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Gazala Habib
Definition
• Potable water: A water that can be consumed at any desired amount without concern for adverse health effects
is termed as potable water (Davis and Cornwell, 1998). Potable does not necessarily mean that the water tastes
good.
• Potable and palatable (which is pleasing to drink)
• Water should be both potable and palatable
• Physical characteristics of water:
• Mass density: Mass per unit volume (1000 kg/m3)
• Specific weight: Weight (force) per unit volume
𝛾 = 𝜌 × 𝑔 = 1000 ∗ 9.81 = 9.81 𝐾𝑁/𝑚2
• Specific gravity:
𝜌
𝑆=
𝜌0
Where 𝜌 0 = 1000 𝑘𝑔/𝑚3
• Dynamic viscosity: (Pa.S=Ns/m2=kg/m.s)
𝑚
𝜇=
𝑙×𝑡
• Kinematic viscosity: (m2/s)
𝜇
𝜐=
𝜌
Water quality
• Physical characteristics
• Turbidity: The presence of suspended material such as clay, silt, finely divided
organic material, plankton, and other particulate material in water is know as
turbidity.
• Color: Dissolved organic material from decaying vegetation and some
inorganic matter cause color in water.
• Taste and odor: taste in water can be caused by organic compounds, inorganic
salts and dissolved gases. These material may come from domestic
agricultural and natural sources.
• Temperature
Water pollutants and their removal
mechanisms
• The impurities can be found in three states
• Suspended
• Colloidal
• Dissolved
• A dissolved substance is homogeneously dispersed in the liquid. Dissolved substances can be simple atoms or
complex molecular compounds.
• The substance cannot be removed from the liquid without accomplishing a phase change such as distillation,
precipitation, adsorption, extraction, or passage through "ionic" pore-sized membranes.
• In distillation either the liquid or the substance itself is changed from a liquid phase to a gas phase in order to
achieve separation.
• In precipitation the substance in the liquid phase combines with another chemical to form a solid phase, thus
achieving separation from the water.
• Adsorption also involves a phase change, wherein the dissolved substance reacts with a solid particle to form a
solid particle-substance complex.
• Liquid extraction can separate a substance from water by extracting it into another liquid, hence a phase change
from water to a different Iiquid.
• A membrane with pore sizes in the ionic-size range can separate dissolved substances from the solution by a
high-pressure filtering process.
Suspended solids
• A second unit, equivalent weight (EW), is frequently used in softening and redox
reactions.
• The equivalent weight is the molecular weight divided by the number (n) of electrons
transferred in redox reactions or the number of protons transferred in acid/base reactions.
• Normality (N)is the number of equivalent weights per liter of solution and is related to
molarity(M) by
N=M.n
Alkalinity of water
• Alkalinity: alkalinity is defined as the sum of all titrable bases down to
about pH 4.5. It can be found by experimentally determining how much
acid it takes to lower the pH of water to 4.5.
• In most waters the only significant contribution to alkalinity are the
carbonate species and any free H+ and OH- ions. The total H+ that can be
taken up by water containing primarily carbonate species is
• Alkalinity=[HCO3-] +2[CO32-]+[OH-]-[H+]
• 𝐻2 𝐶𝑂3 ⇌ 𝐻+ + 𝐻𝐶𝑂3 −
−
• 𝐻𝐶𝑂 3
⇌ 𝐻+ + 𝐶𝑂3 2−
𝑚𝑔 𝑚𝑔 𝐸𝑊𝐶𝑎𝐶𝑂3
𝑎𝑠 𝐶𝑎𝐶𝑂3 = ( 𝑜𝑓 𝑠𝑝𝑒𝑐𝑖𝑒𝑠) ×
𝐿 𝐿 𝐸𝑊𝑠𝑝𝑒𝑐𝑖𝑒𝑠
Alkalinity calculation
• Example 1: A water contains 100.0 mg/l of 𝐶𝑂3 2− and 75.0 mg/l of 𝐻𝐶𝑂3 − at a pH of 10. Calculate the alkalinity
exactly at 25 C. Approximate the alkalinity by ignoring [OH-] and [H+] ions.
Equivalent weights (EW)
𝐶𝑂3 2− Molecular Weight=12+3*16=60; n=2; EW=30
𝐻𝐶𝑂3 − MW=1+12+3*16=61; n=1; EW=61
𝐻+ MW=1; n=1; EW=1
𝑂𝐻 − MW=16+1=17; n=1; EW=17
𝐶𝑎𝐶𝑂3 MW=40+12+3*16=100; n=2; EW=50
𝐾𝑤 = 10−14
pH=10
𝑝𝐻 = − log10 [𝐻+ ]
𝐾𝑤
𝑂𝐻− =
[𝐻− ]
Alkalinity calculation
𝐾𝑤 10−14
• 𝑂𝐻 − = = = 10−4 𝑚𝑜𝑙𝑒𝑠/𝐿
[𝐻 − ] 10−10
• Concentration in mg/l
𝑚𝑜𝑙𝑒𝑠 𝑔 𝑚𝑔
• [𝐻 + ] −10
= 10 ( ) × 𝑚𝑜𝑙𝑒𝑐𝑢𝑙𝑎𝑟 𝑤𝑒𝑖𝑔ℎ𝑡 × 10 3
𝐿 𝑚𝑜𝑙𝑒 𝑔
+ −10 𝑚𝑜𝑙𝑒𝑠 𝑔 3 𝑚𝑔 −7 𝑚𝑔
• [𝐻 ] = 10 ×1 × 10 = 10
𝐿 𝑚𝑜𝑙𝑒 𝑔 𝐿
− −4 𝑚𝑜𝑙𝑒𝑠 𝑔 3 𝑚𝑔 𝑚𝑔
• 𝑂𝐻 = 10 × 17 × 10 = 1.7
𝐿 𝑚𝑜𝑙𝑒 𝑔 𝐿
𝑚𝑔 𝑚𝑔 𝐸𝑊𝐶𝑎𝐶𝑂3
• 𝑎𝑠 𝐶𝑎𝐶𝑂3 = ( 𝑜𝑓 𝑠𝑝𝑒𝑐𝑖𝑒𝑠) ×
𝐿 𝐿 𝐸𝑊𝑠𝑝𝑒𝑐𝑖𝑒𝑠
2− 𝑚𝑔 50
• 𝐶𝑂3 𝑎𝑠 𝐶𝑎𝐶𝑂3 (𝑖𝑛 ) = 100.0 × = 167
𝐿 30
Alkalinity calculation
− 𝑚𝑔 50
• 𝐻𝐶𝑂3 𝑎𝑠 𝐶𝑎𝐶𝑂3 (𝑖𝑛 ) = 75.0 × = 61.5
𝐿 61
+ 𝑚𝑔 −7 50
• 𝐻 𝑎𝑠 𝐶𝑎𝐶𝑂3 (𝑖𝑛 ) = 10 × = 5 × 10−7
𝐿 1
− 𝑚𝑔 50
• 𝑂𝐻 𝑎𝑠 𝐶𝑎𝐶𝑂3 (𝑖𝑛 ) = 1.7 × = 5.0
𝐿 17
• Total alkalinity as
𝑚𝑔 −7
𝑚𝑔
𝐶𝑎𝐶𝑂3 𝑖𝑛 = 167 + 61.5 + 5 × 10 + 5.0 = 233.5
𝐿 𝐿
Problem
• Using following equations derive two equations which allow
calculation of the bicarbonate and carbonate alkalinities in mg/L as
CaCO3 from measurements of the total alkalinity (A) and the pH.
• 𝐾𝑤 = 𝑂𝐻 − 𝐻+
• 𝐾𝑤 = 𝑖𝑜𝑛 𝑝𝑟𝑜𝑑𝑢𝑐𝑡 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟 = 10−14 𝑎𝑡 25 ℃
• 𝑝𝐾𝑤 = 14 𝑎𝑡25 ℃
• 𝐴𝑙𝑘𝑎𝑙𝑖𝑛𝑖𝑡𝑦 = 𝐻𝐶𝑂3− + 2 𝐶𝑂32− + 𝑂𝐻 − − 𝐻 +
• 𝑟𝑒𝑓𝑒𝑟𝑠 𝑡𝑜 𝑐𝑜𝑛𝑐𝑒𝑛𝑡𝑟𝑎𝑡𝑖𝑜𝑛 𝑖𝑛 𝑚𝑜𝑙𝑒𝑠/𝐿
• 𝐻2 𝐶𝑂3 ⇌ 𝐻 + + 𝐻𝐶𝑂3− 𝑝𝐾𝑎1 = 6.35 𝑎𝑡 25℃
• 𝐻𝐶𝑂3− ⇌ 𝐻 + + 𝐶𝑂32− 𝑝𝐾𝑎2 = 10.33 𝑎𝑡 25℃
Solution
• 𝐴𝑙𝑘𝑎𝑙𝑖𝑛𝑖𝑡𝑦 = 𝐻𝐶𝑂3− + 2 𝐶𝑂32− + 𝑂𝐻− − 𝐻+
• 𝐴 = 𝐻𝐶𝑂3− + 2 𝐶𝑂32− + 𝑂𝐻 − − 𝐻+
𝑚𝑔 𝑚𝑔 𝑚𝑔 𝑚𝑔 𝑚𝑔
• 𝐴 𝑖𝑛 𝑎𝑠 𝐶𝑎𝐶𝑂3 = 𝐻𝐶𝑂3− 𝑖𝑛 𝑎𝑠 𝐶𝑎𝐶𝑂3 + 𝐶𝑂32− 𝑖𝑛 𝑎𝑠 𝐶𝑎𝐶𝑂3 + 𝐻 + 𝑎𝑠 𝐶𝑎𝐶𝑂3 − 𝐻 + 𝑎𝑠 𝐶𝑎𝐶𝑂3
𝑙 𝑙 𝑙 𝑙 𝑙
𝑚𝑔 𝑚𝑔 𝐸𝑊 𝑜𝑓𝐶𝑎𝐶𝑂3
• 𝐻𝐶𝑂3− 𝑖𝑛 𝑎𝑠 𝐶𝑎𝐶𝑂3 = 𝐻𝐶𝑂3
−
×
𝑙 𝑙 𝐸𝑊 𝑜𝑓𝐻𝐶𝑂3−
𝑚𝑔 𝑚𝑜𝑙𝑒 𝑔 𝑚𝑔 50
• 𝐻𝐶𝑂3− 𝑖𝑛 𝑎𝑠 𝐶𝑎𝐶𝑂3 = [𝐻𝐶𝑂3− ]( )× 𝑀𝑊 𝑜𝑓𝐻𝐶𝑂3− (𝑚𝑜𝑙𝑒) × 1000 ( ) ×
𝑙 𝑙 𝑔 61
𝑚𝑔 𝑚𝑜𝑙𝑒 𝑔 𝑚𝑔 50
• 𝐻𝐶𝑂3− 𝑖𝑛 𝑙
𝑎𝑠 𝐶𝑎𝐶𝑂3 = [𝐻𝐶𝑂3− ]( 𝑙
)× 61(𝑚𝑜𝑙𝑒) × 1000 ( 𝑔
) × 61
𝑚𝑔
• 𝐻𝐶𝑂3− 𝑖𝑛 𝑙 𝑎𝑠 𝐶𝑎𝐶𝑂3 = 50000 [𝐻𝐶𝑂3− ]
𝑚𝑔 𝑚𝑔 𝐸𝑊 𝑜𝑓𝐶𝑎𝐶𝑂3
• 𝐶𝑂32− 𝑖𝑛 𝑎𝑠 𝐶𝑎𝐶𝑂3 = 𝐶𝑂32− 𝑖𝑛 ×
𝑙 𝑙 𝐸𝑊 𝑜𝑓𝐶𝑂32−
𝑚𝑔 𝑚𝑜𝑙𝑒 𝑔 𝑚𝑔 50
• 𝐶𝑂32− 𝑖𝑛 𝑎𝑠 𝐶𝑎𝐶𝑂3 = 𝐶𝑂32− × 60(𝑚𝑜𝑙𝑒) × 1000( ) ×
𝑙 𝑙 𝑔 30
𝑚𝑔
• 𝐶𝑂32− 𝑖𝑛 𝑙 𝑎𝑠 𝐶𝑎𝐶𝑂3 = 2 𝐶𝑂32− × 50000
𝑚𝑔
• 𝐻+ 𝑎𝑠 𝐶𝑎𝐶𝑂3 = 𝐻 + × 50000
𝑙
𝑚𝑔
• 𝑂𝐻 − 𝑙 𝑎𝑠 𝐶𝑎𝐶𝑂3 = 𝑂𝐻− × 50000
𝑚𝑔
• 𝐴 𝑖𝑛 𝑎𝑠 𝐶𝑎𝐶𝑂3 = 50000 [𝐻𝐶𝑂3− ] + 2 𝐶𝑂32− × 50000 + 𝑂𝐻− × 50000 − 𝐻+ × 50000
𝑙
𝑚𝑔
𝐴 𝑖𝑛 𝑎𝑠 𝐶𝑎𝐶𝑂3
• 𝑙
= [𝐻𝐶𝑂3− ] + 2 𝐶𝑂32− + 𝑂𝐻− − 𝐻+
50000
𝑚𝑔
𝐴 𝑖𝑛 𝑙 𝑎𝑠 𝐶𝑎𝐶𝑂3
• 𝐻𝐶𝑂3− = − 2 𝐶𝑂32− − 𝑂𝐻− + 𝐻+
50000
[𝐻 + ][𝑊 − ]
• 𝐾𝑎 = 𝐻𝑊
• 𝑝𝐾𝑎 = − log 𝐾𝑎
[𝐻 + ][𝐶𝑂32− ]
• 𝐾𝑎2 = 𝐻𝐶𝑂3−
𝐾𝑎2 𝐻𝐶𝑂3−
• [𝐶𝑂32− ] = [𝐻 + ]
• 𝐾𝑤 = 𝐻+ 𝑂𝐻−
𝐾𝑤
• 𝑂𝐻− = 𝐻+
𝑚𝑔
𝐴 𝑖𝑛 𝑎𝑠 𝐶𝑎𝐶𝑂3 𝐾𝑎 𝐻𝐶𝑂3− 𝐾𝑤
• 𝐻𝐶𝑂3− = 𝑙
− 2 − + 𝐻+
50000 [𝐻 + ] 𝐻+
𝑚𝑔
𝐴 𝑖𝑛 𝑙 𝑎𝑠 𝐶𝑎𝐶𝑂3 𝐾𝑎2 𝐻𝐶𝑂3− 𝐾𝑤
• 𝐻𝐶𝑂3− = − 2 − + 𝐻+
50000 [𝐻 + ] 𝐻+
𝑚𝑔
𝐾𝑎2 𝐻𝐶𝑂3− 𝐴 𝑖𝑛 𝑙 𝑎𝑠 𝐶𝑎𝐶𝑂3 𝐾𝑤
• 𝐻𝐶𝑂3− + 2 = − + 𝐻+
[𝐻 + ] 50000 𝐻+
𝑚𝑔
𝐾 𝐴 𝑖𝑛 𝑙 𝑎𝑠 𝐶𝑎𝐶𝑂3 𝐾𝑤
• 𝐻𝐶𝑂3− 1+ 2 𝑎2 = − + 𝐻+
[𝐻 + ] 50000 𝐻+
• 𝐴𝑙𝑘𝑎𝑙𝑖𝑛𝑖𝑡𝑦 𝑑𝑢𝑒 𝑡𝑜 𝐻𝐶𝑂3−
𝑚𝑔
𝐴 𝑖𝑛 𝑎𝑠 𝐶𝑎𝐶𝑂3 𝐾𝑤
𝑙 − + 𝐻+
50000 𝐻+
• 𝐻𝐶𝑂3− = 𝐾
1+2 𝑎2
+
[𝐻 ]
𝒎𝒈
𝑚𝑔 𝑚𝑔 𝐸𝑊𝐶𝑎𝐶𝑂3 𝟐𝑲𝒂𝟐 (𝑯𝑪𝑶−
𝟑 𝒊𝒏 𝒂𝒔 𝑪𝒂𝑪𝑶𝟑 )
𝟐𝟓 = 𝒍
𝑎𝑠 𝐶𝑎𝐶𝑂3 = ( 𝑜𝑓 𝑠𝑝𝑒𝑐𝑖𝑒𝑠) × [𝑯+ ]
𝐿 𝐿 𝐸𝑊𝑠𝑝𝑒𝑐𝑖𝑒𝑠
𝑚𝑔 50 2 × 4.68 × 10−11 × 98.36
𝐴𝑙𝑘𝑎𝑙𝑖𝑛𝑖𝑡𝑦 𝑑𝑢𝑒 𝑡𝑜 𝑏𝑖𝑐𝑎𝑟𝑏𝑜𝑛𝑎𝑡𝑒 𝑖𝑜𝑛 𝑎𝑠 𝐶𝑎𝐶𝑂3 = 120 × = 98.36 25 =
𝐿 61 [𝐻+ ]
𝑚𝑔 50
𝐴𝑙𝑘𝑎𝑙𝑖𝑛𝑖𝑡𝑦 𝑑𝑢𝑒 𝑡𝑜 𝑐𝑎𝑟𝑏𝑜𝑛𝑎𝑡𝑒 𝑖𝑜𝑛 𝑎𝑠 𝐶𝑎𝐶𝑂3 = 15 × = 25
𝐿 30 𝐻 + = 3.68 × 10−10
𝒎𝒈
𝒎𝒈 𝟐𝑲𝒂𝟐 (𝑯𝑪𝑶− 𝟑 𝒊𝒏 𝒂𝒔 𝑪𝒂𝑪𝑶𝟑 )
𝟐−
𝑪𝑶𝟑 𝒊𝒏 𝒂𝒔 𝑪𝒂𝑪𝑶𝟑 = 𝒍
𝒍 [𝑯+ ] 𝑝𝐻 = − log(3.68 × 10−10 ) = 9.4
𝐻𝐶𝑂3− ⇌ 𝐻 + + 𝐶𝑂32− 𝑝𝐾𝑎2 = 10.33 𝑎𝑡 25℃
Outdoor bathing (Organised) B •Total Coliforms Organism MPN/100ml shall be 500 or less pH between
6.5 and 8.5 Dissolved Oxygen 5mg/l or more
•Biochemical Oxygen Demand 5 days 20C 3mg/l or less
Drinking water source after conventional treatment C •Total Coliforms Organism MPN/100ml shall be 5000 or less pH between
and disinfection 6 to 9 Dissolved Oxygen 4mg/l or more
•Biochemical Oxygen Demand 5 days 20C 3mg/l or less
Propagation of Wild life and Fisheries D •pH between 6.5 to 8.5 Dissolved Oxygen 4mg/l or more
•Free Ammonia (as N) 1.2 mg/l or less
Glucose:
6*12+12*1+6*16=72+12+96=180 g
Oxygen: 6*32=192 g
−𝑟𝐴 = −𝑘𝐿𝑡
𝑘 = 𝑅𝑒𝑎𝑐𝑡𝑖𝑜𝑛 𝑟𝑎𝑡𝑒 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡, 𝑑 −1
𝑑𝐿𝑡
= −𝑘𝐿𝑡
𝑑𝑡
𝐿
𝑑𝐿𝑡 𝑡 𝐵𝑂𝐷 = 𝐿0 (1 − 𝑒 −𝑘𝑡 )
= −𝑘 𝑑𝑡
𝐿
𝐿0 𝑡 0
𝐵𝑂𝐷 = 𝐿0 (1 − 10−𝐾𝑡 )
𝐿𝑡
ln = −𝑘𝑡 𝑘 = 2.303(𝐾)
• Actual BOD is less than ThOD due to 𝐿0
incorporation of some of the carbon into new Ultimate BOD (L0) is defined as
bacterial cell. 𝐿𝑡 = 𝐿0 𝑒 −𝑘𝑡 maximum BOD excreted by the
• The test is bioassay means to measure by waste, which will be equal to
biological means. concentration of organic matter at
𝐵𝑂𝐷 = 𝐿0 − 𝐿𝑡 = 𝐿0 − 𝐿0 𝑒 −𝑘𝑡
t=0.
BOD and COD
• A water sample is inoculated by bacteria which consume organic matter to obtain
energy for their life process.
• The organisms utilize the oxygen in process of consuming the waste, the process
is called aerobic decomposition.
• The BOD test is indirect measurement of organic matter, because we only
measure the change in concentration of dissolved oxygen caused by
microorganisms as they degrade organic matter. Although not all organic matter
is biodegradable.
• Chemical oxygen demand (COD) is a measure of the capacity of water to
consume oxygen during the decomposition of organic matter and the oxidation
of inorganic chemicals such as Ammonia and nitrite.
• Strong chemical oxidizing agent (chromic acid, H2CrO4) is mixed with water
sample and then boiled. The difference between the amount of oxidizing agent at
the beginning of the test and that remaining at the end of the test is used to
calculate the COD.
BOD Rate constant
• The value of rate constant (k) depends upon following properties.
• The nature of waste
Easily degradable: sugar, sucrose, starch etc.
Slowly degradable: cellulose (toilet paper)
Undegradable: hair fingernails
• The ability of organisms to utilize the waste
Not all microorganisms degrade organic matter. Difficulty come specially in case of
industrial waste. The bacterial seed need to be used for inoculation.
• The temperature
The biological process speedup as temperature increases and slow down as the
temperature drops.
Sample k (base e, at 20 °C) day-1 K (base 10, at 20 °C) day-1
Raw sewage 0.35-0.70 0.15-0.30
Well treated sewage 0.12-0.23 0.05-0.10
Polluted river water 0.12-0.23 0.05-0.10
BOD
• Five days BOD is selected as standard value for most waste water analysis for the regulatory
purpose.
• Ultimate BOD is better indicator of total strength of waste.
• Any type of waste having a define BOD the ratio of BOD5 to ultimate BOD is constant so that
BOD5 indicates a relative waste strength.
• Some of the compounds such as protein which contain N also oxidize with consumption of
molecular oxygen.
• The mechanism and rates of N oxidation is distinctly different from carbon oxidation.
• The oxygen consumption due to oxidation of carbon is called carbonaceous BOD (CBOD) and
while that due to nitrogen oxidation is called nitrogenous BOD (NBOD).
• The organisms that oxidize carbon in organic compounds for energy cannot oxidize the nitrogen in
these compounds. Instead the nitrogen is release into surrounding water as ammonia (NH3).
• At normal pH the ammonia is in the form of ammonium cation (NH4+).
• Ammonia is oxidized to nitrate by nitrifying bacteria (special group) as their source of energy in a
process called nitrification.
𝑚𝑖𝑐𝑟𝑜𝑜𝑟𝑔𝑎𝑛𝑖𝑠𝑚𝑠
𝑁𝐻4+ + 2𝑂2 ⇌ 𝑁𝑂3− + 𝐻2 𝑂 + 2𝐻 +
Problem
Problem 1. If the BOD3 of a waste is 75 mg/L and K is 0.150 d-1, what is the ultimate BOD?
• 75 = 𝐿0 1 − 100.150×3
• 𝐿0 = 116 𝑚𝑔/𝐿
Problem 2. A waste is being discharged into a river that has a temperature of 10 °C. What
fraction of the maximum oxygen consumption has occurred in four days if BOD rate
constant determined in the laboratory under standard conditions is 0.115 d-1.
𝑘 𝑇 = 𝑘20 (𝜃)𝑇−20
[𝜃 𝑖𝑠 𝑇𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 𝑐𝑜𝑒𝑓𝑓𝑖𝑐𝑖𝑒𝑛𝑡 = 1.135 𝑓𝑜𝑟 𝑡𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒𝑠 𝑏𝑒𝑡𝑤𝑒𝑒𝑛 4 −
20℃ 𝑎𝑛𝑑 1.056 𝑓𝑜𝑟 𝑡𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒𝑠 𝑏𝑒𝑡𝑤𝑒𝑒𝑛 20 − 30 ℃]
Problem 3 (a) Compute the theoretical NBOD of a waste water containing 30 mg/L of
ammonia as nitrogen (we often use NH3.N expression for ammonia as nitrogen).
(b) If waste water analysis was reported as 30 mg/L of ammonia (NH3), what would be
theoretical NBOD be?
DO sag curvee
• The water quality management in
rivers require to assess the dissolved
oxygen concentration profile down
stream from the waste discharge.
• This profile is called DO sag curve
because the DO concentration dips as
oxygen demanding materials are
oxidized and then rises again further
downstream as the oxygen is
replenished from the atmosphere.
• Mass balance approach is used to
determine the DO
Oxygen Sag curve
DO sag curve Mass of DO in wastewater
Up flow clarifier
Important criteria for sedimentation tank
• Purpose of inlet to evenly distribute flow and suspended particles across the cross section of the settling zone.
• Inlet water velocity: At inlet is decided in such a way that the due to turbulence the suspended particle can be evenly
distributed but the velocity slowdown to the design velocity of the settling tank.
• Length of the settling tank: Inlet and settling zone are designed separately and their length added together.
• Depth of the sludge storage zone: depends upon method of cleaning, the frequency of cleaning and quantity of sludge
estimated to be produced.
• With a well-flocculated solid and good inlet design, over 75 percent of the solids may settle in the first fifth of the tank.
For coagulant floc, Hudson recommends a sludge storage depth of about 03 m near the outlet and 2 m or more near
the inlet (Hudson, 1981).
• Mechanically-cleaned basins may be equipped with a bottom scraper, such as shown in Figure 4-33. The sludge is
continuously scraped to a hopper where it is pumped out. For mechanically cleaned. basins, a one percent slope
toward the sludge withdrawal point is used. A sludge hopper is designed with sides sloping with a vertical to horizontal
ratio of 1.2: 1 to 2: 1.
• Outlet Zone: The outlet zone is designed so as to remove the settled water from the basin without carrying away any of the
floc particles.
𝑄
𝑣=
𝐴𝑐
𝑚
𝑣 = 𝑤𝑎𝑡𝑒𝑟 𝑣𝑒𝑙𝑜𝑐𝑖𝑡𝑦 𝑖𝑛
𝑠
𝑚3
𝑄 = 𝑤𝑎𝑡𝑒𝑟 𝑓𝑙𝑜𝑤 𝑟𝑎𝑡𝑒
𝑠
𝐴𝑐 = 𝐶𝑟𝑜𝑠𝑠 𝑠𝑒𝑐𝑡𝑖𝑜𝑛𝑎𝑙 𝑎𝑟𝑒𝑎 𝑚2
Sedimentation tank outlet
• Scouring: Within the sedimentation tank, the flow is going through a very large area
(basin depth times width); consequently, the velocity is slow. To remove the water from
the basin quickly, it is desirable to direct the water into a pipe or small channel for easy
transport, which will produce a significantly higher velocity. If a pipe" were to be-placed
at the end of the sedimentation basin, all the water would "rush" to the pipe. This
rushing water would create high velocity profiles in the basin, which would tend to raise
the settled floc from the basin and into the effluent water. This phenomenon of washing
out the floc is called scouring.
• Rather than put a pipe at the end of the sedimentation basin, it is desirable to first put a
series of troughs, called weirs, which provide a large area for the water to flow through
and minimize the velocity in the sedimentation tank near the outlet zone. The weirs then
feed into a central channel or pipe for transport of the settled water.
• The length of weir required is a function of the type of solids. The heavier the. solids, the
harder it is to scour them, and the higher. the allowable outlet velocity. Therefore,
heavier particles require a. shorter length of weir than do light particles.
Sedimentation Concepts
• Settling velocity 𝑣𝑠
• The velocity at which the tank is designed to operate, called the
over flow rate 𝑣0 .
• The particle settling velocity must be greater than the liquid-rise
velocity (𝑣𝑠 > 𝑣0 ).
• If 𝑣𝑠 > 𝑣0 100 percent particle removal
• If 𝑣𝑠 < 𝑣0 is less than 0 % particle removal
• In design the procedure is to determine the particle settling
velocity and set the over flow rate at some lower value.
• Over flow rate 50-70% of settling velocity for upflow clarifier.
• It is sometimes3referred to as the surface loading rate because it
𝑚
has units of .
𝑑×𝑚2
• This can be thought of as the amount of water that-goes through
each m2 of tank surface area per day.
Sedimentation Concepts
𝑣𝑜𝑙𝑢𝑚𝑒/𝑡𝑖𝑚𝑒
• 𝑣0 =
𝑠𝑢𝑟𝑓𝑎𝑐𝑒 𝑎𝑟𝑒𝑎
𝐷𝑒𝑝𝑡ℎ×𝑠𝑢𝑟𝑓𝑎𝑐𝑒 𝑎𝑟𝑒𝑎/𝑡𝑖𝑚𝑒 𝑑𝑒𝑝𝑡ℎ ℎ
• 𝑣0 = = =
𝑠𝑢𝑟𝑓𝑎𝑐𝑒 𝑎𝑟𝑒𝑎 𝑡𝑖𝑚𝑒 𝜃
• However the particle removal does not depend upon depth of the tank as long as 𝑣𝑠 > 𝑣0 the
particle will settle downward and removed from the bottom.
• An ideal horizontal sedimentation tank is based upon three assumptions (Hazen, 1904, and Camp,
1946).
• 1. Particles and velocity vectors are evenly distributed across the tank cross section. This is the
function of the inlet zone.
• 2. The liquid moves as an ideal slug down the length of the tank.
• 𝐺 = 𝑣𝑒𝑙𝑜𝑐𝑖𝑡𝑦 𝑔𝑟𝑎𝑑𝑖𝑒𝑛𝑡 𝑠 −1
• 𝑃 = 𝑝𝑜𝑤𝑒𝑟 𝑖𝑛𝑝𝑢𝑡, 𝑊
• 𝑉 = 𝑣𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟 𝑖𝑛 𝑚𝑖𝑥𝑖𝑛𝑔 𝑡𝑎𝑛𝑘, 𝑚3
• 𝜇 = 𝑑𝑦𝑛𝑎𝑚𝑖𝑐 𝑣𝑖𝑠𝑐𝑜𝑐𝑖𝑡𝑦, 𝑃𝑎. 𝑠
• The chemical reaction in coagulation is completed in less than 0.1 s.
• Therefore it is necessary that mixing should be as instantaneous and
Rapid mixing complete as possible.
• Vertical shaft mixed is used for rapid mixing
• Coagulation occurs predominantly by two mechanisms: (a) adsorption of
the soluble hydrolysis species on the colloid and destabilization (b)
Sweep coagulation where the colloid is trapped in the hydroxide
precipitate.
• The reactions in adsorption-destabilization occurs very fast within 1 s.
• Sweep coagulation is slow and occurs in the range of 1 to 7 s.
• If charge reversal is apparent from the dose-turbidity curve then
adsorption-destabilization is the predominant mechanism.
• If dose-turbidity curve does not show charge reversal (i.e. curve is
relatively flat at higher doses) then the predominant mechanism is
sweep coagulation.
• G values in the range of 3000 to 5000 s-1 and detention time on the
order of 0.5 s are recommended for adsorption-desorption reactions.
• For sweep coagulation, detention time of 1-10 s and G values in the
range of 600-1000 s-1 are recommended.
Flocculation
• Flocculation is important process that affect particle removal efficiency.
• The aim of flocculation is to bring the particles into contact so that they will collide, stick together
and grow to a size that will readily settle.
• Enough mixing is required to bring the floc into contact and to keep the floc from settling in the
flocculation basin.
• To much mixing will shear the floc particles.
• Therefore the velocity gradient should be maintained within a narrow range.
• Heavier the floc and the higher the suspended solid concentration, the more mixing required to
keep the floc in suspension.
• Softening flocs are heavier than coagulation floc therefore requires a higher G value.
• Increase in floc concentration also increases the G value.
• At 20 C the detention time in flocculation basin is 20 min, at 15 °C the detention time is increased
by 7% and at 10 °C it is increased by 15% and then at 5 °C it is increased by 25%
Disinfection
• ·Disinfection is used in water treatment to reduce pathogens (disease-producing microorganisms) to an
acceptable level. Disinfection is not the same as sterilization. Sterilization implies the destruction of all living
organisms.
• Three categories of human enteric pathogens are normally of consequence: bacteria, viruses, and amebic
cysts. Purposeful disinfection must be capable of destroying all three.
• The water disinfectants must possess the following properties:
• They must destroy the kinds and numbers of pathogens that may be introduced into water within a
practicable period of time over an expected range in water temperature.
• They must meet possible fluctuations in composition, concentration, and condition of the waters or
wastewaters to be treated.
• They must be neither toxic to humans and domestic animals nor unpalatable or otherwise
objectionable in required concentrations.
• They must be dispensable at reasonable cost and safe and easy to store, transport, handle, and apply.
• Their strength or concentration in the treated water must be deterrnined easily, quickly, and
(preferably) automatically.
• They must persist within disinfected water in a sufficient concentration to provide reasonable residual
protection against its possible recontamination before use, or-because this is not a normally attainable
property-the disappearance of residuals must be a warning that recontamination may have taken place.
Chick’s law of disinfaction
• Under ideal conditions, the rate of die-off follows Chick's law, which states
that the number of organisms destroyed in a unit time is proportional to
the number of organisms remaining (Chick, 1908):
𝑑𝑁
• − = 𝑘𝑁
𝑑𝑡
• This is a first-order reaction. Under real conditions the rate of kill may
depart significantly from Chick's law.
• Increased rates of kill may occur because of a time lag in the disinfectant
reaching vital centres in the cell.
• Decreased rates of kill may occur because of declining concentration of
disinfectant in solution or poor distribution of organisms and disinfectant.
Chlorine as disinfectant
• Chlorination
• Chlorine may be used as the element (Cl2), or as sodium hypocrlorite(NaOCl), or as calcium
hypochlorite [Ca(OCl)2].
• 𝑪𝒍𝟐 𝒈 + 𝑯𝟐 𝑶 ⇌ 𝑯𝑶𝑪𝒍 + 𝑯+ + 𝑪𝒍−
• Reaction pH
• Dilute solution and pH above 1.0 equilibrium displaced to right and very little 𝐶𝑙2 𝑔 exists in
solution.
• Hypochlorous acid is week acid and dissociate poorly at levels of pH about 6
• Between 6.0 and 8.5 the HOCl completely dissociate to H+ and OCl- ions.
• 𝑯𝑶𝑪𝒍 ⇌ 𝑯+ + 𝑶𝑪𝒍− , 𝒑𝑲 = 𝟕. 𝟓𝟑𝟕 𝒂𝒕 𝟐𝟓℃
• Cl exists as HOCl at pH levels between 4.0 to 6.0.
• Below pH 1.0 the chlorine revert back to Cl2.
• Chlorine in the form of HOCl and OCl- is defined as free chlorine.
• Chlorine reacts with protein and amino acid of bacterial cell and alter the same and ultimately
destroy the cell protoplasm.
CT Concept
• Empirical expression for CT for defining the nature of biological
inactivation.
• 𝐶𝑇 = 0.9847 𝐶 0.1758 𝑝𝐻 2.7519 𝑇𝑒𝑚𝑝−0.1467
• C= disinfectant concentration
• T= Contact time between the microorganisms and disinfectant
• pH=-log[H+]
• Temp= temperature in ℃
Combined available chlorine/Reaction with Ammonia
• 𝑁𝐻3 + 𝐻𝑂𝐶𝑙 ⇌ 𝑁𝐻2 𝐶𝑙 + 𝐻2 𝑂
monochloramine
• In general high 𝐶𝑙2 : 𝑁𝐻3 ratios, low temperatures and low pH levels favour
dichloramine formation.
• Cl2 also reacts with organic nitrogenous material such as protein and
amino acid to form organic chloramine complexes.
• The chloramines are known as combined available chlorine.
• Disinfecting ability of chloramines is much lower than that of free chlorine
Break point chlorination
• With molar 𝐶𝑙2 : 𝑁𝐻3 ratio 1:1 (5:1 on
mass basis) chloramine and
dichloramine will be formed and
relative amounts of each depend on pH
and other factors.
• Further increase in 𝐶𝑙2 : 𝑁𝐻3 ratio
results in oxidation of ammonia and
reduction of chlorine
• At molar ratio 2:1 and if sufficient time
is provided for reactions to complete
the break point occurs. At this point the
oxidation/reduction reactions are
complete and further addition of
chlorine produces free residual
chlorine.
Other disinfectants
• Chlorine dioxide (ClO2): form on-site by combining chlorine and
sodium chlorite.
• Ozonation
• Ultraviolet radiation