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TEST IN FORMATION
Sol. Compound has C3 and C3/2 axis of symmetry but no C2 axis of symmetry..
g y- ;kSfxd esa C3 rFkk C3/2 lefefr dk v{k mifLFkr gS ysfdu C2 lefefr dk v{k mifLFkr ugha gSA
(A) (B)
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(C) (D)
7. Which of the following is the lowest molecular weight hydrocarbon which is chiral.
(A*) 3-Methylhexane (B) 2, 4-Dimethylpentane
(C) 2, 2-Dimethylpentane (D) 3, 3-Dimethylpentane
fuEu esa ls dkSu U;wure v.kq Hkkj ;qDr gkbMªksdkcZu tks fd fdjSy gSA
(A*) 3-esfFkygsDlsu (B) 2, 4-MkbZesfFkyisUVsu (C) 2, 2-MkbZesfFkyisUVsu (D) 3, 3-MkbZesfFkyisUVsu
8. Which among the following compound has (L) configuraiton ?
fuEu esa ls fdl ;kSfxd dk (L) foU;kl gS\
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9. Which of the following compound posses plane of symmetry :
fuEu esa ls dkSulk ;kSfxd leferh dk ry j[krk gS :
10.
11. A compound was having [] = 40.3º in polarimeter experiment in clockwise direction what can be the structure is :
,d ;kSfxd dk [] = 40.3º gS ftls iksysjhehVj iz;ksx ls nf{k.kkorZ fn'kk esa Kkr fd;k x;k gSA vr% bldh lajpuk gksxhA
(A) (B)
. (C) (D*)
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dk izdkf'kd ?kw.kZu – 45° gS rks dk izdkf'kd ?kw.kZu gksxkA
(A) + 45° (B) 0° (C) – 45° (D*) dqN dgk ugha tk ldrk A
13. In which of the following spatial representation of group/atoms is different from the given strucuture P.
P=
dkSuls fodYi esa fn;s x;s lewgksa ,oa ijek.kqvksa ds f=kfoe vfHkfoU;kl lajpuk P ls fHkUu gSA
P=
14. If the optical rotation produced by is +36º, then the optical rotation produced by
will be :
;fn }kjk mRiUu izdkf'kd ?kw.kZu +36º gS rks }kjk mRiUu izdkf'kd ?kw.kZu gksxk&
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16. The following two compounds are
fuEu ;qXe ds e/; lEc/k gSA
&
Sol. Moderate
(A)
(B)
18. Relation between (I) and (II) (whose configuration in given below is):
uhps fn;s x;s ;kSfxd (I) rFkk (II) ds e/; laca/k gS %
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19. Which of the following is correct for the given compound ?
fn; x;s ;kSfxd ds fy, fuEu esa ls dkSulk lgh gS \
20.
1.
Which of the following statement(s) is/are correct for the above compounds ?
(A*) the compound I posses an axis of symmetry.
(B) the compound II posses a centre of symmetry.
(C*) compound I and II both are optically active and enantiomers of each other.
(D*) Diastereomers of both compounds are identical and meso.
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mijksDr ;kSfxdksa ds fy, fuEu esa ls dkSuls dFku lgh gS \
(A*) ;kSfxd I v{k lefefr j[krk gSA
(B) ;kSfxd II dsUnz lefefr j[krk gSA
(C*) ;kSfxd I rFkk II nksuksa izdkf'kd lfØ; gSa rFkk ,d nwljs ds izfrfcEc:ih gSaA
(D*) nksuksa ;kSfxdksa ds foofje leko;oh le:i ,oa ehlks gSA
H
C2 C2
H C2 H
H H
Sol. (A) C C C2 3 C2 (B) 3 C2
H H C2
H C2 H
H H
C2
H H C2
H H C2
H H H H C2 C2
(C) 5 C2 (D) C2 7 C2
C2
C2 C2
H H C2 H H
C2
C2
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6._ Which of the following pair of compounds can be separated by fractional distillation ?
fuEu esa ls ;kSfxdksa dk dkSulk ;qXe izHkkth vklou }kjk i`Fkd gks ldrk gS \
7. Comprehension
Each optically active compound has a characteristic specific rotation. Specific rotation is a number of de-
grees of rotation caused by a solution of 1 gm of compound per mL of solution in a sample tube 1 dm long at
a specific temperature and wavelength. Thus specific rotation can be calculated from the observed rotation
using the following formula
[ ] T
c.
When sodium D line is used, is indicated by D.
S.No. Name of compound Concentration Specific rotation length of tube observed rotation
I. 2-butanol 1.0 M - 10 cm +1.030
II. 1-butanol 1.0 M - 10 cm -
III. lactic acid 0.35 g/mL +160 5.0 cm +2.8 0
VI. -Cholestane - +240 - -
vuq P Ns n
izR;sd izdkf'kd lfØ; ;kSfxd esa ,d vfHkyk{kf.kd fof'k"V ?kw.kZu ik;k tkrk gSA fu;r rki rFkk rjaxnS/;Z ij 1dm yEch
ufydk esa 1gm ;kSfxd ds izfr ml foy;u }kjk mRiUu ?kw.kZu dh ek=kk dks fof'k"B ?kw.kZu dgrs gSaA vr% fof'k"B ?kw.kZu dh
x.kuk fuEufyf[kr lw=k dh lgk;rk ls izsf{kr ?kw.kZu }kjk dh tk ldrh gSA
[ ] T
c.
tc lksfM;e D js[kk dk mi;ksx djrs gS] rks dks D }kjk iznf'kZr fd;k tkrk gSA
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Ø-la - ;kSfxd dk uke lkUnz r k fof'k"B ?kw.kZu ufydk dh yEckbZ izsf{kr ?kw.kZu
0
I. 2-C;wVsukWy 1.0 M - 10 cm +1.03
II. 1-C;wVsukWy 1.0 M - 10 cm -
0
III. ysfDVd vEy 0.35 g/mL +16 5.0 cm +2.8 0
VI. -dksysLVsu - +240 - -
(i). What is the specific rotation of 2-butanol?
2-C;wVsukWy dk fof'k"B ?kw.kZu D;k gksxk?
(A*) +13.90 (B) -13.90 (C) +1.390 (D) -1.390
(ii). What is the specific rotation of 1-butanol?
1-C;wVsukWy dk fof'k"B ?kw.kZu D;k gksxk?
0
(A) 1.3 (B*) 00 (C) +13.90 (D) Insufficient Data vk¡dM+s vi;kZIr
gSA
(iii). What is the observed rotation of a solution of lactic acid when the concentration is double or the length of the
tube is doubled-
;fn lkUnzrk nksxquh dj nh tk;s vFkok ufydk dh yEckbZ nksxquh dj nh tk;s rks ySfDVd vEy ds foy;u dk izsf{kr ?kw.kZu
D;k gksxk \
Concentration doubled Length doubled
lkUnzrk nksxquh yEckbZ nksxquh
0
(A*) +5.6 +5.60
(B) +2.80 +5.60
(C) +5.60 +2.80
(D) +2.80 +2.80
(iv). What is the specific rotation of lactic acid when both the concentration and length of tube is doubled?
;fn lkUnzrk rFkk ufydk dh yEckbZ nksuksa dks nksxquh dj fn;k tk;s rks ySfDVd vEy dk fof'k"B ?kw.kZu D;k gksxk ?
(A*) +160 (B) 320 (C) 640 (D) 00
(v). What is the specific rotation of mirror image of -Cholestane given in table ?
rkfydk esa fn;s x;s -dksysLVsu ds niZ.k izfrfcEc ds fof'k"B ?kw.kZu dk eku D;k gksxk \
(A) +240 (B*) -240 (C) 00 (D) Insufficient Data.¼ vk¡dMs vi;kZIr
gS ½
8. Match List I (Compounds) with List II (Relation) and select the correct answer using the code given below the
lists :
lwph I (;kSfxd) dks lwph II ¼lEcUèk½ ls lqesfyr dhft, rFkk lwfp;ksa ds uhps fn;s x;s dksM dk iz;ksx djds lgh mÙkj pqfu;s
: List I lwph I List II lwph II
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(R) (3) Diastereomer foofje :i leko;oh
Codes ¼dksM½ :
P Q R S P Q R S
(A) 2 1 3 4 (B*) 3 2 1 4
(C) 4 2 1 3 (D) 3 1 2 4
10.
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ChemINFO-1.2 Oxidation
Daily Self-Study Dosage for mastering Chemistry Anti hydroxylation of Alkenes
Peroxy acid have general structure as (RCO3H). They are relatively unstable and easily gives na-
scent O hence, acting as oxidant. It converts alkene into epoxides. A combination of RCO 3H followed by hydrolysis
[RCO3H(H3O+)] further breaks epoxide to anti hydroxylation product.
Note :
1. It is anti addition. Both OH groups add on the opposite
(b) CH3CO3H = PAA (Peracetic acid)
side of pi-bond.
2. Double bond of aromatic ring cannot react with these (c) PhCO3H = PBA (Per benzoic acid)
reagents.
(d) CF3CO3H = TFPAA (Trifluoro peracetic acid).
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
11.
12. Peroxyacid
CH2 = CH2 X , X is -
OH
|
(A) CH2 — CH2 (B) (C*) (D)
|
OH
(1) Peroxyacid
13. P Product is
( 2)H3O
(A) m-CPBA/ H3O (B) CH3 COOOH/H3O (C) F3CCOOOH/H3O (D*) All of these
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ChemINFO-1.2 Oxidation
Daily Self-Study Dosage for mastering Chemistry ,Ydhuksa dk ,s.Vh gkbMªksfDlyhdj.k
,Ydhuksa dk ,UVh gkbMªkWfDlyhdj.k
ijkWDlh vEy dh lkekU; lajpuk ¼lw=k½ (RCO3H) gksrk gSA ;g eq[; :i ls vLFkk;h gksrs gS rFkk vklkuh ls uotkr
O ns nsrs gSA vr% ;g vkWDlhdkjd inkFkZ dh Hkk¡fr dk;Z djrs gSA ;g ,Ydhu dks ,ikWDlkbM esa ifjofrZr dj nsrs gSA RCO3H dk
la;kstu blds ckn bldk tyvi?kVu [RCO3H(H3O+)] djus ij ;g vkxs ,ikWDlkbM dks ,UVh gkbMªkWDlhyhdj.k esa rksMrk gSA
lkekU; vfHkfØ;k :
( i)
Ex.1
(ii) H3O
Ex.2
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
11. gS&
OH
|
(A) CH2 — CH2 (B) (C*) (D)
|
OH
( i)
13. P mRikn gS&
(ii) H3O
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