8
Sol. Process AC=polytropic process P=KV
R
So molar heat capacity C m =C v + =2R
2
5R
Process AB is isobaric C m =C p =
2
TC

q AC
 nCm dT
TA
  0.8
q AB TB
 nC p,mdT
TA

43. 7
except Na 2CO3 and BaCO3 all other are correct

SECTION – D

44. 00145.80
0 WA PA0 M A
Sol: P  748  648  100 then
liquid =
WB PB0 M B
 M A =145.8
45. 00002.00
Pb
Sol. Z=1+ high pressure
RT

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AITS-CRT-IV (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 6

dz b 1 RT 22.4  4 
So = = b   4 NA   r3 
dp RT 2.8 2.8 2.8  3 
 4 3
So 4  N A   r  for one mole of gas =2
 3 
46. 00070.31
Sol. m-eq. of Ba(MnO 4 ) 2 =m-eq.of H 2 O 2
 33.6 
 M   3
 11.2 
w
 10  1000  3  125  2;
375
w=28.125
w
% purity=  100
40
28.125
  100  70.31
40

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7 AITS-CRT-IV (Paper-2)-PCM (Sol.)-JEE(Advanced)/18

Mathematics PART – III

SECTION – A
47. B
x2 dx
 ( x cos x  sin x) ( x sin x  cos x)
 
f g

fg ' gf ' g ' f '


 
fg g f
g
 ln  c
f
48. B


A x1 , 1-x12 

B x 2 ,12-2 x 2 

P(t2,12-2t)
Q

y  12  2 x

P  (4,8)
 OP  16  64  80
PQ  OP  OQ
 80  1
49. B
50. AC
51. ABC
A  obvious
B  (adjA) 1
adj (adjA)

adjA
n 2
A A A
n 1

A A
C  A1  AT

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AITS-CRT-IV (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 8

1
(cofactor matrix)T  AT
A
 again transpose
1
(cofactor matrix)  A
A
If, A  1  aij  Aij
and A  1  aij  Aij
D  AAT  AT A  I
BB T  BT B  I
LHS ( AB ) BT AT

I

 AIA  AAT  I
T

Similarly ( A1 )( A1 )T  A1 ( AT )T  A1 A  I


52. ABC
 1  1  1   1 
Sol.  1   1   1   ...  1  
 2  4  6   2012 
1 3 5 7 2011 2012!
     ......   2012
2 4 6 8 2012 2 (1006!) 2
53. ABCD
Sol. point p on lineL1 P (2   ,1  7  , 2  5 )
P(4  r , 3  r ,  r )
Point P on line L2
   1, r  3
54. BCD
z
θ

 z1  π
(A) If arg   = then z1 and z 2
 z2  2
Subtend right angle at circum centre origin.
 the chord joining z1 and z 2 will subtend an angle  at z such that
π
θ= if z =1
4
π π
θ< if z >1 , θ> if z <1
4 4

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9 AITS-CRT-IV (Paper-2)-PCM (Sol.)-JEE(Advanced)/18

1 1 1
(B) z1 z2  z 2 z3  z3 z1  z1 z2 z3  
z1 z2 z3
 z1  z 2  z3
 ( z1  z2 )( z2  z3 )( z3  z1 )  ( z1  z 2 )( z 2  z3 )( z3  z1 ) 
(C)   
 z1 z2 z3  z1 z 2 z3 
(D)The triangle formed by joining z1 ,z 3and z 2 is isosceles and right angled at z3 .
55. B
56. C
Sol. (1)

C1
c2 C1
c2

C1
c2 c1 c2

. .
.
(2) A C B
AB=AC+BC
= 225  25  4r (9)  4( r )(4)

A B
A B
AB=AB 200= 4(9)r
50
4r(4) = 200,r=
9
25
r=
2

A B C
AC-BC=AB
4(9)r - 4(4)r = 200
2 r = 200
r=50

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AITS-CRT-IV (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 10

SECTION – C
57. 1
58. 1
H n+1 -H n
Sol: Tn =
H n H n+1
1
As H n+1 -H n =
n+1
1 1 1 1
 Tn =   T1 = 
H n H n+1 H1 H 2
1 1
T2 = 
H 2 H3
  
1 1
Tn = -
H n H n+1
1 1
T1 +T2 +...+Tn = -
H1 H n+1
As n  , T1 +T2 +...+0=1
59. 3
Sol. Given polynomial is a cubic with real coefficients  at least one real root and other are
conjugate complex zeroes.
Let a  x  iy , b  x  iy, c  2 x b
 abc  0
 a 2  b 2  c 2  250
 3 x 2  y 2  125
Using Pythagoras c a
2 2 2 2 2
9x  y  9x  y  4 y
y2
 3x2 
3
4 y2 h2 4 y 2
  125   3
3 125 125
60. 8
Sol. If a is the smallest element of such a set then 13-a is the largest and the remaining elements
12  2 a
can be choosen from 12-2a elements i.e., 2
Also, 13  a  a a7
Number of such set  210  28  26  ...  20  1365
 3  5  7 13
 Divisors divisible by 5 is 8.
61. 1
2
 1 1 1
Sol. Number of distinct terms in  x  y  z     is 18 and number of distinct terms in
 xy yz zx 

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11 AITS-CRT-IV (Paper-2)-PCM (Sol.)-JEE(Advanced)/18

2
 1 1 1
 x  y  z     is 19
 x y z
 mn 1
62. 7
Sol. Clearly a team of 4 with two batsman and two bowler can be formed as
Case-I: 2 bowler+2batsman
4 4
Number of ways= C 2 × C 2 =36
Case-II: 2 bowler+1 batsman +1 all-rounder
4
C 2 ×4 C1×1C1 =24
Case-III: 1bowler +2 batsman +1 all-rounder
4
C1×4 C 2 ×1C1 =24
24  24 4
Probability that all-rounder is selected= 
36  24  24 7
 p7
63. 3
Sol. For x-intercept y=0
 x2 a 3
 x  2  a  3or  3
 x  2  a  3 ora  3
For 3 x-intercepts
a+3>0and a-3=0 .....(i)
or a+3=0 and a-3>0 .....(ii)
From Eq. (i) a=3 and Eq. (ii) is rejected.
Hence, sum=3
64. 5
65. 5
66. 9
27 3
2
Sol.  xf '( x)dx    3 x f ( x3 )dx
0 0
3
x t
 3x2 dx  dt
27 27
 xf '( x) dx   f ( x ) dx  
0 0
27
   ( f ( x )  xf '( x)) dx  ( xf ( x)) 27
0
0
  27 f (27)  0
1 1
 27   9 {f is decreasing f (27)  }
3 3
SECTION – D
67. 02011.25
2007
Sol. dividend= x ,
2
Divisor= x  5x  6

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AITS-CRT-IV (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 12

Let Q(x)be quotient, R(x)=ax+b be remainder


x 2007 =Q(x).(x 2 -5x+6)+ax+b
x 2007 =Q(x).(x-2)(x-3)+ ax+b
 .....(i )
R( x)
Now R(0)=b=?
Put x=2 in Eq. (i)
2a  b  22007 ....(ii )
Put x=3 in Eq. (i)
3a+b=32007 .......(iii )
Eq. (iii)-Eq.(ii) gives
a  32007  2 2007
2007
Now b=2 -2a=22007 -2(32007 -22007 )=22007 +2.22007 -2.32007
=2.3[22006 -32006 ]=ab(a c -b c )
Hence a=2;b=3;c=2006
68. 05142.85
Sol. Consonants b,c,d,f,g,h (6)
Vowels a,e,i,o,u (5)
W:
Case I: If word begins with consonants
6 5
then ( C 4  4!)  ( C3  3!)=360  60=21600
Case II:If word begins with vowels
(5 C 4  4!)  (6 C3  3!)=120  120=12400
Total=3600
69. 00833.33
x x
Sol.  e
f (t )
dt   g ( x  t )dt  2 x  3
a 0
x x
f (t )
 e dt   g (t )dt  2 x  3 (Using King Property)
a 0
Differential both sides, we get
e f ( x)  g ( x)  2
 g ( x)  e f ( x)  2
 g '( x )  e f ( x ) . f '( x )
 e f ( x ) is always greater than zero.
sign of g’(x) is same as sign of f '( x) .
sign of g’(x)
  
-1 -2 ........... 96 97 98 99 100
Clearly, local extermum (maximum or minimum) will oxxur at
x=99,97,95,….,3,1
50
Sum of all the values=1+3+5+…+99= [2 1  (50  1)  2]  2500
2

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