4541 2 PRAKTIS BESTARI JUJ PAHANG 2016

MARKING SCHEME P2 JUJ CHEMISTRY 2016

Question No Sub Mark

Mark Scheme
Mark
1 (a) (i) diffusion 1 1
(ii) 1. Matter is made up of tiny particle 1
2. The particles move randomly in between air particles 1
3. From higher concentration region to lower concentration 1 3
region
(b) (i) To ensure even heating of naphthalene 1 1

(ii) 1 1

Melting point
Takat lebur

(iii) Heat energy absorbed by particles is used to overcome the forces of 1 1

attraction between particles
(iv) Move faster 1 1
(v) 1 1

Total 9
 4541 3 PRAKTIS BESTARI JUJ PAHANG 2016

Question No Sub Mark

Mark Scheme
Mark
2 (a) (i) Ion 1 1
(ii) Anhydrous calcium chloride 1 1

(iii) Magnesium / zinc and hydrochloric acid 1 +1 2

a: any suitable metal and acid
(iv) Flow the hydrogen gas into the combustion tube for a few minutes 1 1
before heating
(v) The heating, cooling and weighing process are repeated until a 1 1
constant mass is obtained
(vi) Magnesium is more reactive than hydrogen 1 1

(b) (i) CH2 1 1

(ii) The chemical formula that shows the simplest ratio of atoms of each 1 1
elements in a substance
Total 9 9

Question No Sub Mark

Mark Scheme
Mark
3 (a) Able to write letter P and Q in the correct boxes in the periodic table 1+1 2

P Q

(b) An oxide which can reacts with both acids and bases to form salts 1 1
and water
(c) 1. Size of atom V is larger than atom X // distance between nucleus 1 2
and valence electron in atom V is further than atom X
2. Forces of attraction between nucleus and valence electron in
1
atom V is weaker. // Atom V is more easier to release electron
** adp atom in pt2
(d) To fill the bulb // inert atmosphere for welding 1 1
** any one
(e) Able to mark √ in the correct box 1 1

pH Value
4 7 11
√
4541 4 PRAKTIS BESTARI JUJ PAHANG 2016

Question No Sub Mark

Mark Scheme
Mark
(f) (i) WX4 // CCl4 1 1
(f) (ii) 1. Correct electron arrangement and nucleus is shown
1 2
2. Correct labelled and number of atoms
1

X W X

Answer :
Total 10

Question No Sub Mark

Mark Scheme
Mark
4 (a) (ii) Ethanoic acid 1 1
(iii) 1. Hydrochloric acid is a strong acid and ethanoic acid is a weak 1 3
acid // HCl ionise completely in water and ethanoic acid ionise
partially in water
2. concentration of hydrogen ion in HCl is higher than in ethanoic 1
acid
3. the higher the concentration of hydrogen ion, the lower the pH
value 1
4(b) (i) The solution that the concentration is accurately known 1 1
(ii) To get accurate concentration 1 1
(iii) To make sure all NaOH is transferred into the volumetric flask 1 1
(iv) n = MV 1 1
1000
(v) 1. n= 0.4(250) // 0.1 1
1000
1 2
2. mass NaOH = 0.1 x 40 g // 4 g
Total 10
4541 5 PRAKTIS BESTARI JUJ PAHANG 2016

Question No Mark Scheme Sub

Mark
5(a) (i) Green 1 1
(ii) To ensure hydrochloric acid has reacted completely 1 1
(iii) 1. Correct formulae of reactants and products 1
2. Balance equation
1
FeO + 2HCl FeCl2 + H2O 2
(iv) Can 1 1
5 (b) 1. Dilute nitric acid and silver nitrate solution is added into the test 1 2
tube
2. White precipitate formed 1
5(c) (i) Sodium carbonate / ammonium carbonate / potassium carbonate 1 1
(ii) Double decomposition reaction // precipitation reaction 1 1
(iii) 1. Add iron(II) chloride solution into solution X. 1
2. Filter 1 2
Total 11

Question Answer Sub mark marks

6(a) CnH2n+1OH 1 1
(b) Compound Q : Propene //Propena 1
Compound R : Propanoic acid //Asid propanoik 1
Compound S : Ethyl propanoate // etil propanoat 1 3
(c) 1. Functional apparatus 1
2. Label 1 2
Porcelain chip
Glass wool
Soaked in Compound Q
Compound P
Heat

water

(d) (i) Acidified Potassium mangganate (VII) / KMnO4 // 1 1

Acidified Potassium dichromate (VI) / K2Cr2O7
1. Correct formulae of reactants and products 1
(ii) 2. Balance equation 1 2

C3H7OH + 2[O]  C2H5COOH + H2O

(e) (i) Carboxylate // - COO - 1 1
4541 6 PRAKTIS BESTARI JUJ PAHANG 2016

1 1
(ii) H H O

H H
H C C C

O C C H
H H

H H

TOTAL 11

Question No Sub Mark

Mark Scheme
Mark
7 (a) (i) 2-methylbut-1,3-diene//isoprene 1

1 2
(ii) 1. Substance X= methanoic acid//formic acid//ethanoic 1
acid//[formula acid]
2. Substance Y = ammonia solution//NH3 1
3. Positive charged hydrogen ion from acid neutralize the 1
negative charged of protein membrane
4. Neutral particles collide with each other causes the membrane 1
to break
5. The rubber polymers are freed/entangled/coagulate 1
6. Hydroxide, OH- ions neutralised H+ ion produced by bacteria 1
7. Protein membrane remains negatively charged 1
8. The rubber polymers cannot coagulate 1 8
7 (b) 1. correct formulae of reactants and products
2. balanced equation

Experiment I : NH3 + HNO3 NH4NO3 1+1

Experiment II : 2NH3 + H2SO4 (NH4)2SO4 1+1

3. Fertilizer A : ammonium nitrate 1 6

4. Fertilizer B : ammonium sulphate 1
7(c) 1. Fertilizer A 1
2. % nitrogen in fertilizer A
=28/80 x 100 1
=35.00%
3. % nitrogen in fertilizer B
1
=28/132 x 100
=21.21%
4. Percentage of nitrogen in fertilizer A is higher than in 1 4
fertilizer B
Total 20
4541 7 PRAKTIS BESTARI JUJ PAHANG 2016

Question 8 Rubric Sub Total

mark mark
8 (a) (i) 1. Change in temperature = 36.8 – 30.0 oC // 6.8oC 1
2. Q = mcӨ = [25 + 25] x 4.2 x 6.8 J // 1428 J 1

3. n = MV / 1000 = 1.0 x 25 // 0.025 1

1000
4. ∆H = 1428 / 0.025 1

-1
5. - 57.1 kJ mol 1
6. Correct formula of reactants and products 1
7
7. Balanced chemical reaction 1

H2SO4 + 2NaOH → Na2SO4 + 2H2O

(a) (ii) 1. Arrow upwards, label ‘Energy’ and two levels shown 1

2. Reactants and products are on the correct level 1

-1
3. ∆H = -57.1 kJmol is shown 1
Energy
H+ + OH-

∆H = - 57.1 kJ mol-1

H2O

4. The reaction is exothermic // heat release 1

5. Total energy content of reactants is higher than the product 1

6. Heat release during bond formation is greater than heat absorbed 1 6

during bond breaking
(a) (iii) 1. Heat of neutralization using ethanoic acid is lower 1

2. Sulfuric acid is a strong acid whereas ethanoic asid is a weak 1

acid
1
3. Most of the ethanoic acid exist as a molecules

4. Heat energy is absorbed to completely ionizes the ethanoic acid 1 4

4541 8 PRAKTIS BESTARI JUJ PAHANG 2016

(b) 1. The reaction is exothermic reaction 1

2. The temperature increase 1

3. Heat is absorbed by the food 3

1
20
TOTAL

Question No Sub Mark

Mark Scheme
Mark
9 (a) 1. size of the chicken meat 1
2. Total surface area of chicken satay is larger than chicken grilled 1
3. More heat energy is absorbed by chicken satay compare to 1
chicken grilled 3
(b) (i) Exp I : 1
50/60 cm3s-1 // 0.833 cm3s-1
Exp 2 :
3 -1 3 -1 1
50/40 cm s // 1.25 cm s 2
(b) (ii) 1. Present of copper (II) sulphate as a catalyst in exp II 1
2. Catalyst lower the activation energy 1
3. More colliding particles can overcome the activation energy 1
4. Frequency of effective collision between X and H+ ions in exp II 1
higher than exp I
5. Rate of reaction in exp II is higer than exp I 1 5
(b) (iii) 1. Metal X : Zinc/ magnesium 1
2. Acid Y : Nitric acid//hydrochloric acid//sulphuric acid 1
** pt 1 and pt2 can consider in the procedure

3. Functional diagram 1
4. labeled diagram 1

sulphuric acid

asid sulfurik
Hydrogen gas

Zinc powder
4541 9 PRAKTIS BESTARI JUJ PAHANG 2016

Question No Sub Mark

Mark Scheme
Mark
Sample answer for the procedure :
5. Fill a burette with water, invert into a basin with water 1
6. [20-100]cm3 of [0.5-2.0] moldm-3 nitric acid is poured into a 1
conical flask.
7. [2-5]g/Excess zinc/ magnesium granules/powder are added into 1
the acid
8. A stopper with delivery tube is immediately connected to collect 1
the gas released.
9. Start the stop watch and record the volume of gas collected at 1
30s intervals.
10. Experiment is repeated by adding copper(II) sulphate. 1 10

Total 20

Question Answer Sub marks

mark
10 (a)(i)
Test tube I Test tube II
1. Reaction occur Reaction does not occur 1
2. Iron is more Copper is less
electropositive than L electropositive than M 1
3. Iron can displace L Copper cannot displace M 1

4.Fe, M, Cu 1
5.Brown solid : Copper [Reject : Cu] 1
6.Solution M : zinc nitrate // [any soluble salt in which the metal is 1
more electropositive than copper] 6

(ii) 1.Correct formulae of reactants and products 1

2.Balance equation 1

Cu + 2AgNO3  Cu(NO3)2 + 2Ag

3.Substance oxidise : Copper / Cu 1

+
4.Substance reduce : Silver nitrate / AgNO3 / Ag 1 4
(b) 1. Metal X and metal Y : Copper and zinc // [any suitable 1
pair of metal]
2. Solution used : copper(II) sulphate, zinc sulphate and 1
sulphuric acid
4541 10 PRAKTIS BESTARI JUJ PAHANG 2016

3. Diagram 1
G

Copper Zinc
Kuprum Zink

Copper(II) sulphate Zinc sulphate

Kuprum(II) sulfat Zink sulfat

H2SO4

4. Pour sulphuric acid into a U tube 1

5. Slowly and carefully pour zinc sulphate solution into the left arm 1
of U tube
6. Slowly and carefully pour copper(II) sulphate solution into the 1
right arm of U tube
7. Dip zinc electrode into zinc sulphate solution and copper 1
electrode into copper(II) sulphate solution.
8. Connect both electrode to galvanometer to complete the circuit. 1
9. Cu2+ + 2e  Cu 1 10
2+
10. Zn  Zn + 2e 1
TOTAL 20