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Metals
These have high melting point, have very low vapour pressure, are very good
conducts of heat, are chemically inert and act as electrical insulators. Therefore,
these oxides are used for lining furnaces and hence used as refractory materials.
Due to small size of beryllium ion, BeO is covalent but still has high melting
point because of its polymeric nature.
Be(OH)2 and Mg(OH)2 being insoluble are obtained from suitable metal ion solutions
by precipitation with OH- ions.
The solubility of the alkaline earth metal hydroxides in water increases with
increase in atomic number down the group. This is due to the fact that the lattice
energy decreases down the group due to increase in size of the alkaline earth
metals cation whereas the hydration energy of the cation remains almost unchanged.
The resultant of two effects i.e.
Becomes more negative as we move from Be(OH)2 to Ba(OH)2 which accounts for increase
in solubility.
Halides of Alkali Earth Metals
The alkaline earth metals combine directly with halogen at appropriate temperature forming halides MX 2.
These halides can also be prepared by the action of halogen acids (HX) on metals, metals oxides, hydroxides
and carbonates.
M + 2HX → MX2 + H2
The halides of all other alkaline earth metals are ionic. Their ionic character, however increases as the size of
the metal ion increase.
Except BeCl2 all other chlorides of group 2 form hydrates but their tendency to form hydrates decreases for eg
–
MgCl2.6H2O, CaCl2.6H2O.
The hydrated chloride, bromides and iodides of Ca, Sr and Ba can be dehydrated on heating but those of Be
and Mg undergo hydrolysis.
BeF2 is very soluble in water due to the high hydration energy of the small Be+2ion. The other fluorides (MgF 2,
CaF2, SrF2 and BaF2) are almost insoluble in water. Since on descending the group lattice energy decreases
more rapidly than the hydration energy. Therefore whatever little solubility these fluorides have that increase
down the group.
The chlorides, bromides and iodides of all other elements i.e. Mg, Ca, Sr, Ba are ionic have much lower
melting points than the fluorides and are readily soluble in water. The solubility decreases some what with
increasing atomic number.
Except of BeCl2 and MgCl2, the other chlorides of alkaline earth metals impart characteristics colour to flame.
CaCl2 = Brick red colour
SrCl2 = Crimson colour
BaCl2 = Grassy green colour
Uses
Calcium fluoride or fluorospar (CaF2) is by far the most important of all the fluorides of the alkaline earth
metals since it is the only large scale source of fluorine.
CaCl2 is widely used for melting ice on roads, particularly in very cold countries because 30% eutectic mixture
of CaCl2/ice freezes at 218 K as compared to NaCl /ice at 255K.
M + H2SO4 → MSO4 + H2
Solubility:The solubility of the sulphates in water decreases down the groups i.e. Be > Mg > Ca > Sr > Ba.
Thus BeSO4 and MgSO4 are highly soluble, CaSO4 is sparingly soluble but the sulphates of Sr, Ba and Ra are
virtually insoluble.
Reason
The magnitude of the lattice energy remains almost constant as the sulphate is so big that small increase in
the size of the cation from Be to Ba does not make any difference. However the hydration energy decreases
from Be+2 to Ba+2 appreciably as the size of the cation increase down the group. Hence, the solubilities of
sulphates of alkaline earth metals decrease down the group mainly due to the decreasing hydration energies
from Be+2 to Ba+2. The high solubility of BeSo4 and MgSO4 is due to high hydration energies due to smaller
Be+2 and Mg+2 ions.
Stability: The sulphates of alkaline earth metal decompose on heating giving the oxides and SO 3.
MSO4 MO + SO3
The temperature of decomposition of these sulpahtes increases as the basicity of the hydroxide of the
corresponding metal increase down the group
Mg + H2SO4 → MgSO4 + H2
The resulting solution upon concentration and cooling gives crystals of MgSO 4.7H2O.
Isomorphism: MgSO4.7H2O is isomorphous with ZnSO4.7H2O & FeSO4.7H2O compounds having same crystal
structure are called isomorphous and the phenomenon is called Isomorphism.
Action of Heat: When heated it losses 6 molecules of water to give Magnesium sulphate monohydrate which
becomes anhydrous when heated to 503 K and finally decomposes to MgO & SO3 gas on strong heating.
It is used in preparation of platinised asbestors which is used as a catalyst in the contact process for the
manufacture of H2SO4.
Illustrations.
Question:
What are isomorphous salts?
Solution:
The salts having the similar crystal structure are called isomorphous salts.
Examples: MgSO4.7H2O, ZnSO4.7H2O, FeSO4.7H2O
Oxides of Magnesium and Calcium
MgO (Magnesia)
It is made by heating magnesite (MgCO3).
The temperature should not be raised above 1270 K. Otherwise silica present as impurity in lime will combine
with calcium oxide to form infusible calcium silicate.
CaO + SiO2 CaSiO3
(ii) Properties
It is white amorphous powder, which emits intense white light (lime light), when heated in the oxy-hydrogen
flame.
It reacts with strongly heated silica,forming easily fusible calcium silicate.
CaO + SiO2 → CaSiO3
CaO reacts with water evolving huge amount of heat and produce slaked lime.
CaO + H2O → Ca(OH)2
Action of acids and acidic oxides : It is a basic oxide and hence combines with acids and acidic oxides
forming salts.
CaO + 2HCl → CaCl2 + H2O
CaO + SO2 → CaSO3
Reaction with coke: When heated with coke in electric furnace at 2273 – 3273 K, it forms calcium carbide.
CaO + 3C CaC2 + Co
It is used in lime soda process for the conversion of Na 2CO3 to NaOH & vice versa.
It is used for softening water, for making slaked lime Ca(OH) 2 by treatment with water and calcium carbide
CaC2.
Illustration
Question :
Why does a piece of burning magnesium continue to burn in SO2?
Solution:
This is because the reaction of Mg with SO2 is exothermic.
2Mg + SO2 → 2MgO + 1/8S8 + Heat
Hydroxides of Mg & Ca
From calcium chloride: It is obtained by treating calcium chloride with caustic soda.
CaCl2 + 2NaOH → Ca (OH)2 + 2NaCI
(ii) Physical Properties Calcium Hydroxide
It is a white amorphous powder sparingly soluble in water, the solubility
decreasing further with rise in temperature. An aqueous solution is known as lime
water and a suspension of slaked lime in water is called milk of lime.
Illustration.
Question :
Which is the weakest base among NaOH, Ca(OH)2, KOH and Be(OH)2
Solution:
Be(OH)2 is weakest base , because alkali metal hydroxides are more stronger base than alkaline earth metal hydroxides. Also basic
group. So Be(OH)2 is the weakest one.
Illustrations.
Question :
Thermal decomposition of a compound 'X' yields, a basic oxide ( Y ) and acidic oxide( Z ) simultaneously. The acidic oxide(Z) can be
Solution:
CaCO3 (X) → CaO (Y) + CO2 (Z)
It is used as a raw material for the manufacture of Na2Co3 in solvay – ammonia process.
Commercial limestone contains iron oxide, alumina, magnesia, silica & sulphur with a CaO content of 22 –
56% MgO content upto 21%. It is used as such as a fertilizer
.
Bicarbonates of Mg & Ca
Calcium bicarbonate [Ca(HCO3)2]
It is obtained when CaCO3 is dissolved in water containing CO2 but it remains in the solution form
CaCO3 + H2O + CO2→ Ca(HCO3)2.
Illustrations.
Question :
NaHCO3 and NaOH cannot exist together in solution- Why?
Solution:
NaHCO3 is an acid salt which must react with NaOH which is strong base. The reaction is as follows:
NaHCO3 + NaOH → Na2CO3 + H2O
Halides of Mg & Ca
Calcium Chloride (CaCl2×6H2O)
It separates out as deliquescent crystals when a solution of lime or calcium carbonate in HCl is evaporated.
The effect of heat on gypsum or the dihydrate presents a review of interesting changes. On heating the
monoclinic gypsum is first converted into orthorhombic form without loss of water. When the temperature reaches
120°C, the hemihydrate or plaster of paris is the product. The latter losses water, becomes anhydrous above
200°C and finally above 400°C, it decomposes into calcium oxide.
The temperature should not be allowed to rise above 393 K because above this temperature the whole of
water of crystallization is lost. The resulting anhydrous CaSO4 is called dead burnt plaster because it does not
have the properties of setting with water.
The gypsum should not be allowed to come in contact with carbon containing fuel otherwise some of it will be
reduced to calcium sulphite.
a d a d
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