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3. A hydrocarbon (A) gives 1 mole of 2, 5-diketohexanal, 1 mole of glyoxal and 1 mole of acetaldehyde
on reductive ozonolysis. The improbable structure of (A) would be :
6. The equilibrium : SO2Cl2(g) SO2(g) + Cl2(g) is attained at 25°C in a closed container and inert
gas helium is introduced. Which of the following statement(s) is(are) correct?
I. Concentrations of SO2, Cl2 and SO2Cl2 change. II. More chlorine is formed.
III. Concentration of SO2 is reduced. IV. More SO2 Cl2 is formed.
The correct choice is :
(A) I, II, III (B) II, III, IV (C) III, IV (D) None
7. The solubility of CsBr3 in water is 746 ppm. Assuming the density of solution is 1g/cc the solubility
product of CsBr3 is : [Atomic masses are : Cs = 133, Br = 80]
(A) 1.6 × 10–11 M4 (B) 4 × 10–6 M2 (C) 8 × 10–9 M3 (D) 3.2 × 10–14 M2
8. The values of van der Waal’s constant 'a' and 'b' for three different gases are given below. What is the
correct order of liquefaction of gases?
Gases a b
X2 1.3 0.090
Y2 4.1 0.023
Z2 2.2 0.075
(A) X2 > Y2 > Z2 (B) Y2 > Z2 > X2 (C) Z2 > Y2 > X2 (D) X2 > Z2 > Y2
9. An optically active alkene (A) has the molecular formula C6H12. The catalytic hydrogenation of (A)
gives an achiral product. The structure of (A) would be
(A) CH3 CHCH=CHCH3 (B) CH3CHCH2CH=CH2
CH3 CH3
(C) CH3CHCH=CH2 (D) CH3CCHCH3
C2 H 5 C2H5
10. Acidic strength of boron trihalide are in order of :
(A) BF3 < BCl3 < BBr3 < BI3 (B) BI3 < BBr3 < BCl3 < BF3
(C) BBr3 < BCl3 < BF3 < BI3 (D) BF3 < BI3 < BCl3 < BBr3
11. The correct order in which the O–O bond length increases in the following is :
(A) O2 < O3 < H2O2 (B) H2O2 < O3 < O2
(C) O3 < O2 < H2O2 (D) O2 < H2O2 < O3
12. Which of the following statements is incorrect on the basis of heat of combustion?
(A) trans-2-hexene has less heat of combustion than 2-methyl-2-pentene
(B) cis-2-pentene has higher heat of combustion than trans-2-pentene
(C) 1-hexene has higher heat of combustion than trans-2-hexene
(D) 2, 5-dimethylhexane has lower heat of combustion than octane
13. When FeCl3 reacts with K4 [Fe(CN)6] in aqueous solution blue 0.1M FeCl 3 0.01M K4[Fe(CN)6 ]
14. Select the correct statement(s) regarding phosphoric acid, Given that :
f H H3PO 4 1290kJmol1 , f H H 2 PO 4 1302kJ mol1 ,
S H3 PO 4 176 Jmol1K 1 ,S H 2 PO 4 89 J mol1K 1 .
235 1 92 1
15. Fill in the blank : 92 U 0 n
______ 36 Kr 3 0 n
141 139 139 141
(A) 56 Ba (B) 56 Ba (C) 54 Ba (D) 54 B
16. An electron in a hydrogen like species atom jumps in such a way that its kinetic energy changes from x
to x/4. The change in potential energy will be :
3 3 3 3
(A) x (B) x (C) x (D) x
2 8 4 4
17. If 1 molal solution of Benzoic acid in Benzene has a freezing point depression of 2.6°C
(Kf = 5.12°C mol–1 kg) and boiling point elevation of 2.53°C (Kb = 2.53°C mol–1 kg), then select the
incorrect statement(s).
I. There is formation of dimer of benzoic acid during freezing
II. There is no change in structure of benzoic acid during boiling
III. There is no change in structure of benzoic acid either during freezing or boiling
IV. Dimer formation in both freezing and boiling
(A) I, II (B) II, III (C) I, III (D) Only I
2
18. How many optically active isomers are possible for the complex Pt ox 2 Cl2
(A) 2 (B) 3 (C) 4 (D) 1
19. Equal volume each of two sols of AgI, one obtained by adding KI to slight excess of AgNO3 and
another obtained by adding AgNO3 to slight excess of KI are mixed together than :
(A) A true solution will be obtained (B) The two sols will stabilize each other
(C) Two sols will coagulate each other mutually
(D) The sol particle will acquire more electric charge
Alcoholic
20. ClCH 2 CHCl2
KOH,
X major product . What will be the major product ‘X’?
21. Total number of monobromo (excluding stereo isomers), dibromo and tribromo derivatives of
cyclopentane are :
(A) 4 (B) 6 (C) 8 (D) 10
22. The number of moles of lead nitrate needed to coagulate 2 moles of colloidal (AgI) I is :
(A) 2 (B) 1 (C) 1/2 (D) 2/3
23. 1 mole of equimolar mixture of ferric oxalate and ferrous oxalate will require x moles of KMnO4 in
acidic medium for complete oxidation, x is :
(A) 0.6 mole (B) 0.9 mole (C) 0.3 mole (D) 1.8 mole
24. Match List - 1 with List - 2 and select the correct answer using codes given below in the lists.
List - 1 List - 2
I. Cyanide process (a) Extraction of Au
II. Zone refining (b) Extraction of Al
III. Electrolytic reduction (c) Pine oil
IV. Floatation process (d) Ultrapure Ge
Code:
(A) I-c, II-a, III-d, IV-b (B) I-d, II- b, III.-c, IV-a
(C) I-c, II-b, III-d, IV-a (D) I-a, II-d, III- b, IV- c
25. The cubic unit cell of Al(molar mass 27 g mol–1) has an edge length of 405 pm. Its density is 2.7 g cm–3.
The cubic unit cell is :
(A) face centered (B) body centered
(C) primitive (D) End centered
1. AB is a straight horizontal smooth rod. A bead D slides along the wire and is at A when a string DCB is
horizontal.
At C, another bead of equal mass as D is fixed to the string and the end B is fixed to rod. DC = CB = a.
The velocity of D when it is at a distance a from A will be:
1/2 1/ 2 1/2 1/2
3 3ga 3ga 2 3ga 3 3ga
(A) (B) (C) (D)
4 4 5 5
xx x xx x
xx xxx xxxxx
A xxxxx B A xxxxx B
xxx xx xxxxx
x x x xxx x x x xxx
x xx x xx
Q Q
Figure (a) Figure (b)
(A) Bulb A goes out bulb B gets brighter (B) Bulb B goes out bulb A gets brighter
(C) Bulb A goes out bulb B gets dimmer (D) Bulb B goes out bulb A gets dimmer
4. A particle is projected form the ground at an angle of 60 with horizontal at speed u = 20 m/s.
The radius of curvature of the path of the particle, when its velocity makes an angle of 30 ° with
horizontal is nearly : (g = 10m/s2)
(A) 10.6 m (B) 12.8 m (C) 15.4 m (D) 24.2 m
m2
8. Two particles are inter connected by an ideal spring (see figure). The spring
g
is compressed and system is projected in air under gravity. At an instant, if
m1
the acceleration of m1 is a find acceleration of m2 at this instant will be:
m1 g m1a m1 g m2 g – m1a
(A) g (B) ga (C) (D)
m2 m2
10. A disc of mass m and radius R is under pure rolling with a constant
velocity V0 on a smooth surface. The center of mass of the disc C is offset C
from center O by a distance r. A time varying couple M is applied such that v0
the disc continues to roll with a constant velocity. Initial position of the O
point C is shown in the figure. The correct plot of variation of couple M
with time t will be: (Take clockwise torque as positive)
mgr mgr
M t M t
(A) (B)
–mgr –mgr
mgr
(C) t
(D) t
M M
–mgr
11. In the arrangement shown in figure the mass of 2 blocks A & B are 6 kg
and 2 kg respectively. The height h = 10 cm. All the pulleys & thread are
massless and frictionless. When the system is released from the instant
shown, find the maximum height reached by block B. (g = 10 m / sec 2 )
(A) 20 cm (B) 25.7 cm
(C) 30 cm (D) 35.2 cm
14. Three long thin wires, each carrying current I in the same direction are in the x-y plane of a gravity
free-space, mass per unit length of the central wire is . The central wire is along y-axis while the
other two are along x d . If the central wire is displaced along the z-direction by a small amount and
released keeping the other two wires fixed, the frequency of oscillation is :
I 0 I 0
(A) (B) 0 I d (C) 2 d 0 (D)
d 2 d
15. On a semicircular ring of radius 4R, charge +3q is distributed in such a way
that on one quarter +q is uniformly distributed and on another quarter +2q is
uniformly distributed. Along its axis a smooth non-conducting and uncharged
pipe of length 6R is fixed axially as shown. A small ball of mass m and charge
+q is thrown from the other end of pipe with initial speed u. The minimum u
for which the ball can come out of the pipe is just greater than :
7q2 3q 2 6q 2 9q 2
(A) (B) (C) (D)
40 0 Rm 40 0 Rm 40 0 Rm 40 0 Rm
16. A disc and ring of mass M and radius 2R and R respectively are connected by a light inextensible thread
as shown. A force F is applied at the topmost point of disc. It was observed that the surface was rough
enough for both of them to roll without slipping.
Which of the following statements is correct?
(A) Friction force between disc and ground is backward
(B) Friction force between ring and ground is forward
F
(C) Minimum value of coefficient of friction is
2 Mg
3F
(D) Minimum value of coefficient of friction is
4 Mg
17. A charged particle of unit mass and unit charge moves with velocity v (8iˆ 6 ˆj ) m/s in a magnetic field
of B 2kˆ T . Choose the INCORRECT alternative.
(A) The path of the particle may be x 2 y 2 4 x 21 0
(B) The path of the particle may be x 2 y 2 25
(C) The path of the particle may be y 2 z 2 25
(D) The time period of the particle will be 3.14 s
19. The system in figure is released from rest from the position shown
(there is no friction). After blocks have moved distance H/3, collar
B is removed and block A and C continue to move without any
sudden change in their speeds due to removal of caller. The speed of
C just before it strikes the ground is :
4 2
(A) gH (B) gH
3 3
13gH
(C) (D) 2 2gH
3
20. Two identical objects A and B are at temperatures TA and TB, respectively. Both objects are placed in a
room with perfectly absorbing walls maintained at a temperature T (TA > T > TB). The objects A and B
attain the temperature T eventually. Select the correct statements from the following:
(A) A only emits radiation, while B only absorbs it until both attain the temperature T
(B) B loses more heat by radiation than it absorbs, while A absorbs more radiation than it emits,
until they attain the temperature T.
(C) Both A and B only absorb radiation, but do not emit it, until they attain the temperature T
(D) Each object continuous to emit and absorb radiation even after attaining the temperature T
21. With what force must a man pull on the rope to hold the plank in position if the
weight of man is 60 kg? Neglect the wt. of the plank, rope and pulley.
[Take g = 10 m/s2]
(A) 100 N (B) 150 N
(C) 125 N (D) None of these
23. 10 kg of water at 0 C is placed in a large evacuated enclosure (vessel). If the latent heat of vaporization
is seven times the latent heat of fusion, what fraction of water will ultimately freeze?
7 1 4 3
(A) (B) (C) (D)
8 7 7 7
24. There are two pipes each of length 2 m, one is closed at one end and other is open at both ends.
The speed of sound in air is 340 m/s. The frequency at which both can resonate is:
(A) 340 Hz (B) 510 Hz (C) 42.5 Hz (D) None of these
25. A spherical water drop of radius R has a charge q, distributed uniformly over its surface. The drop splits
into two identical droplets and being separated by a large distance. These droplets have equal charges,
distributed uniformly over the surface. Fractional change in electrostatic potential energy is :
(A) 2 1/ 3
1 (B)
21 / 3 1
(C)
2 2/3
1 (D)
24 / 3 1
21 / 3 22 / 3 24 / 3
(A)
2 n 2 n1 1 (B)
2 n 2n 1 (C)
2 n 2n 1 (D)
2 n 1 2 n 1
3. If a, b, c are positive real numbers, such that c 2 a 2 b 2 ab , min a,b , max{a,b} , then :
(A) c (B) c (C) c (D) c
4. C1 and C2 are circles of unit radius with centres at (0, 0) and (1, 0) respectively. C3 is a circle of unit
radius, passes through the centres of the circles C1 and C2 and have its centre above x-axis. Equation of
the common tangent to C1 and C3 which does not pass through C2 is
(A) x 3 y 2 0 (B) 3 x y 2 0 (C) 3 x y 2 0 (D) x 3y 2 0
(i 1)( j 1)
1i j n
5. p lim is equal to :
n n4
1 1 1 1
(A) (B) (C) (D)
4 6 8 3
6. The number of solutions of the equation 8[log x] 6[e x ] 13 12[cos x], where [ ] denotes greatest
integer function is
(A) 1 (B) 2 (C) infinitely many (D) 0
1 x 1 x 1 x 1 x
7. lim tan 2 tan 2 3 tan 3 ... n tan n is :
n 2 2 2 2 2 2 2 2
1 1
(A) cot x (B) sin x (C) cot x (D) cot x
x x
8. Consider the parabola x 2 8 y , then number of normals that can be drawn from the point 1, 5 to the
parabola is :
(A) 1 (B) 2 (C) 3 (D) None of these
1 x
x2 x3 7
9. If the function f x 4e 2 1 x and g x f 1 x then the value of g ' equals
2 3 6
to
1 1 6 6
(A) (B) (C) (D)
5 5 7 7
2
10. If f x and g x f x 1 2 f x are monotonically increasing functions, then x R,
2 1 1
(A) f x 1 (B) f x (C) f x (D) f x
3 3 2
12. Two equilateral triangles are constructed from a line segment of length L. If M and m are maximum and
minimum values of the sum of areas of two plane figures then :
(A) M = 2m (B) M 3m (C) 2M 3 3 m (D) M = 4m
cos 2 1
13. For any real value of , the value of expression R a, b then b a is :
cos 2 cos
(A) 0 (B) 1 (C) 2 (D) None of these
14. The locus of the point of intersection of the tangents at the extremities of a chord of the circle
x 2 y 2 a 2 which touches the circle x 2 y 2 2ax 0 passes through the point :
a a
(A) 2 , 0 (B) 0, 2 (C) (0, a) (D) None of these
15. Identify following statements for True (T) and False (F):
S1 : An old man while dialing a 7 digit telephone number remembers that the first four digits consist
of one 1’s, one 2’s and two 3’s. He also remembers that the fifth digit is either a 4 or 5 while
has no memory of the sixth digit, he remembers that the seventh digit is 9 minus the sixth digit.
Maximum number of distinct trials he has to try to make sure that he dials the correct telephone
number, is 240.
S2 : A woman has 11 close friends. The number of ways in which she can invite 5 of them to
dinner, if two particular of them are not on speaking terms and will not attend together is 378.
S3 : 10 IIT and 2 PET students sit in a row. If the total number of ways in which exactly 3 IIT
students sit between 2 PET students is 10! , then is 6.
Which of the following choice is correct?
(A) TTT (B) TTF (C) TFF (D) FTF
16. In a G.P., the ratio of the sum of the first eleven terms to the sum of the last eleven terms is 1/8 and the
ratio of the sum of all the terms without the first nine to the sum of all terms without the last nine is 2.
Then the number of terms of the G.P. is :
(A) 15 (B) 43 (C) 38 (D) 28
17. A circle with centre in the first quadrant is tangent to y x 10, y x 6 and the y-axis. Let (h, k) be
the centre of the circle. If the value of h k a b a , where a, b Q , find the value (a + b).
(A) 10 (B) 12 (C) 14 (D) None of these
(A)
4m 1 a (B)
2m 1 a
Im I m 1 Im I m 1
m 1 m2
(C)
2m 1 a (D)
4 m 1 a
Im I m 1 Im I m 1
m4 m2
22. Let f and g are two functions such that f (x) and g (x) are continuous in [a, b] and differentiable in (a, b).
f b f a
Then at least one c a, b such that f c
ba
I. If f x f b , then f c 0 (RMVT)
f b f a
II. If f a f b and a b, then f c (LMVT)
ba
f b f a f c
III. If g x 0 , then (Cauchy theorem)
g b g a gc
sin sin
Let 0 , then is equal to :
2 cos cos
(A) tan (B) tan (C) cot (D) cot
23. The area of the region bounded by the curve y x 2 and y sec1[ sin 2 x] , (where [.] denotes the
greatest integer function) is:
4
(A) square unit (B) square unit
3
2 1
(C) square unit (D) square unit
3 3
8 8 4 4
24. Given f ( x) and g ( x) the g ( x) is :
1 x 1 x f (sin x) f (cos x)
(A) Periodic with period (B) Periodic with period
2
(C) Periodic with period 2 (D) Not periodic