2480271 c1 RU POCCHHICKAS @EEPALIMA ‘@EJEPAIIBHAA CIIYXKBA 110 MHTEJUIEKTY AJIbHOM COBCTBEHHOCTH (1g aby (13) RU 2480 271°" C1 (1) MIIK BOID 67/00 (2006.01) BOID 71/36 (2006.01) BE2¥ 3000 (2011.01) (12) OTMCAHUE W30BPETEHUA K MATEHTY (2122) Basa: 201211081204, 21.03.2012 (24) flara navata orevera epoka zefieraia nareHTa: 21.03.2012, Tpuopuren(i: (22) Alara noaasn vaanKr: 21.03.2012 (45) OnyGumconano: 27.04.2013 Brost. Ne 12 (56) Caucox soxysenron, yruponanmtax orueTe 0 ronexe: RU 2400462 C1, 27.09.2010. SU 1198925 Al, 10.07.1999. US 20080290020 A1, 27.11.2008. WO 2010/126767 A8, 04.11.2010. Anapec suis nepenuext: 350040, r.Kpacuozap, ya. Craspontonpcxas, 149, @EBOY BIO "Ky6TY", omen urrenmexTyaxbMt0m coGcTBeNHOCTA (72) Awroptsi): Tivesaencxas Haranus Jprrpuesna (RU). Hurxoteno Buxrop Bacimbens (RU), Mensunx Hanexna Annpeenna (RU) (73) Marererood.1a.arens(} eneparrsHoe rocynapernenHoe 6rosvxeTHO oGpazonarembHoe yupexkxenme BuIcitero mpospeccionamsHoro o6pasonanns "KyGanicKua rocynapersensih yxusepenrer” (@TEOY BIO "KyéTY") (RU) (54) CIOCOB MOY YEH KOMMO3MMOHHOM KATHOHOOBMEHHOM MEMBPAHBI (57) Peshepar: Haodperenie Mempantioft ormocures x KaTHOHOOGMEHIEEL MeMOpaHl, MCHOMIVEMBIX JUL oBeccommaims —pacropoa —_9ukeK1porntt08 MeroxoM ouleKrpoamamna. Croco nosysentst KOMITOIHUMOHHOM KaTHOHOOGMeHIOR MeMOpattet AKOMAeT HBFOTORIeHHe FEIeHKH HomEMepa Cc YiuepostiBIMH HaHOTpyGKaNH Ha MeMGpante- HowuiomKe, — cHayaia pactsop HoamMepa ¢ yreposwiHiM —-HaHorpyOxamn, oOpadartipaior —YabTpAxByKOM, Honyuemmntt KoMToaT Ha MeMOpany-toLtoxKy nH cymar, Bayete Mew6panni-nost0xx HeHOMIBYIOF cy.nupoKaTHONUTORYIO HonooGMennyIo — MeMGpany, Kommlowtra Gepyr o6paGorannyio yimrpaanykom Hattoeat emect 1-25%-noro pacrsopa cy:tidbuposantoro Homverpadroporatena — © ——_-yrsteposmnaMi HanorpyOKavm, KoTopuit nanocsr Tommumoit, oBecttesRALoMTet paRHOMEpHyIO HLIeHKY, Ha ONY 1H MovepAHOCTeR HexOZNON KarHoHOOGMeNOM MeMOpanb-tlouloaskH, rpeanapHrTetsHo ofevenpennyio, cymar mp2 x0 sammeprenanis, — & ospepraior BOUICICTRNIO DUKTPHYECKOFO TOKA NIpestesDIOM iulorHocrit B TeveHHe Me Menee 100 Textueesist pexyusravom smuseres paapaGorKa, pocrore, aKoLOTHYECKH GevonALKOrO eHEcoGA HomyueHs KoMMOURBIONHO KatHoMOOBMeNOM Mew@pants, rupospoSuocrt 4 yayuntennte MaccooBmenie xapaxtepuctunn. 4 3. its, 3 TaGa, 7 aut, 1 mp. uwetomeit bLzosvz2 nu bo2480271 c1 RU RUSSIAN FEDERATION FEDERAL SERVICE FOR INTELLECTUAL PROPERTY (12) ABSTRACT OF INVENTION ” RU" 2480 274 1 (1) inc BOID 67/00 (2006.01) BOID 71/36 (2006.01) B82¥ 30/00 (2011.01) (2122) Application: 2012110812/04, 21.03.2012 (24) Effective date for property rights: 21.03.2012 Priority (22) Date of filing: 21.03.2012 (45) Date of publication: 27.04.2013 Bull. 12 Mail address: 350040, g.Krasnodar, ul. Stavropol'skaja, 149, FGBOU VPO "KubGU", otdel intellektual'no} sobstvennosti (72) Inventor(s): Pis'menskaja Natalija Dmitrieva (RU), Nikonenko Viktor Vasilevich (RU), Mel'nik Nadezhda Andreevna (RU) (73) Proprictor(s): Federal'noe gosudarstvennoe bjudzhetnoe obrazovatel'noe uchrezhdenic vysshego professional'nogo obrazovanija "Kubanskij gosudarstvennyj universitet” (FGBOU VPO "KubGU") (RU) (54) METHOD OF MAKING COMPOSITE CATION-EXCHANGE MEMBRANE (57) Abstract: FIELD: process engineering. SUBSTANCE: invention relates to membranes, namely, to fabrication of cation-exchange membranes used for electrolyte solution desalination by electrodialysis. Proposed method comprises making polymer film with carbon nanotubes on membrane substrate. First, polymer solution is mixed with carbon nanotubes and processed by ultrasound. Produced applied on substrate Said membrane ‘membrane substrate composite is sand dried. represents a sulfecationite ion-exchange membrane while composite represents 1-25%-mix of sulfonated polytetrafluoroethylene with carbon nanotubes processed by ultrasound. Said solution is applied to ‘make uniform film on one of initial cation-exchange pre-degreased membrane substrate to be dried at 25- 80°C unless hardening. Now, itis subjected to limit- density electric current for, atleast 100 hours. EFFECT: efficient process, higher hydrophobic property and better mass exchange characteristics Sel, 3tbl, 7 dwg, Lex bLzosvz2 nu boRU 2.480271 CL Voo6perenne oTHocnres K MeMGpanHoit TeXHHKe H TEXHOMOTHH, a HMeHHO TlomyeHHIO KaTHOHOOGMeHHBIX MeMOpaH, HeTIOsbSYEMbIX U1 OO€CCOMMBAHH PACTBOPOB INeKTPOTHTOB MeTOJOM sneKTpomHasIHa, Vosnectes cnoco6 nony4enitt HoHOOOMEHHOM MeMGpanbr 3 conomHMepa TetpadropoTHeHa, BKMOUAIOUNL HaTOXKEHHE MEHOK Apyr Ha Apyra, TepMateckyto oGpaGorky no aapmeHHMeM pH 170-300°C nom AaBTeHHeM 8-87 Kr/eM? 2-10 MMH TOCTEAYIOMUNM OXTAKTCHHEM TIPH TOM 7Ke AABNEHHH, COCAMHAEMBIE MOBEPXHOCTH MTEHOK Teper HANOKCHHEM MOABEPTAlOT IHEPOXOBAHHIO, OGEHKUPHBAHMTO, 3aTEM OOPAdorKe B 1- 95¢%-HOM BOAHOM pacTBope OpranHyeckoro pacTBopHTests 0,25-4 4 (maTeHT Pd Ne1 198935, MITK(6) CO8J 5/22, ony6.1, 10.07.1999). HezoctaTKom HaBecTHOFO criocoGa sBAAeTeR ero TPYAOEMKOCTS H IHEproeMKOCTE. HanSonee 6ansknM anamorom K 3aRBTeMOMY ABAAIETeR cOCOS WITOTOBTEHHA KOMMOSHTA MosHMeEp/yTepOAHbIE HAHOTPYOKH Ha NOAIOAKE, BKITOYAIOUIMT PAacTBOPEHHE TOAHMEpa B MepBOM PacTBOPHTENe, KAK TO: TOMLYO.T, MeTAHONI, GeHSOUI, NpH TeMnepatype 90°C, o6paGorky yabrpasBYKOM HaXOAAILEXCR BO BTOPOM pacrBopHTeste (aumeribopmamiea) auta yraepogusix HaHoTpyGoK (VHT). Cmeumpanite pacrsopentoro nonuMepa ¢ pacrsopom VHT 1 o6pa6orky yabrpasayKoM mosy4eHHOro pacrBopa OcyIeCTBASIOT B MpHCYTCTBHH MepeMeHHOTO MarHHTHOTO Tosa B TeHeHHe BpeMeHt, AocraTouHoro ans pacnpererenns VHT no sceft Marpe nommMepa, a 3aTeM HaHeceHHe KOMNOSHTa Ha TOATOKKY H TepMoobpadorky, KOTOpHIE NPOHCKOAAT B MpHcyTeTBHH TOCTOsHHOTO MarHiTHOrO Hosts (TlaTeHT Pd Ne2400462, MITK(S1) CO7C 1/00 (2006.01), B82B 1/00 (2006.01), ony6u1. 27.09.2010). Heaocrarkom H3BectHoro cocoa sBnseTCA ero MHOrocTaHHHoCTh H TPY.10eMKoCT. TexHHdeckHM peaysIbTaTOM saxBNAeMOro HBOSpETeHHs ABNAETCA PaspaGorka NpocTOro, SKOMIOTHYECKH GeIOHACHOTO CHlOCOGA NOMyYeHHS KOMMOIMUMOHHOH KaTHOHOOGMEHHOF MeMGpanbl, HMcIOULeH BLICOKYIO CTeneHb FHAPOdPOGHOCTH H YaIYYULEHHbIE MAccooGMEHHDIE XapakTepHcTHKH, TexHMMeCKHA pesyinbTaT JOCTHTAeTCA TEM, 4TO CHOCOG MOAYYeHHS KOMMOSHIOHHOM KaTHOHOOGMEHHOM MeMGpaHb! BKAOGET HSFOTODLMEHHE MLICHKH TlONMEpa € YrIepOAHBIMH HaHoTpy6Kamu Ha MeMGpanie-rowvioxkke. PactBop HonlMepa CMeLIMBAIOT © YrsIepoHBIMHL HAHOTPYOKAMH, OOpaGaTHIBAIOT YTbTPAIBYKOM, a 3ATEM HAHOCAT TOAYEHHBIH KOMMOSHT Ha MeMGpaky-llowtoxky H NoABepratoT TepMooSpaGorke. B kayecTBe MeMGpaHbl- TOATORKH HCNOMTESYIOT Cy:T(hOKATHOHHTOBYIO HOHOOOMEHHYIO MeMOpaHY, B KaecTBe KOMNosHTa GepyT OSpaSoTaHHy!o ynbTpAsByKOM eMecb 1-25%-HBIFL pacTBOpA cynbduposanHoro noaMTeTpadTopsTimena ¢ YrAepOAHBIMH HAHOTPYOKAMH, KOTOPBIAL HAHOCST TORMIMHOA, OGecTeMMBATOMLeh PABHOMEPHYIO MUTCHKY, Ha OAHY H3 MOBepXHOCTeM HCXOAHOM KATHOHOOSMEHHOM MeMOpaHbI-NOATOKKH, MPeABAPHTEMBHO OGEHKUPEHHYTO, cymat npn 25-80°C 0 saTBepaenanna, a 3aTeM NloaBepraroT BOSAeICTBMIO 3neKTpHIECKOTO ToKa MpeaeAbHOH MTOTHOCTH B TeteHHE He MeHee 100 acon. Boxlelicrie sitekrpHteckHM TOKOM MOXHO OCyUeCTBIATS, HANpHMeED, B omeKTpomHamHaHOn atefiKe, MpetenbHax MNOTHOCTS TOKA MOET GbIT ONpereNeHa KAK 9KCTIepHMeHTAABHO, TAK H TeOpeTHYECKH, HO He MeHee 2 MA/cM?, OKcepHMeHTATbHO BEIABMEHO, TO HanHUne 3% YrepoAHBIX HaHOTOpYGOK B CIITDI SBARETCA ONTHMATBHBIM, T.K. TIP MEHBUIEM HX COepKAHHH He TIOMy4aeM MOATBEPATCHHE TeXHHMECKOTO PesysTbTATA, a GOMbIIIEE HX KOMAHECTBO MPH AOCTHKEHHH TEXHHYECKOTO esyAIBTATA CyINECTBEHHO BIHKET Ha CTOHMOCTS MeMOpaHil B oramue of nporotuna B npeanaraemom cnocoGe HcrlombsyIoT o”MH pacTRopHTeb HonuMepa, oGpadorky yabTpasByKOM eMecH cymbHpoBANHOrO omMTeTpapTopsTiTeHa C op: 3