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Adjuvants

Tolcide® PSA
A new Tolcide® formulation

Tolcide® Biocidal Products Tolcide®


Registered Applications
w Biodegrades to inert non-biocidal compounds
w US EPA Green Chemistry Award Winner
w Fast Acting, Broad Spectrum Biocide
w Tolcide® Products
w Effective across a wide pH range (3-11)
for Oil & Gas
w Effective Against SRB’s, APB’s • Water-floods
and Legionella • Pipeline Transmission
w Excellent Biofilm and MIC Control and Storage
w Dissolves iron sulfide
w EPA sub-registrations available upon request • Hydro-testing
w Easily field tested with Tolcide field test kits • Drilling Muds, Packer
Fluids, Completion
and Workover Fluids
Mode of Action • Pipeline Pigging
and Scraping
Causes Cell Lysis upon contact with the • Gas Storage Well
cell’s membrane (direct reduction of and Systems
micro population)
w Direct control of micro population
• Well Remediation
• Fracturing
SRB Before Tolcide® PS 
Reacts with Intra-cellular enzymes
which reduce cell’s chemical activity
and energy. w Industrial Water
w Does not reduce micro population Treatment Operations
but does reduce cell’s production • Re-Circulating Water
of H2S and acids which are main Cooling Towers
reasons for removing microbial
pests • Service and Auxiliary
SRB After Tolcide® PS Treatment Systems
O • Heat Transfer Systems
Tolcide® Products
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• Air-Washer Systems
• Fire Protection Systems
• PS70AF (70% THPS, EPA registered
Manufacturing Concentrate) • Macro-Fouling
• PS 70A (70% THPS, EPA & BPD
registered field use product)
• PS 50A (50% THPS,EPA & BPD
registered field use product) cH2O
• PS 20A (20% THPS, EPA registered Field Use Product)
w Conversion to THPO lends to favorable environmental profile
and easy deactivation
w PS “A” series products contain proprietary polymer for increased
biofilm penetration

Visit www.solvay.com for more information on Tolcide® Products (Case studies & Product Data Sheets)
Tolcide® PSA
A New Standard in Holistic Microbial Control

Tolcide® PS 50A and Tolcide® PS


70A are Solvay’s 3rd generation
THPS products with enhanced
biocidal performance. These ready
to use biocides combine both
THPS and biopenetrant to give
superior microbial control.

Feedback from end-users:

w Reduction of H2S in
production systems

w Reduction of MIC leading to


w Experiment conducted in a sand-packed bioreactor w Experiment conducted in a sand-packed bioreactor
increased tubular lifetime w Generic THPS is able to control souring w Tolcide® PS 50 A dosed continuously at low dosage is
w Tolcide® PS 50 A was shown to be fundamentally more able to inhibit H2S production
w Improved injectivity in WI & effective than generic THPS, as demonstrated by the
reduced recovery rate after treatment
PWRI systems

w Improved productivity due to


FeS stabilized crude oil

With Demulsifier

With Tolcide® PS

With Tolcide® PS

FeS/schmoo removal from


+Demulsifier

production wellbore/tubulars

w Reduced discharge sheen due


Tolcide® PS 50A
to dissolution of particulate FeS
Tolcide® Tolcide®
w Improved fluids separation

Tolcide® PS 50A Tolcide® PS 50A


Tolcide® is a Dual Use Product: Biocide and FeS Dissolver ECO Profile
Tolcide® THPS products encapsulate Fe and form a soluble molecule
• Tolcide® is Biodegradable

• Tolcide® Breaks Down


to THPO
• THPO is inert ingredient
& non-toxic to aquatic
organisms

• Tolcide® is VOC free

Tolcide® dissolves FeS (Iron Sulfide) and helps filter plugging/throughput of FeS
containing production fluids

Produced Water The Same


Containing FeS Produced Water
Particulates Treatment with
Tolcide®

Glutaraldehyde
Tolcide®
FEATURE Gluteraldehyde + Quat
“A” Series Products
DBNPA Products
Effective in Sour Systems Yes No

FeS Dissolution Yes No

Control of schmoo Yes No

Will not react with H2S Yes No


Holistic treatment –
Yes No
PWRI, Preventative and Curative Treatments
Effective Microbial Control at low
Yes No
and high pH

Facilitates demulsification Yes No


Yes - reduces potential
for resistant bacterial
Multi-mode of action No
populations
to emerge
Effective control of MIC Yes No

Control of biofilm without sloughing Yes No

Intracellular Mechanisms Yes No

Suitable for all fields Yes No


The way we do business
Solvay puts into practice a sustainable development policy called Solvay Way because we are convinced our future is depen-
dent upon the responsible way in which we conduct our current activities — a way that reflects our commitment to each of our
stakeholders. Solvay Way encompasses three interlinked, equally important spheres: the Environment Sphere, the People
Sphere and the Economic Sphere.

Based on a framework of responsibilities, Solvay Way allows Solvay sites and businesses to conduct self-assessments of their
practices and establish action plans that promote continuous progress. At Solvay, the way we do business creates sustainable
value for all our stakeholders through innovation and partnership.

> Responsible Care is the chemical industry’s voluntary continuous improvement


initiative to promote safe handling of products. (1987)

> The UN’s Global Compact aims to ensure that heads of companies promote and
uphold 10 universal principles concerning human rights, working conditions,
respect for the environment and anti-corruption. (2003)

> The International Federation of Chemical, Energy, Mine a


 nd General Workers’
Unions. (2005)

> Solvay Novecare has achieved world-wide ISO-9001 Quality Management System
Multi-Site Certification. (2008)

SOLVAY NOVECARE - Dileo Graphic Design, mariadileo@comcast.net


North America
Solvay Novecare – 8 Cedar Brook Drive – Cranbury, NJ 08512 – USA
Phone: +1-800-973-7873 – Fax: +1-609-860-0463 – NovecareCC@solvay.com

Europe
Solvay Novecare – 40, rue de la Haie-Coq – F-93306 Aubervilliers Cedex – France
Phone: +33 (0) 1 53 56 50 00 – Fax: +33 (0) 1 53 56 53 90

Asia Pacific
Solvay Novecare – 1, Biopolis Drive – #05-01/06 AMNIOS – Singapore 138 622
Phone: +65 - 6291 1921 – Fax: +65 - 6394 3376

Latin America
Solvay Novecare – Centro Empresarial – Avenida Maria Coelho Aguiar, 215, Bloco B-1º Andar
Cep: 05804-902 – São Paulo-SP Brazil
Phone: +55 11 3747-7637 – Fax: +55 11 3741-8378

www.solvay.com
2015
FEB

While the information herein is believed to be reliable, we do not guarantee its accuracy. Customers (direct and indirect) are urged to make their own tests with
products described herein. Various patents owned by Solvay or others may be pertinent to their use and to compositions containing them. Nothing contained
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herein is intended as a recommendation to use our products so as to infringe any patent. We assume no liability for any intellectual property rights violation by
customers (direct or indirect). Customers (direct and indirect) should make their own patent investigation related to the freedom to operate for any specific intended
use. If a relevant patent is identified, customers (direct and indirect) should secure a license from the patent owner. Customers (direct and indirect) should evaluate
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the products to determine notably their strength, performance and safety. All applicable laws and regulations should be consulted. All the names mentioned are
registered trademarks of Solvay, its subsidiaries or affiliates.

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