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JEE ( Main ) Examination–2019/Morning Session/12-01-2019

TEST PAPER OF JEE(MAIN) EXAMINATION – 2019


(Held On Saturday 12th JANUARY, 2019) TIME : 9 : 30 AM To 12 : 30 PM
CHEMISTRY
1. Iodine reacts with concentrated HNO3 to yield 5. Freezing point of a 4% aqueous solution of X
Y along with other products. The oxidation is equal to freezing point of 12% aqueous
state of iodine in Y, is :- solution of Y. If molecular weight of X is A,
(1) 5 (2) 3 (3) 1 (4) 7 then molecular weight of Y is :-
Ans. (1) (1) A
2. The major product of the following reaction is: (2) 3A
(3) 4A
CN
(4) 2A
(i) DIBAL-H Ans. (2)
O +
(ii) H3O 6. Poly-b-hydroxybutyrate-co-b-
O
hydroxyvalerate(PHBV) is a copolymer of___.
CHO (1) 3-hydroxybutanoic acid and
CHO
4-hydroxypentanoic acid
(1) (2) O
EN (2) 2-hydroxybutanoic acid and
O
O 3-hydroxypentanoic acid
(3) 3-hydroxybutanoic acid and
CHO CH=NH 2-hydroxypentanoic acid
(3) (4) (4) 3-hydroxybutanoic acid and
OH OH
3-hydroxypentanoic acid
OH
CHO Ans.. (4)
7. Among the following four aromatic
LL
Ans. (3)
compounds, which one will have the lowest
3. ˆˆˆ
In a chemical reaction, A + 2B ‡ˆˆ
K
†
ˆ 2C + D,, melting point ?
the initial concentration of B was 1.5 times of
the concentration of A, but the equilibrium (1)
concentrations of A and B were found to be
equal. The equilibrium constant(K) for the
A

aforesaid chemical reaction is : O

(2) OH
1
(1) 16 (2) 4 (3) 1 (4) OH
4
O
Ans. (2)
4. Two solids dissociate as follows
CH3
ˆˆ† B(g) + C(g) ; K = x atm2
A(s) ‡ˆˆ p 1
O
ˆˆ† C(g) + E(g) ; K = y atm2 (3)
D(s) ‡ˆˆ p2
O
The total pressure when both the solids CH3
dissociate simultaneously is :-
(1) x2 + y2 atm (2) x2 + y2 atm OH
(4)
(3) 2 ( x + y atm ) (4) x + y atm
Ans. (1)
Ans. (3)
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JEE ( Main ) Examination–2019/Morning Session/12-01-2019
13. Given
OH
Gas H2 CH3 CO2 SO2
8. CH3CH2 –C–CH3 cannot be prepared by : Critical 33 190 304 630
Ph Temperature/K
(1) HCHO + PhCH(CH3)CH2MgX On the basis of data given above, predict which
(2) PhCOCH 2CH3 + CH3MgX of the following gases shows least adsorption
on a definite amount of charcoal ?
(3) PhCOCH3 + CH3CH2MgX
(1) H2 (2) CH4
(4) CH 3CH2COCH3 + PhMgX
(3) SO2 (4) CO2
Ans. (1)
Ans. (1)
9. The volume of gas A is twice than that of gas
14. For diatomic ideal gas in a closed system,
B. The compressibility factor of gas A is thrice
which of the following plots does not correctly
than that of gas B at same temperature. The
describe the relation between various
pressures of the gases for equal number of
thermodynamic quantities ?
moles are :
(1) 2PA = 3PB
(2) PA = 3PB Cv Cp
(3) PA = 2PB (1) (2)
(4) 3PA = 2PB
Ans. (1)
EN
10. The element with Z = 120 (not yet discovered)
T P

will be an/a :
(1) transition metal Cv U
(2) inner-transition metal (3) (4)
(3) alkaline earth metal V T
LL
(4) alkali metal
Ans. (3) Ans. (2)
11. Decomposition of X exhibits a rate constant of 15. The standard electrode potential E ! and its
0.05 mg/year. How many years are required for
the decomposition of 5 mg of X into 2.5 mg ? æ dE ! ö
temeprature coefficient ç ÷ for a cell are 2V
(1) 50 (2) 25 è dT ø
A

(3) 20 (4) 40
and –5 × 10–4 VK–1 at 300 K respectively. The
Ans.(1)
cell reaction is
12. The major product of the following reaction is :
Zn(s) + Cu2+ (aq) ® Zn2+(aq) + Cu(s)
CH3O (1) Cl2/CCl4
(2) AlCl3(anhyd.)
( )
The standard reaction enthalpy D r H! at 300

K in kJ mol–1 is,
Cl Cl [Use R = 8jK–1 mol–1 and F = 96,000 Cmol–1]
(1) –412.8 (2) –384.0
(1) CH3O (2) CH3O (3) 206.4 (4) 192.0
Ans. (1)
16. The molecule that has minimum/no role in the
CH3O CH3O formation of photochemical smog, is :
(3) (4) (1) CH2 = O (2) N2
Cl
Cl (3) O3 (4) NO
Ans. (4) Ans. (2)
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JEE ( Main ) Examination–2019/Morning Session/12-01-2019
17. In the Hall-Heroult process, aluminium is 20. What is the work function of the metal if the
formed at the cathode. The cathode is made out light of wavelength 4000 Å generates
of : photoelectrons of velocity 6 × 105 ms–1 form
(1) Platinum it ?
(2) Carbon (Mass of electron = 9 × 10–31 kg
Velocity of light = 3 × 108 ms–1
(3) Pure aluminium
Planck's constant = 6.626 × 10–34 Js
(4) Copper
Charge of electron = 1.6 × 10–19 JeV–1)
Ans. (2)
(1) 0.9 eV
18. Water samples with BOD values of 4 ppm and
(2) 4.0 eV
18 ppm, respectively, are : (3) 2.1 eV
(1) Highly polluted and Clean (4) 3.1 eV
(2) Highly polluted and Highly polluted Ans. (3)
(3) Clean and Highly polluted 21. Among the following compounds most basic
(4) Clean and Clean amino acid is :
Ans. (3) (1) Lysine
19. In the following reactions, products A and B (2) Asparagine
are :
O

H3C H3C CH3


O

H
dil NaOH
EN [A]
Ans.
22.
(3) Serine
(4) Histidine
(4)
The metal d-orbitals that are directly facing the
+
ligands in K3[Co(CN)6] are :
H 3O (1) dxz, dyz and dz2
[A] [B]
D (2) dxy, dxz and dyz
(3) dxy and dx2–y2
LL
O O
OH H2C (4) dx2–y2 and dz2
H3C H H
(1) A = ; B= Ans. (4)
H3C 23. The hardness of a water sample (in terms of
CH3 H3C CH3
equivalents of CaCO 3 ) containing 10 –3 M
CaSO4 is :
O O (molar mass of CaSO4 = 136 g mol –1)
A

OH CH3
C (1) 100 ppm
H3C H H
(2) A = ; B= (2) 50 ppm
H3C CH3 H3 C CH3 (3) 10 ppm
(4) 90 ppm
O O Ans. (1)
CH3 CH3 24. The correct order for acid strength of
(3) A = CH3 ; B = CH3 compounds
HO CHºCH, CH 3–CºCH and CH2=CH2
is as follows :
O O (1) CH º CH > CH2 = CH2 > CH3–C º CH
CH3 CH3
(2) HC º CH > CH3 –C º CH > CH2 = CH2
(4) A = CH3 ; B = CH3
(3) CH3–C º CH > CH2 = CH2 > HC º CH
HO
(4) CH3–C º CH > CH º CH > CH2 = CH2
Ans. (4) Ans. (2)

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JEE ( Main ) Examination–2019/Morning Session/12-01-2019
25. Mn2(CO)10 is an organometallic compound due 27. The pair of metal ions that can give a spinonly
to the presence of : magnetic moment of 3.9 BM for the complex
(1) Mn – Mn bond [M(H2O)6]Cl2, is :
(2) Mn – C bond (1) Cr2+ and Mn2+ (2) V2+ and Co2+
(3) Mn – O bond (3) V2+ and Fe2+ (4) Co2+ and Fe2+
Ans. (2)
(4) C – O bond
28. In the following reaction
Ans. (2)
HCl
26. The increasing order of reactivity of the Aldehyde + Alcohol ¾¾¾ ® Acetal
following compounds towards reaction with Aldehyde Alcohol
alkyl halides directly is : HCHO tBuOH

CH3CHO MeOH
O O The best combinations is :
(1) HCHO and MeOH
NH 2 NH (2) HCHO and tBuOH
(3) CH3CHO and MeOH
(A) O
(4) CH3CHO and tBuOH
(B)
Ans. (1)

CN
NH2
EN
NH2
29. 50 mL of 0.5 M oxalic acid is needed to
neutralize 25 mL of sodium hydroxide solution.
The amount of NaOH in 50 mL of the given
sodium hydroxide solution is :
(C) (D) (1) 40 g (2) 20 g (3) 80 g (4) 10 g
Bonus
(1) (B) < (A) < (D) < (C) 30. A metal on combustion in excess air forms X,
(2) (B) < (A) < (C) < (D) X upon hydrolysis with water yields H2O2 and
LL
(3) (A) < (C) < (D) < (B) O2 along with another product. The metal is :
(4) (A) < (B) < (C) < (D) (1) Rb (2) Na (3) Mg (4) Li
Ans. (2) Ans. (1)
A

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