HUNTSMAN GAS TREATING

2011
 SOLUTION ANALYSIS
αβχδε Gas Treating Sample Results 20000101.a01
Manufacturers of JEFFTREAT® Products and DGA® Agent. GA# 99101201
Plant Mgr. Text878: Motiva 24 PHONE: xxx-yyy-zzzz
Refinery or Plant Name FAX: xxx-yyy-zzzx
24
Address

AMINE: MDEA UNIT ID: Amine Unit Received: 12/31/1999

TYPE: LEAN APPLICATION: Refinery Reported: FINAL 01/01/2000
Bulk composition: Other ID: LEAN MDEA
Acid loading /
BULK COMPOSITION, %w
H2O, H2S, CO2 content Usable 39.47 OK neutralization
Water + Alternate Units
Water + 53.40 OK
H2S + 0.04 OK 25.0 gr/gal 0.0037 m/m
CO2 + 0.00 OK 0.00 scf/gal + 0.0001 m/m
Total Loading = 0.0038 m/m OK
Neutralization Calculations %w Amine basis
Strong Acid Anions + 1.43 Caution Speciated Acids: 2.99 av 3.14 Caution
Titrated Acids: 3.30
Strong Bases + 0.05 OK Strong Bases: - 0.23
Nitrogen balance Bound Amine + 2.91 Caution Acids - Bases: = 2.91Caution
Amine balance:
% Neutralization = 7 OK

Additional H2S < 1 gr/gal %w amine

SAMPLE RECOVERY = 97.30 OK This solvent <50 ppmw ammonia. OK
NITROGEN BALANCE AMINE BALANCE MDEA FRAGMENTS
%w as Amine
Total N: 45.9
in Titr. Am: - 38.4 %w as Amine %w
Soluble metals: in Anions: - 1.2 Titrated: 38.4 DEA: 1.03 Anion Specification:
in Bound Am: - 3.0 Bound: + 3.0 MMEA: + 0.57
Identified: - 42.6 C2+ Acids: + 0.20 Organic and inorganic
Iron, Nickel, Sodium… Excess N: = 3.3 High Excess Am: = -1.2 OK Total Fragments: = 1.80 OK
SOLUBLE METALS ANION SPECIATION
ppmw ORGANIC ppmw INORGANIC ppmw
To check the corrosion. Iron
Chromium
2.8
<1
OK
OK
Acetate
Formate +
685
1698
OK
OK
Chloride 304 OK

Nickel <1 OK Glycolate + 563 OK Sulfite + <200 OK

0.80 Caution Lactate + trace OK Sulfate + 265 OK
Sodium 435 Oxalate + 592 OK Thiosulfate 113 OK Physical properties:
Potassium Propionate trace OK Thiocyanate 10219 High
Potassium
Calcium
20
2.0 OK Total* Org. = 3685 OK Total* Inorg. = 10901 High
Color, density, viscosity
Silicon <10 Total* Speciated Anions = 14586 * Totals include traces
Foaming tendency FOAMING TENDENCY PHYSICAL PROPERTIES
COLOR: LT.YLOW/CLEAR/NOSOLIDS/NOOIL OK
Rate Volume, cc Breaktime, s
For 19.9 %w amine Actual
125 57 Nil 13 OK DENSITY g/ml 60°F: 1.0217 1.0232 OK
250 60 Nil VISCOSITY cS 100°F: 1.50 1.41 OK
500 72 Nil

01-Jan-2000 HUNTSMAN CORPORATION BUSINESS CONFIDENTIAL

2011