;

;Input Summary created by Aspen Plus Rel. 36.0 at 16:13:46 Mon Feb 11, 2019

;Directory Filename C:\Users\KANISH~1\AppData\Local\Temp\~ap16be.txt

DYNAMICS

DYNAMICS RESULTS=ON

IN-UNITS MET PRESSURE=bar TEMPERATURE=C DELTA-T=C PDROP=bar &

INVERSE-PRES='1/bar'

DEF-STREAMS CONVEN ALL

MODEL-OPTION

DATABANKS 'APV100 PURE32' / 'APV100 AQUEOUS' / 'APV100 SOLIDS' &

/ 'APV100 INORGANIC' / 'APESV100 AP-EOS' / &

'NISTV100 NIST-TRC' / NOASPENPCD

PROP-SOURCES 'APV100 PURE32' / 'APV100 AQUEOUS' / &

'APV100 SOLIDS' / 'APV100 INORGANIC' / 'APESV100 AP-EOS' &

/ 'NISTV100 NIST-TRC'

COMPONENTS

MALEI-01 C4H2O3 /

HYDRO-01 H2 /

TETRA-01 C4H8O-4 /

BUTANOL C4H10O-1 /

1-PRO-01 C3H8O-1 /

WATER H2O /
 CARBO-01 CO2 /

BUTANE C4H10-1

SOLVE

RUN-MODE MODE=SIM

CHEMISTRY C-1

PARAM

FLOWSHEET

BLOCK H101 IN=1 OUT=2

BLOCK P101 IN=2 OUT=3

BLOCK C101 IN=5 OUT=6

BLOCK H102 IN=3 OUT=4

BLOCK H103 IN=6 OUT=7

BLOCK R101 IN=4 S3 OUT=8

BLOCK S1 IN=12 OUT=26 13

BLOCK H106 IN=11 OUT=12

BLOCK CO101 IN=8 OUT=9

BLOCK F101 IN=9 OUT=11 10

BLOCK V101 IN=10 OUT=15

BLOCK DC101 IN=S13 25 OUT=17 16

BLOCK DC102 IN=41 OUT=21 20

BLOCK S2 IN=21 OUT=23 22

BLOCK V102 IN=23 OUT=24

BLOCK CO102 IN=24 OUT=25

BLOCK S3 IN=38 OUT=36 31

BLOCK B2 IN=S5 OUT=41

BLOCK B3 IN=36 OUT=S1

BLOCK B1 IN=S1 OUT=S2

BLOCK B6 IN=26 OUT=27

 BLOCK B4 IN=S2 7 27 OUT=S3

BLOCK F-102 IN=S4 OUT=38 S5

BLOCK B7 IN=17 OUT=S4

BLOCK B12 IN=15 OUT=S13

PROPERTIES PENG-ROB

PROPERTIES NRTL / NRTL-HOC / OLI / WILS-HOC / WILSON

PROP-DATA HOCETA-1

IN-UNITS MET PRESSURE=bar TEMPERATURE=C DELTA-T=C PDROP=bar &

INVERSE-PRES='1/bar'

PROP-LIST HOCETA

BPVAL TETRA-01 BUTANOL .5000000000

BPVAL TETRA-01 1-PRO-01 .5000000000

BPVAL TETRA-01 WATER .5000000000

BPVAL BUTANOL BUTANOL 2.200000000

BPVAL BUTANOL 1-PRO-01 1.550000000

BPVAL BUTANOL WATER 1.550000000

BPVAL BUTANOL TETRA-01 .5000000000

BPVAL BUTANOL CARBO-01 .3000000000

BPVAL 1-PRO-01 BUTANOL 1.550000000

BPVAL 1-PRO-01 1-PRO-01 1.400000000

BPVAL 1-PRO-01 WATER 1.550000000

BPVAL 1-PRO-01 TETRA-01 .5000000000

BPVAL 1-PRO-01 CARBO-01 .3000000000

BPVAL WATER BUTANOL 1.550000000

BPVAL WATER 1-PRO-01 1.550000000

BPVAL WATER WATER 1.700000000

BPVAL WATER TETRA-01 .5000000000

BPVAL WATER CARBO-01 .3000000000

BPVAL CARBO-01 BUTANOL .3000000000

 BPVAL CARBO-01 1-PRO-01 .3000000000

BPVAL CARBO-01 WATER .3000000000

BPVAL CARBO-01 CARBO-01 .1600000000

PROP-DATA NRTL-1

IN-UNITS MET PRESSURE=bar TEMPERATURE=C DELTA-T=C PDROP=bar &

INVERSE-PRES='1/bar'

PROP-LIST NRTL

BPVAL TETRA-01 BUTANOL 0.0 337.3552000 .3000000000 0.0 0.0 &

0.0 68.30000000 107.1500000

BPVAL BUTANOL TETRA-01 0.0 -197.0771000 .3000000000 0.0 &

0.0 0.0 68.30000000 107.1500000

BPVAL TETRA-01 1-PRO-01 0.0 393.8595000 .3000000000 0.0 &

0.0 0.0 65.80000000 97.40000000

BPVAL 1-PRO-01 TETRA-01 0.0 -222.1008000 .3000000000 0.0 &

0.0 0.0 65.80000000 97.40000000

BPVAL TETRA-01 WATER 1.214162000 157.7809000 .4725526000 &

0.0 0.0 0.0 63.41000000 100.0000000

BPVAL WATER TETRA-01 4.760148000 -733.4016000 .4725526000 &

0.0 0.0 0.0 63.41000000 100.0000000

BPVAL BUTANOL 1-PRO-01 0.0 -88.31770000 .3000000000 0.0 &

0.0 0.0 40.00000000 117.6000000

BPVAL 1-PRO-01 BUTANOL 0.0 112.9459000 .3000000000 0.0 0.0 &

0.0 40.00000000 117.6000000

BPVAL BUTANOL WATER -2.040500000 763.8692000 .3000000000 &

0.0 0.0 0.0 19.17000000 117.6000000

BPVAL WATER BUTANOL 13.11020000 -3338.953600 .3000000000 &

0.0 0.0 0.0 19.17000000 117.6000000

BPVAL 1-PRO-01 WATER -1.741100000 576.4458000 .3000000000 &

0.0 0.0 0.0 25.00000000 100.0000000

BPVAL WATER 1-PRO-01 5.448600000 -861.1792000 .3000000000 &

 0.0 0.0 0.0 25.00000000 100.0000000

BPVAL 1-PRO-01 BUTANE 0.0 193.2439000 .3000000000 0.0 0.0 &

0.0 10.00000000 40.00000000

BPVAL BUTANE 1-PRO-01 0.0 314.7243000 .3000000000 0.0 0.0 &

0.0 10.00000000 40.00000000

PROP-DATA PRKBV-1

IN-UNITS MET PRESSURE=bar TEMPERATURE=C DELTA-T=C PDROP=bar &

INVERSE-PRES='1/bar'

PROP-LIST PRKBV

BPVAL HYDRO-01 CARBO-01 -.1622000000 0.0 0.0 -273.1500000 &

726.8500000

BPVAL CARBO-01 HYDRO-01 -.1622000000 0.0 0.0 -273.1500000 &

726.8500000

BPVAL HYDRO-01 BUTANE -.3970000000 0.0 0.0 -273.1500000 &

726.8500000

BPVAL BUTANE HYDRO-01 -.3970000000 0.0 0.0 -273.1500000 &

726.8500000

BPVAL WATER CARBO-01 .1200000000 0.0 0.0 -273.1500000 &

726.8500000

BPVAL CARBO-01 WATER .1200000000 0.0 0.0 -273.1500000 &

726.8500000

BPVAL CARBO-01 BUTANE .1333000000 0.0 0.0 -273.1500000 &

726.8500000

BPVAL BUTANE CARBO-01 .1333000000 0.0 0.0 -273.1500000 &

726.8500000

PROP-DATA WILSON-1

IN-UNITS MET PRESSURE=bar TEMPERATURE=C DELTA-T=C PDROP=bar &

INVERSE-PRES='1/bar'

PROP-LIST WILSON
 BPVAL TETRA-01 BUTANOL 0.0 138.3872000 0.0 0.0 68.30000000 &

107.1500000 0.0

BPVAL BUTANOL TETRA-01 0.0 -281.9413000 0.0 0.0 &

68.30000000 107.1500000 0.0

BPVAL TETRA-01 1-PRO-01 0.0 143.3323000 0.0 0.0 &

65.80000000 97.40000000 0.0

BPVAL 1-PRO-01 TETRA-01 0.0 -308.4914000 0.0 0.0 &

65.80000000 97.40000000 0.0

BPVAL TETRA-01 WATER -9.447266000 2110.940000 0.0 0.0 &

63.41000000 100.0000000 0.0

BPVAL WATER TETRA-01 1.119921000 -847.7955000 0.0 0.0 &

63.41000000 100.0000000 0.0

BPVAL BUTANOL 1-PRO-01 0.0 -94.99490000 0.0 0.0 &

40.00000000 117.6000000 0.0

BPVAL 1-PRO-01 BUTANOL 0.0 69.20070000 0.0 0.0 40.00000000 &

117.6000000 0.0

BPVAL BUTANOL WATER 22.77770000 -10000.00000 0.0 0.0 &

19.17000000 117.6000000 0.0

BPVAL WATER BUTANOL 1.104800000 -588.7333000 0.0 0.0 &

19.17000000 117.6000000 0.0

BPVAL 1-PRO-01 WATER -4.740500000 625.5155000 0.0 0.0 &

25.00000000 100.0000000 0.0

BPVAL WATER 1-PRO-01 1.191900000 -557.7540000 0.0 0.0 &

25.00000000 100.0000000 0.0

BPVAL 1-PRO-01 BUTANE 0.0 -426.3083000 0.0 0.0 10.00000000 &

40.00000000 0.0

BPVAL BUTANE 1-PRO-01 0.0 -194.0596000 0.0 0.0 10.00000000 &

40.00000000 0.0

STREAM 1

SUBSTREAM MIXED TEMP=30. PRES=1.

 MOLE-FLOW MALEI-01 1209402. <kmol/oper-year>

STREAM 5

SUBSTREAM MIXED TEMP=100. PRES=25.

MOLE-FLOW HYDRO-01 6047011. <kmol/oper-year>

BLOCK B4 MIXER

PARAM

BLOCK S1 FSPLIT

PARAM MAXIT=100 TOL=0.001

FRAC 13 0.02

BLOCK S2 FSPLIT

PARAM PRES=8. TOL=0.0001

FRAC 23 0.98

PROPERTIES NRTL FREE-WATER=STEAM-TA SOLU-WATER=3 &

TRUE-COMPS=YES

BLOCK S3 FSPLIT

FRAC 31 0.03

BLOCK B1 HEATER

PARAM TEMP=220. PRES=40. DPPARMOPT=NO

BLOCK B7 HEATER

PARAM TEMP=40. PRES=1. DPPARMOPT=NO

PROPERTIES NRTL FREE-WATER=STEAM-TA SOLU-WATER=3 &

TRUE-COMPS=YES

BLOCK B12 HEATER

 PARAM TEMP=70. PRES=1. DPPARMOPT=NO

PROPERTIES NRTL FREE-WATER=STEAM-TA SOLU-WATER=3 &

TRUE-COMPS=YES

BLOCK CO101 HEATER

PARAM TEMP=40. PRES=40. DPPARMOPT=NO

BLOCK CO102 HEATER

PARAM TEMP=70. PRES=1. DPPARMOPT=NO

PROPERTIES NRTL FREE-WATER=STEAM-TA SOLU-WATER=3 &

TRUE-COMPS=YES

BLOCK H101 HEATER

PARAM TEMP=70. PRES=1. DPPARMOPT=NO

BLOCK H102 HEATER

PARAM TEMP=220. PRES=42. DPPARMOPT=NO

BLOCK H103 HEATER

PARAM TEMP=220. PRES=42. MAXIT=60 TOL=0.001 DPPARMOPT=NO

BLOCK H106 HEATER

PARAM TEMP=142. PRES=25. DPPARMOPT=NO

BLOCK F-102 FLASH2

PARAM TEMP=20. PRES=1.

PROPERTIES NRTL FREE-WATER=STEAM-TA SOLU-WATER=3 &

TRUE-COMPS=YES

BLOCK F101 FLASH2

PARAM TEMP=25. PRES=40. TOL=1E-006

BLOCK DC101 RADFRAC

PARAM NSTAGE=20 ALGORITHM=STANDARD INIT-OPTION=STANDARD &

MAXOL=50 TOLOL=1E-005 NPHASE=2 DAMPING=NONE

COL-CONFIG CONDENSER=PARTIAL-V

FEEDS S13 13 / 25 5

PRODUCTS 16 20 L / 17 1 V

P-SPEC 1 1.

COL-SPECS D:F=0.42 MOLE-RR=5.

PROPERTIES PENG-ROB FREE-WATER=STEAM-TA SOLU-WATER=3 &

TRUE-COMPS=YES

BLOCK-OPTION FREE-WATER=NO

BLOCK DC102 RADFRAC

PARAM NSTAGE=20 ALGORITHM=STANDARD INIT-OPTION=STANDARD &

ABSORBER=NO MAXOL=100 DAMPING=NONE

COL-CONFIG CONDENSER=PARTIAL-V

FEEDS 41 6 ABOVE-STAGE

PRODUCTS 21 1 V / 20 20 L

P-SPEC 1 8.

COL-SPECS B:F=0.7 MOLE-RR=5.

PROPERTIES PENG-ROB FREE-WATER=STEAM-TA SOLU-WATER=3 &

TRUE-COMPS=YES

BLOCK R101 RSTOIC

PARAM TEMP=220. PRES=40. SERIES=YES HEAT-OF-REAC=NO &

COMBUSTION=NO

STOIC 1 MIXED MALEI-01 -1. / HYDRO-01 -5. / TETRA-01 1. / &

WATER 2.

STOIC 2 MIXED MALEI-01 -1. / HYDRO-01 -6. / BUTANOL 1. / &

WATER 2.
 STOIC 3 MIXED MALEI-01 -1. / HYDRO-01 -3. / 1-PRO-01 1. / &

CARBO-01 1.

STOIC 4 MIXED TETRA-01 -20. / HYDRO-01 -23. / BUTANE 3. / &

BUTANOL 17. / WATER 3.

CONV 1 MIXED MALEI-01 0.98

CONV 2 MIXED MALEI-01 0.01

CONV 3 MIXED MALEI-01 0.01

CONV 4 MIXED TETRA-01 0.01

BLOCK B2 PUMP

PARAM PRES=8.

PROPERTIES NRTL FREE-WATER=STEAM-TA SOLU-WATER=3 &

TRUE-COMPS=YES

BLOCK P101 PUMP

PARAM PRES=40.

BLOCK B3 COMPR

PARAM TYPE=ISENTROPIC PRES=40. SB-MAXIT=30 SB-TOL=0.0001

BLOCK B6 COMPR

PARAM TYPE=ISENTROPIC PRES=40. SB-MAXIT=30 SB-TOL=0.0001

BLOCK C101 COMPR

PARAM TYPE=ISENTROPIC PRES=40. SB-MAXIT=30 SB-TOL=0.0001

BLOCK V101 VALVE

PARAM P-OUT=1.

BLOCK V102 VALVE

PARAM P-OUT=1.5
 PROPERTIES NRTL FREE-WATER=STEAM-TA SOLU-WATER=3 &

TRUE-COMPS=YES

EO-CONV-OPTI

SENSITIVITY F1-DC101

PARAM CASES=NO

DEFINE PRODUCT MOLE-FRAC STREAM=20 SUBSTREAM=MIXED &

COMPONENT=TETRA-01

DEFINE WASWATER MOLE-FRAC STREAM=16 SUBSTREAM=MIXED &

COMPONENT=TETRA-01

DEFINE PURGELOS MASS-FLOW STREAM=22 SUBSTREAM=MIXED &

COMPONENT=TETRA-01 UOM="kg/hr"

DEFINE PURGLOS2 MASS-FLOW STREAM=13 SUBSTREAM=MIXED &

COMPONENT=TETRA-01 UOM="kg/hr"

TABULATE 1 "PRODUCT"

TABULATE 2 "WASWATER"

TABULATE 3 "PURGELOS"

TABULATE 4 "PURGLOS2"

VARY BLOCK-VAR BLOCK=F101 VARIABLE=PRES SENTENCE=PARAM UOM= &

"bar"

RANGE OPT-LIST=RANGE LOWER="10" UPPER="50" INCR="1"

CONV-OPTIONS

PARAM TEAR-METHOD=BROYDEN

WEGSTEIN MAXIT=60

BROYDEN MAXIT=61

STREAM-REPOR MOLEFLOW

;
;