ORGANIC CHEMISTRY

TARGET : JEE (Main + Advanced) 2016

Course : VIJETA (JP) NO. 21

Answer Key DPP No. # 21 (JEE-MAIN)

1. (C*) 2. (A*) 3. (B*) 4. (A*) 5. (C*)
6. (D*) 7. (D*) 8. (B*) 9. (D*) 10. (C*)
11. (C*) 12. (D*) 13. (B*) 14._ (A*) 15. (A*)
16. (A*) 17. (C*) 18. (D*) 19. (B*) 20. (C*)

This DPP is to be discussed in the week (20.07.2015 to 25.07.2015)

DPP No. # 21 (JEE-MAIN)
Total Marks : 60 Max. Time : 40 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.20 (3 marks, 2 min.) [60, 40]

1. The correct structure of benzene was proposed by

(A) Faraday (B) Davy (C*) Kekule (D) Wohler
fuEu esa ls fdl oSKkfud us csUthu dh lgh lajpuk dh [kkst dh Fkh \
(A) QSjkMs (B) Msoh (C*) dsdwys (D) oksgyj

2. Which is an aromatic compound

fuEu esa ls dkSulk ,sjkseSfVd ;kSfxd gS \

(A*) (B) (C) (D)

Sol. Species (I), (II) & (VI) are aromatic in nature due to presence of 6 electrons in cyclic conjugation.
iztkfr (I), (II) rFkk (VI) ,sjkseSfVd gSa D;ksafd bu ;kSfxdksa esa 6bysDVªkWu pfØ; la;qXeu esa gSA

3. Which is an anti-aromatic compound

fuEu esa ls dkSulk ,sUVh&,sjkseSfVd ;kSfxd gS \

(A) (B*) (C) (D)

4. Which of the following is Aromatic compound.

fuEu esa ls dkSuls ,jksesfVd ;kSfxd gSA

(A*) (B) (C) (D)

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5. Which is a non-aromatic compound
fuEu esa ls dkSulk ukWu&,sjkseSfVd ;kSfxd gS \

(A) (B) (C*) (D)

6. Which of the following is Aromatic in nature.

fuEu esa ls dkSulk ,jksesfVd gSA

(A) (B) ,

(C) (D*)

7. Which of the following is Aromatic compound.fuEu esa ls dkSuls ,jksesfVd ;kSfxd gSA

(A) (B) (C) (D*) All of these mijksDr lHkh

8. Which is an anti-aromatic compound

fuEu esa ls dkSulk ,sUVh&,sjkseSfVd ;kSfxd gS \

(A) (B*) (C) (D)

9. Which of the following reaction is possible ?

fuEu esa ls dkSulh vfHkfØ;k lEHko gSa \

(A) + AgClO4 + 2 AgCl 

(B)

(C)

(D*) All of these mijksDr lHkh

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10. Which of the following is/are polar stable molecule/s
fuEu esa ls dkSulk@dkSuls /kzqoh; LFkkbZ v.kq gSA

(A) (B) (C*) (D)

Sol. Z=   etc 

Azulene has dipole moment 0.8. Its resonating structure II with charge separation has aromatic stability in
both the rings so these structures have more contribution to resonance hybrid and are responsible for its
dipole moment.

S=   etc 

11. In which of the following reactions H2 gas is liberated :

(A) (B*)

(C*) (D)

fuEu esa ls dkSulh vfHkfØ;k esa H2 xSl eqDr gksrh gS %

(A) (B*)

(C*) (D)

Sol. Anti aromatic compound is not form in any reaction.

1
(a) + H
2 2

1
(b) + H
2 2

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12. Select the incorrect option for the properties mentioned against the following :

(A) > (Rate of reaction with CH3MgBr).

(B) < (Rate of reaction in ethanol at 550 C)

(C) < (Nucleophilicity).

(D*) > (Rate of giving yellow precipitate with AgNO 3).

fuEu fodYiksa ds lkeus fn;s x;s xq.kkas dk dkSulk fodYi xyr gS] pqfu;s %

(A) > (CH3MgBr ds lkFk vfHkfØ;k dh nj)

(B) < (550 C ij ,FksukWy esa vfHkfØ;k dh nj)

(C) < (ukfHkd Lusgrk)

(D*) > (AgNO3 ds lkFk ihyk nsus dh nj)

13. Which is the most likely group for substituent 'X' based on the relative rate factors for chlorination in the given
compound
fn;s x;s ;kSfxd dh Dyksjhuhdj.k vfHkfØ;k dh nj dks izHkkfor djus okyk fuEu ls dkSu lk lewg izfrLFkkih X ds fy;s mi;qDr
gksxk \

(A) – CF3 (B*) – C(CH3)3 (C) – CH3 (D) – CH = O

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 CO,HCl
14._     (Y) Product will be : (mRikn gksxk)
AlCl 3

(A*) (B) (C) (D)

15. The major products of the following reaction are

fuEu vfHkfØ;k ds eq[; mRikn gSa %

H O / 
3 Products mRikn

(A*) H2O (B) (C*) PhCHO (D) CH3CH2OH

16. Following equation illustrates

fuEu vfHkfØ;k n'kkZrh gSA
300 350 ºC
C6H5Cl + 2NaOH 300

atm
 C H ONa + NaCl + H O
6 5 2

(A*) Dow’ process (B) Kolbe’s process (C) Carbylamine test (D) Haloform reaction
(A*) MkWm fofèk (B) dksYcs fofèk (C) dkfcZy,ehu ijh{k.k (D) gSyksQkWeZ vfHkfØ;k

17. Phenol + CHCl3 + KOH —product is :

(A) Benzoic acid (B) p-chlorophenol (C*) Salicylaldehyde (D) salicylic acid
QhukWy + CHCl3 + KOH —mRikn gS :
(A) csUtksbd vEy (B) p-DyksjksQhukWy (C*) lsfylfYMgkbM (D) lsfylsfyd vEy

Sol. + CHCl3 + KOH 

18. A and B are respectively :

(A ,oa B Øe'k% gksxsa%)

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 (A) (B)

(C) (D*)

19. The rate determing step of following reaction is :

fuEu vfHkfØ;k esa nj fu/kkZjr in gS %

(A) 1 (B*) 2 (C) 3 (D) 4

Sol. Attack of electrophile on benzene.
gy bysDVªkWuLusgh dk csathu ij vkØe.kA

20. m-Nitromandelic acid is synthesized by

m-ukbVªkses.Msfyd vEy fuEu }kjk la’'ysf"kr gksrk gS&

(A)

(B)

(C*)

(D)

Sol.(C)

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