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Februar 2015 10:10 10

Abbreviations and Symbols

Information on purity and application
컄 see
[] Chemical Abstracts Registry Number (CAS)
CHR A compound in this catalogue is designated as being
> more than
thin-layer chromatographically pure (CHR) if no
< less than impurities can be detected during test conditions
min minimum with 20 µg sample.
max maximum ~CHR For products with impurities which under our
conditions, (see CHR), allow the main compound
µm 0,001 mm
to be designated; such products can be identified
~ approximate as being "almost thin-layer chromatographically
[α]a specific rotation pure" (~CHR).
+4°C storage in refrigerating room C.I. No colour index number
-20°C storage in deep-freeze room conc. concentrated
® registered symbol, registered trade mark cP centipoise
ë corrosive cryst. crystallized
í explosive cSt centistoke
è=/ è+ highly flammable / extremely flammable D density
ç fire-activating, oxidizing DAB Deutsches Arzneibuch
ê=/ ê+ toxic / very toxic (German Pharmacopoeia)

én harmful DAC Deutscher Arzneimittel-Codex

(German Drugs Codex)
éi irritant
DC thin-layer chromatography
f dangerous for the environment
dec. decomposition
m GHS01 exploding bomb
depur. depuratum, purified quality
l GHS02 flame dest. distilled

o GHS03 flame over circle DIN German Industrial Standards

E No number codes for food additives that have been
k GHS04 gas cylinder assessed for use within the EC

h GHS05 corrosion EC No the official number of a chemical substance that is

commercially available within the EC
i GHS06 skull and crossbones extra pure suitable for laboratory use

g GHS07 exclamation mark F melting point, melting range

FCC Food chemical codex
n GHS08 health hazard
FIP Fédération Internationale Pharmaceutique
j GHS09 environment Flp flash point
Å Ångström = 10-10 m g gramme
ACS American Chemical Society GC gas chromatography
ADR European agreement on international road transport (GC) content defined by gas chromatography
of hazardous goods H Hazard statement acc. to regulation
AW atomic weight (EC) No 1272/2008 (CLP, GHS)
Amp. ampoule HPLC high performance liquid chromatography
aq water IE international unit (Internationale Einheit)
art. artificial ISO International Organization for Standardization
asym. asymmetrical IU international unit
AT argentometric titration JP Japanese Pharmacopoeia
BP British Pharmacopoeia kg kilogramme
bp boiling point, boiling range l, ltr litre
bp12 boiling point at 12 torr Lit. literature
c amount-of-substance concentration LSC liquid scintillation counting
CAS Chemical Abstract Service lyophil. lyophilized (readily soluble form)
CELLPURE® suitable for cell culture M or mol/l molarity, amount-of-substance concentration
GB_25_Abkuerzungen_Symbole_2015.fm Seite 2123 Montag, 2. Februar 2015 10:10 10

Abbreviations and Symbols

M molecular weight or molar mass ROTICUBE® Combi-box of 5 litre or 10 litre, consisting of a stable
mg milligramm outer card box with inner bag made of PE; comes with
stopcock.
ml mililitre
ROTIDRY® dried solvents, filled under protective gas
Mol.% molar percent
ROTIDRY®SEPT dried solvents, in a septum bottle
nat. natural
ROTIGEN® product is suitable for DNA-synthesis
nD refractive index
ROTIPHORESE® product is suitable for electrophoresis
o.r. on request
ROTIPURAN® highly pure product
P Precautionary statement acc. to regulation (EC) No
1272/2008 (CLP, GHS) ROTISOLV® solvent for specific use - brand name Roth
Pa s Pascal second ROTITAINER® Stackable containers which can also be handled
easily by female workers. Matching safety pumps are
p.a. pro analysi = for analytical purposes available. Solid substances are delivered in plastic
Pestilyse® solvent, suitable for residue analysis buckets.
(environmental, water and food analysis) S Safety statement acc. to regulation 67/548/EEC
pH pH value sec. secondary
pKa pKa value sicc. dry, anhydrous (siccus)
pharm. pharmaceutical quality, for pharmaceutical purposes sine H2O water free
Ph.Eur. European Pharmacopoeia stab. stabilized
ppb parts per billion = 1 µg per kg subl. sublimated
ppm parts per million = 0,0001 %, 1 mg per kg sym. symmetrical
ppt parts per trillion = 1 ng per kg synth. synthetic
prim. primary techn. technical quality. Products with the purity designation
PUFFERAN® can be used as buffer "technicum" feature a different content. They are
pulv. pulverised generally mass produced and may have a slightly
foreign odour and colour. They are used for general
pure suitable for synthesis and laboratory use
technical purposes.
puriss. purissimum, especially pure quality. Products with
tert. tertiary; standard for thin-layer chromatograhy (TLC)
such designation have a content of at least 99%,
unless a different content is stated in %. Their TLC thin layer chromatography
appearance and characteristic data correspond to the U unit
appertaining literature or deviate only slightly from it. USP United States Pharmacopoeia
They are suitable for purposes requiring a high degree
of purity. With a number of products having this WGK water hazard class
degree of purity, analysis certificates plus guarantee WGK 1 generally not water hazardous
will be supplied or attached to the container. Delicate WGK 2 water hazardous
products are packaged under protective gas.
WGK 3 extremely water hazardous
purum chemically pure quality. Products having the purity
designation "purum" have a content of at least 97%,
unless a different content is stated, and their colour
and characteristic data, apart from minor deviations,
correspond to the literature. This degree of purity is
recommended for laboratory work such as syntheses,
which are subject to purity requirements.
Delicate products are packaged under protective gas.
R Risk statement acc. to regulation 67/548/EEC
rect. rectification
redest. redistilled
resubl. resublimated
ROTICHROM® suitable as standard in chromatography
ROTICHROM®GC reference substance for gas chromatography,
delivered with GC chromatogram
ROTICHROM®HPLC reference substance for HPLC, delivered with HPLC
chromatogram
ROTICHROM®TLC reference substance for thin-layer chromatography,
delivered with thin-layer chromatogram
GB_26_R_und_S_Kennzeichnung_2015.fm Seite 2124 Montag, 2. Februar 2015 10:11 10

Labelling acc. to Regulation 67/548/EEC

Symbols Risk-phrases Safety-phrases

ê
T+ Very toxic 26, 27, 28, 39 1, 4, 13, 20, 21, 22, 27, 28, 29,
35, 36, 37, 38, 45

ê
T Toxic 23, 24, 25, 39, 45, 46, 48, 49, 60, 61 1, 4, 13, 20, 21, 22, 27, 28, 35, 36, 37, 38, 45

é
Xn Harmful 20, 21, 22, 40, 42, 46, 48, 60, 61, 62, 63, 64, 65, 68 2, 13, 36, 37, 45

ë
C Corrosive 34, 35 2, 18, 20, 25, 26, 27, 28, 37, 39, 45

é
Xi Irritant 36, 37, 38, 41, 43 2, 18, 24, 25, 26, 27, 28, 37, 39, 45

í
E Explosive 1, 2, 3, 4, 5, 6, 16 1, 2, 3, 4, 35,
(7, 9, 14, 25, 27, 39, 50)

ç
O Oxidizing 7, 8, 9 2, 14, 25, 40, 50

è
F+ Extremely flammable 12 2, 3, 9, 15, 16, 29, 33, 43

è
F Highly flammable 11, 15, 17 2, 3, 9, 16, 29, 33

f
N Dangerous for the 50, 51, 52, 53, 54, 55, 56, 57, 58, 59 29, 56, 57, 59, 60, 61
environment
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R+S-Phrases
R-Phrases R 48: Danger of serious damage to health by prolonged exposure.
R 49: May cause cancer by inhalation.
R 1: Explosive when dry.
R 50: Very toxic to aquatic organisms.
R 2: Risk of explosion by shock, friction, fire or other sources of
ignition. R 51: Toxic to aquatic organisms.

R 3: Extreme risk of explosion by shock, friction, fire or other R 52: Harmful to aquatic organisms.
sources of ignition. R 53: May cause long-term adverse effects in the aquatic
R 4: Forms very sensitive explosive metallic compounds. environment.

R 5: Heating may cause an explosion. R 54: Toxic to flora.

R 6: Explosive with or without contact with air. R 55: Toxic to fauna.

R 7: May cause fire. R 56: Toxic to soil organisms.

R 8: Contact with combustible material may cause fire. R 57: Toxic to bees.

R 9: Explosive when mixed with combustible material. R 58: May cause long-term adverse effects in the environment.

R 10: Flammable. R 59: Dangerous for the ozone layer.

R 11: Highly flammable. R 60: May impair fertility.

R 12: Extremely flammable. R 61: May cause harm to the unborn child.

R 14: Reacts violently with water. R 62: Possible risk of impaired fertility.

R 15: Contact with water liberates extremely flammable gases. R 63: Possible risk of harm to the unborn child.

R 16: Explosive when mixed with oxidizing substances. R 64: May cause harm to breastfed babies.

R 17: Spontaneously flammable in air. R 65: Harmful: may cause lung damage if swallowed.

R 18: In use, may form flammable/explosive vapour air mixture. R 66: Repeated exposure may cause skin dryness or cracking.

R 19: May form explosive peroxides. R 67: Vapours may cause drowsiness and dizziness.

R 20: Harmful by inhalation. R 68: Possible risk of irreversible effects.

R 21: Harmful in contact with skin.

R 22: Harmful if swallowed. Combination of R-Phrases
R 23: Toxic by inhalation.
R14/15: Reacts violently with water, liberating extremely flammable
R 24: Toxic in contact with skin.
gases.
R 25: Toxic if swallowed.
R 15/29: Contact with water liberates toxic, extremely flammable gas.
R 26: Very toxic by inhalation.
R 20/21: Harmful by inhalation and in contact with skin.
R 27: Very toxic in contact with skin.
R 20/22: Harmful by inhalation and if swallowed.
R 28: Very toxic if swallowed.
R 20/21/22: Harmful by inhalation, in contact with skin and if swallowed.
R 29: Contact with water liberates toxic gas.
R 21/22: Harmful in contact with skin and if swallowed.
R 30: Can become highly flammable in use.
R 23/24: Toxic by inhalation and in contact with skin.
R 31: Contact with acids liberates toxic gas.
R 23/25: Toxic by inhalation and if swallowed.
R 32: Contact with acids liberates very toxic gas.
R 23/24/25: Toxic by inhalation, in contact with skin and if swallowed.
R 33: Danger of cumulative effects.
R 24/25: Toxic in contact with skin and if swallowed.
R 34: Causes burns.
R 26/27: Very toxic by inhalation and in contact with skin.
R 35: Causes severe burns.
R 26/28: Very toxic by inhalation and if swallowed.
R 36: Irritating to eyes.
R 26/27/28: Very toxic by inhalation, in contact with skin and if
R 37: Irritating to respiratory system. swallowed.
R 38: Irritating to skin. R 27/28: Very toxic in contact with skin and if swallowed.
R 39: Danger of very serious irreversible effects. R 36/37: Irritating to eyes and respiratory system.
R 40: Limited evidence of a carcinogenic effect. R 36/38: Irritating to eyes and skin.
R 41: Risk of serious damage to eyes. R 36/37/38: Irritating to eyes, respiratory system and skin.
R 42: May cause sensitization by inhalation. R 37/38: Irritating to respiratory system and skin.
R 43: May cause sensitization by skin contact. R 39/23: Toxic : danger of very serious irreversible effects through
R 44: Risk of explosion if heated under confinement. inhalation.
R 45: May cause cancer. R 39/24: Toxic : danger of very serious irreversible effects in contact
R 46: May cause heritable genetic damage. with skin.
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R+S-Phrases
R 39/25: Toxic : danger of very serious irreversible effects if R 50/53: Very toxic to aquatic organisms, may cause long-term
swallowed. adverse effects in the aquatic environment.
R 39/23/24: Toxic : danger of very serious irreversible effects through R 51/53: Toxic to aquatic organisms, may cause long-term adverse
inhalation and in contact with skin. effects in the aquatic environment.
R 39/23/25: Toxic : danger of very serious irreversible effects through R 52/53: Harmful to aquatic organisms, may cause long-term adverse
inhalation and if swallowed. effects in the aquatic environment.
R 39/24/25: Toxic : danger of very serious irreversible effects in contact R 68/20: Harmful : possible risk of irreversible effects through
with skin and if swallowed. inhalation.
R 39/23/24/25: Toxic : danger of very serious irreversible effects through R 68/20/21: Harmful : possible risk of irreversible effects through
inhalation, in contact with skin and if swallowed. inhalation and in contact with skin.
R 39/26: Very toxic : danger of very serious irreversible effects R 68/20/21/22: Harmful : possible risk of irreversible effects through
through inhalation. inhalation, in contact with skin and if swallowed.
R 39/27: Very toxic : danger of very serious irreversible effects in R 68/20/22: Harmful : possible risk of irreversible effects through
contact with skin. inhalation and if swallowed.
R 39/28: Very toxic : danger of very serious irreversible effects if R 68/21: Harmful : possible risk of irreversible effects in contact
swallowed. with skin.
R 39/26/27: Very toxic : danger of very serious irreversible effects R 68/21/22: Harmful : possible risk of irreversible effects in contact
through inhalation and in contact with skin. with skin and if swallowed.
R 39/26/28: Very toxic : danger of very serious irreversible effects R 68/22: Harmful : possible risk of irreversible effects if swallowed.
through inhalation and if swallowed.
R 39/27/28: Very toxic : danger of very serious irreversible effects in
contact with skin and if swallowed. S-Phrases
R 39/26/27/28: Very toxic : danger of very serious irreversible effects
S1: Keep locked up.
through inhalation, in contact with skin and if swallowed.
S2: Keep out of the reach of children.
R 42/43: May cause sensitization by inhalation and skin contact.
S3: Keep in a cool place.
R 48/20: Harmful : danger of serious damage to health by prolonged
exposure through inhalation S4: Keep away from living quarters.
R 48/21: Harmful : danger of serious damage to health by prolonged S5: Keep contents under ... (appropriate liquid to be specified by
exposure in contact with skin. the manufacturer).
R 48/22: Harmful : danger of serious damage to health by prolonged S6: Keep under ...(inert gas to be specified by the manufacturer).
exposure if swallowed. S7: Keep container tightly closed.
R 48/20/21: Harmful : danger of serious damage to health by prolonged S8: Keep container dry.
exposure through inhalation and in contact with skin.
S9: Keep container in a well-ventilated place.
R 48/20/22: Harmful : danger of serious damage to health by prolonged
S12: Do not keep the container sealed.
exposure through inhalation and if swallowed.
S13: Keep away from food, drink and animal feeding stuffs.
R 48/21/22: Harmful : danger of serious damage to health by prolonged
exposure in contact with skin and if swallowed. S14: Keep away from ... (incompatible materials to be indicated by
the manufacturer).
R 48/20/21/22: Harmful : danger of serious damage to health by prolonged
exposure through inhalation, in contact with skin and if S15: Keep away from heat.
swallowed. S16: Keep away from sources of ignition - No smoking.
R 48/23: Toxic : danger of serious damage to health by prolonged S17: Keep away from combustible material.
exposure through inhalation.
S18: Handle and open container with care.
R 48/24: Toxic : danger of serious damage to health by prolonged
S20: When using do not eat or drink.
exposure in contact with skin.
S21: When using do not smoke.
R 48/25: Toxic : danger of serious damage to health by prolonged
exposure if swallowed. S22: Do not breathe dust.
R 48/23/24: Toxic : danger of serious damage to health by prolonged S23: Do not breathe gas/fumes/vapour/spray (appropriate
exposure through inhalation and in contact with skin. wording to be specified by the manufacturer).
R 48/23/25: Toxic : danger of serious damage to health by prolonged S24: Avoid contact with skin.
exposure through inhalation and if swallowed. S25: Avoid contact with eyes.
R 48/24/25: Toxic : danger of serious damage to health by prolonged S26: In case of contact with eyes, rinse immediately with plenty of
exposure in contact with skin and if swallowed. water and seek medical advice.
R 48/23/24/25: Toxic : danger of serious damage to health by prolonged S27: Take off immediately all contaminated clothing.
exposure through inhalation, in contact with skin and if
S28: After contact with skin, wash immediately with plenty of ...
swallowed.
(to be specified by the manufacturer).
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R+S-Phrases
S29: Do not empty into drains. Combination of S-Phrases
S30: Never add water to this product.
S 1/2 Keep locked up and out of the reach of children.
S33: Take precautionary measures against static discharges.
S 3/7 Keep container tightly closed in a cool place.
S35: This material and its container must be disposed of in a safe
S 3/9/14 Keep in a cool, well-ventilated place away from ...
way.
(incompatible materials to be indicated by the manufacturer).
S36: Wear suitable protective clothing.
S 3/9/14/49 Keep only in the original container in a cool, well-ventilated
S37: Wear suitable gloves. place away from ... (incompatible materials to be indicated
S38: In case of insufficient ventilation, wear suitable respiratory by the manufacturer).
equipment. S 3/9/49 Keep only in the original container in a cool, well-ventilated
S39: Wear eye/face protection. place.
S40: To clean the floor and all objects contaminated by this S 3/14 Keep in a cool place away from ... (incompatible materials to
material, use ... (to be specified by the manufacturer). be indicated by the manufacturer).
S41: In case of fire and/or explosion do not breathe fumes. S 7/8 Keep container tightly closed and dry.
S42: During fumigation/spraying wear suitable respiratory S 7/9 Keep container tightly closed and in a well-ventilated place.
equipment (appropriate wording to be specified by the S 7/47 Keep container tightly closed and at a temperature not
manufacturer). exceeding ... °C (to be specified by the manufacturer).
S43: In case of fire, use ... (indicate in the space the precise type S 20/21 When using do not eat, drink or smoke.
of fire-fighting equipment. If water increases risk, add
S 24/25 Avoid contact with skin and eyes.
- ’Never use water’).
S 27/28 After contact with skin, take off immediately all
S45: In case of accident or if you feel unwell, seek medical advice
contaminated clothing, and wash immediately with plenty of
immediately (show te label where possible).
- (to be specified by the manufacturer).
S46: If swallowed, seek medical advice immediately and show
S 29/35 Do not empty into drains; dispose of this material and its
this container or label.
container in a safe way.
S47: Keep at temperature not exceeding ... °C (to be specified by
S 29/56 Do not empty into drains, dispose of this material and its
the manufacturer).
container at hazardous or special waste collection point.
S48 Keep wet with ... (appropriate material to be specified by the
S 36/37 Wear suitable protective clothing and gloves.
manufacturer).
S 36/37/39 Wear suitable protective clothing, gloves and eye/face
S49: Keep only in the original container.
protection.
S50: Do not mix with ... (to be specified by the manufacturer).
S 36/39 Wear suitable protective clothing and eye/face protection.
S51: Use only in well-ventilated areas.
S 37/39 Wear suitable gloves and eye/face protection.
S52: Not recommended for interior use on large surface areas.
S 47/49 Keep only in the original container at a temperature not
S53: Avoid exposure - obtain special instructions before use. inhalation and in contact with skin.
S56: Dispose of, this material and its container at hazardous or
special waste collection point.
S57: Use appropriate container to avoid environmental
contamination.
S59 Refer to manufacturer/supplier for information on recovery/
recycling.
S60: This material and its container must be disposed of as
hazardous waste.
S61: Avoid release to the environment. Refer to special
instructions/Safety data sheets.
S62: If swallowed, do not induce vomiting : seek medical advice
immediately and show this container or label.
S63: In case of accident by inhalation : remove casualty to fresh
air and keep at rest.
S64: If swallowed, rinse mouth with water (only if the person is
conscious).
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Classification & Labelling acc. to (EC) 1272/2008

Hazard Pictograms Hazard Statements H Codes
The hazard pictogram on the designation label indicates the main hazard Hazard statements for physical hazards
arising from a substance. If there are several hazardous qualitiies, several
H200 Unstable explosives.
symbols are necessary.
H201 Explosive; mass explosion hazard.
Each pictogram is allocated a hazard designation and coding
that do not appear on the designation label. H202 Explosive, severe projection hazard.
H203 Explosive; fire, blast or projection hazard.
H204 Fire or projection hazard.

GHS01 H205 May mass explode in fire.

exploding bomb H220 Extremely flammable gas.
H221 Flammable gas.
H222 Extremely flammable aerosol.
H223 Flammable aerosol.
GHS02 H224 Extremely flammable liquid and vapour.j
flame
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H228 Flammable solid.
H229 Pressurised container: May burst if heated.
GHS03
H230 May react explosively even in the absence of air.
flame over circle
H231 May react explosively even in the absence of air at elevated pressure
and/or temperature.
H240 Heating may cause an explosion.
H241 Heating may cause a fire or explosion.
GHS04
H242 Heating may cause a fire.
gas cylinder
H250 Catches fire spontaneously if exposed to air.
H251 Self-heating; may catch fire.
H252 Self-heating in large quantities; may catch fire.
H260 In contact with water releases flammable gases which may
GHS05
ignite spontaneously.
corrosion
H261 In contact with water releases flammable gases.
H270 May cause or intensify fire; oxidiser.
H271 May cause fire or explosion; strong oxidiser.
H272 May intensify fire; oxidiser.
GHS06
skull and crossbones H280 Contains gas under pressure; may explode if heated.
H281 Contains refrigerated gas; may cause cryogenic burns or injury.
H290 May be corrosive to metals.

Hazard statements for health hazards

GHS07
exclamation mark H300 Fatal if swallowed.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
GHS08 H310 Fatal in contact with skin.
health hazard
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
GHS09
H317 May cause an allergic skin reaction.
environment
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
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Classification & Labelling acc. to (EC) 1272/2008

H330 Fatal if inhaled. Supplemental Hazard Information
H331 Toxic if inhaled. H Codes
H332 Harmful if inhaled.
EUH001 Explosive when dry.
H334 May cause allergy or asthma symptoms or breathing difficulties
if inhaled. EUH006 Explosive with or without contact with air.
H335 May cause respiratory irritation. EUH014 Reacts violently with water.
H336 May cause drowsiness or dizziness. EUH018 In use may form flammable/explosive vapour-air mixture.
H340 May cause genetic defects. EUH019 May form explosive peroxides.
H341 Suspected of causing genetic defects. EUH029 Contact with water liberates toxic gas.
H350 May cause cancer. EUH031 Contact with acids liberates toxic gas.
H350i May cause cancer by inhalation. EUH032 Contact with acids liberates very toxic gas.
H351 Suspected of causing cancer. EUH044 Risk of explosion if heated under confinement.
H360 May damage fertility or the unborn child. EUH066 Repeated exposure may cause skin dryness or cracking.
H360F May damage fertility. EUH070 Toxic by eye contact.
H360D May damage the unborn child. EUH071 Corrosive to the respiratory tract.
H360FD May damage fertility. May damage the unborn child. EUH201 Contains lead. Should not be used on surfaces liable to be chewed
or sucked by children.
H360Fd May damage fertility. Suspected of damaging the unborn child.
EUH201A Warning! Contains lead.
H360Df May damage the unborn child. Suspected of damaging fertility.
EUH202 Cyanoacrylate. Danger. Bonds skin and eyes in seconds.
H361 Suspected of damaging fertility or the unborn child. Keep out of the reach of children.
H361f Suspected of damaging fertility . EUH203 Contains chromium (VI). May produce an allergic reaction.
H361d Suspected of damaging the unborn child. EUH204 Contains isocyanates. May produce an allergic reaction.
H361fd Suspected of damaging fertility. EUH205 Contains epoxy constituents. May produce an allergic reaction.
Suspected of damaging the unborn child.
EUH206 Warning! Do not use together with other products.
H362 May cause harm to breast-fed children. May release dangerous gases (chlorine).
H370 Causes damage to organs. EUH207 Warning! Contains cadmium. Dangerous fumes are formed during
H371 May cause damage to organs. use. See information supplied by the manufacturer. Comply with the
safety instructions.
H372 Causes damage to organs through prolonged or repeated exposure.
EUH208 Contains (name of sensitising substance). May produce an allergic
H373 May cause damage to organs through prolonged or repeated reaction.
exposure.
EUH209 Can become highly flammable in use.
H300+H310 Fatal if swallowed or in contact with skin.
EUH209A Can become flammable in use.
H300+H330 Fatal if swallowed or if inhaled. EUH210 Safety data sheet available on request.
H310+H330 Fatal in contact with skin or if inhaled. EUH401 To avoid risks to human health and the environment, comply with the
H300+H310+H330 Fatal if swallowed, in contact with skin or if inhaled. instructions for use.
H301+H311 Toxic if swallowed or in contact with skin.
H301+H331 Toxic if swallowed or if inhaled.
H311+H331 Toxic in contact with skin or if inhaled.
H301+H311+H331 Toxic if swallowed, in contact with skin or if inhaled.
H302+H312 Harmful if swallowed or in contact with skin.
H302+H332 Harmful if swallowed or if inhaled.
H312+H332 Harmful in contact with skin or if inhaled.
H302+H312+H332 Harmful if swallowed, in contact with skin or if inhaled.

Hazard statements for environmental hazards

H400 Very toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
H413 May cause long lasting harmful effects to aquatic life.
H420 Harms public health and the environment by destroying ozone
in the upper atmosphere.
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Classification & Labelling acc. to (EC) 1272/2008

Classification Labelling
Hazard class Category codes Pictogram, code Signal word Hazard statements
Unstable
Unst. Expl. H200 Unstable explosives.
explosives

Divisions 1.1 Expl. 1.1 H201 Explosive; mass explosion hazard.

Danger
Divisions 1.2 Expl. 1.2 H202 Explosive, severe projection hazard.

Explosive Divisions 1.3 Expl. 1.3 GHS01 H203 Explosive; fire, blast or projection hazard.

Divisions 1.4 Expl. 1.4 Warning H204 Fire or projection hazard.

Divisions 1.5 Expl. 1.5 No pictogram Danger H205 May mass explode in fire.

Divisions 1.6 Expl. 1.6 No pictogram, no signal word, no hazard statement

Category 1 Flam. gas 1 Danger H220 Extremely flammable gas.

Flammable gas

GHS02

Category 2 Flam. gas 2 No pictogram Warning H221 Flammable gas.

Category 1 Flam. aerosol 1 Danger H222 Extremely flammable aerosol.

Flammable
aerosol
Category 2 Flam. aerosol 2 Warning H223 Flammable aerosol.
GHS02

Oxidising gas Category 1 Ox. gas 1 Danger H270 May cause or intensify fire; oxidiser.

GHS03

Compressed gas

Dissolved gas H280 Contains gas under pressure; may explode if heated.
Gas under
Press. gas Warning
pressure
Liquefied gas

Refrigerated GHS04 H281 Contains refrigerated gas; may cause cryogenic burns or injury.
liquefied gas

Category 1 Flam. Liq. 1 H224 Extremely flammable liquid and vapour.

Danger
Flammable liquid Category 2 Flam. Liq. 2 H225 Highly flammable liquid and vapour.

Category 3 Flam. Liq. 3 Warning H226 Flammable liquid and vapour.

Category 1 Flam. Sol. 1 Danger

Flammable solid GHS02 H228 Flammable solid.
Category 2 Flam. Sol. 2 Warning
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Classification & Labelling acc. to (EC) 1272/2008

Classification Labelling
Hazard class Category codes Pictogram, code Signal word Hazard statements

Self-react. A

Type A H240 Heating may cause an explosion.

Org. Perox. A
GHS01 Danger

Self-reactive
substance or Self-react. B
mixture Type B H241 Heating may cause a fire or explosion.
Org. Perox. B GHS01 + GHS02

Organic peroxide Self-react. CD

Type C and D Danger
Org. Perox. CD
H242 Heating may cause a fire.
Self-react. EF
Type E and F Warning
Org. Perox. EF GHS02
Self-react. G
Type G No pictogram, no signal word, no hazard statement
Org. Perox. G

Pyrophoric liquid Category 1 Pyr. Liq. 1

Danger H250 Catches fire spontaneously if exposed to air.
Pyrophoric solid Category 1 Pyr. Sol. 1

Self-heating Category 1 Self-heat. 1 Danger H251 Self-heating; may catch fire.

substance or
mixture Category 2 Self-heat. 2 Warning H252 Self-heating in large quantities; may catch fire.
In contact with water releases flammable gases which may
Substance or Category 1 Water-react. 1 Danger H260
ignite spontaneously.
mixture which in GHS02
contact with Category 2 Water-react. 2 Danger
water emits H261 In contact with water releases flammable gases.
flammable gas Category 3 Water-react. 3 Warning

Ox. Liq. 1
Category 1 Danger H271 May cause fire or explosion; strong oxidiser.
Ox. Sol. 1
Oxidising liquid Ox. Liq. 2
Category 2 Danger
Oxidising solid Ox. Sol. 2
H272 May intensify fire; oxidiser.
Ox. Liq. 3
Category 3 GHS03 Warning
Ox. Sol. 3

Substance or
mixture corrosive Category 1 Met. Corr. 1 Warning H290 May be corrosive to metals.
to metals

GHS05

Category 1 Acute Tox. 1 H300 Fatal if swallowed.

H310 Fatal in contact with skin.
Category 2 Acute Tox. 2 H330 Fatal if inhaled.
Danger
H301 Toxic if swallowed.
Category 3 Acute Tox. 3 GHS06 H311 Toxic in contact with skin.
Acute toxicity H331 Toxic if inhaled.

H302 Harmful if swallowed.

Category 4 Acute Tox. 4 Warning H312 Harmful in contact with skin.
H332 Harmful if inhaled.

GHS07
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Classification & Labelling acc. to (EC) 1272/2008

Classification Labelling
Hazard class Category codes Pictogram, code Signal word Hazard statements

Category 1A Skin Corr. 1A

Category 1B Skin Corr. 1B Danger H314 Causes severe skin burns and eye damage.

Skin corrosion/ Category 1C Skin Corr. 1C GHS05

irritation

Category 2 Skin Irrit. 2 Warning H315 Causes skin irritation.

GHS07

Category 1 Eye Dam. 1 Danger H318 Causes serious eye damage.

Serious eye damage/ GHS05

eye irritation

Category 2 Eye Irrit. 2 Warning H319 Causes serious eye irritation.

GHS07

Category 1 Resp. Sens. 1

Respiratory May cause allergy or asthma symptoms or breathing difficulties
Category 1A Resp. Sens. 1A Danger H334
sensitization if inhaled.
Category 1B Resp. Sens. 1B

GHS05

Category 1 Skin Sens. 1

Skin sensitization Category 1A Skin Sens. 1A Warning H317 May cause an allergic skin reaction.
Category 1B Skin Sens. 1B

GHS07
Category 1A Muta. 1A
Germ cell Danger H340 May cause genetic defects. (*)
Category 1B Muta. 1B
mutagenicity
Category 2 Muta. 2 Warning H341 Suspected of causing genetic defects. (*)
Category 1A Carc. 1A H350 May cause cancer. (*)
Danger
Category 1B Carc. 1B H350i May cause cancer by inhalation.
Carcinogenicity GHS08
Category 2 Carc. 2 Warning H351 Suspected of causing cancer. (*)
(*) state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard
H360 May damage fertility or the unborn child. (*)
Category 1A Repr. 1A H360F May damage fertility. (*)
Danger
H360D May damage the unborn child. (*)
Category 1B Repr. 1B H360FD May damage fertility. May damage the unborn child. (*)
H361 Suspected of damaging fertility or the unborn child.
H361f Suspected of damaging fertility.
Reproductive Category 2 Repr. 2 Warning H361d Suspected of damaging the unborn child.
toxicity GHS08 H361fd Suspected of damaging fertility. Suspected of damaging the
unborn child.
Additional
category for effects Lact. No pictogram No signal word H362 May cause harm to breast-fed children.
on or via lactation
(*) state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard
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Classification & Labelling acc. to (EC) 1272/2008

Classification Labelling
Hazard class Category codes Pictogram, code Signal word Hazard statements

Category 1 STOT SE 1 Danger H370 Causes damage to organs. (*)

Category 2 STOT SE 2 Warning H371 May cause damage to organs. (*)

Specific target GHS08
organ toxicity –
single exposure
H335 May cause respiratory irritation.

Category 3 STOT SE 3 Warning

H336 May cause drowsiness or dizziness.

GHS07

Causes damage to organs through prolonged or repeated

Category 1 STOT RE 1 Danger H372
exposure. (*)
Specific target
organ toxicity –
repeated May cause damage to organs through prolonged or repeated
exposure Category 2 STOT RE 2 Warning H373
exposure. (*)
GHS08
(*) state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard

Aspiration hazard Category 1 Asp. Tox. 1 Danger H304 May be fatal if swallowed and enters airways.

GHS08

Acute aquatic hazard Acute 1 Aquatic Acute 1 Warning H400 Very toxic to aquatic life.

Chronic 1 Aquatic Chronic 1 Warning H410 Very toxic to aquatic life with long lasting effects.

Chronic 2 Aquatic Chronic 2 No signal word H411 Toxic to aquatic life with long lasting effects.
Long-term GHS09
aquatic hazard
Chronic 3 Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
No pictogram No signal word
Chronic 4 Aquatic Chronic 3 H413 May cause long lasting harmful effects to aquatic life.

Hazardous for the Harms public health and the environment by destroying
Category 1 Ozone 1 Warning H420
ozone layer ozone in the upper atmosphere.

GHS07