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according to the Global Harmonized System (and with all of the information required by the HPR)
SECTION 1.Identification
Product identifier
Product number 354400
Product name Glutaraldehyde, 25% Aqueous Solution
Synonyms cidex, glutaral, glutaraldehyd (czech), glutardialdehyde, glutaric
dialdehyde, nci-c55425, 1,5-pentanedial, 1,5-pentanedione,
potentiated acid glutaraldehyde, sonacide, cudex, ncl-c55425, 1m5-
pentanedial, glutaric acid dialdehyde, glutaric aldehyde
Relevant identified uses of the substance or mixture and uses advised against
Identified uses Biochemical research/analysis
GHS-Labeling
Hazard pictograms
Signal Word
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SAFETY DATA SHEET
according to the Global Harmonized System (and with all of the information required by the HPR)
Danger
Hazard Statements
H302 + H332 Harmful if swallowed or if inhaled.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
Precautionary Statements
P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing must not be allowed out of the workplace.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P285 In case of inadequate ventilation wear respiratory protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
P321 Specific treatment (see supplemental first aid instructions on this label).
P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.
P363 Wash contaminated clothing before reuse.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
Other hazards
None known.
Hazardous ingredients
Chemical name (Concentration)
CAS-No.
Glutaraldehyde (>= 20 % - < 30 % )
111-30-8
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SAFETY DATA SHEET
according to the Global Harmonized System (and with all of the information required by the HPR)
Environmental precautions
Do not empty into drains.
Recirculation prohibited
Engineering measures
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SAFETY DATA SHEET
according to the Global Harmonized System (and with all of the information required by the HPR)
Technical measures and appropriate working operations should be given priority over the use of personal
protective equipment.
Individual protection measures
Protective clothing should be selected specifically for the workplace, depending on concentration and quantity of
the hazardous substances handled. The chemical resistance of the protective equipment should be inquired at
the respective supplier.
Hygiene measures
Immediately change contaminated clothing. Apply skin- protective barrier cream. Wash hands
and face after working with substance.
Eye/face protection
Tightly fitting safety goggles
Hand protection
full contact:
Glove material: Nitrile rubber
Glove thickness: 0.4 mm
Break through time: > 480 min
splash contact:
Glove material: natural latex
Glove thickness: 0.6 mm
Break through time: > 240 min
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC
and the related standard EN374, for example KCL 730 Camatril® -Velours (full contact), KCL 706
Lapren® (splash contact).
The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374
with samples of the recommended glove types.
This recommendation applies only to the product stated in the safety data sheet and supplied by us
as well as to the purpose specified by us. When dissolving in or mixing with other substances and
under conditions deviating from those stated in EN374 please contact the supplier of CE-approved
gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
Other protective equipment:
protective clothing
Respiratory protection
required when vapors/aerosols are generated.
Recommended Filter type: Filter A (acc. to DIN 3181) for vapors of organic compounds
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective
devices are performed according to the instructions of the producer. These measures have to be
properly documented.
Odor pungent
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SAFETY DATA SHEET
according to the Global Harmonized System (and with all of the information required by the HPR)
pH No information available.
Chemical stability
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SAFETY DATA SHEET
according to the Global Harmonized System (and with all of the information required by the HPR)
heat-sensitive
Conditions to avoid
Strong heating.
Incompatible materials
Aluminum, various metals, Mild steel
Aspiration hazard
Regarding the available data the classification criteria are not fulfilled.
Carcinogenicity
IARC No ingredient of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
OSHA No component of this product present at levels greater than or
equal to 0.1% is on OSHA’s list of regulated carcinogens.
NTP No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
ACGIH No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by ACGIH.
Further information
After absorption:
Headache, Dizziness, Nausea, Vomiting, Diarrhea, Circulatory collapse, somnolence,
Drowsiness, Unconsciousness, Discomfort, narcosis, Coma, death
Other dangerous properties can not be excluded.
Handle in accordance with good industrial hygiene and safety practice.
Ingredients
Glutaraldehyde
Acute oral toxicity
LD50 Rat: ca. 151 mg/kg
OECD Test Guideline 401
Skin irritation
Rabbit
Result: Corrosive
OECD Test Guideline 404
(50% solution)
Eye irritation
Rabbit
Result: Irreversible effects on the eye
Draize Test
(50% solution)
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SAFETY DATA SHEET
according to the Global Harmonized System (and with all of the information required by the HPR)
Sensitization
Open epicutaneous test Guinea pig
Result: positive
(50% solution) (ECHA)
Human experience
Result: positive
(ECHA)
Genotoxicity in vitro
In vitro mammalian cell gene mutation test
MOUSE LYMPHOMA TEST
Result: positive
(50% solution) (ECHA)
Ames test
Salmonella typhimurium
Result: positive
Method: US-EPA
(50% solution)
Ingredients
Glutaraldehyde
Toxicity to fish
LC50 Oncorhynchus mykiss (rainbow trout): 3.5 mg/l; 96 h (ECOTOX Database)
Toxicity to algae
static test ErC50 Desmodesmus subspicatus (green algae): 0.6 mg/l; 72 h
Analytical monitoring: yes
OECD Test Guideline 201
Toxicity to bacteria
static test EC20 activated sludge: ca. 15 mg/l; 0.5 h
OECD Test Guideline 209
Biodegradability
90 - 100 %; 28 d; aerobic
OECD Test Guideline 301A
Readily biodegradable.
M-Factor
1
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SAFETY DATA SHEET
according to the Global Harmonized System (and with all of the information required by the HPR)
Training advice
Provide adequate information, instruction and training for operators.
Page 11 of 12
SAFETY DATA SHEET
according to the Global Harmonized System (and with all of the information required by the HPR)
Labeling
Hazard pictograms
Signal Word
Danger
Hazard Statements
H302 + H332 Harmful if swallowed or if inhaled.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
EUH071 Corrosive to the respiratory tract.
Precautionary Statements
Prevention
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P308 + P310 IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
Key or legend to abbreviations and acronyms used in the safety data sheet
Used abbreviations and acronyms can be looked up at www.wikipedia.org.
Revision Date06/17/2018
The information contained herein is based on the present state of our knowledge. It characterizes the product with regard to
appropriate safety precautions. It does not represent a warranty of any product properties and we assume no liability for any
loss or injury which may result from the use of this information. Users should conduct their own investigations to determine
the suitability of the information.
All rights reserved. Millipore and the “M” Mark are registered trademarks of Merck KGaA, Darmstadt, Germany.
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