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ORGANIC CHEMISTRY

TARGET : JEE (Main + Advanced) 2016

Course : VIJETA (JP) NO. 24

This DPP is to be discussed in the week (10.08.2015 to 15.08.2015)


DPP No. # 24 (JEE-MAIN)
Total Marks : 60 Max. Time : 40 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.20 (3 marks, 2 min.) [60, 40]

NaOH
1. + C2H5I 
 X , X is :X gS %

(A*) C6H5OC2H5 (B) C2H5OC2H5 (C) C6H5OC6H5 (D) C6H5I

2. x X is (X gS)


(A*) Na2S (B) Sn/HCl (C) LiAIH4 (D) All of these (mijksDr lHkh)
Sol. It is selective reduction of –NO2 group
;g –NO2 lewg dk p;ukRed vip;u gSA

3. + CHCl3 + KOH  Product is :

(A*) Phenyl isocyanide (B) Benzyl amine (C) Benzyl chloride (D) p- aminophenol

+ CHCl3 + KOH  mRikn gS %

(A*) Qsfuy vkblkslk;ukbM (B) csfUty ,ehu (C) csfUty DyksjkbM (D) p- ,ehuksfQukWy

4. Benzenediazonium chloride on treatment with KCN in presence of copper powder gives :


(A) Benzoic acid (B) Aniline
(C) Benzene (D*) Benzene carbonitrile
csfUty MkbZ,tksfu;e DyksjkbM rkEcs ds pw.kZ dh mifLFkfr esa KCN ds lkFk mipkfjr djus ij nsrk gS %
(A) csUtksbd vEy (B) ,fuyhu
(C) csUthu (D*) csUthu dkcksZukbVªhbZy

5. Reaction of benzenediazonium chloride with alkaline phenol gives an azo dye. This is an example of
(A*) Electrophilic subsitution (B) Nucleophilic subsitution
(C) Oxidative coupling (D) Free-radical reaction

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csUthu MkbZ,tksfu;e DyksjkbM dh vfHkfØ;k {kkjh; fQukWy ds lkFk djkus ij ,d ,stks jaatd izkIRk gksrk gSA ;g ,d
mnkgj.k gS %
(A*) bysDVªkWuLusgh izfrLFkkiu (B) ukfHkdLusgh izfrLFkkiu
(C) vkWDlhdkjh ;qXeu (D) eqDr&ewyd vfHkfØ;k

6. The most activated ring is available in :

(A) in CCl4 (B*) in dil NaOH (C) in dil HCl (D) in dil HCl

fuEu esa ls dkSulk ;kSfxd vf/kdre~ lfØ;dkjh oy; j[krk gS %

(A) CCl4 esa (B*) ruq NaOH esa (C) ruq HCl esa (D) ruq HCl esa

Sol. NaOH Maximum + I & + M group.


 


gy NaOH vf/kdre + I rFkk + M lewg


 


7. Nitrobenzen can be prepared from benzene by using a mixture of conc. HNO 3 and conc. H2SO4. In the
mixture, nitric acid acts as a/an
(A) Catalyst (B) Reducing agent (C) Acid (D*) Base
lkUnz HNO3 vkSj lkUnz H2SO4 ds ,d feJ.k dk mi;ksx dj csUthu ls ukbVªkscsUthu cukrs gSA feJ.k esa ukbfVªd vEy
ds :i esa dk;Z djrk gS %
(A) mRizsjd (B) vipk;d (C) vEy (D*) {kkj

8. For the given reaction consider the statement 1,2 and 3 :


fuEu vfHkfØ;k dk iz{ks.k djds dFku 1, 2 ,oa 3 dk fu/kkZj.k dhft, %

+ 

(I) (II)
(1) Presence of –NO 2 group in aromatic ring I will increase the rate of reaction.
(2) Presence of –NO2 group in aromatic ring II will increase the rate of reaction.
(3) In this reaction a Wheland intermediate ( complex) is formed.
(1) ,sjkseSfVd oy; I ij –NO2 lewg dh mifLFkfr vfHkfØ;k dh nj dks c<+krh gSA
(2) ,sjkseSfVd oy; II ij –NO2 lewg dh mifLFkfr vfHkfØ;k dh nj dks c<+rh gSA
(3) bl vfHkfØ;k esa fOgyS.M e/;orhZ ¼ ladqy½ curk gSA
(A) TTT (B) FFF (C*) FTT (D) FTF
9. Which of the following compounds does not couple with benzenediazonium chloride to form an azo dye ?
(A) Phenol (B*) Toluene (C) Aniline (D) -naphthol
fuEu esa ls dkSuls ;kSfxd ,d ,tksjatd ds cukus ds fy;s csUthu Mkb,tksfu;e DyksjkbM ds lkFk ;ksx ugha djrs gS\
(A) fQukWy (B*) VkWywbZu (C) ,uhyhu (D) -uS¶FkkWy
Sol. Toluene is not active enough to couple with diazonium salts.
VkWywbZu] Mkb,tksfu;e yo.kksa ds lkFk ;qXeu ugha djrk gSA

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10. In the given reaction sequence the reactant X is

X Y Z

fuEu vfHkfØ;k vuqØe esa vfHkdkjd X gksxk :

(A) (B) (C) (D*)

Sol.

11. The end product of following reaction is :


fuEu vfHkfØ;k dk vfUre mRikn gS %

aq. NaOH
   
(2)

(A) (B) (C) (D*)

Sol.

CH3CHO + N2 +

12.

If Y is a yellow solid, then Z is :

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;fn Y ,d ihyk Bksl gS] rks Z gksxk :

(A*) (B) (C) (D)

Sol.

13. Gabriel phthalimide synthesis is used in the preparation of :


(A*) Primary amines (B) Secondary amines
(C) Tertiary amines (D) Mixture of all the three
xSfczy FkSysekbM la'ys"k.k fdlds fuekZ.k esa mi;ksxh gS %
(A*) izkFkfed ,ehu (B) f}rh;d ,ehu
(C) r`rh;d ,ehu (D) rhuks dk feJ.k

14. The final product in the following sequence of reaction is


fuEu vfHkfØ;k vuqØe esa vfUre mRikn gS&
NaNO 2 / HCl C6H6 / NaOH
C6H5NH2    A    B
273  278 K

(A) C6H5N2Cl (B) C6H5OH (C*) C6H5–C6H5 (D) C6H5N = NOH

15. Identify the end product in the given reaction :


nh xbZ vfHkfØ;k esa vfUre mRikn igpkfu;s %
2H2SO4 NaOH,270C
C6H6   A  B

(A) (B) (C*) (D)

16. CH2N2
  Product is : mRikn gS %

(A) (B) (C) (D*)

17. The structure of the compound that gives a tribromo derivative on treatment with bromine water is :
fuEu esa ls dkSulk ;kSfxd czksehu ty ds lkFk mipkfjr djus ij VªkbZ czkseks O;qRiUu nsrk gS \

(A*) (B) (C) (D)

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18. Aniline in a set of reactions yield a product D. The structure of the product D would be :
(,fuyhu fuEu vfHkfØ;k vuqØe }kjk mRikn D nsrk gSA mRikn D dh lajpuk D;k gksxh %)

2 NaNO CuCN H2 HNO2


   A   B 
 C  
 D
HCl Ni

(A) C6H5CH2NH2 (B) C6H5NHCH2CH3 (C) C6H5NHOH (D*) C6H5CH2OH

NaNO
2 H
2
Sol.   CuCN 
 HNO
2
HCl 
 Ni 

19. Diazocoupling reaction in aromatic compounds is an electrophilic substitution reaction. In which of the
following reaction the ring subsitution is most suitable for diazocoupling reaction?
,sjkseSfVd ;kSfxdksa esa MkbZ,tks;Xq eu vfHkfØ;k ,d bysDVªkWuLusgh izfrLFkkiu vfHkfØ;k gksrh gSA fuEu esa ls dkSulh vfHkfØ;k
esa oy; izfrLFkkiu MkbZ,tks;qXeu vfHkfØ;k ds fy, vf/kd mi;qDr gS\

(A) + (B) +

(C*) + (D) +

Sol. The aryl diazonium ion (ArN2+ ) functions as electrophile, so presence of electron withdrawing group (–SO3H)
increases its electrophilicity. Diazocoupling is possible only in strongly activated rings.
,fjy MkbZ,tksfu;e vk;u (ArN2+ ) bysDVªkWuLusgh dh rjg dk;Z djrs gSA blfy, e– vkd"khZ lewg (–SO3H) dh mifLFkfr
ds dkj.k bldh bysDVªkWuLusfgrk c<+rh gSA MkbZ,tks;qXeu dsoy izcy :i ls lfØ; oy;ksa ds fy;s lEHko gSA

Aq.NaNO2
20.   A , A is : A gS :
HCl ( 0C )

(A) (B) (C) (D*)

Aq.NaNO2
Sol.   
HCl ( 0C )

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