t [min] C [mol/L] Cmed Δt Δt * Cmed E(t) t * C * Δt C * Δt

0 0 0.5 1 0.5 0.0000 0 0

1 1 3 1 3 0.0203 1 1
2 5 6.5 1 6.5 0.1014 10 5
3 8 9 1 9 0.1623 24 8
4 10 9 1 9 0.2028 40 10
5 8 7 1 7 0.1623 40 8
6 6 5 1 5 0.1217 36 6
7 4 3.5 1 3.5 0.0811 28 4
8 3 2.6 1 2.6 0.0609 24 3
9 2.2 1.85 1 1.85 0.0446 19.8 2.2
10 1.5 1.05 1 1.05 0.0304 15 1.5
11 0.6 0.3 1 0.3 0.0122 6.6 0.6
12 0 - - - 0 - -
SUMATORIA 49.3 1 244.4 49.3

k 0.1 min-1 IMPULSO

t(media) 4.957
varianza σ2 4.994

Flujo NO IDEAL, utilizo modelo de dispersión:

varianza(θ) σ2 0.203

D/(u*L) 0.1148 Dispersión grande

varianza (θ) σ2 0.2032
Control 0.0000
k*tm 0.4957

Utilizando el gráfico:

1-XA 0.55
XA 0.45

Calculando por cinética:

CA/CA0 0.624
1-XA 0.624
XA 0.376
(t-tm)^2*C*Δt EXP(kt)*E*Δt
0.0000 0.0000
C vs t
15.6610 0.0184
12
43.7312 0.0830
30.6514 0.1202 10
9.1662 0.1360 8
0.0145 0.0984
6
6.5220 0.0668
16.6888 0.0403 4
27.7722 0.0273 2
35.9537 0.0181
0
38.1417 0.0112 0 2 4 6 8 10 12 14
21.9078 0.0041
- - E(t) vs t
246.211 0.624 0.2500

0.2000

0.1500

0.1000

0.0500

0.0000
0 2 4 6 8 10 12
12 14

10 12
 t [s] Cx10-3 [g/L] Cmedx10-3 Δt Δt * Cmed E(t)x10-3 E(t) t * C * Δt
0 0 0 150 0 0 0 0
150 0 0.5 25 12.5 0 0 0
175 1 2 25 50 0.0010 0.00000102 4.375
200 3 5.2 25 130 0.0031 0.00000306 15
225 7.4 8.4 15 126 0.0075 0.00000754 24.975
240 9.4 9.55 10 95.5 0.0096 0.00000958 22.56
250 9.7 9.55 10 95.5 0.0099 0.00000988 24.25
260 9.4 8.8 15 132 0.0096 0.00000958 36.66
275 8.2 6.6 25 165 0.0084 0.00000835 56.375
300 5 3.75 25 93.75 0.0051 0.00000509 37.5
325 2.5 1.85 25 46.25 0.0025 0.00000255 20.3125
350 1.2 0.85 25 21.25 0.0012 0.00000122 10.5
375 0.5 0.35 25 8.75 0.0005 0.00000051 4.6875
400 0.2 0.1 50 5 0.0002 0.00000020 4
450 0 - - - 0.0000 0.00000000 -
981.5 0.0585838 - 261.195
IMPULSO

c) Varianza de la distribución d) Conversión

σ2 1750.56137 k 0.0115 s-1

CA0 9.07421411 mol/l

σθ2 0.02504733
σθ 2
0.02507705
D/(uL) 0.01269981
Control 8.8327E-10

Utilizando el gráfico

k*tm 3.0402
1-XA 0.09
XA 0.91
 C * Δt (t-tm)^2*C*Δt EXP(kt)*E*Δt a) Curva E(t)
0 0 0.000000
0 0 0.000000
E(t) vs t
0.025 199.6633 0.000191
0.075 310.7372 0.000762 0

0.111 172.0270 0.001504 0

0.094 55.8144 0.001513 0
0.097 20.0230 0.001752
0
0.141 2.6895 0.002857
0.205 23.1757 0.004935 0
0.125 158.7102 0.004012 0
0.0625 229.7694 0.002674
0
0.03 219.9882 0.001711 0 50 100 150 200 250 300 350 400 450 500
0.0125 152.9946 0.000950
0.01 183.9620 0.001014 b) Tiempo medio de residencia
- - -
0.988 1729.555 0.024 t(media) 264.367409 s

ρ 840 kg/m3 0.84 kg/l

PM 92.57 g/mol 0.09257 kg/mol

el gráfico
400 450 500
 t [min] C [mg/l] ΔC t*ΔC F(t) E(t) E(t) E(t)*t*Δt
0 0 0 0 0 2.44E-02 -6.20E-03 0
2 0 0.8 1.6 0 -1.43E-03 5.48E-03 0.02192
4 0.8 1.2 4.8 0.02 -1.41E-02 8.04E-03 0.06432
6 2 2.4 14.4 0.05 1.24E-02 1.88E-02 0.22512
8 4.4 4.6 36.8 0.11 6.85E-02 5.49E-02 0.43936
9 9 3.6 32.4 0.225 1.00E-01 8.79E-02 0.79146
10 12.6 7.4 74 0.315 1.30E-01 1.34E-01 1.338
11 20 10 110 0.5 1.57E-01 1.95E-01 2.14126
12 30 4 48 0.75 1.80E-01 1.21E-01 1.4532
13 34 2 26 0.85 2.02E-01 9.82E-02 1.2766
14 36 2 28 0.9 2.27E-01 7.95E-02 1.113
15 38 1 15 0.95 2.64E-01 6.50E-02 0.975
16 39 1 16 0.975 3.27E-01 5.47E-02 1.7504
18 40 0 0 1 6.05E-01 4.67E-02 1.6812
20 40 - - 1 1.28E+00 5.55E-02 -
SUMATORIA 40 407 - 3.56E+00 1.02E+00 13.27084

k*CA0 0.01 min-1 a 9.00E-07 a'

V 1 m3 b -4.00E-05 b'
c 0.0006 c'
v0 0.01 m3/min d -0.0026 d'
e -0.0027 e'
Cmáx 40 mg/l f 0.0244 f'
g -0.0055
t(media) 13.27084 min
F(t) vs t
σ 2
11.4821824
1.2

tm(nominal) 100 min 1

f(x) = 8.90220483431827E-07x^6 - 4.27267349539773E-05x^5 + 0.0006391486x^4 - 0.0026156342x^3 - 0.0026530592x^2 + 0.0244324912x - 0.0054824
2.50E-01 R² = 0.9921857171
0.8
2.00E-01
0.6
1.50E-01

1.00E-01 0.4

5.00E-02
0.2

0.00E+00
0 5 10 15 20 25 0
0 5 10 15 20 25
-5.00E-02

a) Aplicando el modelo de la dispersión

 σθ2 0.065197
σθ 2
0.065201
D/(uL) 0.033739 Módulo de dispersión grande
Control 1.706313E-11

k*t*CA0 1
1-XA 0.5
XA 0.5
 (t-tm)^2*E*Δt E*Δt
-2.1838284094 -0.0124
1.392268904 0.01096 C vs t
1.3820514668 0.01608 45
1.9834990887 0.03752 40
35
1.5257739465 0.05492
30
1.6040321344 0.08794 25
1.4314451581 0.1338 20
1.0038060067 0.19466 15
0.1955806544 0.1211 10
5
0.0072033928 0.0982
0
0.0422681073 0.0795 0 5 10 15 20 25
0.1943496299 0.065
0.814845585 0.1094
2.0888867321 0.0934 ESCALÓN
- -
11.4821823974 1.09008

5.40E-06 a 9.00E-05 a' 3.60E-04 a

-2.00E-04 b -0.0011 b' -0.0033 b
0.0024 c 0.0055 c' 0.011 c
-0.0078 d -0.0062 d' -0.0062 d
-0.0054 e -0.0005
0.0244

0.6 1.2

0.5 1
f(x) = 8.98713657916654E-05x^4 - 0.0010613353x^3 + 0.0054864684x^2 - 0.0061527134x - 0.0005122122 f(x) = 0.0006558159x^3 - 0.0377117561x^
R² = 0.9965873158 R² = 0.9976127046
91486x^4 - 0.0026156342x^3 - 0.0026530592x^2 + 0.0244324912x - 0.0054824118 0.4 0.8

0.3 0.6

0.2 0.4

0.1 0.2

0 0
0 2 4 6 8 10 12 11 12 13 14 15 16 17

b) Aplicando el modelo de tanques en serie

 N 15.338129

1-XA 0.5
XA 0.5
 7.00E-04 a' 2.10E-03
-0.0377 b' -0.0754
0.7235 c' 0.7235
-3.632

= 0.0006558159x^3 - 0.0377117561x^2 + 0.7235425131x - 3.6320176559

0.9976127046

11 12 13 14 15 16 17 18 19 20 21