Академический Документы
Профессиональный Документы
Культура Документы
NaOH
1. + C2H5I
X , X is :X gS %
2. x X is (X gS)
(A*) Na2S (B) Sn/HCl (C) LiAIH4 (D) All of these (mijksDr lHkh)
Sol. It is selective reduction of –NO2 group
;g –NO2 lewg dk p;ukRed vip;u gSA
(A*) Phenyl isocyanide (B) Benzyl amine (C) Benzyl chloride (D) p- aminophenol
(A*) Qsfuy vkblkslk;ukbM (B) csfUty ,ehu (C) csfUty DyksjkbM (D) p- ,ehuksfQukWy
5. Reaction of benzenediazonium chloride with alkaline phenol gives an azo dye. This is an example of
(A*) Electrophilic subsitution (B) Nucleophilic subsitution
(C) Oxidative coupling (D) Free-radical reaction
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 1
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
csUthu MkbZ,tksfu;e DyksjkbM dh vfHkfØ;k {kkjh; fQukWy ds lkFk djkus ij ,d ,stks jaatd izkIRk gksrk gSA ;g ,d
mnkgj.k gS %
(A*) bysDVªkWuLusgh izfrLFkkiu (B) ukfHkdLusgh izfrLFkkiu
(C) vkWDlhdkjh ;qXeu (D) eqDr&ewyd vfHkfØ;k
(A) in CCl4 (B*) in dil NaOH (C) in dil HCl (D) in dil HCl
(A) CCl4 esa (B*) ruq NaOH esa (C) ruq HCl esa (D) ruq HCl esa
7. Nitrobenzen can be prepared from benzene by using a mixture of conc. HNO 3 and conc. H2SO4. In the
mixture, nitric acid acts as a/an
(A) Catalyst (B) Reducing agent (C) Acid (D*) Base
lkUnz HNO3 vkSj lkUnz H2SO4 ds ,d feJ.k dk mi;ksx dj csUthu ls ukbVªkscsUthu cukrs gSA feJ.k esa ukbfVªd vEy
ds :i esa dk;Z djrk gS %
(A) mRizsjd (B) vipk;d (C) vEy (D*) {kkj
+
(I) (II)
(1) Presence of –NO 2 group in aromatic ring I will increase the rate of reaction.
(2) Presence of –NO2 group in aromatic ring II will increase the rate of reaction.
(3) In this reaction a Wheland intermediate ( complex) is formed.
(1) ,sjkseSfVd oy; I ij –NO2 lewg dh mifLFkfr vfHkfØ;k dh nj dks c<+krh gSA
(2) ,sjkseSfVd oy; II ij –NO2 lewg dh mifLFkfr vfHkfØ;k dh nj dks c<+rh gSA
(3) bl vfHkfØ;k esa fOgyS.M e/;orhZ ¼ ladqy½ curk gSA
(A) TTT (B) FFF (C*) FTT (D) FTF
9. Which of the following compounds does not couple with benzenediazonium chloride to form an azo dye ?
(A) Phenol (B*) Toluene (C) Aniline (D) -naphthol
fuEu esa ls dkSuls ;kSfxd ,d ,tksjatd ds cukus ds fy;s csUthu Mkb,tksfu;e DyksjkbM ds lkFk ;ksx ugha djrs gS\
(A) fQukWy (B*) VkWywbZu (C) ,uhyhu (D) -uS¶FkkWy
Sol. Toluene is not active enough to couple with diazonium salts.
VkWywbZu] Mkb,tksfu;e yo.kksa ds lkFk ;qXeu ugha djrk gSA
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 2
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
10. In the given reaction sequence the reactant X is
X Y Z
Sol.
aq. NaOH
(2)
Sol.
CH3CHO + N2 +
12.
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 3
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
;fn Y ,d ihyk Bksl gS] rks Z gksxk :
Sol.
16. CH2N2
Product is : mRikn gS %
17. The structure of the compound that gives a tribromo derivative on treatment with bromine water is :
fuEu esa ls dkSulk ;kSfxd czksehu ty ds lkFk mipkfjr djus ij VªkbZ czkseks O;qRiUu nsrk gS \
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 4
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
18. Aniline in a set of reactions yield a product D. The structure of the product D would be :
(,fuyhu fuEu vfHkfØ;k vuqØe }kjk mRikn D nsrk gSA mRikn D dh lajpuk D;k gksxh %)
NaNO
2 H
2
Sol. CuCN
HNO
2
HCl
Ni
19. Diazocoupling reaction in aromatic compounds is an electrophilic substitution reaction. In which of the
following reaction the ring subsitution is most suitable for diazocoupling reaction?
,sjkseSfVd ;kSfxdksa esa MkbZ,tks;Xq eu vfHkfØ;k ,d bysDVªkWuLusgh izfrLFkkiu vfHkfØ;k gksrh gSA fuEu esa ls dkSulh vfHkfØ;k
esa oy; izfrLFkkiu MkbZ,tks;qXeu vfHkfØ;k ds fy, vf/kd mi;qDr gS\
(A) + (B) +
(C*) + (D) +
Sol. The aryl diazonium ion (ArN2+ ) functions as electrophile, so presence of electron withdrawing group (–SO3H)
increases its electrophilicity. Diazocoupling is possible only in strongly activated rings.
,fjy MkbZ,tksfu;e vk;u (ArN2+ ) bysDVªkWuLusgh dh rjg dk;Z djrs gSA blfy, e– vkd"khZ lewg (–SO3H) dh mifLFkfr
ds dkj.k bldh bysDVªkWuLusfgrk c<+rh gSA MkbZ,tks;qXeu dsoy izcy :i ls lfØ; oy;ksa ds fy;s lEHko gSA
Aq.NaNO2
20. A , A is : A gS :
HCl ( 0C )
Aq.NaNO2
Sol.
HCl ( 0C )
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 5
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029