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CHEMISTRY
PAPER1
ANSWER
JUTANG 2OO9
JOHOFi
PETAJARAN
silJilr (SPM)
MAtAVSilA
GHEMISTRV
(MARKING PAPER
$GHEME 2]
SectionA
Alloy : Substance
Y 1
-Alloyhasforeignatoms 1
(iii) Substance
Y. 1
Theforeignatomsdisruptthe orderlyarrangement
of the metalatomsand preventthelayersof metal
atomsfromslidingovereachother. 1
HH
(ii)
H-c-c-cl 1
Nameof monomer:chloroethene 1
(iii) To makedrainpipes/artificialleatherlwater-proof
/bags//as insulatorfor electric
clothes/shoes
wiring 1 10
Question Explanation Mark E Mark
No.
2(a) (i) Melting 1
(ii) Molecule 1
(ii) Electron 1
H C I +N a OH )N a C l +HzO
Fromthe equation,
1 mol of NaOH reactwith 1 mol of HCI
= 25 cm3
t
Hydrochloric
acid/ HCI
Sodiumhydroxide/ NaOH
solution
.t
(b) |
Na*,cl-,H",oH- 1
I
(c) (i) Oxygen 1
]
(ii) InserUPlace/PuVBring theglowingwooden 1
splinterintothetesttube.
Theglowingwoodensplinterwillrekindles // 1
Gaswilllight up the glowingwooden splinter.
(lf otherstest of gas given,notaccepted)
(e) Platinum 1 10
4
Explanation
Numberof carbonatomspermolecule
oC
1 . Y axiswithboilingpointas labeland
as unit, X axiswithnumberof carbon
atompermoleculeas label.
2. Suitableandconsistentscale
3. Smoothlinewith6 pointstransferred
correctly
Liquid
Correctstructural formuIae
Conect namesof the fwo isomers
HHHH
H -C
ll l l C
l l rl
H H ;H
Butane/ n-Butane
a
H
I
H- c-H
HIH 1
rt l
c c_ H
ttl
HHH
4
2-methylpropane 1 10 ,!
(iii) +2to0 1
'(iv) 25xo'2=
No. of mole of CUSO+ o.oo5 1
1000
10
(v) massof ZnSOr = 0.005x 160= 0.8g. 1
.7
SectionB
of magnesium
combustion
- forthe complete 1 2
_l
(ii) fEGment- I
I lMg
30.64 = - 30.64 |
I Mass(s) I -28.24 132,24 2l
l= 1' 6 -l
,l
I
I Numberof l2L
= 0.1 I 1.6 = I
I moles
of 124 I 16 0.1 |
latoms | | |
lSimplestratiol 1 |
|
1 I 1l
lofmoles t |
fEmFrGAi-- 1 5
I formula I
(bxi) |--
1
I Similaritv| | heatins I
t'
I I betweena gas I betweena gas I 1
I I anda solid I anda solid -TI
lrvtediis tormeo
I lformed I I I
IDifferencewithoxygengas
I I I reactedwith I I
I I I hvdrooenqas I
I I The massof the I Themassof the I 1 Max.4
I I solidincreases I soliddecreases I
(ii) acid// or anydiluteacid
Dilutehydrochloric
2
Zinc llor any reactivemetal
1
(iii) 2HCl + .Zn + ZnClz + Hz
(iv)
Max.6
2
Total marks 20
Question Explanation
No
I (a)
(i) Lead(ll)chloride/l Silverchloride// Mercury
chloride
BlackpowderX: Copper(ll)oxide
BluesolutionY: Copper(ll)chloride
Anion:Chlorideion// Cl-
ri
,;
':
a::,
- colourless to yellow
- Presence of chromate(Vl) ionsgivethe 1
yellowcolourto the solutionl/ Chromate(Vl)
ionsin the first5 test tubesare all reacted//
In the last3 testtubes,chromate(Vl) ionsare 1
in excess 6
Total marks 20
10
SectionC
2-
x2* Y2-
X atomwithan electron
arranqement
of 2.8.2 1
ll
donates2 valenceelectronsto achievethe
stableoctetelectronarrangement, 2.8. X2*
ion is formed// X X" + 2e-
Y atomwithan electronarrangement of 2.6
accept2 electrons to achieve the stable octet
electronarrangemenj, 2.8.Y2-ion is formed
ll Y + 2e- -> Yz-
The oppositely-charged ions,X2*and Y2' are
attractedto eachotherbYa strong
electrostaticforce.
An ioniccompound XY is formed
(c)
1. A crucibleis filledwithsolidP untilit is halffull' 1
2. Two carbonelectrodesare dippedin the solidP 1
and connectedto the batteries.
3. Switchis turnedon and observation is recorded'
4. The solidP is then heated it
until melts
completely.
5. The switchis turnedon againand observation is
recorded.
6. Steps1 to 5 are repeatedusingsolidQ to
replacesolidP.
7. Observations:
P doesnot lightup the bulbin bothsolidand
moltenstates.
Q lightsup the bulbin moltenstateonly.
10
P: naphthalene// any suitableanswer
Q: bromide
fead(ll) ll anysuitablean$ /er
12
Question Explanation Mar k I Mark
No.
1 0( a ) CH+ 2Az CO2 + ZHzO I
R MMo f me th a n eC, H += 12 + 4 = 16 A
I
Thus
1 g of methanereleases= 898x 1 116kJ g-1 1
= 5 6 . 1 2 5k J g -1 1 4
(Correct answer and unit\
13
(c) Plottedqraph
4. Consistentscale 1
of alcohols(kJ mol-1)
Heatof^combustion
Numberof carbon
from
Heatof combustionincreases
methanol,ethanol,propanol,butan-l-ol,
Heatof combustionincreases
because:
1. Numberof carbonatompermolecule / mole
increasesfrom methanolto butanol.
3. MorecarbondioxidelCO2andwaterlHzO
moleculeare formed.
4. Morecovalentbondsareformedin the
products. 1
5. Moreheatis givenout. 1 6
Totalmarks 20
END OF MARKINGSCHEME
14
-
:'
JULANG zCICIg
JOHOR
s[J[tPETAJARAN (SPM]
MATAVSTA
GHEMISTRV
(MARKTNG PAPER
SGHEME 3)
:E
:5:
= @en g
MARKilygScHEME
Samplganswer:
Sampleanswer:
The reactivityincrease//
Z
Sampleanswer:
Lithium,sodiumand potassiumshowdifferentreactivity// A
I
Potassium.
Sodium.lithium
lncrease
No responseor wrongresponse U
ij.
:1
.Lfvtetnod b manipulatevatbble. - r#
@ fne respondingvariable-
3. The controlledvariable. -l
- lI
Sampleanswer: I
I
I
1) metals
(i) Use differenttypes of (alkali)i(group
of the reactionbetweenmetalsand
Vigorousness
oxygen.
Sampleanswer:
Reactivityincreasesfor the reactionbetweenalkalimetals
and oxygenwhengoingdownGroup1/ fromlithiumto
potassium. //
in Group1 is more/less
The metalwhichis lower/upper
reactive i/
SampleAnswer:
Metalsin Group1 can reactwith oxygen.//
Alkalimetalshavedifferentreactivity.
No responseor wrongresponse
:
QuestionNo.
Ableto giveth&perationaldqfrnitionaccuratelyby stating
.':
- alkalimetals
vigorously/ more vigorous/ reactive with axygen
- more / highlyreactive
Sampleanswer:
Sampleanswer:
Samoleanswer:
with oxygen.
Metalscan reactvigorously
No responsear wrongresponse
QuestionNo.
1 (eXi) Abteto statethe Positionof frX in Group1 accurately.
Sampleanswer.
peiiooslolz
Sampleanswer:
Below/underpotassium/l
Lowerthan potassium
Sampleanswer:
/Voresponsear wrongresponse
ilstionNoF ffiibric E : Score
= 1 (e)(ii) + Able to arrangethe metalsin ascending;s76", basedw
Ttheir reactivity. ;. .;=
-F
I Sampleanswer:
I
I Lithium,Sodium,Potassium,
X ll Li, Na, K, X
II
to arrangeany three of the metalsin ascending order
IAble
based on their reactivitv.
II
I Sampleanswer: L
Sampleanswer:
X, K, Na, Li ll
/Voresponseor wrongresponse U
Score
@etweenthe massofsodl
the time takenfor themifalto burncompletelyin
Sampleanswer:
Sampleanswer:
Sampleanswer:
Biggermass burnslonger.//
The metalsneedslongertime //
No responseor wrongresponse
e- E pu5rlc = ffi-ie
QuestionNdF
1 (g) Able to reeordallthe re@thgswith one decimalplace
accgrately. +
-F
Sampleanswer:
Sampleanswer: 2
10.8 ll 1 0 . 1, 1 0 . 5 ,1 0 . 9 ll
10.1,10.6, 1 0 . 0 ,1 0 . 6 , = 1 0 . 9
Sampleanswer: 1
No responseor wrongresponse 0
QuestionNo. bric
1 (h) ffi fq blue and red litmuspapel
-+
'correetly.
Sampleanswer:
Sampleanswer:
Sampleanswer:
No responseor wrongresponse
=: Score
QuestiffiNo. Rubri€
/i \ - the
Abteto write the two balancedcheffical equation-,4.or
reaction accurately.- :=
€
Sampleanswer
withanyalkalimetalsfrom
Notes:Sodiumcan be replaced
Table1.
Sampleanswer:
i. Na + 02 ) Na2O and z
i. 4Na + 02 ) 2NazO ll
Samoleanswer:
Na v2 ll NazO and 1
i. Na Oz ) NazO ll
Noresponseor wrongresponse 0
10
QuestionNo.
r u.l :=
r/:\ intostrong
Abteto ciasslfuall alkalinesoluflons
.€ :
one weak alkalicorrecfF
Sampleanswer:
/ NaOH'
Strongalkali. Sodiumhydroxide
PotassiumhYdroxideI KOH
/
CalciumhYdroxide Ca(OH),
NH3
Weakalkali : Ammoniasolution,
correctly.
Sampleanswer:
/ NaOH,
Strongalkali: Sodiumhydroxide
i KOH
PotassiumhYdroxide
@ of strongalkaliandweakalkali
correctly.
Sampleanswer:
No responseor wrongresponse
11
€ ;!r :€
-a--:: :: ::: :
: €:
ExperimeE{' *"rtrO.T H2SO4) Na2SOa+ S +EOz
.r r n <+
+ l-12Lr:-
-:= a
Sampleanswer:
Responsein questionform.
Sampleanswer:.
in temoerature
Howdoes the increase/decrease affectthe
rateof reaction?
Sampleanswer:
will increase/decreasethe
The higher/ lowerin temperature
rateof reaciion.//
0
Rubric gcore
QuestionNo.
2 (ii;
:
y'" the thre€v ariables correctlY
Sampleanswer
variable:
Manipulated
Temperature solution
of sodiumthiosulphate
Constantvariable:
Volumeand concentration sulphuric
of sodiumthiosulphate/
acid / sizeof conicalflask
l:
';:
13
Qtfttion No. .::
-= RE*Fric Score
? (iri) Able to s/afe fhe relationship;&rrectlybetweiZpthe
manipulatedvaliableandthe respondingvafrble with
'=--* directian. ;$.
Sampleanswer:
The higher/lower the temperature of sodiumthiosulphate
solution,the higher/lower
the rate of reaction./l
Sampleanswer:
The higher/lower
the temperature,
the higher/lower
the rate
of reaction.//
z
The higher/lower
the temperature,
the shorter/longer
the
timetakenfor mark'X'to disappear ll
Sampleanswer;
1
Differenttemperature,
differentreactivity.
//
No responsearwrongresponse tl
14
QuestTonNo. Rub& Score
2@i Ableto givecompbte tistof m
--:-
::- Sample
answer: F
Materials:
Sodiumthiosulphate
solution,
sulphuric
acid.
3
Apparatus:
Conicalflask,
,bunsenburner,measuringcylinder(10ml),,
measuring
cylinder(50ml),stop-watch,
filter/white
/cardboard
paper.
Answer:
Materials:
Sodiumthiosulphate
solution,
sulphuric
acid. 2
Apparatus:
Conicalflask,thermometer,
bunsenburner,filterI white
icardboardpaper.
No responseorwrong response n
15
:
Qu€stionNo. € -= -E ScoiE
Rubric
2 (v) Ableto listallJhe
- stepscorrectly -J.
I
:::.. -:l
SampleAns@ .-t
.J
-'l
1. 'X 'markis drawnon a pieceof whiteifilter/ cardboard l
I
paper.
50 cm3of sodiumthiosuphate solutioni(0.01-1.0)
moldm-31 is measured with a (50 cm3) measuring
cylinderandis pouredintoa conicalflask.
3 . The solutionis slowlyheateduntil30 "C.
5 cm3of hydrochlorii acidt(0.1-2.0)moldm-31 is
-.
measured with a (10cm")measuring cylinderand is
addedto the conicalflask.A stop-watchis started
immediately
5. The conicalflask is swirledand is placedon a
whiteifilter/cardboardpaperwith a mark'X'.
The'X' markis observedverticallyfromthe top
throughthe solution.
-7
The stop-watchis stoppedimmediately whenthe 'X'
markcannotbe seen.Time is recorded,
The experimentis repeatedby usingthe sodium
thiosuphate solutionat 40 oC,50 oC,60 oCand70'C
r p cn cr - iir r e h r
No responseor wrongresponse 0
QueSlionNo. ':
KUDnC ; Score
2 (vi) Mle to tabulat&he data with followingaspecfs
.:::
;-F-
1. Correcttitlffirith units
2. Completelistof temperatures
Sample
answer:
Temperature Time
("c) (s) Z
5U
40
60
70
1. At least1 titlescorrectwithoutunits
2. lncompletelistof tempereatures
Sampleanswer:
Temperature
1
30
No responseor wrongresponse 0
r7
:€ in:'
Exp#nent2:2H&+ 7n ) ffiL. + H,
€uestionNo. Rubric Sco_re
-:.
t lt l
Able to gi-vethe stalement of the probf@accurately.
-- Responseis in questionform.
Sampleanswer:
Howdoesthetemperature of hydrochloric
acidsolution
affectthe rateof reaction?i/
Sampleanswer:
in temperatureaffectthe
Howdoesthe increase/decrease
rateof reaction?
Sampleanswer:
will increase/decreasethe
The higher/ lowerin temperature
rateof reaction.//
Manipulated
Variable.
Temperature
of hydrochloric
acid
Responding variable:
Rateof reaction// Volumeof gas per unittime
Constantvariable:
Mass/sizeo'fzincll
Volumeandconcentration
of hvdrochloric
acid
Noresponseor wrangresponse n
19
Questio@o. E Ru b ric + - core
z ( lllF Able tostate the relationshipcorrectlybetween theF
manipttWedvariableand the responclingvariablewith
directiffi
:
.-
Sampleanswer:
The higher/lower the temperature of hydrochloric
acid,the
higher/lowerthe rate of reaction./l
The increaseldecrease
in temperatureof hydrochloric
acid
willincrease/decreadb
the rateof reaction.//
Sampleanswer:
The higher/lower
the temperature,
the higher/lower
the rate
of reaction.//
z
The higher/lower
the temperature,
the higherilowerthe
volumeof the hydrogengas releasedper unittime. //
The increase/decrease
in temperature
will
increaseidecrease
the rateof reactions.//
Sampleanswer;
Differenttemperature,differentreactivity.i/ 1
Temperature
changes,the time takenis different.
Noresponse
or wrongresponse 0
20
Ru b ric
2 (iv) - | AOieto g@ completelistof mateialsand apparatuf
I Sampleanswer:
Materials:
Zinc,hydrochloric
acid
A ,^.
/- 1^^^-^1,
PPclrcr [u 5 .
Conicalflask,thermometer , bunsenburner,stop-watch
measuring cylinder(50 ml),delivery
tubeandstopper,
burette.basin.
Answer:
Materials:
acid
Zinc,hydrochloric
A pparatus:
bunsenburner,deliverytube,
Conicalflask,thermometer,
burette
tVoresponseor wrongresponse
2l
QuestionNo, -+ Rubfr +Score
-+
2 (v) Able to list all fhe:ffeps correctly*
saffiteAniwer:
1-, Buretteis filledwithwaterandinvertedinto a basin
containing water.
2. The buretteis clampedverticallyusingretortstand.
3. lnitialreadingof buretteis recorded.
4. t20-501 cm'of hydrochloric acid [(0.01-1.0)
mol
dm{l is measured witha (50ml) measuring cylinder
and is poured intoa conicalflask.
5. The solutionis slowlyheateduntil30 "C.
6. 2 g of zincis weighed,and is put intothe conical
-- flask.
7. The conicalflask is closedimmediatelywith a
stopperwhichis joinedto the deliverytube and
the stopwatchis started.
B. The burettereadingis recordedat intervalof 30
secondsuntilthe reactionis completed.
9. The experimentis repeatedby usingthe
hydrochloric acidat 40'C, 50 oC,60 oCand
70 oCrespectively.
No responseor wrongresponse tl
22
QuestionNo. Rubric + Score
2 (vi) datawithfo|Iow@aspects
AbIeto-tabulat€the
1. Correcttitteswith units
2. Completelistof temPeratures
Sampleanswer:
Temperature Time
\ \,/ (s) 2
JU
-40
bU
70
1. At least 1 titlescorrectwithoutunits
2. lncompletelistof tempereatures
Sampleanswer:
Temperature
1
JU
No responseor wrongresponse 0
ENDOF MARKINGSCHEME
LJ