Вы находитесь на странице: 1из 6

Diagram Boudouard - Chaudron

1. FeO + CO → Fe + CO2

T (K) ∆G⁰ ln (pCO2/pCO) pCO2/pCO pCO2 pCO


760 -1042 0.6900113898 1.993738241 0.66596946 0.33403054
960 118 -0.0618604261 0.940014079 0.484539823 0.515460177
1060 698 -0.331399379 0.71791839 0.417900172 0.582099828
1160 1278 -0.5544660986 0.574378841 0.364828862 0.635171138
1260 1858 -0.7421254024 0.476100933 0.322539552 0.677460448
1360 2438 -0.9021877498 0.405681159 0.288601122 0.711398878
1460 3018 -1.0403237482 0.35334027 0.261087531 0.738912469
1560 3598 -1.1607500032 0.313251153 0.238531032 0.761468968

2. CO2 + C → 2CO
T (K) ∆G⁰ ln ((pCO)2/pCO2)pCO/pCO2 (pCO)2 pCO pCO2
760 9108 -6.0313087702 0.002402348 0.00239659 0.048954983 0.99760341
960 768 -0.4026170106 0.668568105 0.400683738 0.632995843 0.599316262
1060 -3402 1.6152158844 5.028973483 0.834134285 0.913309523 0.165865715
1160 -7572 3.2851465561 26.71289897 0.96391572 0.981792096 0.03608428
1260 -11742 4.6900088672 108.854145 0.990897021 0.995438105 0.009102979
1360 -15912 5.8882737796 360.7819573 0.997235904 0.998616996 0.002764096
1460 -20082 6.9223928136 1014.745188 0.999015501 0.999507629 0.000984499
1560 -24252 7.8239324842 2499.7162 0.999600115 0.999800037 0.000399885

3. 3Fe2O3 + CO → 2Fe3O4 + CO2


T (K) ∆G⁰ ln (pCO2/pCO) pCO2/pCO pCO2 pCO
760 -17661.2 11.6952295182 119997.8996 0.999991667 8.33341E-06
960 -20235.2 10.608119443 40462.0365 0.999975286 2.471391E-05
1060 -21522.2 10.2184007369 27402.80712 0.999963509 3.649128E-05
1160 -22809.2 9.8958749111 19848.32523 0.99994962 5.037955E-05
1260 -24096.2 9.6245436608 15131.64705 0.999933918 6.608229E-05
1360 -25383.2 9.393114065 12005.42686 0.999916711 8.328873E-05
1460 -26670.2 9.1933871535 9831.896787 0.999898301 0.000101699
1560 -27957.2 9.0192662563 8260.713611 0.99987896 0.00012104

4. 3Fe3O4 + CO → 3FeO + CO2


T (K) ∆G⁰ ln (pCO2/pCO) pCO2/pCO pCO2 pCO
760 166 -0.1099250391 0.89590129 0.472546379 0.527453621
960 -1664 0.8723368562 2.392495243 0.705231716 0.294768284
1060 -2579 1.2244684791 3.402357178 0.772848963 0.227151037
1160 -3494 1.5158877532 4.553461683 0.819932133 0.180067867
1260 -4409 1.7610499996 5.818543657 0.853341116 0.146658884
1360 -5324 1.9701589745 7.171816534 0.877628188 0.122371812
1460 -6239 2.1506228844 8.590207437 0.895726969 0.104273031
1560 -7154 2.3079503955 10.05379722 0.90953335 0.09046665

5. Fe3O4 + 4CO → 3Fe + 4CO2


T (K) ∆G⁰ ln (pCO2/pCO)4 pCO2/pCO pCO2 pCO
760 -2960 1.9601091304 1.632360754 0.620112859 0.379887141
960 -1310 0.6867555779 1.187308398 0.542817098 0.457182902
1060 -485 0.2302703421 1.059256859 0.514387923 0.485612077
1160 340 -0.1475105427 0.963794062 0.490781636 0.509218364
1260 1165 -0.4653262077 0.890180033 0.470949866 0.529050134
1360 1990 -0.7364042748 0.831851725 0.454104289 0.545895711
1460 2815 -0.9703483602 0.784595414 0.439648902 0.560351098
1560 3640 -1.1742996142 0.745593373 0.427128898 0.572871102
pCO/(pCO+pCO2)
0.3340305395
0.5154601767
0.5820998283
0.6351711379
0.6774604483
0.7113988783
0.7389124687
0.7614689676

pCO/(pCO+pCO2)
0.0467771156
0.5136651993
0.8463032606
0.9645494476
0.9909381713
0.9972397164
0.9990159854
0.9996001945 Diagram Boudouard - Chaudron
1.2

1
pCO/(pCO+pCO2)
8.33340975148E-06 0.8 <FeO> + (CO) ⇌ <Fe> + (CO2)
2.4713913897E-05 (CO2) + <C> ⇌ 2(CO)
pCO/(pCO+pCO2)

3.64912800443E-05 3<Fe2O3> + (CO) ⇌ 2<Fe3O4> +


0.6 (CO2)
5.03795463385E-05
<Fe3O4> + (CO) ⇌ 3<FeO> +
6.60822919252E-05 0.4 (CO2)
8.3288726245E-05 <Fe3O4> + 4(CO) ⇌ 3<Fe> +
0.0001016994 4(CO2)
0.2
0.0001210403
0
0 0 0 0 0 0 0 0 0 0 0
70 8 0 9 0 10 0 11 0 1 2 0 1 3 0 14 0 15 0 1 6 0 1 7 0

pCO/(pCO+pCO2) Temperatur
0.5274536206
0 0 0 0 0 0 0 0 0 0 0
70 80 9 0 10 0 11 0 1 2 0 1 3 0 14 0 15 0 1 6 0 1 7 0

Temperatur

0.2947682836
0.2271510374
0.180067867
0.1466588835
0.1223718124
0.1042730313
0.0904666497

pCO/(pCO+pCO2)
0.3798871406
0.4571829017
0.4856120769
0.5092183642
0.529050134
0.545895711
0.5603510981
0.5728711024
dron

<FeO> + (CO) ⇌ <Fe> + (CO2)


(CO2) + <C> ⇌ 2(CO)
3<Fe2O3> + (CO) ⇌ 2<Fe3O4> +
(CO2)
<Fe3O4> + (CO) ⇌ 3<FeO> +
(CO2)
<Fe3O4> + 4(CO) ⇌ 3<Fe> +
4(CO2)