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transport phenomena
Contents
1. Introduction to transport phenomena
2. Vector and Tensor analysis
3. Viscosity and mechanism of Momentum transport
4. Equations of change for isothermal systems
5. Energy Transport
6. Mass Transport
7. Analogies in heat, mass and momentum transport
Transport Phenomena
What exactly are "transport phenomena"?
Transport
Materials
Phenomena
Science
PROCESS
EQUIPMENT
DESIGN
Chemical
Reaction Process
Kinetics Economics
Examples
Consider a two phase continuous
A
stirred tank reactor.
• The reaction is of the form A going Catalyst
to B, and is catalyzed by a solid
catalyst.
• AB
• A is converted to B at the surface
of the solid catalyst B
• MICROSCOPIC
o Small region/volume element is selected
o Use of equations of change
o Velocity, temperature, pressure and concentration
profiles are determined
• MOLECULAR
o Molecular structure and intermolecular forces
become significant
o Complex molecules, extreme T and P, chemically
reacting systems
Vectors
SCALARS, VECTORS AND TENSORS
î ĵ y
x
18
SCALARS, VECTORS AND TENSORS
The velocity vector u is given as
dx dx dy dz
u î ĵ k̂
dt dt dt dt
The acceleration vector a is given as
du du dv dw d2x d2x d2y d2z
a î ĵ k̂ 2 2 î 2 ĵ 2 k̂
dt dt dt dt dt dt dt dt
The units that we will use in class are length L, time T, mass M and
temperature °. The units of a parameter are denoted in brackets. Thus
[x ] L
[u] LT1
[a ] ? LT2
Newton’s second law is a vectorial statement: where F denotes the
force vector and m denotes
the mass (which is a scalar)
F ma
19
SCALARS, VECTORS AND TENSORS
The dimensions of the force vector are the dimension of mass times
the dimension acceleration
[F] [Fx ] MLT 2
[g] LT202
SCALARS, VECTORS AND TENSORS
t xx t xy t xz
t t yx t yy t yz
t t zy t zz
zx
The stress tensor has 9 components. What do they mean? Use the
following mnemonic device: first face,
21 second stress
SCALARS, VECTORS AND TENSORS
Consider the volume element below.
z
tyy tyz
y
tyx
x
The face is in the direction y.
• The force per unit face area acting in the x direction on that face is
the stress tyx (first face, second stress).
• The forces per unit face area acting in the y and z directions on that
face are the stresses tyy and tyz.
• Here tyy is a normal stress (acts normal, or perpendicular to the
face) and tyx and tyz are shear stresses (act parallel to the face)
23
SCALARS, VECTORS AND TENSORS
Some conventions are in order
z
tyx
tyy tyz tyy
tyz y
tyx
x
Thus xi, xj and xp all refer to the same vector (x1, x2 and x3) , as the
index (subscript) always runs from 1 to 3.
25
SCALARS, VECTORS AND TENSORS
Scalar multiplication: let be a scalar and A = Ai be a vector.
Then A Ai (Ai, A2, A3 ) is a vector.
Dot or scalar product of two vectors results in a scalar:
A B A1B1 A2B2 A3B3 scalar
In index notation, the dot product takes the form
3 3 3
A B Ai Bi Ak Bk Ar Br
i 1 k 1 r 1
1 0 0
1 if i j
ij 0 1 0
0 if i j
0 0 1
Since there are two free indices, the result is a second-order tensor, or
matrix. The Kronecker delta corresponds to the identity matrix.
î ĵ k̂ î ĵ k̂
C det A1 A 2 A 3 A1 A 2 A3
B1 B2 B3 B1 B2 B3
î ĵ k̂ î ĵ î ĵ k̂ î ĵ
A1 A 2 A 3 A1 A 2 A1 A 2 A 3 A1 A2
B1 B2 B3 B1 B2 B1 B2 B3 B1 B2
ijuj ui
This manipulation works because the Kronecker delta ij = 0 except when
i = j, in which case it equals 1.
33
MECHANISMS OF
MOMENTUM TRANSPORT
Topics
• Definitions
• Properties at a point
• Molecular Transport of Momentum
• Convective Momentum Transport
Definitions
• Fluid: as a substance which deforms continuously under
the action of a shear stress.
ΔFn
ΔFs
Fn
lim ii
A A A
Fs ΔA
lim ij
A A A
vx(y)
t=0 Large t
V
• In this Figure :
o First: The system is at rest, but a time t= 0
o Second: At t= 0 the lower plate is set in motion in the
direction at a constant velocity
o Third: At time proceeds (Small t), the fluid gain
momentum
o Fourth: Ultimately the linear steady-state velocity
profile shown in the figure is established.
At steady-state motion, a constant force F is
required to maintain the motion of the lower plate.
The force is proportional to the area and to the
velocity and inversely proportional to the distance
between plates.
F V
(1)
A Y
Where F/A is , which is the force in the
direction x per unit area perpendicular to the y
direction.
It is the force exerted by the fluid of lesser y on the
fluid of greater y, therefore V/Y can be replaced by
–dvx/dy.
• The equation can also be written as
dvx (2)
yx
dy
Newton’s Law of viscosity
Where:
μ: viscosity of fluid, (Pa.s)
yx : Flux tensor (shear stress) in the positive y
direction , [(N/m2)= Pa]
vx: velocity in x direction, (m/s)
y: distance, (m)
Generalization of Newton’s Law of viscosity
• The equation (2) was defined only in terms of a simple
steady state shearing flowing in which vx as a function of y
alone, and vy and vz are zero.
• This situation is not really so common. Usually the system
is composed by a flow in which the three velocity
components may depend on all three coordinates and
possibly on time.
Consider
• A general flow pattern in which the velocity shows in
various directions depends on the time.
• The velocity components are given by
vx vx ( x, y, z, t );
vy v y ( x, y, z, t ),
vz v2 ( x, y, z, t )
• There will be then, 9 stress components (where i and j
may be taken on the designations (x, y, z), instead of the
component that appears in equation (2)
yx ij
Pressure and viscous forces acting on
planes
z
x, y, z
x
• The volume element can be cut to each of three
coordinates in turn.
• Find the forces that have been exerted on that surface by
the fluid that was removed.
• There will be two forces that contribute
o Associated with the pressure
o Associated with the viscous forces
• Pressure force
o Always perpendicular to the exposed surface
• For example in x direction the force will be a vector pδx that is the
pressure (a scalar) multiplied by the unit vector δx in the x
direction. Similarly for the other sections.
o Pressure forces will be exerted when the fluid is
stationary as well as when it is in motion
Viscous forces
• They exist only when there are velocity gradients
within the fluid.
• They are neither perpendicular nor parallel
xto the
surface element, rather at some angle to the
surface.
• Those forces represent in the Figure are vectors
with scalar components.
o For example, x has components xx , xy , xz
• Pressure and Viscous
Forces acting on y
planes
x x
pδy
pδx
z pδz
Two Ways to Interpret the definition
ij p ij ij
• force in the j direction on a unit area to the i
direction, where it is understood that the fluid in
the region of lesser xi is exerting the force on the
fluid of a greater xi.
• flux of j-momentum in the positive (+) i direction,
It is understood that is, from the region of lesser
xi to that of greater xi.
Convective Momentum Transport
• The momentum can be transported by bulk flow of
the fluid. This process is called convective
transport. Use the same figure on three planes
• The fluid vector at the centre is v
• The volume rate of flow across the area in the first
figure is vx. The fluid carries with it momentum ρv
per unit volume.
• Hence the momentum flux across this area is then
vxρv (vectors)
• Convective momentum
fluxes through planes
of unit area
perpendicular to the
coordinates direction x
pvyv
pvxv
pvzv
Shell momentum
balance and Velocity
distribution
Laminar Flow
Shell Momentum Balance
• Volume element
• Consist in the establishment of a region in the
space, within a specific system, at which the
fundamental physical laws are applied to obtain
equations to describe the phenomena that occur in
the system.
• It is a region characterized with a constant volume.
• The limit surfaces that limit this volume are called
control surfaces.
Volume control
L Solid surface
Δx
Sum
flow flow of
forces
density density
of of that are 0
momentum momentum acting
in out on
system
• Flow density
o Momentum at entry or exit the system by molecular
transport or by global fluid motion.
• Sum of forces
o Gravity force
o Pressure
Procedure to set and solve viscous flow
problems
Identify the no vanishing velocity component and
the spatial variable on which it depend.
Write a momentum balance over the thin shell
perpendicular to the relevant spatial variable.
Let the thickness of the shell approach zero and
make use of the definition of the first derivative to
obtain the corresponding differential equation for
the momentum flux.
Procedure to set and solve viscous flow
problems (Cont.)
• Integrate this equation to get the momentum flux
distribution.
• Insert Newton’s Law of viscosity and obtain a
differential equation for the velocity.
• Integrate this equation to get the velocity
distribution.
• Use the velocity distribution to get other quantities,
such as the maximum velocity, average velocity,
or force on solid surface.
Boundary conditions
• Considerations
o There is not material passing through the interface
(there is not adsorption, absorption, dissolution,
evaporation, melting or chemical reaction at the surface
between the two phases.
Boundary conditions
• At solid-fluid interfaces
• The fluid velocity is equal the velocity with which the solid
surface is moving.
• This statement is applied to both the tangential and normal
component of the velocity vector.
• The base of this statement can be found in the roughness
of the surface and the adhesion forces between solid and
fluid.
Boundary Conditions
• At liquid-liquid interfacial plane
• The velocity and flux tensor have the same value in both
faces.
• The flow density (stress-tensor) and the velocity are
continuous through the interface
Boundary Conditions
• At liquid-gas interfacial plane of constant x, the
stress-tensor components xy and xz are taken to
be zero.
• The gas side velocity gradient is not too large
• The momentum is practically nor being transfer,
therefore for calculation purposes can assumed
that
dv
0 or 0
dy
Flow of a falling film
L
L
Width = B x
y Volume
element
Momentum
Out
Δx
Gravity
force
Considerations
• Isothermal, laminar and stationary flow of a falling film
down an inclined flat plane of length L and width B.
• The plane is α angle with respect of the gravity force.
• Newtonian fluid
• The viscosity and density are constant.
Considerations (Cont.)
• The length (L ) is sufficiently small or taken very
far from both extreme, therefore the velocity
distribution is not affected.
• The film has a small thickness δ in x-direction and
B in z-direction.
• The volume element has a width B and finite
thickness Δx.
• The force that produce the fluid motion is a
component of the gravity force – gy= ρcosα
Considerations (Cont.)
• The direction of the flow is taken in the positive
direction of the coordinates axis.
• The flow density xy at the entry and exit of the
volume element is evaluated at the position with
respect to the location of coordinates axis
(molecular transport).
Considerations
• The flow density at the entry and exit of the volume due to
the bulk of fluid is evaluated at the position with respect to
the location of coordinates axis (convective transport). It is
represented by ρvyvy. This magnitude is also evaluated for
the inlet and outlet points for y = 0 and y = L.
• Applying the general equation of momentum balance and
multiplying each term by the magnitude that transform this
balance of momentum in force balance
BL xy x xy
1 2 x x
( Bx) v y2 v 2
y 0 y
3 4 yL
BLx g cos 0
5
• Terms 3 and 4 are the equal (ρvyvy) in y =0 and y
=L. Can be eliminated.
• Therefore the equation is
BL xy x xy BLx g cos 0
1 2 x x 5
multiplying by (1/ BLx) and taken
xy x xy
x x
g cos
1 2
lim
x 0 x
• The left term of the equation by definition is the
first derivate of xy with respect to x, therefore,
d xy
g cos
dx
• Integrating xy ( g cos ) x C1
xy ( g cos )( x )
Velocity Distribution
• Based on the assumption of Newtonian fluid,
then,
dv
xy y ((ggcos
dv y
cos)()(xx))
xy dx
dx
dvyy ((ggcos
dv
cos))( x)
dx ( x)
dx
int
integrating
• Integrating, egrating
((ggcos
) x 2
2
vvy cos )((xx ))CC2
x
y 22 2
• Applying BC:2; x = 0 and vy = 0, then C2=0
( g cos ) 2
x
vy ( x )
2
• Using this expression we can determine the
maximum velocity, average velocity, mass flow
rate, film thickness and force of the fluid in the
solid surface.
• Maximum Velocity (x =δ and (dvy/dx) = 0
( g cos )
2
v ymax
2
• Average velocity
• Mass flow rate
B
w v y dxdz B v y
0 0
L B
Fy ( xy x ) dxdy
0 0
Flow Through a Circular Tube
Assumptions:
1. Steady-state flow
2. Incompressible fluid
3. Only Vx component is significant
4. At the solid-liquid interface, no-slip condition
Recall: Cylindrical Coordinates
Flow Through a Circular Tube
pressure : PA z 0 PA z L
net momentum flux : rz A1 r rz A2 r r
P 2 r r z 0 P 2 r r z L rz 2 rL r rz 2 rL r r 0
Dividing by 2 Lr :
P z 0 P z L rz r r rz r r r
r 0
L r
Let x 0 :
P0 PL d
r rz r 0
L dr
Flow Through a Circular Tube
P0 PL d
r rz r 0
L dr
P0 PL C1 r zero!
rz r
2L r
Flow Through a Circular Tube
P0 PL
rz r
2L
From the definition of flux: BOUNDARY CONDITION!
dv At r = R, vz = 0.
rz z
dr
P P
0 0 L R2 C2
4 L
Plugging in: P P
C2 0 L R2
dv z P0 PL 4 L
r
dr 2L
P0 PL 2 P0 PL 2
P0 PL 2 vz r R
vz r C2 4 L 4 L
4 L
Flow Through a Circular Tube
P0 PL 2 2
vz R r
4 L
Average Velocity:
2 R
zv dA v rdrd z
v z v z , ave 0
0
dA rdrd
2 R
0 0
Hagen-Poiseuille Equation
P0 PL 2
v ave D
32L
water
air
ethyl
alcohol
Non-Newtonian Fluids
blood
ketchup
toothpaste
Non-Newtonian Fluids
grease
polymer melt
cake batter
Non-Newtonian Fluids
whipped cream
Non-Newtonian Fluids
• Foods
o Emulsions (mayonnaise, ice cream)
o Foams (ice cream, whipped cream)
o Suspensions (mustard, chocolate)
o Gels (cheese)
• Biofluids • Electronic and Optical Materials
o Suspension (blood) – Liquid Crystals (monitor
o Gel (mucin) displays)
o Solutions (spittle) – Melts (soldering paste)
• Personal Care Products • Pharmaceuticals
o Suspensions (nail polish, face scrubs) – Gels (creams, particle
precursors)
o Solutions/Gels (shampoos,
conditioners) – Emulsions (creams)
o Foams (shaving cream)
– Aerosols (nasal sprays)
• Polymers
Non-Newtonian Fluids
f
τ
2
0 – Newtonian fluid
1 – Bingham plastics
2 – pseudoplastic fluids
0 3 – dilatant fluids
slope η
3
• When the viscosity decreases with increasing shear rate, we call the
fluid shear-thinning.
• In the opposite case where the viscosity increases as the fluid is
subjected to a higher shear rate, the fluid is called shear-thickening.
• Shear-thinning behavior is more common than shear-thickening.
• Shear-thinning fluids also are called pseudoplastic fluids.
• We describe the relationship between the shear stress
and shear rate as follows.
• Here, η is called the “apparent viscosity” of the fluid, and is
a function of the shear rate.
• Many shear-thinning fluids will exhibit Newtonian behavior
at extreme shear rates, both low and high.
• For such fluids, when ln(apparent viscosity) is plotted
against ln(shear rate), we see a curve like this.
Non-Newtonian Fluids
• Or
• After integration,
•
• The final expression for the shear stress (or momentum flux)
distribution and velocity are found to be
• (ii) The average velocity is obtained by dividing the volumetric flow rate
by the cross-sectional area as shown below.
• Thus, the ratio of the average velocity to the maximum velocity for
Newtonian fluid flow in a narrow slit is 2/3.
Non-Newtonian (Power law)
• For the region 0 ≤ x ≤ B, the velocity decreases with increasing x and
therefore dVz / dx ≤ 0. On the other hand, for the region −B ≤ x ≤ 0, the
velocity decreases with decreasing x and therefore dvz / dx ≥ 0. Thus,
the power law model is given as
• Combining both,
• Total Time Derivative: This accounts for the fact that the
observer is moving (how c varies
with t because of changing location).
This is a specific case of the
• Substantial Time Derivative : Total Time Derivative for which the
velocity v of the observer is the
same as the velocity of the flow. It
is also called the Derivative
Following the Motion
7
Equation of Continuity
differential control volume:
Equation of Continuity
• Rate of Mass accumulation
= (Rate of Mass In) - (Rate of Mass Out)
• Rate of Mass In through face at x is
r r r r vx v y vz
vx vy vz r
t x y z x y z
Dr vx v y vz
r r v
Dt x y z
Continuity equation
• For incompressible fluids r / t = 0, and the equation
becomes:
div v = 0.
vx v y vz ui
• Alternative ways to write this: x y z 0 and x 0
i
12
Different forms of the continuity equation
D
r dV r U dS 0 r dV 0
t V S Dt V
Integral form Integral form
Conservation form Non conservation form
U
r Dr
( rU) 0 r U 0
t Dt
Differential form Differential form
Conservation form 13
Non conservation form
Differential Equation of Continuity In
cylindrical coordinates:
d r 1 r rvr 1 r v r vz
0
dt r r r z
y
where r x y , tan
2 2 1
x
If fluid is incompressible:
vr vr 1 v vz
0
r r r z
Equations of Motion
Fluid is flowing in 3
directions
Momentum
transport is fully
defined by 3
equations of
motion
Momentum Balance
Consider the x-component of the momentum
transport: Sum of forces
Rate of Rate of Rate of
acting in
accumulation x momentum in x momentum out x
the system x
Rate of Rate of
momentum in x momentum out x
Rate of Rate of
momentum in x momentum out x convective
Rate of Rate of
momentum in x momentum out x molecular
Momentum Balance
r v y vx r v y vx DxDz
y y Dy
Sum of forces
Rate of Rate of Rate of
acting in
accumulation x momentum in x momentum out x
the system x
Rate of Rate of
momentum in x momentum out x
Rate of Rate of
momentum in x momentum out x convective
Rate of Rate of
momentum in x momentum out x molecular
Due to convective transport:
Rate of Rate of
momentum in x momentum out x convective
r vx vx x r vx vx x Dx DyDz
r v y vx r v y vx DxDz
y y Dy
Rate of Rate of
momentum in x momentum out x molecular
xx x xx x Dx DyDz
yx yx DxDz
y y Dy
Sum of forces
acting in px px Dx DyDz r g x DxDyDz
the system
x
Consider the x-component of the momentum
transport:
Sum of forces
Rate of Rate of Rate of
acting in
accumulation x momentum in x momentum out x
the system x
Rate of r vx
DxDyDz
accumulation x t
Substituting:
r vx
DxDyDz r vx vx x r vx vx x Dx DyDz
t
r v y v x r v y v x DxDz
y y Dy
yx yx DxDz
y y Dy
px px Dx
rg
Dx
x
Taking the limit as ∆x, ∆y and ∆z 0:
r vx r vx vx r v y vx r v z v x
t x y z
xx yx zx p
r gx
x y z x
Rearranging:
r vx r vx vx r v y vx r vz vx
t x y z
xx yx zx p
r gx
x y z x
For the convective terms:
r vx vx r v y vx r vz vx
x y z
vx vx vx r vx r v y r vz
r vx vy vz vx
x y z x y z
For the accumulation term:
r vx vx r
r vx
t t t
vx vx v y vz r r r
r vx r vx vy vz
t x y z x y z
Substituting:
v y v y v y v y xy yy zy p
r r vx vy vz r gy
t x y z x y z y
Assumptions
1. Newtonian fluid
2. Obeys Stokes’ hypothesis *
3. Continuum
4. Isotropic viscosity
5. Constant density
Navier-Stokes Equations
Dvx p 2 vx 2 vx 2 vx
r r gx 2 2 2
Dt x x y z
Dv y p vy vy vy
2 2 2
r r gy 2 2 2
x
Dt y y z
Dvz p 2 vz 2 vz 2 vz
r r gz 2 2 2
Dt z x y z
Dv
r p r g 2 v
Dt
Navier-Stokes Equations
vr vr v vr v2 vr
r vr vz
t r r r z
p 1 rvr 1 2 vr 2 vr vr
2
r gr 2 2 2
r r r r r r z
2
Integration of the Euler’s equation along a stream line gives the Bernoulli eqn.
Application
Viscous flow:
vx vx vx vx
2 2 2
r vx 2 2 2
x x y z
Application
The Navier-Stokes equations may be reduced
using the following simplifying assumptions:
5. Semi-infinite system
Dy Dx, Dz
Dz
Dy
Dx
vx vx vx vx
2 2 2
r vx 2 2 2
x x y z
Application
The Navier-Stokes equations may be reduced
using the following simplifying assumptions:
6. Laminar flow (no convective transport)
vx vx2
r vx 2
x y
vx 2
2 0 vx c1 y c2
y
Application
The Navier-Stokes equations may be reduced
using the following simplifying assumptions:
6. Laminar flow (no convective transport)
Boundary conditions:
1 at y 0 lower plate , vx v0
v0
c2 v0 , c1
2 at y upper plate , vx 0
v0 y
vx y v0 or vx v0 1
Example
Example 1 (bent pipe), page 47
r1,V1
Bx y
Area=A1 Area=A2=A1 x
By
r2,V2
Fx P1 A1 P2 A2 Cos( ) Bx
Fy 0 P2 A2 Sin( ) W By
Weight of Fluid
Example
out in
V1
By
Area=A1 Area=A2=A1
Q
Bx
V2
V1 V2Cos( )
Bx P1 A1 P2 A2 Cos( ) m
By P2 A2 Sin( ) W m
V2 sin( )
Example
P1,V1 Pipe with U turn
P2,V2
P1 “L” bend
E
F
Total Force y Fy P2 A2
direction
P2
Fluxx rV A1
1
2
Fty Q(u2 y u1 y )
u1 y u1 sin 0 0
u2 y u2 sin
Fty Qu2 sin
• Calculate the pressure force
F p = pressure force at 1 - pressure force at 2
Fpx = p1 A1 cos 0 – p2 A2 cos θ = p1 A1 – p2 A2 cos θ
Fpy = p1 A1 sin 0 – p2 A2 sin θ = – p2 A2 sin θ
R = - Fresultant
Force on a pipe nozzle
Force on the nozzle at the outlet of a pipe. Because
the fluid is contracted at the nozzle forces are
induced in the nozzle. Anything holding the nozzle
(e.g. a fireman) must be strong enough to withstand
these forces.
• The same analysis will be followed as before.
• Step in Analysis:
1. Draw a control volume
2. Decide on co-ordinate axis system
3. Calculate the total force
4. Calculate the pressure force
5. Calculate the body force
6. Calculate the resultant force
• 1 & 2 Control volume and Co-ordinate axis are shown in
the figure above.
• 3 Calculate the total force
FT FTx Q(u2 u1 )
Using the continuity, Q = A u
1 1
FTx Q ( )
2
A2 A1
• 4 Calculate the pressure force
p1 u12 p2 u22
z1 gz2 h f
g 2 g g 2 g
Friction is neglected for short distance and the nozzle is
horizontal i.e. z1 and z2 are equal and p2 is atmospheric
i.e. 0 and with continuity
Q 2 1 1
p1 ( 2 2)
2 A2 A1
• 5 Calculate the body force
The only body force is the weight due to gravity in the y-
direction - but we need not consider this as the
only forces we are considering are in the x-direction.
R FRx
Example
Example 1 (bent pipe), page 47
1,V1
Bx y
Area=A1 Area=A2=A1 x
By
2,V2
Fx P1 A1 P2 A2 Cos( ) Bx
Fy 0 P2 A2 Sin( ) W By
Weight of Fluid
Example
out in
V1
By
Area=A1 Area=A2=A1
Q
Bx
V2
V1 V2Cos( )
Bx P1 A1 P2 A2 Cos( ) m
By P2 A2 Sin( ) W m
V2 sin( )
Example
P1,V1 Pipe with U turn
P2,V2
P1 “L” bend
E
F
Total Force y Fy P2 A2
direction
P2
Fluxx V A1
1
2
22
Work done by surface stresses in x-direction
v x zx |z z xy
v x yx |x xz v x yx |x x xz
v x p |x yz v x p |x x yz
v x xx |x yz v x xx |x x yz
z
y v x zx |z xy
x
Work done is force times velocity. 23
Work done by surface stresses
• The total rate of work done by surface stresses is
calculated as follows:
o For work done by x-components of stresses add all
terms in the previous slide.
o Do the same for the y- and z-components.
• Add all and divide by xyz to get the work done per unit
volume by the surface stresses:
( v x xx ) ( v x yx ) ( v x zx ) ( v y xy )
div ( pu)
x y z x
( v y yy ) ( v y zy ) ( v z xz ) ( vz yz ) ( v z zz )
y z x y z
24
Energy flux due to heat conduction
qz |z z xy
q y |y y xz
qx |x yz
qx |x x yz
z
y
x
qz |z xy q y |y xz
The heat flux vector q has three components, qx, qy, and qz.
25
Energy flux due to heat conduction
• Summing all terms and dividing by xyz gives the net rate of
heat transfer to the fluid particle per unit volume:
q x q y q z
div q
x y z
• Fourier’s law of heat conduction relates the heat flux to the
local temperature gradient:
T T T
qx k qy k qz k
x y z
• In vector form: q k grad T
• Thus, energy flux due to conduction: div q div(k grad T )
• This is the final form used in the energy equation.
26
Energy equation
• Setting the total derivative for the energy in a fluid particle
equal to the previously derived work and energy flux terms,
results in the following energy equation:
DE ( v x xx ) ( v x yx ) ( v x zx ) ( v y xy )
div ( pu)
Dt x y z x
( v y yy ) ( v y zy ) ( v z xz ) ( v z yz ) ( v z zz )
y z x y z
div ( k grad T ) S E
D[ 12 (u 2 v 2 w 2 )] xx yx zx
u.grad p u
Dt x y z
xy yy zy xz yz zz
v w u. S M
x y z x y z
28
Internal energy equation
• Subtract the kinetic energy equation from the energy
equation.
• Define a new source term for the internal energy as
Si = SE - u.SM. This results in:
Di u u u v
p div u xx yx zx xy
Dt x y z x
v v w w u
yy zy xz yz zz
y z x y z
div (k grad T ) S i
29
Enthalpy equation
• An often used alternative form of the energy equation is
the total enthalpy equation.
o Specific enthalpy h = i + p/.
o Total enthalpy h0 = h + ½ (u2+v2+w2) = E + p/.
( h0 )
div( h0u) div(k grad T )
t
(u xx ) (u yx ) (u zx ) (v xy )
x y z x
(v yy ) (v zy ) ( w xz ) ( w yz ) (u zz )
y z x y z
Sh
30
Equations of state
• Fluid motion is described by five partial differential
equations for mass, momentum, and energy.
• Amongst the unknowns are four thermodynamic variables:
, p, i, and T.
• We will assume thermodynamic equilibrium, i.e. that the
time it takes for a fluid particle to adjust to new conditions
is short relative to the timescale of the flow.
• We add two equations of state using the two state
variables and T: p=p(,T) and i=i(,T).
• For a perfect gas, these become: p= RT and i=CvT.
• At low speeds (e.g. Ma < 0.2), the fluids can be considered
incompressible. There is no linkage between the energy
equation, and the mass and momentum equation. We then
only need to solve for energy if the problem involves heat
transfer. 31
Viscous stresses
• A model for the viscous stresses ij is required.
• We will express the viscous stresses as functions of the
local deformation rate (strain rate) tensor.
• There are two types of deformation:
o Linear deformation rates due to velocity gradients.
• Elongating stress components (stretching).
• Shearing stress components.
o Volumetric deformation rates due to expansion or
compression.
• All gases and most fluids are isotropic: viscosity is a scalar.
• Some fluids have anisotropic viscous stress properties,
such as certain polymers and dough. We will not discuss
those here.
32
Heat Transfer
Mekonnen Gebrehiwot
Objectives
• Understand the basic mechanisms of heat transfer,
• Identify the mechanisms of heat transfer that occur
simultaneously in practice
• Develop an awareness of the cost associated with
heat losses
• Solve various heat transfer problems encountered in
practice
2
HEAT TRANSFER
• Heat: The form of energy that can be transferred from one
system to another as a result of temperature difference.
• Heat Transfer deals with the determination of the rates of
such energy transfers as well as variation of temperature.
• The transfer of energy as heat is always from the higher-
temperature medium to the lower-temperature one.
• Heat transfer stops when the two mediums reach the same
temperature.
• Heat can be transferred in three different modes:
conduction, convection, radiation
3
Heat Transfer supplements the First and Second Laws of Thermodynamics,
with additional rules to analyse the Energy Transfer RATES.
4
Application Areas of Heat Transfer
5
Energy Transfer
Energy can be transferred to or from a given mass
by two mechanisms: heat transfer and work. when is constant:
Heat transfer rate: The amount of heat transferred
per unit time.
Heat flux: The rate of heat transfer per unit area
normal to the direction of heat transfer.
6
HEAT TRANSFER MECHANISMS
• Heat can be transferred in three basic modes:
o conduction
o convection
o Radiation
15
Thermal Diffusivity
cp Specific heat, J/kg · °C: Heat capacity
per unit mass
cp Heat capacity, J/m3·°C: Heat capacity
per unit volume
Thermal diffusivity, m2/s: Represents
how fast heat diffuses through a material
0 °C
25 °C
Solution:
(a) Noting that heat transfer through the roof is by conduction and the
area of the roof is:
A= 6 m×8 m=48 m2.
The steady rate of heat transfer through the roof is determined to be
ሶ
𝑄=kA(T 1-T2)/L= (0.8)(48 )(25-0)/0.25= 3840 W= 3.84 kW
(b) The amount of heat lost through the roof during a 10-hour period and
its cost are determined from
Q = 𝑄tሶ =(3.84 kW)(10 h) = 38.4 kWh Why is the
Cost/day = (Amount of energy)(Unit cost of energy) bill so high?
= (38.4 kWh)($0.2/kWh) =$7.68
Cost/month = (cost/day)×(30day/month)= $7.68×30=$230.4
CONVECTION
• Convection: The mode of
energy transfer between a
solid surface and the
adjacent liquid or gas that
is in motion, and it involves
the combined effects of
conduction and fluid
motion.
• The faster the fluid motion,
the greater the convection
heat transfer.
• In the absence of any bulk
fluid motion, heat transfer
Heat transfer from a hot surface to air
between a solid surface
by convection.
and the adjacent fluid is by
pure conduction. 19
• Forced convection: If the fluid
is forced to flow over the
surface by external means
such as a fan, pump, or the
wind.
• Natural (or free) convection:
If the fluid motion is caused by
buoyancy forces that are
induced by density differences
due to the variation of The cooling of a boiled egg by
temperature in the fluid. forced and natural convection.
Heat transfer processes that involve change of phase of a fluid are also
considered to be convection because of the fluid motion induced during
the process, such as the rise of the vapor bubbles during boiling or the
fall of the liquid droplets during condensation.
20
Newton’s law of cooling
Stefan–Boltzmann law
= 5.670 108 W/m2 · K4 Stefan–Boltzmann constant
Blackbody: The idealized surface that emits radiation at the maximum rate.
24
Radiation emitted by real surfaces
27
When a surface is completely enclosed by a much larger (or black)
surface at temperature Tsurr separated by a gas (such as air) that does
not intervene with radiation, the net rate of radiation heat transfer
between these two surfaces is given by
28
Summary
Heat Transfer Mechanisms
Conduction
Fourier’s law of heat conduction
Thermal Conductivity
Thermal Diffusivity
Convection
Newton’s law of cooling
Radiation
Stefan–Boltzmann law
Summary
Most gases between two solid surfaces Although there are three mechanisms of heat
do not interfere with radiation. transfer, a medium may involve only two of
them simultaneously.
Liquids are usually strong absorbers of
31
radiation.
When radiation and convection occur simultaneously between a
surface and a gas:
32
Thermal Resistance
Δx
R is called thermal
resistance
33
• Similarly for convection,
• For Radiation,
34
Combined Thermal Resistance
• Often, Convection and Radiation act together
o The resistances of convection and radiation are considered as a
single resistance:
35
Combined Thermal Resistance
• The total thermal resistance is given by,
• If the object considered has different layers, one can easily simulate
this by introducing the appropriate thermal resistances.
• one can also introduce contact resistances between different layers.
36
Multilayered plane walls
37
Parallel Walls
• Uniform Temperature at 1 and 2
• Heat flux split between sections
• Thermal Resistance based on local
areas
• Set up system of equations based upon
energy balance into nodes
39
40
Conduction in Cylinders and spheres
Consider steady heat conduction through a hot-water pipe.
• Heat transfer happens in the normal direction to the pipe surface.
• Fluid temperatures inside and outside the pipe remain constant,
o Thus heat transfer modeled as steady and one-dimensional.
43
• Thus heat transfer modeled as steady and one-dimensional:
• For a cylinder,
2𝜋𝑟𝐿
• For a sphere,
44
Critical radius of insulation
• We know
o Adding more insulation to a plane wall decreases heat transfer
o The thicker the insulation, the lower the heat transfer rate
o This is expected, since the heat transfer area A is constant, and
adding insulation always increases the thermal resistance of
the wall without increasing the convection resistance.
46
The critical radius of insulation for a cylindrical body:
II-48
Conduction
• Fourier’s Law
II-49
Heat Conduction Analysis- 1D
• 1-D (plane wall)
II-50
II-51
Heat Conduction Analysis- 1D
II-52
Heat Conduction Analysis-3D
1) Cartesian coordinates
II-53
1) Cartesian coordinates
II-54
Heat Conduction Analysis- 3D
General 3-Dimension Heat Conduction equation:
1) Cartesian coordinates
If, k = constant
II-55
Thermal Diffusivity
• The larger value of α, the faster heat will diffuse through
the material.
II-56
Heat Conduction Analysis- 3D
3-Dimension Heat Conduction equation:
2) Cylindrical coordinates
3) Spherical coordinates
II-57
Convection Heat Transfer
II-58
• Heat transfer by convection varies from situation
to situation (upon the fluid flow conditions), and it
is frequently coupled with the mode of fluid flow.
• In practice, analysis of heat transfer by
convection is treated empirically (by direct
observation).
• Convection heat transfer is treated empirically
because of several factors:
o Fluid velocity
o Fluid viscosity
o Heat flux
o Surface roughness
o Type of flow (single-phase/two-phase)
II-59
Convection
• Heat transfer in the presence of a fluid motion on a solid surface
•Various mechanisms at play in the fluid:
- advection physical transport of the fluid
- diffusion conduction in the fluid
- generation due to fluid friction
•But fluid directly in contact with the wall does not move relative to it; hence
direct heat transport to the fluid is by conduction in the fluid only.
U y U T
q y
u(y) T(y)
Ts
y T
T U
qconv kf h Ts T T(y)
y y 0
T
Ts
depends
But y y 0 on the whole fluid motion, and both fluid flow
and heat transfer equations are needed
Convection
Free or natural convection
(induced by buoyancy May occur with
forces) phase change
Convection (boiling,
condensation)
forced convection (driven
externally)
Common classifications:
A. Based on geometry:
External flow / Internal flow
B. Based on driving mechanism
Natural convection / forced convection / mixed convection
C. Based on number of phases
Single phase / multiple phase
D. Based on nature of flow
Laminar / turbulent
How to solve a convection problem ?
• Solve governing equations along with boundary conditions
• Governing equations include
1. conservation of mass
2. conservation of momentum
3. conservation of energy
• In Conduction problems, only (3) is needed to be solved.
Hence, only few parameters are involved
• In Convection, all the governing equations need to be
solved.
large number of parameters can be involved
Forced convection: Non-dimensional groupings
• Nusselt No. Nu = hx / k = (convection heat transfer strength)/
(conduction heat transfer strength)
• Prandtl No. Pr = / = (momentum diffusivity)/ (thermal diffusivity)
• Reynolds No. Re = U x / = (inertia force)/(viscous force)
Viscous force provides the dampening effect for disturbances in the
fluid. If dampening is strong enough laminar flow
Otherwise, instability turbulent flow critical Reynolds number
d d
Laminar Turbulent
FORCED CONVECTION:
external flow (over flat plate)
An internal flow is surrounded by solid boundaries that can restrict the
development of its boundary layer, for example, a pipe flow. An external flow, on
the other hand, are flows over bodies immersed in an unbounded fluid so that the
flow boundary layer can grow freely in one direction. Examples include the flows
over airfoils, ship hulls, turbine blades, etc.
bles •Fluid particle adjacent to the
solid surface is at rest
T
Ts
•These particles act to retard the
motion of adjoining layers
x q
• boundary layer effect
Momentum balance: inertia forces, pressure gradient, viscous forces,
body forces
Energy balance: convective flux, diffusive flux, heat generation, energy
storage
h=f(Fluid, Vel ,Distance,Temp)
Hydrodynamic boundary layer
One of the most important concepts in understanding the external flows is the
boundary layer development. For simplicity, we are going to analyze a boundary
layer flow over a flat plate with no curvature and no external pressure variation.
U U Dye streak
U U
laminar turbulent
transition
Boundary layer definition
Boundary layer thickness (d): defined as the distance away from the surface
where the local velocity reaches to 99% of the free-stream velocity, that is
u(y=d)=0.99U. Somewhat an easy to understand but arbitrary definition.
Boundary layer is usually very thin: d/x usually << 1.
Hydrodynamic and Thermal
boundary layers
The Thermal Boundary Layer is a region of a fluid flow, near a solid surface,
where the fluid temperatures are directly influenced by heating or cooling
from the surface wall.
0<t<T, 0<y<dt
The two boundary layers may be expected to have similar characteristics but
do not normally coincide. Liquid metals tend to conduct heat from the wall
easily and temperature changes are observed well outside the dynamic
boundary layer. Other materials tend to show velocity changes well outside
the thermal layer.
Effects of Prandtl number, Pr
d dT
dT d, dT d
Pr >>1 Pr = 1 Pr <<1
>> = <<
e.g., oils e.g., air and gases e.g., liquid metals
have Pr ~ 1
(0.7 - 0.9)
u T TW
similar to
U T TW
(Reynold’s analogy)
Boundary layer equations (laminar flow)
• Simpler than general equations because boundary layer is thin
T
U
U
y dT
d
x TW
• Equations for 2D, laminar, steady boundary layer flow
u v
Conservation of mass : 0
x y
u u dU u
Conservation of x - momentum : u v U
x y dx y y
T T T
Conservation of energy : u v
x y y y
dU
• Note: for a flat plate, U is constant, hence 0
dx
Exact solutions: Blasius
d 4.99
Boundary layer thickness
x Re x
w 0.664
Skin friction coefficient C f 1
2 U
2
Re x
Re U x , u
x
w
y
y 0
UL
L
1 1.328
Average drag coefficient C D C f dx Re L
L0 Re L
Nu x 0.339 Re x Pr
1 1
Local Nusselt number 2 3
N u 0.678 Re L Pr
1 1
Average Nusselt number 2 3
Heat transfer coefficient
• Local heat transfer coefficient:
1 1
Nu x k 0.339k Re x Pr 2 3
hx
x x
• Average heat transfer coefficient:
1 1
Nu k 0.678k Re L Pr 2 3
h
L L
• Recall: qw h ATw T , heat flow rate from wall
x Hydrodynamic
Boundary Layer, d
C D 0.072 Re L
1
Re L
0.072 Re 0xc.8 1.328 Re 0xc.5
Nu x 0.029 Re 0x.8 Pr
1
3
N u 0.036 Re 0L.8 Pr 3 Pr 3 0.036 Re 0xc.8 0.664 Re 0xc.5
1 1
Nu k
* Calculate heat transfer coefficient in usual way : h etc.
x
Forced convection over exterior bodies
• Much more complicated.
•Some boundary layer may exist, but it is likely
to be curved and U will not be constant.
• Boundary layer may also separate from the
wall.
• Correlations based on experimental data can
be used for flow and heat transfer calculations
• Reynolds number should now be based on a UD
characteristic diameter. Re
D
Pr.62
Nu C Re m
D
Prs.25
Re D C m
1 40 0.75 0.4
40 - 103 0.51 0.5
103 - 2 105 0.26 0.6
2 105 - 106 0.08 0.7
constant
x
xfd,t
II-80
II-81
Natural Convection
• The procedures for calculating h are very
similar with the forced convection
• calculate first the Nusselt number and from
its value the coefficient of convection
• Difference: No external source - Re cannot
be used and should be replaced by
another number: the Grashof number (Gr)
II-82
• Quite often in practice, the Grashof number and Prandtl
number appear always combined as a product.
• This is why a new number was defined, the Rayleigh
number:
II-83
II-84
Example 1
Engine oil at 60°C flows over a 5 m long flat plate
whose temperature is 20°C with a velocity of 2 m/s.
Determine the rate of heat transfer per unit width of
the entire plate.
II-85
Example 2
Air at a temperature of 30 °C and 6 kPa pressure flow
with a velocity of 10 m/s over a flat plate 0.5 m long.
Estimate the heat transferred per unit width of the
plate needed to maintain its surface at a temperature
of 45 °C.
II-86
Solution:
Properties of the air evaluated at the film temperature
o Tf = 75/2 = 37.5 oC
From air properties table at 37.5 oC:
o = 16.95 x 10-6 m2/s.
o k = 0.027 W/m. oC
o Pr= 0.7055
o Cp= 1007.4 J/kg. oC
Note: These properties are evaluated at atmospheric
pressure, thus we must perform correction for the
kinematic viscosity
• ) act. = )atm.x (1.0135/0.06) = 2.863 x10-4 m2/s.
II-87
II-88
Example 3
Water at 25 °C is in parallel flow over an isothermal,
1-m long flat plate with velocity of 2 m/s. Calculate the
value of average heat transfer coefficient.
II-89
Example 4
A vertical 1.2 m high and 1.8 m wide double-pane window
consists of two sheets of glass separated by a 2.5 cm air gap at
atm pressure. If the glass surface temperatures across the air
gap are measured to be 20°C and 4°C, Determine the rate of
heat transfer through the window by:
a) natural convection,
b) radiation.
II-90
Mass Transfer
INTRODUCTION
Whenever there is an imbalance of a commodity in a medium, nature tends to
redistribute it until a “balance” or “equality” is established. This tendency is often referred
to as the driving force, which is the mechanism behind many naturally occurring
transport phenomena.
The commodity simply creeps away during
redistribution, and thus the flow is a diffusion
process. The rate of flow of the commodity is
proportional to the concentration gradient
dC/dx, which is the change in the concentration
C per unit length in the flow direction x, and the
area A normal to flow direction.
kdiff is the diffusion coefficient of the medium, which is a measure of how fast a
commodity diffuses in the medium, and the negative sign is to make the flow in the
positive direction a positive quantity (note2that dC/dx is a negative quantity since
concentration decreases in the flow direction).
The diffusion coefficients and thus diffusion rates of gases
depend strongly on temperature.
The diffusion rates are higher at higher temperatures.
The larger the molecular spacing, the higher the diffusion rate.
Diffusion rate: gases > liquids > solids
3
ANALOGY BETWEEN HEAT AND MASS
TRANSFER
We can develop an understanding of mass transfer in a short time with
little effort by simply drawing parallels between heat and mass transfer.
Temperature
The driving force for mass transfer is
the concentration difference.
Both heat and mass are transferred
from the more concentrated regions
to the less concentrated ones.
If there is no difference between the
concentrations of a species at
different parts of a medium, there will
be no mass transfer.
4
Conduction
Mass is transferred by conduction (called diffusion) and convection only.
Rate of mass Fick’s law of
diffusion diffusion
5
Heat Generation
Heat generation refers to the conversion of some form of energy such
as electrical, chemical, or nuclear energy into sensible thermal energy
in the medium.
Some mass transfer problems involve chemical reactions that occur
within the medium and result in the generation of a species throughout.
Therefore, species generation is a volumetric phenomenon, and the
rate of generation may vary from point to point in the medium.
Such reactions that occur within the medium are called homogeneous
reactions and are analogous to internal heat generation.
In contrast, some chemical reactions result in the generation of a
species at the surface as a result of chemical reactions occurring at the
surface due to contact between the medium and the surroundings.
This is a surface phenomenon, and as such it needs to be treated as a
boundary condition.
In mass transfer studies, such reactions are called heterogeneous
6
reactions and are analogous to specified surface heat flux.
Convection
Mass convection (or convective mass transfer) is the mass transfer mechanism
between a surface and a moving fluid that involves both mass diffusion and bulk
fluid motion.
Fluid motion also enhances mass transfer considerably.
In mass convection, we define a
concentration boundary layer in an
analogous manner to the thermal boundary
layer and define new dimensionless
numbers that are counterparts of the
Nusselt and Prandtl numbers.
Newton’s law
of cooling
Rate of mass
convection
1 Mass Basis
On a mass basis, concentration is expressed in
terms of density (or mass concentration).
9
Special Case: Ideal Gas Mixtures
At low pressures, a gas or gas mixture can conveniently be approximated as
an ideal gas with negligible error.
The total pressure of a gas mixture P is equal to the sum of the partial
pressures Pi of the individual gases in the mixture..
Here Pi is called the partial pressure of species i,
which is the pressure species i would exert if it
existed alone at the mixture temperature and volume
(Dalton’s law of additive pressures).
Then using the ideal gas relation PV = NRuT where
Ru is the universal gas constant for both the species i
and the mixture, the pressure fraction of species i can
be expressed as
14
STEADY MASS DIFFUSION THROUGH A WALL
Many practical mass transfer problems involve the diffusion of a species through a
plane-parallel medium that does not involve any homogeneous chemical reactions under
one-dimensional steady conditions.
diffusion resistance of 15
the wall
The rate of mass diffusion through a plane wall is
proportional to the average density, the wall area,
and the concentration difference across the wall, but
is inversely proportional to the wall thickness.
16
Steady one-dimensional mass transfer
through nonreacting cylindrical and
spherical layers
On a molar basis
17
MASS CONVECTION
Now we consider mass convection (or convective mass transfer), which is the
transfer of mass between a surface and a moving fluid due to both mass diffusion
and bulk fluid motion.
The analogy between heat and mass convection holds for both forced and natural
convection, laminar and turbulent flow, and internal and external flow.
Mass convection is also complicated because of the complications associated with
fluid flow such as the surface geometry, flow regime, flow velocity, and the variation
of the fluid properties and composition.
Therefore, we have to rely on experimental relations to determine mass transfer.
Mass convection is usually analyzed on a mass basis rather than on a molar basis.
19
A Schmidt number of near unity
(Sc = 1) indicates that momentum
and mass transfer by diffusion are
comparable, and velocity and
concentration boundary layers
almost coincide with each other.
20
The relative thicknesses of velocity, thermal, and
concentration boundary layers in laminar flow:
average mass
transfer coefficient
23
hmass is the mass transfer coefficient
DAB is the mass diffusivity.
The Nusselt and Sherwood numbers
represent the effectiveness of heat
and mass convection at the surface,
respectively.
26
Analogy between Friction, Heat Transfer, and Mass
Transfer Coefficients
27
Special Case: Pr Sc 1 (Reynolds Analogy)
28
To develop the equations which describe pollutant concentration in the plug of fluid
as it flows down the PFR,
Conduct a mass balance on a control volume which encloses a section of the PFR of
infinitesimally small thickness dx, as shown.
Since the thickness is small, we can assume that the fluid in that region of the PFR is
well-mixed. The mass balance equation for this control volume is We have set equal
to zero, indicating that this is a steady-state problem. We are assuming here that
Plug-Flow Chemical Reactor
z A
k
B
r kCA
• Assumptions
o Pure reactant A in feed stream
o Perfect plug flow
o Steady-state operation
o Isothermal operation
o Constant physical properties (r, k)
Plug-Flow Chemical Reactor cont.
z
• Overall mass Component balance
balance (QC A ) z (QC A ) z Dz kC A ADz 0
( r Q ) z ( r Q ) z Dz 0
A in A out A consumed
Q ( C A ) z ( C A ) z Dz
Mass in Mass out
lim kC A 0
(Q ) z (Q ) z Dz
Dz 0 A Dz
lim 0
Dz 0
Dz
Q dC A
kC A 0
dQ A dz
0 Q dC A
dz kC A 0 C A (0) C Ai
Qi Q0 Q A dz
Practice problems
3. Water at 20 °C flows between two large stationary parallel plates which are 2 cm apart.
If the maximum velocity is 1m/s, determine (a) average velocity, (b) the velocity
gradients at the plates and (c) the difference in pressure between two points 10 m
apart. Viscosity of water at 20 °C is 0.001 Pa-s. Consider the flow to be a fully developed
one.
4. A mixture of He and N2 gas is contained in a pipe at 298 K and 1 atm total pressure
which is constant throughout. At one end of the pipe at point (1) the partial pressure
pA1 of He is 0.60 atm and at the other end 0.2 m, pA2 = 0.20 atm. Calculate the flux of
He at steady state if DAB of the He-N2 mixture is 0.687 cm2/s.
5. Heat conduction in an annulus.
(a) Heat is flowing through an annular wall of inside
radius r0 and outside radius r1 as in the Figure. The
thermal conductivity varies linearly with temperature
from k0 at T0 to k1 at T1. Develop an expression for the
heat flow through the wall.
(b) Show how the expression in (a) can be simplified
when r1 − r0 is very small. Interpret the result physically.
6. Review the application of shell balance theory for flow through an annulus found in the
text book (BSL, page 57).
Practice problems
3. Water at 20 C flows between two large stationary parallel plates which are 2 cm apart.
If the maximum velocity is 1m/s, determine (a) average velocity, (b) the velocity
gradients at the plates and (c) the difference in pressure between two points 10 m
apart. Viscosity of water at 20 C is 0.001 Pa-s. Consider the flow to be a fully developed
one.
4. A mixture of He and N2 gas is contained in a pipe at 298 K and 1 atm total pressure
which is constant throughout. At one end of the pipe at point (1) the partial pressure
pA1 of He is 0.60 atm and at the other end 0.2 m, pA2 = 0.20 atm. Calculate the flux of
He at steady state if DAB of the He-N2 mixture is 0.687 cm2/s.
5. Heat conduction in an annulus.
(a) Heat is flowing through an annular wall of inside
radius r0 and outside radius r1 as in the Figure. The
thermal conductivity varies linearly with temperature
from k0 at T0 to k1 at T1. Develop an expression for the
heat flow through the wall.
(b) Show how the expression in (a) can be simplified
when r1 − r0 is very small. Interpret the result physically.
6. Review the application of shell balance theory for flow through an annulus found in the
text book (BSL, page 57).
1. The General Continuity Equation can be written in terms of concentration c as
follows:
(1)
where s is the source of the quantity c per unit volume and unit time.
In such case, the ‘source’ term s is properly speaking a ‘sink’ and has a negative value.
Under first-order chemical kinetics, the rate of removal of the chemical is proportional
to its own concentration.
s = −Kc, where K is a constant of decay, with dimension equal to the inverse of time.
(2)
To solve this equation, we need to know the initial concentration of the pollutant.
Let us denote it as c(x, t = 0) = c0(x).
If there were no chemical degradation (K = 0), this patch would simply move
downstream without change, and the solution would be c(x, t) = c0(x − ut), which
corresponds to a mere translation down the x–axis by the traveled distance ut. On the
other hand, if there were no movement (u = 0) and only chemical degradation, the
solution would be c(x, t) = exp(−Kt) c0(x), which is the initial distribution attenuated
over time. Combining these two limiting solutions, it is not difficult to show that the
distribution of concentration corresponding to the combined case of advection and
degradation at any later time t is given by
(3)
Now, we track the maximum of the concentration over time. Equation (3) tells
that the maximum at time t is the initial maximum times the factor exp(−Kt).
The contamination episode ends when the maximum concentration falls to the
drinking standard and thus at time t such that (0.005 mg/L) = exp(−Kt)× (0.025
mg/L).
The solution is exp(−Kt) = 0.005/.025 = 0.20, giving Kt = 1.609 and t = 8.047
days =6.953 × 105 s.
Over this time, the river water has traveled a distance ut = (0.15 m/s)(6.953 ×
105 s)= 104.3 km. Thus, more than 100 kilometers of river are being
contaminated, and the episode will last slightly more than 8 days.
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