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NO ITEMS PAGE

1. PURPOSE 2

2. SCOPE 2

3. DEFINITION 2

4. DOCUMENT 2

5. RESPONSIBILITY 2

6. PROCEDURE 3
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1. PURPOSE

1.1 To determine the concentration of F-( g/l ) in plater solution

2. SCOPE

2.1 This procedure is mend for laboratory use only

3. DEFINITION

3.1 Nil

4. DOCUMENT

4.1 Nil

5. RESPONSIBILITY

5.1 Laboratory Asst.

5.2 Laboratory Leader, QC Asst. Executive/ Executive/ Senior Executive and Quality Control Manager
have to ensure this procedure is follow accordingly.

5.2 To be analyzed every 4 hours.

5.3 Test result to be recorded in LABORATORY SOLUTION ANALYSIS LOGSHEET

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6. PROCEDURE

DOCUMENTED
NO PROCEDURE DESCRIPTION
INFORMATION
1 Safety: personal protect equipments
Prepare to (PPEs)
Chemical,  Safety shoes.
Reagent, Device,  Mask.
PPEs  Plastic gloves.
 Long sleeves

Devices
 Erlenmeyer Flask 500 ml
 Conical measuring flask 50 ml
 Measuring bulb pipette 100 ml , 25 ml
 Filter paper 15.0 cm
 Filter Funnel 7.5 cm
 Burette 50 ml
 Glass Beaker 250 ml
 Volumetric Flask 250 ml
 Polyethylene Beaker 300 ml

Chemical reagent
 1 N Hydrochloric Acid standard
solution (HCl)
 Aqueous Ammonia Solution ( 1 : 9 )
 Saturated Boric Acid solution ( H3BO3
65g/l )
 Ethanol Absolute (Special grade)
 Potassium Chloride (KCl) (Special
grade)
 Methyl red indicator 0.1 %
 Phenohthalien indicator 1 %
 Aqueous ammonia solution ( 1 : 2 ) for
reclaim sample analysis
 Nitric acid ( HNO3 ) for reclaim sample
analysis
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2 Preparation of 1 N HCl
Prepare to
standard a. Chemical reagents
Chemical  Hydrochloric Acid (special grade) 37 %
 Sodium Carbonate Anhydrous (Na2CO3)
 Bromolphenol Blue (C19 H10 Br4 O5 S)

b. Devices
 Measuring Cylinder 1000 ml, 100 ml, 50ml
 Volumetric Flask 1000 ml
 Filter funnel
 Direct reading analytical balance
 Conical Flask 250 ml
 Burette 50 ml
 Wash bottle 500 ml
 Weighing bottle
 Erlenmeyer flask 300ml

c. Preparation of 1 N HCl
 Measure 90ml of HCl and put in the
volumetric and dilute with water until final
standard level 1000ml.

STANDARDIZATION
 Weigh 1gm of anhydrous sodium
carbonate
 Put in the Erlenmeyer flask and
dissolved it with 50ml demineralised
water.
 1-2 drops of bromophenol blue
indicator ( BPB )
 Titrate with 1NHCl until color change
from blue to yellow (end point)

Calculation
F = Weigh of Na2CO3 (gm) x Purity Na2CO3
Volume of 1 N HCl (ml) x 0.0530
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3 a. Filter the electrolyte through dry filter

Procedure paper, using filter funnel and
polyethylene beaker.
b. Pipette 100ml of the filtered electrolyte in
the 250ml volumetric flask and add to it
about 150ml of aqueous ammonia ( 1 :
9 ) to the standard level.
c. After plunging, shake well until the
solution becomes thoroughly milky, filter
the solution through dry filter paper.
(Advisable to shake slowly while topping
up )
d. Pipette 25ml of the filtered solution.( Be
sure that the solution is very clear before
taking the sample. To confirm these,
discard the first and second filtered
collected). Use only the clear solution in
the Erlenmeyer flask.
e. Add in about 2 drops of Methyl Red
indicator and neutralized the above
solution with 1N HCl standard solution
until the color change from yellow to
pink.
f. Add in the above solution 40ml of Ethyl
Alcohol, about 8 gm of potassium
chloride and 3 – 4 drops of methyl red
indicator.
g. Mix them well. Have the potassium
chloride slightly dissolve and also have
the boron and fluorine reacted well.
h. Titrate the above solution with 1N HCl
standard solution until bright crimson
color remains permanently.

Calculation :
F-(g/l) = 1N HCl qty (ml) - blank tit (ml)x F x 29.4
Sample quantity (ml ) 25
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4 Test result to be record in LABORATORY LABORATORY

Record result SOLUTION ANALYSIS LOGSHEET SOLUTION
ANALYSIS
LOGSHEET