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ORGANIC CHEMISTRY

DPP NO.

TARGET : JEE (Main + Advanced) 2016 02


Course : VIJETA (JP) Date : 06-04-2015 DAILY PRACTICE PROBLEMS

T E S T I N FO R M AT I O N
DATE : 19.04.2015 SCHOLARSHIP TEST

Syllabus : Complete IX Syllabus

This DPP is to be discussed in the week (06-04-2015 to 11-04-2015)


DPP No. # 02 (JEE-ADVANCED)
Total Marks : 53 Max. Time : 32 min.
Multiple choice objective ('–1' negative marking) Q.1 to Q.6 (4 marks, 2 min.) [24, 12]
Matching List Type (Only One options correct) ('–1' negative marking) Q.7 (3 marks, 2 min.) [03, 02]
Match the Following (no negative marking) Q.8 (8 marks, 6 min.) [08, 06]
Single Integer Type Questions Q.9 to Q.10 (3 marks 2 min.) [06, 04]
ChemINFO : 4 Questions ('–1' negative marking) Q.11 to Q.14 (3 marks, 2 min.) [12, 08]

1. In which options both compounds can show geometrical isomerism


fuEu esa ls dkSuls p;u esa lHkh ;kSfxd T;kfefr; leko;ork iznf'kZr djrs gSA

(A) , (B*) , C2FClBrI.

(C) , Ph2N2 (D*) CH3–CH = N–OH , H2C = CH–CH = CH–CN.

Sol. (A)

yes no

(B) C2FClBrI.

Yes yes
 
(C) Ph– N = N –Ph

no yes

(D*) CH2=CH–CH=CH–CN.

yes yes

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2. Which of the following can not show geometrical isomerism?
fuEu esa ls dkSu T;kferh; leko;ork ugha n'kkZrk gS \

(A) (B) (C*) (D)

3. For which of the following pairs of compounds are the CORRECT notations given.
;kSfxdksa ds fuEu esa ls dkSuls ;qXe esa lgh ladsr fn;k x;k gS \

(A) (B*)

anti azobenzene syn azobenzene syn acetaldoxime Anti acetaldoxime


,UVh ,tkscsUthu flu ,tkscsUthu flu ,lhVsYMksfDte ,UVh ,lhVsYMksfDte

(C*) (D)

Trans–o–aminocinnamic acid Cis–o–aminocinnamic acid Z-isomer E-isomer


foi{k-o-,ehuksflusfed vEy lei{k-o-,ehuksflusfed vEy Z-leko;oh E-leko;oh

4. Which of the following compound has Z configuration ?


fuEu esa ls dkSuls ;kSfxd dk Z foU;kl gksxk ?

(A) (B*)

(C*) (D*)

5. In which of the following first one has lower dipole moment than second ?
fuEu esa ls fdlesa izFke dk f}/kqzo vk?kw.kZ f}rh; ls de gS

(A) , (B) ,

(C*) , (D*) ,

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6. The incorrect order with respect to the properties mentioned for the following pair of compounds is :
fuEu ;kSfxd ;qXeksa ds fy, iznf'kZr HkkSfrd xq.kksa esa dkSulk Øe xyr n'kkZ;k x;k gSA

(A) < (Stability) ¼LFkkf;Ro½

¼foi{k½ ¼lei{k½

(B) < (Stability) ¼LFkkf;Ro½

(C*) > (Boiling point) ¼DoFkukad½

(D*) > dipole moment () ¼f}/kqzo vk?kw.kZ½ ()

7. Match List I (Compounds) with List II (Relation) and select the correct answer using the code given below the
lists :
lwph I (;kSfxd) dks lwph II ¼lEcUèk½ ls lqesfyr dhft, rFkk lwfp;ksa ds uhps fn;s x;s dksM dk iz;ksx djds lgh mRrj pqfu;s
: List I lwph I List II lwph II

(P) (1) Identical leku

(Q) (2) Homologues letkr

(R) (3) Structural isomers lajpuk leko;oh

(S) (4) Geometrical Isomers T;kferh; leko;oh

Codes ¼dksM½ :
P Q R S P Q R S
(A) 4 3 1 2 (B) 1 2 3 4
(C*) 4 3 2 1 (D) 4 2 1 3

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8. Match the column-I with column-II :
dkWye-I dks dkWye-II ls lqesfyr dhft, %
Column-I Column-II

(A) Geometrical isomerism (P)

(B) Z-isomer (Q)

(C) Cis-isomer (R)

(D) E-isomer (S)

dkWye-I dkWye-II

(A) T;kfefr leko;ork (P)

(B) Z-leko;oh (Q)

(C) fll&leko;oh (R)

(D) E-leko;oh (S)

Sol. A  Q, R, S B  Q, R C  Q, R, S D S

9. Geometrical isomerism is possible in how many of the following molecules/compounds.


fuEu fdrus v.kq ;k ;kSfxdksa es T;kfefr; leko;oh lEHko gS \

Cl
NH Br
(1) (2) (3) (4)
NH

Me
NH

(5) (6) (7) (8) MeS
NH

(9) (10)

Ans. 6 (2, 3, 4, 5, 6 ,8)

10. Total number of position isomers of tetrachlorocyclobutane which can shows geometrical isomerism are :
VsVªkDyksjks lkbDyks C;wVsu ds dqy fdrus fLFkfr leko;oh T;kfefr leko;ork n'kkZrs gSA
Ans. 3

Sol.

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ChemINFO-1.1 Oxidation
Daily Self-Study Dosage for mastering Chemistry Syn hydroxylation of Alkenes and Alkynes
Syn hydroxylation of Alkenes and Alkynes
General Reactions : H.A. = Hydroxylating agent. It may be any one of these:
(a) Baeyer’s reagent: cold dilute 1% alkaline KMnO 4 (pink
H.A. colour) or

(b) i) OsO4 ii) NaHSO3

H.A.
Note :
—CC— 
1. Double bond of Aromatic ring cannot react with these
reagents.

Ex. H.A. 2. It is syn addition. Both OH groups add on the same



side of pi-bond.

Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.

Baeyer's reagent
11.    
 Product
Product will be :

OH

(A) (B) (C*) (D)


OH

12.

Reagent x will be :
(A) 1% alkaline KMnO4 (Baeyer’s reagent) (B) OsO4 /NaHSO3
(C) Peracid/H3O+ (D*) A and B both

Baeyer 's Re agent


13. CH3 – C  C – CH3 or
   Product.
OsO4 / NaHSO3
Product will be :

(A) (B*) (C) (D) None of these

14. Which one of the following can not undergo in hydroxylation.

(A) (B) (C*) (D)

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ChemINFO-1.1 Oxidation
Daily Self-Study Dosage for mastering Chemistry Syn hydroxylation of Alkenes and Alkynes
Syn hydroxylation of Alkenes and Alkynes

lkekU; vfHkfØ;k : H.A. = gkbMªksfDlyhdj.k vfHkdeZdA bues ls ,d gks ldrk gSA


(a) cs;j vfHkdeZd % BaMk ruq 1% {kkjh; KMnO4 (xqykch jax )
H.A.

;k
(b) i) OsO4 ii) NaHSO3

Note :
H.A. 1. ,sjksesfVd oy; ds f}cU/k bu vfHkdeZdksa ls vfHkfØ;k ugha djrs
—CC— 
gaAS
2. ;g flu (syn) ;ksx gSA nksuks OH lewg pi-cU/k ds ,d gh i{k dh
Ex. H.A. rjQ ls tqMrs gSaA


Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.

11.    mRikn


mRikn gksxk %
OH

(A) (B) (C*) (D)


OH

12.

vfHkdeZd x gksxk %
(A) 1% {kkjh; KMnO4 (cs;j vfHkdeZd) (B) OsO4 /NaHSO3
(C) ij vEy /H3O+ (D*) A ,oe~ B nksuksa

13. CH3 – C  C – CH3      mRikn.


or OsO / NaHSO4 3

mRikn gksxk %

(A) (B*) (C) (D) bues ls dksbZ ugha

14. Which one of the following can not undergo in hydroxylation ?


fn;s x;s ;kSfxdks es ls fdldk gkbMªksfDlyhdj.k ugha gksxk \

(A) (B) (C*) (D)

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