CONFI-MUL XHT

Scomi Oiltools Chemwatch Hazard Alert Code: 2

Chemwatch: 4880-60 Issue Date: 03/12/2013
Version No: 2.1.1.1 Print Date: 29/08/2014
Safety Data Sheet according to CLASS requirements Initial Date: Not Available
L.GHS.MYS.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier
Product name CONFI-MUL XHT
Chemical Name Not Applicable
Synonyms Not Available
Proper shipping name Not Applicable
Chemical formula Not Applicable
Other means of
Not Available
identification
CAS number Not Applicable

Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses HT Emulsifier.

Details of the manufacturer/importer

Registered company name Scomi Oiltools
Address Level 17, 1 First Avenue, Bandar Utama Selangor Malaysia
Telephone +603 7717 3000
Fax +603 7728 5202
Website www.scomigroup.com.my
Email info@scomigroup.com.my

Emergency telephone number

Association / Organisation Not Available
Emergency telephone
+800 2436 2255
numbers
Other emergency telephone
+800 2436 2255
numbers

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

CHEMWATCH HAZARD RATINGS

Min Max
Flammability 1
Toxicity 1 0 = Minimum
Body Contact 2 1 = Low
2 = Moderate
Reactivity 1 3 = High
Chronic 0 4 = Extreme

GHS Classification Skin Corrosion/Irritation Category 2, Eye Irritation Category 2

Label elements

GHS label elements

SIGNAL WORD WARNING

Hazard statement(s)

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CONFI-MUL XHT

H315 Causes skin irritation

H319 Causes serious eye irritation

Precautionary statement(s): Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection.

Precautionary statement(s): Response

P321 Specific treatment (see advice on this label).
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P302+P352 IF ON SKIN: Wash with plenty of water and soap

Precautionary statement(s): Storage

Not Applicable

Precautionary statement(s): Disposal

Not Applicable

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Substances
See section below for composition of Mixtures

Mixtures
CAS No %[weight] Name GHS Classification
tall oil fatty acid amides/
68990-47-6 50-60 Skin Corrosion/Irritation Category 2, Eye Irritation Category 2; H315, H319[1]
maleic anhydride
Not Available 15-25 polybasic acids Not Applicable

isoparaffins petroleum STOT - SE (Narcosis) Category 3, Aspiration Hazard Category 1, Acute Aquatic Hazard Category 1,
64742-47-8 5-15
hydrotreated HFP Chronic Aquatic Hazard Category 1; H336, H304, H400, H410[1]
dipropylene glycol
34590-94-8 5-15 STOT - SE (Resp. Irr.) Category 3, STOT - SE (Narcosis) Category 3; H335, H336[1]
monomethyl ether

Legend: 1. Classified by Chemwatch; 2. Classification drawn from EC Directive 67/548/EEC - Annex I; 3. Classification drawn from EC Directive 1272/2008 - Annex VI

SECTION 4 FIRST AID MEASURES

Description of first aid measures

If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Eye Contact Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Skin Contact
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
If fumes or combustion products are inhaled remove from contaminated area.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
Inhalation
Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.
Transport to hospital, or doctor.
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
Observe the patient carefully.
Ingestion
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5 FIREFIGHTING MEASURES

Extinguishing media
Water spray or fog.
Foam.
Dry chemical powder.
BCF (where regulations permit).

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CONFI-MUL XHT

Special hazards arising from the substrate or mixture

Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Advice for firefighters

Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Fire Fighting
Prevent, by any means available, spillage from entering drains or water course.
Use water delivered as a fine spray to control fire and cool adjacent area.
Combustible.
Slight fire hazard when exposed to heat or flame.
Fire/Explosion Hazard
Heating may cause expansion or decomposition leading to violent rupture of containers.
On combustion, may emit toxic fumes of carbon monoxide (CO).

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Remove all ignition sources.
Clean up all spills immediately.
Minor Spills
Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Moderate hazard.
Clear area of personnel and move upwind.
Major Spills
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves.

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Safe handling
Other information
DO NOT allow clothing wet with material to stay in contact with skin
Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Prevent concentration in hollows and sumps.
Store in original containers.
Keep containers securely sealed.
No smoking, naked lights or ignition sources.
Store in a cool, dry, well-ventilated area.

Conditions for safe storage, including any incompatibilities

Suitable container
Storage incompatibility
Metal can or drum
Packaging as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Vigorous reactions, sometimes amounting to explosions, can result from the contact between aromatic rings and strong oxidising agents.
Aromatics can react exothermically with bases and with diazo compounds.

PACKAGE MATERIAL INCOMPATIBILITIES

Not Available

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

OCCUPATIONAL EXPOSURE LIMITS (OEL)

INGREDIENT DATA
Source Ingredient Material name TWA STEL Peak Notes
Malaysia Permissible
isoparaffins petroleum hydrotreated HFP Stoddard solvent 525 mg/m3 / 100 ppm Not Available Not Available Not Available
Exposure Limits
Malaysia Permissible
dipropylene glycol monomethyl ether Dipropylene glycol methyl ether 606 mg/m3 / 100 ppm Not Available Not Available skin
Exposure Limits

EMERGENCY LIMITS
Ingredient TEEL-0 TEEL-1 TEEL-2 TEEL-3
CONFI-MUL XHT Not Available Not Available Not Available Not Available

Ingredient Original IDLH Revised IDLH

tall oil fatty acid amides/ maleic
Not Available Not Available
anhydride
polybasic acids Not Available Not Available

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CONFI-MUL XHT

isoparaffins petroleum
29,500 mg/m3 20,000 mg/m3
hydrotreated HFP
dipropylene glycol monomethyl
Unknown mg/m3 / Unknown ppm 600 ppm
ether

MATERIAL DATA
None assigned. Refer to individual constituents.
NOTE P: The classification as a carcinogen need not apply if it can be shown that the substance contains less than 0.01% w/w benzene. Note E shall also apply when the substance is classified
as a carcinogen.

Exposure controls
Appropriate engineering
controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly
effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and
"removes" air in the work environment.

Personal protection

Safety glasses with side shields.

Chemical goggles.
Eye and face protection
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of
lenses or restrictions on use, should be created for each workplace or task.
Skin protection See Hand protection below
Wear chemical protective gloves, e.g. PVC.
Wear safety footwear or safety gumboots, e.g. Rubber
NOTE:
Hands/feet protection
The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other protective equipment, to avoid
all possible skin contact.
Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.
Body protection See Other protection below
Overalls.
Other protection P.V.C. apron.
Barrier cream.
Thermal hazards Not Available

Recommended material(s) Respiratory protection

GLOVE SELECTION INDEX Type AK-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI
Glove selection is based on a modified presentation of the: Z88 or national equivalent)
"Forsberg Clothing Performance Index". Where the concentration of gas/particulates in the breathing zone, approaches or exceeds the
The effect(s) of the following substance(s) are taken into account in the computer- "Exposure Standard" (or ES), respiratory protection is required.
generated selection: Degree of protection varies with both face-piece and Class of filter; the nature of protection
CONFI-MUL XHT Not Available varies with Type of filter.

Material CPI Required Minimum Half-Face Full-Face Powered Air

Protection Factor Respirator Respirator Respirator
* CPI - Chemwatch Performance Index
AK-AUS / Class AK-PAPR-AUS /
A: Best Selection up to 5 x ES -
1 P2 Class 1 P2
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion up to 25 x ES Air-line* AK-2 P2 AK-PAPR-2 P2
NOTE: As a series of factors will influence the actual performance of the glove, a final
up to 50 x ES - AK-3 P2 -
selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent basis, factors such as 50+ x ES - Air-line** -
"feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwise
be unsuitable following long-term or frequent use. A qualified practitioner should be consulted. * - Continuous-flow; ** - Continuous-flow or positive pressure demand
^ - Full-face
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen
cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G =
Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
Methyl bromide, AX = Low boiling point organic compounds(below 65 degC)

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance Dark viscous liquid with a characteristic odour; does not mix with water.

Physical state Liquid Relative density (Water = 1) 0.96

Partition coefficient
Odour Not Available Not Available
n-octanol / water
Auto-ignition temperature
Odour threshold Not Available Not Available
(°C)

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CONFI-MUL XHT

Decomposition
pH (as supplied) Not Available Not Available
temperature
Melting point / freezing
Not Available Viscosity (cSt) Not Available
point (°C)
Initial boiling point and
Not Available Molecular weight (g/mol) Not Applicable
boiling range (°C)
Flash point (°C) >65 Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Combustible. Oxidising properties Not Available
Surface Tension (dyn/cm or
Upper Explosive Limit (%) Not Available Not Available
mN/m)
Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water (g/L) Miscible pH as a solution(1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available

SECTION 10 STABILITY AND REACTIVITY

Reactivity See section 7

Unstable in the presence of incompatible materials.
Chemical stability Product is considered stable.
Hazardous polymerisation will not occur.
Possibility of hazardous
See section 7
reactions
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decomposition
See section 5
products

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

The material is not thought to produce respiratory irritation (as classified by EC Directives using animal models). Nevertheless inhalation of vapours, fumes or
aerosols, especially for prolonged periods, may produce respiratory discomfort and occasionally, distress.
Inhaled Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal handling, may be damaging to the health of the
individual.
The acute toxicity of inhaled alkylbenzenes is best described by central nervous system depression.
Accidental ingestion of the material may be damaging to the health of the individual.
Ingestion Dipropylene monomethyl ether (DPME) produces marked central nervous system depression in rats. Lethal doses produced respiratory failure within 48 hours.
Many aliphatic hydrocarbons create a burning sensation because they are irritating to the GI mucosa.

Evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in a substantial number of individuals following
direct contact, and/or produces significant inflammation when applied to the healthy intact skin of animals, for up to four hours, such inflammation being present
Skin Contact twenty-four hours or more after the end of the exposure period. Skin irritation may also be present after prolonged or repeated exposure; this may result in a
form of contact dermatitis (nonallergic). The dermatitis is often characterised by skin redness (erythema) and swelling (oedema) which may progress to
blistering (vesiculation), scaling and thickening of the epidermis. At the microscopic level there may be intercellular oedema of the spongy layer of the skin
(spongiosis) and intracellular oedema of the epidermis.
Evidence exists, or practical experience predicts, that the material may cause eye irritation in a substantial number of individuals and/or may produce significant
ocular lesions which are present twenty-four hours or more after instillation into the eye(s) of experimental animals.
Repeated or prolonged eye contact may cause inflammation characterised by temporary redness (similar to windburn) of the conjunctiva (conjunctivitis);
temporary impairment of vision and/or other transient eye damage/ulceration may occur.
Eye
Instillation of isoparaffins into rabbit eyes produces only slight irritation.

Some nonionic surfactants may produce a localised anaesthetic effect on the cornea; this may effectively eliminate the warning discomfort produced by other
substances and lead to corneal injury.
Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving organs or biochemical systems.
Limited evidence shows that inhalation of the material is capable of inducing a sensitisation reaction in a significant number of individuals at a greater
Chronic frequency than would be expected from the response of a normal population.
Pulmonary sensitisation, resulting in hyperactive airway dysfunction and pulmonary allergy may be accompanied by fatigue, malaise and aching. Significant
symptoms of exposure may persist for extended periods, even after exposure ceases.

TOXICITY IRRITATION
CONFI-MUL XHT
Not Available Not Available

tall oil fatty acid amides/ TOXICITY IRRITATION

maleic anhydride Not Available Not Available

isoparaffins petroleum TOXICITY IRRITATION

hydrotreated HFP Not Available Not Available

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CONFI-MUL XHT

TOXICITY IRRITATION

Dermal (Rabbit) LD50: 9500 mg/kg Eye (human): 8 mg - mild

dipropylene glycol Oral (rat) LD50: 5135 mg/kg Eye (rabbit): 500 mg/24hr - mild
monomethyl ether Skin (rabbit): 238 mg - mild
Skin (rabbit): 500 mg (open)-mild
Not Available Not Available

Not available. Refer to individual constituents.

Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non-allergenic condition known
as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritating compound. Key criteria for the
DIPROPYLENE GLYCOL
diagnosis of RADS include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms
MONOMETHYL ETHER
within minutes to hours of a documented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to severe
bronchial hyperreactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have also been included
in the criteria for diagnosis of RADS.

TALL OIL FATTY ACID

AMIDES/ MALEIC
ANHYDRIDE,
No significant acute toxicological data identified in literature search.
ISOPARAFFINS
PETROLEUM
HYDROTREATED HFP

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity
Serious Eye
STOT - Single Exposure
Damage/Irritation
Respiratory or Skin
STOT - Repeated Exposure
sensitisation
Mutagenicity Aspiration Hazard

Legend: – Data required to make classification available

– Data available but does not fill the criteria for classification
– Data Not Available to make classification

CMR STATUS

SKIN dipropylene glycol monomethyl ether Malaysia Permissible Exposure Limits - Skin skin

SECTION 12 ECOLOGICAL INFORMATION

Toxicity

NOT AVAILABLE
Ingredient Endpoint Test Duration Effect Value Species BCF
tall oil fatty acid amides/
Not Available Not Available Not Available Not Available Not Available Not Available
maleic anhydride
polybasic acids Not Available Not Available Not Available Not Available Not Available Not Available
isoparaffins petroleum
Not Available Not Available Not Available Not Available Not Available Not Available
hydrotreated HFP
dipropylene glycol
Not Available Not Available Not Available Not Available Not Available Not Available
monomethyl ether

DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air
Not Available Not Available Not Available

Bioaccumulative potential
Ingredient Bioaccumulation
Not Available Not Available

Mobility in soil
Ingredient Mobility
Not Available Not Available

SECTION 13 DISPOSAL CONSIDERATIONS

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Waste treatment methods

Recycle wherever possible or consult manufacturer for recycling options.
Product / Packaging Consult State Land Waste Authority for disposal.
disposal Bury or incinerate residue at an approved site.
Recycle containers if possible, or dispose of in an authorised landfill.

SECTION 14 TRANSPORT INFORMATION

Labels Required
Marine Pollutant NO
HAZCHEM Not Applicable

Land transport (UN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Transport in bulk according to Annex II of MARPOL 73 / 78 and the IBC code

Source Ingredient Pollution Category
IMO MARPOL 73/78 (Annex
II) - List of Noxious Liquid isoparaffins petroleum hydrotreated HFP Y
Substances Carried in Bulk

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture
tall oil fatty acid amides/
maleic
anhydride(68990-47-6) is
found on the following
regulatory lists
isoparaffins petroleum
hydrotreated
HFP(64742-47-8) is found
on the following regulatory
lists
dipropylene glycol
monomethyl
ether(34590-94-8) is found
on the following regulatory
lists
"OECD List of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for Substitution – United Kingdom"
"International Maritime Dangerous Goods Requirements (IMDG Code)","IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in
Bulk","Malaysia Permissible Exposure Limits","International Council of Chemical Associations (ICCA) - High Production Volume List","Malaysia Industry
Code of Practice On Chemicals Classification And Hazard Communication - List of Classified Chemicals","OSPAR List of Chemicals for Priority
Action","International Maritime Dangerous Goods Requirements (IMDG Code) - Substance Index","FisherTransport Information","United Nations
Recommendations on the Transport of Dangerous Goods Model Regulations (English)","IMO Provisional Categorization of Liquid Substances - List 2:
Pollutant only mixtures containing at least 99% by weight of components already assessed by IMO","OSPAR National List of Candidates for Substitution –
Norway","OECD List of High Production Volume (HPV) Chemicals","International Agency for Research on Cancer (IARC) - Agents Classified by the IARC
Monographs","International Society of Automotive Engineers (SAE) Declarable Substances Chemical List - ARP9536","International Chemical Secretariat
(ChemSec) SIN List (*Substitute It Now!)","Joint FAO/WHO Expert Committee on Food Additives (JECFA) Compendium of Food Additive Specifications -
Lubricant","Belgium Federal Public Service Mobility and Transport, Regulations concerning the International Carriage of Dangerous Goods by Rail - Table A:
Dangerous Goods List - RID 2013 (Dutch)","OECD Existing Chemicals Database","Sigma-AldrichTransport Information","Malaysia Notification and
Registration Scheme EHS Reference List","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations
(Spanish)","International Air Transport Association (IATA) Dangerous Goods Regulations","Malaysia Notification and Registration Scheme CMR Reference
List","International Fragrance Association (IFRA) Survey: Transparency List","Joint FAO/WHO Expert Committee on Food Additives (JECFA) Compendium of
Food Additive Specifications - Glazing agent","IMO IBC Code Chapter 17: Summary of minimum requirements"
"Malaysia Permissible Exposure Limits","International Council of Chemical Associations (ICCA) - High Production Volume List","OECD List of High
Production Volume (HPV) Chemicals","OSPAR National List of Candidates for Substitution – Norway","Sigma-AldrichTransport Information","OECD Existing
Chemicals Database","International Fragrance Association (IFRA) Survey: Transparency List","IMO IBC Code Chapter 17: Summary of minimum
requirements"

This safety data sheet is in compliance with the Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations 2013 (CLASS).

SECTION 16 OTHER INFORMATION

Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using
available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references

The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other
settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any
process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.

end of SDS