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Received 6 November 2000; received in revised form 31 January 2001; accepted 22 February 2001
Abstract
Scratch test provides a convenient mean to study mechanical properties of thin coatings. The mechanical analysis of this test is very
intricate, especially for polymers, for which a large elastic part accompanies the plastic deformation. Most existing models describe the
ploughing of a rigid plastic body by a rigid indenter. This paper describes a numerical study of the behavior of elastic–plastic materials
during a scratch test. Simulations have been performed with a three-dimensional finite element code, the indenter is a cone of semi-angle
70.3◦ and the contact is frictionless. The scratched material is elastic and perfectly plastic, with a constant flow stress σ0 . For small Young’s
modulus, a sinking-in under load and an elastic recovery at the rear face of the indenter have been observed. In order to take into account
this elastic recovery, we have suggested a new model of the apparent coefficient of friction. For high Young’s modulus, the deformation
is mainly plastic, the behavior was close to the behavior of a metal, frontal and lateral pile-up pads have been observed. The scratch
hardness and the shape ratio have been compared with results obtained in normal indentation under the same conditions: geometry under
load is similar, but the deformation level is higher for scratch than for indentation. We have found a good agreement for the shape ratio
between our numerical results and scratch experiments performed by other authors with a Berkovich pyramid on elastic–plastic materials.
© 2001 Elsevier Science B.V. All rights reserved.
Keywords: Scratch; Indentation; Hardness; Elastic–plastic deformation
1. Introduction on metals. Polymers coating are more and more often used
to increase scratch resistance in many applications: paintings
Scratch test is mainly used to study mechanical properties for automobile industry or optical devices. So, surface de-
of materials near their surface. Understanding of this test is formation mechanisms on polymers have been investigated
of great interest to both academic and industrial communi- for about 10 years [7–9]. Because of the large elastic re-
ties. The scratch hardness and surface deformation mecha- covery of this kind of materials, analysis of this test is far
nisms of materials depend in particular on the rheology of more difficult than for metals. To compute scratch hardness,
the material, the friction at the interface and the indenter ge- Briscoe et al. [9] have considered that for all scratch con-
ometry. Optical observations of the residual groove and the ditions (scratch speed, angle of the indenter) the elastic re-
measure of the apparent coefficient of friction, µ0 = Ft /W , covery is complete at the rear face of the indenter (Fig. 1).
the ratio of ploughing force, Ft , to normal force, W , are im- Gauthier and Schirrer [10] have built a new apparatus to
portant to understand what it occurs during a scratch test evaluate the real contact area under load. Jardret et al. [11]
(Fig. 1). have suggested a model of the apparent coefficient of fric-
Authors have first studied mechanical behavior of metals tion in order to compute a mean contact pressure for a wide
during a scratch test [1,2]. Goddard and Wilman [3] have range of elastoplastic materials.
suggested analytical models for the ploughing, adhesion and In this paper, the influence of the rheology during the
apparent coefficients of friction of several indenters plough- scratch test was studied, the material was modeled with an
ing along a surface of metal. Three-dimensional models of elastic perfectly plastic rheology. This test was modeled with
the ploughing of a rigid plastic material by a hard pyramid a three-dimensional finite element code: Forge3® . Its auto-
have been proposed [4–6]. All these studies concern scratch matic remeshing procedure allows to simulate such a test
with high deformations. The contact between the indenter
∗ Corresponding author. Tel.: +33-493-957428; fax: +33-493-654304. and the material is frictionless, and the indenter is a cone
E-mail address: eric.felder@cemef.cma.fr (E. Felder). of semi-apical angle 70.3◦ . This indenter is the equivalent
0043-1648/01/$ – see front matter © 2001 Elsevier Science B.V. All rights reserved.
PII: S 0 0 4 3 - 1 6 4 8 ( 0 1 ) 0 0 5 3 8 - 5
J.L. Bucaille et al. / Wear 249 (2001) 422–432 423
Table 1
Young’s modulus and rheological factors used in the numerical simulations of scratch
X 1 5 10 20 30 60 80 100 200 1000
E (GPa) 2.793 13.96 27.93 55.86 83.80 167.6 223.4 279.3 558.6 2793
So, in order to limit the CPU time we have decided to choose Table 2
the smaller size of the domain: 35 mm along the x-axis, Sizes of the domain for the preliminary simulations of scratch for X = 60
220 mm along the y-axis and 25 mm along the z-axis. This x (mm) y (mm) z (mm)
analysis shows that a distance of the indentation from the 35 220 25
edge of the specimen equal to 1.5 times the diameter of the 50 200 25
indentation is large enough to induce small boundary effects. 70 250 35
As Tabor [14] has suggested, the thickness of the specimen
is eight times the depth of the indentation.
The indenter speed is equal to 10 mm/s. The scratch length the residual scratch, the mesh size inside this box is equal
is chosen in order that the normal and tangential forces ap- to 3 mm. These boxes move with the indenter. We have not
plied on the indenter reach a steady state. The elements of studied the influence of the size of the elements inside these
the domain are three-dimensional meshes with four nodes boxes on the forces and on the scratch width. The simula-
tetrahedrons. Far from the indenter, the tetrahedrons have a tions require 4000 nodes and 13 000 elements. To simulate
typical length about 5 mm. With the Forge3® software par- one scratch, it requires between 24 and 54 h of CPU time.
allelepiped boxes are used, in which the mesh is refined. For each time increment, normal and tangential forces
Two mesh boxes were used: the first one is in front of the are computed. At the end of the simulation, the residual
indenter, the size inside this box is equal to 1 mm, so that morphology is also measured. A post-processing procedure
10 nodes are at least in contact with the indenter. This box gives the mean of several geometrical parameters such as
allows to describe the deformation and the contact geome- the scratch width and the pile-up height. The definition of
try with sufficient accuracy. A second mesh box describes these geometrical parameters will be provided later.
Fig. 2. Three-dimensional view of the indenter and the mesh for the simulations of scratch.
J.L. Bucaille et al. / Wear 249 (2001) 422–432 425
Fig. 4. Top view of the contact area between the indenter and the mesh (simulation). All the figures have the same scale.
426 J.L. Bucaille et al. / Wear 249 (2001) 422–432
Table 3
The α angle obtained with the results of the numerical simulations
X 1 5 10 20 30 60–1000
α (◦ ) 78 33 17 13 12 0
Fig. 6. Comparison between the frontal and the lateral contact radius for Fig. 7. Comparison between the apparent coefficient of friction computed
several values of the rheological factor X (simulation). with Eq. (5) and the one obtained with the numerical simulations.
J.L. Bucaille et al. / Wear 249 (2001) 422–432 427
where ‘elt’ are the elements of the mesh for which the equiv-
alent plastic strain is lower than the critical value of the
equivalent plastic strain, εeq
c , and is 10% higher than the crit-
ical value of the equivalent plastic strain (Table 4). V elt and
εeq
elt are, respectively, the volume and the equivalent plastic
fall to zero after several time increments (Fig. 9). The chosen to compute εv , for X = 100. This procedure allows
software often remeshes the domain. At each remeshing to have a constant εv as the scratch length increases. In the
procedure, the value of the equivalent plastic strain of each other hand, εeq c is chosen arbitrarily, and the value of ε
v
element is transported to a new element, this transport im- depends of the value of εeq c . This procedure will have to be
plies some lost in the value of the equivalent plastic strain. improved in order not to depend on the choice of εeq c .
So, for simulation of scratch, for which there is about one The volume average deformation, εv , was computed with
remeshing procedure for eight time increments (600 times Eq. (8); for each simulation, the volume average deformation
increments for a complete simulation), equivalent plastic has been computed for six time increments, the mean value
strain falls quickly from 1.8 to 0.2 (Fig. 9). Furthermore, in and the error bar are plotted in Fig. 10. These points are fitted
order to reduce the CPU time, elements in the groove of the by a logarithmic regression for X ≤ 200. For rheological
factors higher than 200, the volume average deformation
is quite constant. It has been confirmed with a simulation
with a rheological factor equal to 500. The choice of the
critical value of the equivalent plastic strain determines the
level of the volume average deformation. For example at
X = 30, as the critical value of the equivalent plastic strain
is increased from 1 to 2.5, the volume average deformation
increases to 50%. It means that we must not focus on the
value of the volume average deformation, but rather consider
its evolution versus the rheological factor X.
The volume average deformation increases as the rheo-
Fig. 9. Equivalent plastic strain in the plane x = 0 for X = 100. For logical factor increases, for X ≤ 200 (Fig. 10): the deforma-
more legibility, the indenter has been removed (simulation). tion level is twice as large for X = 100 than for X = 10. It
428 J.L. Bucaille et al. / Wear 249 (2001) 422–432
Table 4
Critical value of the equivalent plastic straina
X 1 5 10 20 30 60 80 100 200 500 1000
εeq
c 0.1 0.5 1 1 1.5 2 2 2 2 2.5 2.5
a This equivalent plastic strain is used to compute the volume average deformation.
cone:
E
εv = 1.15 log cot θ cot θ, X ≤ 200 (9)
σ0
εv = 2.61 cot θ, X > 200 (10)
Fig. 11. Side view of the scratch in the plane x = 0 for X varying from 1 to 1000 (simulation). The scale along the x-axis and the z-axis are different.
J.L. Bucaille et al. / Wear 249 (2001) 422–432 429
2W
Hs1/2 = (11)
al2
Fig. 15. Ratio between the scratch hardness computed with the whole
contact area and the normal hardness computed by Ramond-Angélélis Fig. 16. Schematic profile of a scratch under load and after unloading,
[12] in simulation of indentation. for X = 5. Definition of several geometrical parameters.
J.L. Bucaille et al. / Wear 249 (2001) 422–432 431
Fig. 17. Shape ratio computed in scratch and in indentation from Fig. 18. Evolution of ha over the penetration depth ratio as a function
Ramond-Angélélis [12] (simulation of indentation). of the rheological factor. Experimental results obtained by Jardret et al.
[12] are compared to numerical results from this work.
material, and for plastic material like metals the deformation [4] P. Gilormini, E. Felder, Theoretical and experimental study of the
level is far higher than for polymers. ploughing of rigid plastic semi-infinite body by a rigid pyramidal
Hardness computed with the whole contact area is always indenter, Wear 88 (1983) 195–206.
[5] A.A. Torrance, A three-dimensional cutting criterion for abrasion,
lower than hardness computed with the lateral contact radius, Wear 123 (1988) 87–96.
the difference is between 20 and 7%. Comparisons with [6] M. De Vathaire, F. Delamare, E. Felder, An upper bound model of
the indentation case have revealed that the behaviors are ploughing by a pyramidal indenter, Wear 66 (1981) 55–64.
quite similar, the ratio between the scratch hardness and the [7] B.Y. Ni, A. Le Faou, Scratching behaviour of polymer films using
normal hardness decreases from 1.2 to 0.9. blunt spherical styli, J. Mater. Sci. 31 (1996) 3955–3963.
[8] B.J. Briscoe, P.D. Evans, S.K. Biswas, S.K. Sinha, The hardness of
The shape ratio is higher in scratch but the general poly(methylmethacrylate), Tribol. Int. 29 (1996) 93–104.
shape of the curve is similar to the one observed by [9] B.J. Briscoe, E. Pelillo, S.K. Sinha, Scratch hardness and deformation
Ramond-Angélélis [12]. It suggests that during a scratch maps for polycarbonate and polyethylene, Polym. Eng. Sci. 36 (1996)
test strains are higher than during an indentation test, for 2996–3005.
the same indenter. Experimental study with a Berkovich [10] C. Gauthier, R. Schirrer, Time and temperature dependence of the
scratch properties of poly(methylmethacrylate) surfaces, J. Mater.
indenter shows a good correlation with our results. We have Sci. 35 (2000) 2121–2130.
suggested a relation between the residual scratch morphol- [11] V. Jardret, H. Zahouani, J.L. Loubet, T.G. Mathia, Understanding
ogy and the rheological factor. and quantification of elastic and plastic deformation during a scratch
test, Wear 218 (1998) 8–14.
[12] C. Ramond-Angélélis, Analyse mécanique des essais d’indentation
sur matériaux élasto-plastiques homogènes ou multi-couches.
Acknowledgements Application à la caractérisation de la rhéologie et de la tenue
mécanique des films minces, Ph.D. thesis, Ecole Nationale Supérieure
Essilor INTL Coatings Research and Development des Mines de Paris, 1998.
[13] K.L. Johnson, The correlation of indentation experiments, J. Mech.
is acknowledged for its interest for the results and its Phys. Solids 18 (1970) 115–126.
financial support for part of this work. We wish to express [14] D. Tabor, The hardness of solids, Proceedings of the Institute of
our thanks to Dr. P. Montmitonnet for helpful criticisms of Physics F, Physics in Technology 1 (1970) 145–179.
this text. [15] P.D. Evans, The hardness and abrasion of polymers, Ph.D. thesis,
London University, London, 1987.
[16] D. Tabor, The Hardness of Metals, Clarendon Press, Oxford, 1951.
[17] J.L. Bucaille, E. Felder, G. Hochstetter, Finite element analysis
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