T=35℃ T=25℃

No. Tiempo(min) V1 de HCl (ml) No.

1 5 7 1
2 10 6.2 2
3 15 5.5 3
4 20 5.1 4
5 25 5.1 5
6 30 5.1 6
7
8
9
10
11
12

T=35℃
No. V1 de HCl (ml) C1: HCl (mol/ml) V2 de NaOH (ml) C2: NaOH (mol/ml)
1 7 0.01 30 0.0023
2 6.2 0.01 30 0.0021
3 5.5 0.01 30 0.0018
4 5.1 0.01 30 0.0017
5 5.1 0.01 30 0.0017
6 5.1 0.01 30 0.0017

Concentracion NaOH T1=35℃ T2=25℃

Tiempo(min) T1=35℃ T2=25℃ ln(tiempo) ln(T1=35℃) ln(T2=25℃)
5 0.00233 0.00307 1.6094379124 -6.0604574186 -5.787164084
10 0.00207 0.00267 2.302585093 -6.1818182756 -5.926926026
15 0.00183 0.00237 2.7080502011 -6.3016194754 -6.046272784
20 0.0017 0.00220 2.9957322736 -6.3771270279 -6.119297919
25 0.0017 0.00207 3.2188758249 -6.3771270279 -6.181818276
30 0.0017 0.00190 3.4011973817 -6.3771270279 -6.265901393
35 0.00187 3.5553480615 -6.28360097
40 0.00180 3.6888794541 -6.319968614
45 0.00177 3.8066624898 -6.338660747
50 0.00173 3.9120230054 -6.357708942
55 0.00170 4.0073331852 -6.377127028
60 0.00170 4.0943445622 -6.377127028
 ln⁡〖� _𝐴𝑜/�_𝐴⁡ 〗 Constate de velocidad instantanea
T1=35℃ -5.7543165281
1/�_𝐴⁡
T1=25℃ -5.3675876534
�_𝐴

Tiempo
5 0.00233 4.4510195062 428.5714285714
10 0.00207 4.5723803632 483.8709677419
15 0.00183 4.692181563 545.4545454545
20 0.0017 4.7676891155 588.2352941176
25 0.0017 4.7676891155 588.2352941176
30 0.0017 4.7676891155 588.2352941176

5 0.00307 4.1777261712 326.0869565217

10 0.00267 4.3174881135 375
15 0.00237 4.4368348712 422.5352112676
20 0.00220 4.5098600062 454.5454545455
25 0.00207 4.5723803632 483.8709677419
30 0.00190 4.6564634804 526.3157894737
35 0.00187 4.6741630575 535.7142857143
40 0.00180 4.7105307016 555.5555555556 TT
45 0.00177 4.7292228347 566.0377358491
0.00350
7005
700
4.8
0.00250
50 0.00173 4.7482710296 576.9230769231 f(x) = 0
0.00300
600
600 R² = 0.8
55 0.00170 4.7676891155 588.2352941176 4.8
4.7
0.00200
f(x)
f(x) == 4.66110
0.00996
f(x)f(x)
=6
R²
R² == 0.912678
0.870114
R² =R²0.8
=
60 0.00170 4.7676891155 588.2352941176 0.00250
500
500 f(x) = - 2
4.6 R² = 0.81
0.00150

ln(CAO/CA)
0.00200
400
400

1/CA
4.4

1/CA
4.5

CA
CA
0.00150
300
300
0.00100
4.2
4.4
0.00100
200
200
Temperatura (K)1/T (K-1) K (l/mol min) Ln(k)
0.00050
4
4.3
308.15 0.0032451728 109.39 4.6949194781 0.00050
100
100
298.15 0.0033540164 26.137 3.263351935 0.00000
3.8
00
4.2
0.00000
000 00 5 10
10
10 5

273.15 0.0036609921 23.94540 3.1757763142

278.15 0.0035951825 24.38372 3.1939157559
283.15 0.003531697 24.82204 3.211732012
288.15 0.0034704147 25.26036 3.2292363973
293.15 0.0034112229 25.69868 3.2464396428
298.15 0.0033540164 26.13700 3.263351935
303.15 0.003298697 26.57532 3.2799829519
308.15 0.0032451728 109.39000 4.6949194781
313.15 0.0031933578 4
318.15 0.0031431715 4.5
323.15 0.0030945381 5
328.15 0.0030473869 5.5
333.15 0.0197970884
Temperatura (K)1/T (K-1) K (l/mol min) Ln(k)
308.15 0.0032451728 334.8534 5.8136928241
298.15 0.0033540164 2640.795 7.8788352872

Orden de constante k 35°C constante k 25°C

Método reacción (l/mol*s) (l/mol*s)2
Método
integral α=2 1.82316667 0.43561667
Método no
lineal α=2 5.58089 61.6021

Valor
reportado en
literatura α=2 0.211 0.112
 T=25℃
Tiempo(min) V1 de HCl (ml)
5 9.2
10 8
15 7.1
20 6.6
25 6.2
30 5.7
35 5.6
40 5.4
45 5.3
50 5.2
55 5.1
60 5.1

T=25℃
No. V1 de HCl (ml) C1: HCl (mol/ml) V2 de NaOH (ml) C2: NaOH (mol/ml)
1 9.2 0.01 30 0.00307
2 8 0.01 30 0.00267
3 7.1 0.01 30 0.00237
4 6.6 0.01 30 0.00220
5 6.2 0.01 30 0.00207
6 5.7 0.01 30 0.00190
7 5.6 0.01 30 0.00187
8 5.4 0.01 30 0.00180
9 5.3 0.01 30 0.00177
10 5.2 0.01 30 0.00173
11 5.1 0.01 30 0.00170
12 5.1 0.01 30 0.00170

-5.4
0.00350

0.00300
-5.6
Concentracion NaOH (mol/ml)

0.00250
-5.8
Ln Concentracion

0.00200

-6
0.00150

0.00100
-6.2

0.00050
-6.4
0.00000
0 10 20 30
-6.6
Tiempo (m
1 1.5 2 2.5 3

T1=35℃Ln Tiempo P
T2=25℃ P
T1=35℃ T2=25℃
 0.00050

C
-6.4
0.00000
0 10 20 30
-6.6
Tiempo (m
Pendiente Orden de reaccion 1 1.5 2 2.5 3

T1=35℃ -4.9175017025 T1=35℃Ln Tiempo P

T1=25℃ -3.907379253 T2=25℃ P
T1=35℃ T2=25℃

6.5954
4.6611

Tiempo
Tiempo
Tiempo VS
Tiempo
Tiempo VS
VS
VSVS CA
ln(CAO/CA)
1/CA
ln(CAO/CA)
1/CA
0.00350
7005
700
4.8
0.00250
f(x) = 0.0128273249x + 4.4452966109
0.00300
600
600
4.8 f(x) R² = 0.8312200667
4.7
0.00200 f(x) == 4.6611035569x
0.0099653281x
f(x)f(x) ++ 348.4354362189
4.2651534069
= 6.5953888887x + 421.6811651347
= - 2.51428571428572E-05x + 0.0023288889
R²
R² == 0.9126780113
0.8701140593
R² =R²0.8448393582
= 0.8152214598
0.00250
500
500 f(x) = - 2.17948717948718E-05x + 0.0027777778
4.6 R² = 0.8177814516
ln(CAO/CA)

0.00150
0.00200
400
400
1/CA

4.4
1/CA

4.5
CA
CA

0.00150
300
300
0.00100
4.2
4.4
0.00100
200
200
0.00050
4
4.3
0.00050
100
100
0.00000
3.8
00
4.2
0.00000
000 00 5 10
10
10 5 10 20
20
20 10 1530
30
30 15 402040
40 20 50
5050
25
25 60
6060
30
30 7070
35
35
35
Tiempo
Tiempo
Tiempo
Tiempo
Timepo (min)
(min)

1/T VS Ln K
5
4.5 f(x) = - 13152.5157081615x + 47.3771057775
4 R² = 1
3.5
3
2.5
Ln K

2
1.5
1
0.5
 4.5 f(x) = - 13152.5157081615x + 47.3771057775
4 R² = 1
3.5
3
2.5
Ln K 2
1.5
1
0.5
0
0.0032 0.00322 0.00324 0.00326 0.00328 0.0033 0.00332 0.00334 0.00336
1/T
 20 30 40 50 60 70
Tiempo (min)
2 2.5 3 3.5 4 4.5

T1=35℃Ln Tiempo Pol ynomi a l (T1=35℃)

T2=25℃ Pol ynomi a l (T2=25℃)
T1=35℃ T2=25℃
 20 30 40 50 60 70

Tiempo (min)
2 2.5 3 3.5 4 4.5

T1=35℃Ln Tiempo Pol ynomi a l (T1=35℃)

T2=25℃ Pol ynomi a l (T2=25℃)
T1=35℃ T2=25℃

1/T VS Ln K
9
8
f(x) = 18973.4803745724x - 55.7585297122
7 R² = 1
6
5
Ln K

4
3
2
1
0
0.0032 0.00322 0.00324 0.00326 0.00328 0.0033 0.00332 0.00334 0.00336
1/T
 3
2
1
0
0.0032 0.00322 0.00324 0.00326 0.00328 0.0033 0.00332 0.00334 0.00336
1/T