JP XII Organic Chemistry PDF

ORGANIC CHEMISTRY
TARGET : JEE (Main + Advanced) 2016
Course : VIJETA (JP) NO. 25
This DPP is to be discussed in the week (24.08.2015 to 29.08.2015)
DPP No. # 25 (JEE-ADVANCED)

Total Marks : 42 Max. Time : 28 min.
One or more than one choice Objective Q.1 to Q.4 (3 marks, 2 min.) [12, 08]
Comprehension Type(One Option Correct) ('–1' negative marking) Q.5 to Q.7 (3 marks, 2 min.) [09, 06]
Matching List Type (One Option Correct) ('–1' negative marking) Q.8 (3 marks 2 min.) [03, 02]
Single Integer Type Questions Q.9 to Q.10 (3 marks 2 min.) [06, 04]
ChemINFO : 4 Questions ('–1' negative marking) Q.11 to Q.14 (3 marks, 2 min.) [12, 08]
1. Which of them yields para Bromophenol as major product.
(A*) NaNO / HCl

2 Steam (B*)
   
   Br waterdil. H2 SO 4 / 
2    
(C) 1 eq. NaOH (D*) Sn / HCl

2 NaNO / H SO CuBr / HBr
    2 
4
   
fuEu esa ls fdl vfHkfØ;k esa iSjk czkseksfQukWy eq[; mRikn ds :i esa curk gSA
(A*) NaNO / HCl

2 (B*) H2SO 4 / 
   
  Br
 2  
(C) 1 NaOH (D*) Sn / HCl

2 NaNO / H SO CuBr / HBr
    2 
4
   
Sol. NaNO / HCl

2 Steam
   
  
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PAGE NO.- 1
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Br water dil. H SO / 
2 2 
4

Sn / HCl NaNO / H SO
2 CuBr / HBr
    2 
4
  
2. Primary (1º) amine group is formed in :

izkFkfed (1º) ,ehu lewg fuEu esa ls fdlesa cusxk %
(A*) NaHS (B*) Br / KOH

 2
(C) CH NH / Cu O / 
3 22 (D) H2 O
  
Sol. NaHS

Br / KOH
2
CH NH / Cu O / 
3 2 2
 
3. The reagents are :

fuEu vfHkfØ;k esa vfHkdeZd gS \
(a )
(b ) (c ) ( d) (e)

   
 

2Cl / Fe HNO 3  H2SO 4,  4

NH HS 2 KCN NaNO / HCl
(A)               ( d  
) H2O / 
  
(a ) (b ) (c ) (e )
HNO  H SO , 
3 2 4 4 2 NH HS NaNO / HCl /  boil
2 Sn / HCl CO / NaOH / 
(B*)  (             
a) (b) (c ) ( d) (e )
HNO  H SO
3 2 4 (i) Cl / Fe Sn / HCl Cl / Fe KCN
(C)        2 
    2     


(a ) (c ) ( d)
(ii) NaOH /  ( ) e H3O 
(b )
HNO3  H2SO 4 ,  4 NH HS
2 NaNO / HCl /  boil
Sn / HCl KCN
(D)  (             
a) (b ) (c ) ( d) (e ) H3O 
PAGE NO.- 2
4. Which of the following observations may be correct
vfHkfØ;k esa izkIr gksus okys mRikn ds fo"k; esa fuEu esa ls dkSulk fodYi lgh gS
(X) (Y) (Z)
KI
(A*) X 
 (B*) Z =
(C*) Y (D) Y =
Sol.(A,B,C)
Paragraph for Question No. 5 to 7
Observe the following reactions and answer the following questions.
PAGE NO.- 3
ç'u 5 ls 7 ds fy, vuqPNsn
fuEu vfHkfØ;kvksa dks izsf{kr djks rFkk uhps fn;s x;s iz'uksa ds mÙkj nhft;sA
5. Product W is :
mRikn W gS %
(A) (B*) (C) (D)
6. Product Z is :
mRikn Z gS %
(A) (B) (C*) (D)
7. The product Y on heating with H2O produces :

(A) m-cresol (B*) Resorcinol (C) Salicylic acid (D) Salicylaldehyde
mRikn B, H2O ds lkFk xeZ djus ij nsrk gS :
(A) m-fØlkWy (B*) fjlkWflZukWy (C) lsfyflfyd vEy (D) lsfylsfYMgkbM
Sol. (5 to 7)
8. Match list I (reaction) with II (products) and then select the correct answer from the codes given below the
lists:
List I List II
(P) Phenol + NaOH + CH3 (1) Phenolphthalein
(Q) Phenol + NaOH +CHCI3 (2) Salicylic acid
(R) Phenol + Phthalic anhydride + conc. H2SO4 (3) Anisole
(S) Phenol + CO2 + NaOH (4) Salicylaldehyde
PAGE NO.- 4
lwph I (vfHkfØ;k) dks lwph II (mRikn) ds lkFk lqesfyr dhft, rFkk lwphc) fd;s x;s dksM ds vk/kkj ij lgh mÙkj dkSulk
gSA
lwph I lwph II
(P) QhukWy + NaOH + C2H5I (1) fQukWY¶FkSyhu
(Q) QhukWy + NaOH +CHCI3 (2) lSyslsfyd vEy
(R) QhukWy + FkSfyd ,ugkbMªkbM + lkUnz H2SO4 (3) ,uhlkWy
(S) QhukWy + + CO2 + NaOH (4) lSfyflysfYMgkbM
Codes dksM :
P Q R S P Q R S
(A) 1 2 3 4 (B) 4 3 2 1
(C*) 3 4 1 2 (D) 4 3 1 2
9. Proudct mRikn.
What is the number of halogen atoms in final product ?

vfUre mRikn esa mifLFkr gSykstu ijek.kqvksa dh la[;k D;k gksxh \
Ans. 04
Sol.
10. A mixture of 1° amides (benzenoid) having molecular formula (C8H9NO) reacted with Br2/NaOH. The number
of 1° amines products formed will be :
tc C8H9NO v.kqlw=k okys 1° ,ekbZM ¼csUtsuksbM½ ds feJ.k dh vfHkfØ;k Br2/NaOH ds lkFk djkrs gS] rks fdrus 1
,ehu mRikn ds :i esa izkIr gksrs gS %
Ans. 04
Sol. + + +
+ + +
PAGE NO.- 5
ChemINFO-2.4 Chemistry in Every day life
Daily Self-Study Dosage for mastering Chemistry Tranquilizers
The chemical substances used for the treatment of stress and mild or even severe mental diseases. These are
used to release mental tension irritability or excitement by inducing a sense of well -being. The examples for
antidepresent drugs are Iproniazid and Phenelzine.
The drugs suitable for reliesing tension are chlordiazepoxide and Meprobalmate.
Equanil is the drug used in controlling depression and hypertension.
The most commonly used tranquilizers are Barbituric acid and its derivatives. These are called barbiturates. These
are hypnotic. i.e sleep producing agents.]
Eg : Veronal , Amytal, Nembutal, Luminal, seconal , valium and serotonin
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
PAGE NO.- 6
11. Which of the following drug is used in controlling depression and hypertension.
(A*) Equanil (B) Serotonin (C) Valium (D)Seconal
12. Which of the following in an antidepressants.

(A) chloroxylenol (B) Bithional (C*) Phenelzine (D) pancillin-G
13. Luminal a barbiturate drug is used as

(A) antihistamine (B*) Sedatives (C) antiseptic (D) antimalaminal
14. Which of the following used as hypnotics

(A) Amytal (B) Nembutal (C) seconal (D*) All the above
PAGE NO.- 7
ChemINFO-2.4 Chemistry in Every day life
Daily Self-Study Dosage for mastering Chemistry Tranquilizers
iz'kkrd og jklk;fud inkFkZ gS ftudk mi;ksx ruko rFkk NksVh ;k cM+h ekufld chekfj;ksa esa fd;k tkrk gSA ;g vPNk gksus dh Hkkouk
dks vfHkizsfjr djds fpark] ruko {kksHk vFkok mÙkstuk ls eqfDr nsrs gSA bizksukbft+M vkSj fQufYtu izf r volknd vkS"kf/k ds mnkgj.k
gSAa
ruko eqfDr ds fy, mi;qDr vkS"kf/k DyksjMkbZ,stkssikWDlkbM rFkk esizkscesV gSaA
bDoSfuy dk iz;ksx volkn vkSj vfrruko ds fu;a=k.k ds fy, fd;k tkrk gSA
ckfcZV~;wfjd vEy rFkk blds O;wRiUu lkekU;r% iz;qDr gksus okys iz'kkard gSA bUgsa ckfcZV~;wjsV dgrs gSA;s funzk tud gksrs gSa vFkkZr~
buds iz;ksx ls uhan vkrh gSA
mnkgj.k : osjksuy] ,ehVy] usEcqVy] Y;wfeuy] lsdksuy] oSfy;e rFkk lsjksVksfuu
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
PAGE NO.- 8
11. fuEu esa ls dkSulh vkS"kfèk dk mi;ksx volkn vkSj vfrruko ds fu;a=k.k ds fy, fd;k tkrk gSA
(A*) bDoSfuy (B) lsjksVksfuu (C) oSfy;e (D) lsdksuy
12. fuEUk esa ls dkSu ,d izfr volknd gS

(A) Dyksj vkWDlhfyuksy (B) fcfFk;ksuSy (C*) fQufYTku (D) iSfuflfyu -G
13. ,d ckfcZV~;wfjd vkS"kf/k Y;wfeuy dks fuEu esa ls fdlds :i esa iz;qDRk fd;k tkrk gS
(A) izfrfgLVSfeu (B*) volknd ¼'kked½ (C) iwfrjks/kh (D) ,UVh eysfj;k
14. fuEu es ls dkSu funzktud ds :i esa iz;qDr gksrk gS&

(A) ,feVy (B) usEcqVy (C) lsdksuy (D*) mijksDRk lHkh
PAGE NO.- 9

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ORGANIC CHEMISTRY

TARGET : JEE (Main + Advanced) 2016

Course : VIJETA (JP) NO. 25

This DPP is to be discussed in the week (24.08.2015 to 29.08.2015)

DPP No. # 25 (JEE-ADVANCED)

1. Which of them yields para Bromophenol as major product.

(A*) NaNO / HCl

(C) 1 eq. NaOH (D*) Sn / HCl

(A*) NaNO / HCl

(C) 1 NaOH (D*) Sn / HCl

Sol. NaNO / HCl

2. Primary (1º) amine group is formed in :

(A*) NaHS (B*) Br / KOH

3. The reagents are :

2Cl / Fe HNO 3  H2SO 4,  4

(X) (Y) (Z)

Paragraph for Question No. 5 to 7

Observe the following reactions and answer the following questions.

(A) (B*) (C) (D)

(A) (B) (C*) (D)

7. The product Y on heating with H2O produces :

What is the number of halogen atoms in final product ?

Equanil is the drug used in controlling depression and hypertension.

12. Which of the following in an antidepressants.

13. Luminal a barbiturate drug is used as

14. Which of the following used as hypnotics

ruko eqfDr ds fy, mi;qDr vkS"kf/k DyksjMkbZ,stkssikWDlkbM rFkk esizkscesV gSaA

12. fuEUk esa ls dkSu ,d izfr volknd gS

14. fuEu es ls dkSu funzktud ds :i esa iz;qDr gksrk gS&

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(A) NaHS (B) Br / KOH