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Van der Waals:

 

P +

a

v

2

 

(

v

b

)

=

RT

Van der Waals:

 

P

+

a

v

2

 

(

v

b

)

=

RT

a =  

27

64



2

2

R T

c

P

c

1
b = 

 
8

RT

c

P

c

Berthelot:

 

P

+

a

Tv

2

 

(

v

b

)

=

RT

Redlich - Kwong (RK)

a =

b =

P =

RT

v

b

0.42748

2

2.5

R T

c

P

c

0.08664 RT

c

P

c

RK

=

a

RK

/

v v

(

+

T

b

)

Soave - Redlich - Kwong (SRK)

RT

v

P =

SRK

 b ( v v + b ) + 1.55171 0.15613

0.42747

2

2

R T

c

a =

P

c

0.08664 RT

c

=

a

P

c

 

1

+

(

b =

0.48508

SRK

2

)(

1

0.5

r

T

)

 

2

Peng - Robinson (PR):

a =

b =

PR

P =

RT

v

b

PR

v

2

+

2

bv

b

2

0.45724

2

2

R T

c

P

c

0.07780 RT

c

= a

 

P c

1

+

(

0.37464

+ 1.54226

0.26992

2

)(

1

0.5

r

T

)

 

2

Forma General

P =

RT

(

v

b

)

 

v

2

+

v

+

 

 Autor Año Ɵ δ ε Van der Waals 1873 0 0 Berthelot 1899 / 0 0 Redlich-Kwong 1949 / b 0 Soave 1972 Ɵ s (T) b 0 Peng-Robinson 1976 Ɵ PR (T) 2b -b 2

Forma General

2
Z 3
+
Z
+
Z +
= 0
EN FUNCIÓN DEL FACTOR DE COMPRESIBILIDAD
 Van der Waals Soave – Redlich - Kwong Peng - Robinson α -(1+B) -1 -(1-B) β A A-B-B 2 A-2B-3B 2 γ -AB -AB -(AB-B 2 -B 3 )

Forma General

Z

B

A

Pv
=
RT
bP
=
RT
P
2 Para las ecuaciones de VdW, SRK y PR
(
RT )
= 
P
En la ecuación de estado de RW
2
2.5
(
R T
)

OTRAS ECUACIONES

Dieterici

P

a

b

=

RT

(

v

b

)

e

2

2

c

4 R T Pe

Pe

=

c

RT

c

2

c

2

=

 

a

RTv

 

Beattie - Bridgeman

Pv RT v B

=

+

2

0

 

1

b

v



 

1

C

vT

3

 

A

0

 

1

a

v

 

Benedict-Webb-Rubin (BWR)

P

=

RT

v

+

RTB A

0

0

C

0

T

2

v

2

+

RTb a + a v

3

C

 

+

6

3

2

v vT

1 +

v

2

 

e

   v  

2

Virial:

Pv

=

A

+

B

C

+
2
v
v

++

 Autor Año Ɵ ƞ δ ε Δ Van der Waals 1873 b 0 0 Clausius 1880 / b 2c c 2 / ( + ) Berthelot / b / 1899 0 0 / Redlich-Kwong 1949 / b b 0 ( + ) ( ) Soave 1972 Ɵ s (T) b b 0 ( + ) Lee-Erbar-Edmister 1973 Ɵ L (T) ƞ(T) b 0 − ƞ( ) ( − )( + ) Peng-Robinson 1976 Ɵ PR (T) b 2b -b 2 + + ( − ) Patel-Teja 1981 Ɵ PT (T) b b+c -cb + + ( − )