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GEST 91/168
Chapter 5 – Mechanical Properties
1st Edition
September 2002
Euro Chlor
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ACKNOWLEDGEMENT
TABLE OF CONTENTS
V MECHANICAL PROPERTIES 6
V.3 Viscosity 9
V.3.1 Liquid Chlorine 9
V.3.2 Gaseous Chlorine 10
REFERENCES 13
TABLE OF TABLES
Table V.1 Compressibility of liquid chlorine 6
Table V.2 Expansion coefficient of liquid chlorine 6
Table V.3 Surface tension of liquid chlorine 8
Table V.4 Viscosity of liquid chlorine 9
Table V.5 Viscosity of gaseous chlorine 11
TABLE OF FIGURES
V MECHANICAL PROPERTIES
specific volume
C For p = 100 kPa
Specificvo lume
Table V.1 gives values quoted by Ullmann [1] over the range 0 - 10Mpa.
T T
Compressibility
°C K
20 293 0.12.10-3
35 308 0.23.10-3
64 347 0.37.10-3
91 364 0.64.10-3
The variation of specific volume per unit volume for a given pressure
increase can be derived from Table IV.2 “Density of compressed liquid
chlorine”, in Chapter 4..
The change of volume per unit volume per degree Celsius at constant
pressure is given in Table V.2:
1
Ullman’s Encyclopedia of Industrial Chemistry, A.6, 399, (1986)
g RT
Z Equation V.1
PV
Z
BPc Equation V.2
Pr T RT
2
J.J. Martin , The Thermodynamic Behavior of the Real Ideal Gas,
Chem. Eng. Prog. Symposium Series, 59, 44, 120-126 (1963)
3
DIPPR
Temp. oC -100 -90 -80 -70 -60 -50 -40 -30 -20
Surface
Tension 41.4 39.4 37.3 35.3 33.3 31.4 29.4 27.5 25.6
mJ/m2
Temp. oC -10 0 10 20 30 40 50 60 70
Surface
Tension 23.7 21.9 20.0 18.2 16.5 14.7 13.0 11.4 9.8
mJ/m2
Temp. oC 80 90 100 110 120 130 140
Surface
Tension 8.2 6.6 5.2 3.8 2.5 1.3 0.3
mJ/m2
50
40
Surface Tension (mJ/m )
2
30
20
10
0
-80 -40 0 40 80 120
o
Temperature ( C)
4
E. J. Marchand, Chim. Phy. Physicochim. Bio., 11, 573 (1913)
V.3 Viscosity
0
T
1 At Bt 2
where t = temperature in °C
A = 5.878.10-3
B = -3.92. 10-6
Temperatur
Temperatur Viscosity
e
e°C 10-3 Pa.s
K
-100 173 1.032
-90 183 0.877
-80 193 0.763
-70 203 0.676
-60 213 0.608
-50 223 0.553
-40 233 0.508
-30 243 0.469
-20 253 0.437
-10 263 0.409
0 273 0.385
12 283 0.364
20 293 0.345
30 303 0.328
40 313 0.313
50 323 0.300
60 333 0.288
70 343 0.276
80 353 0.266
90 363 0.257
100 373 0.249
1.2
1
Viscosity (10 Pa.s)
0.8
-3
0.6
0.4
0.2
-100 -50 0 50 100
o
Temperature ( C)
The equation gives the best fit with the experimental data given in
Table V.5 and Figure V.3, at temperatures up to about 100 oC.
Temperatur
Temperatur Viscosity
e
e°C 10-3 Pa.s
K
-100 173 7.9
-80 193 8.8
-60 213 9.7
-40 233 10.6
-20 253 11.5
0 273 12.4
10 283 12.8
20 293 13.3
30 303 13.9
40 313 14.2
50 323 14.7
60 333 15.1
80 353 16.0
100 373 16.8
150 423 18.8
200 473 20.8
300 573 24.8
400 673 28.8
500 773 32.2
35
30
25
Viscosity ( 10 Pa.s)
-3
20
15
10
5
-100 0 100 200 300 400 500
o
September 2002 Temperature ( C) Page 11 of 14
GEST 91/168 – Chapter 5
1st Edition
24.1 m3/mole[5]
5
A. J. Bondi, J. Phys. Chem, 68, 441, (1964)
6
Vera, Sayegh, and Ratcliff, Fluidplax equilibria 1, 113, (1977)
REFERENCES
1 Ullman’s Encyclopedia of Industrial Chemistry, A.6, 399, (1986)
2 J.J. Martin , The Thermodynamic Behavior of the Real Ideal Gas,
Chem. Eng. Prog. Symposium Series, 59, 44, 120-126 (1963)
3 DIPPR
4 E. J. Marchand, Chim. Phy. Physicochim. Bio., 11, 573 (1913)
5 A. J. Bondi, J. Phys. Chem, 68, 441, (1964)
6 Vera, Sayegh, and Ratcliff, Fluidplax equilibria 1, 113, (1977)
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