PROCEDIMIENTO EXPERIMENTAL

Instalar el equipo de Boyle con baño a temperatura constante, anotar lecturas iniciales,
luego tomar las mediciones a diferentes volúmenes del gas en la columna para obtener
valores de la presión.

Presión (𝟏𝟎𝟓 Pa) Volumen (mL)

1 3

2.1 2.1

2.35 2

2.4 1.9

2.6 1.8

2.9 1.7

3.1 1.6

3.4 1.5

3.7 1.4

4.3 1.3

4.6 1.2

5.3 1.1

6 1

6.9 0.9

8 0.8

9.6 0.7

11.8 0.6

14.7 0.5

19.8 0.4

29.1 0.3
 37.1 0.25

a) Grafica P vs V

GRÁFICA P Vs V
40

35

30
PRESIÓN

25

20

15

10

0
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5
VOLUMEN

b) Grafica P vs 1/V
 Grafico P vs 1/V
2
1.8 y = 6.7927x - 1.2267
R² = 0.9717
1.6
1.4
PRESIÓN (10^5PA)

1.2
1
0.8
0.6
0.4
0.2
0
0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45 0.5
1/VOLUMEN

De los puntos obtenidos en la experiencia se escogen 10 de estos para resolver y

encontrar K, hacemos uso de las otras ecuaciones:

 Gas ideal
 Van der Waals
 Redlich-kwong
 Por compresibilidad de los gases
 Virial

Los puntos escogidos convenientemente son:

Volumen (𝐦𝐋) Presión (𝟏𝟎𝟓 Pa)

3 1

2.5 1.5

2.1 2.1

1.8 2.6

1.5 3.4

1.1 5.3
 0.8 8

0.6 11.8

0.4 19.8

0.25 37.1

a) Grafica P vs V

MUESTRA DE LA GRÁFICA P Vs V
40

35

30

25

20
Presión

15

10

0
0 0.5 1 1.5 2 2.5 3 3.5
Volumen
 b) Grafico P vs 1/V
Esti
Grafico P vs 1/V ma
4 mo
3.5 y = 2.9032x + 0.4501 s K
R² = 0.9438
3 con
los
Presión (10^5 Pa)

2.5
pun
2
tos
1.5
real
1
es:
0.5

0
0 0.2 0.4 0.6 0.8 1 1.2
1/Volumen

𝑘1 = 𝑃1 𝑉1 = 1𝑥105 𝑃𝑎. 3𝑐𝑚3 = 3𝑥105 𝑃𝑎. 𝑐𝑚3

𝑘2 = 𝑃2 𝑉2 = 1,51𝑥105 𝑃𝑎. 2,5𝑐𝑚3 = 3,775𝑥105 𝑃𝑎. 𝑐𝑚3
𝑘3 = 𝑃3 𝑉3 = 2,1𝑥105 𝑃𝑎. 2,1𝑐𝑚3 = 4,41𝑥105 𝑃𝑎. 𝑐𝑚3
𝑘4 = 𝑃4 𝑉4 = 2,6𝑥105 𝑃𝑎. 1,8𝑐𝑚3 = 4,68𝑥105 𝑃𝑎. 𝑐𝑚3
𝑘5 = 𝑃5 𝑉5 = 3,4𝑥105 𝑃𝑎. 1,5𝑐𝑚3 = 5,1𝑥105 𝑃𝑎. 𝑐𝑚3
𝑘6 = 𝑃6 𝑉6 = 5,3𝑥105 𝑃𝑎. 1,1𝑐𝑚3 = 5,83𝑥105 𝑃𝑎. 𝑐𝑚3
𝑘7 = 𝑃7 𝑉7 = 8𝑥105 𝑃𝑎. 0,8𝑐𝑚3 = 6,4𝑥105 𝑃𝑎. 𝑐𝑚3
𝑘8 = 𝑃8 𝑉8 = 11,8𝑥105 𝑃𝑎. 0,6𝑐𝑚3 = 7,08𝑥105 𝑃𝑎. 𝑐𝑚3
𝑘9 = 𝑃9 𝑉9 = 19,8𝑥105 𝑃𝑎. 0,4𝑐𝑚3 = 7,92𝑥105 𝑃𝑎. 𝑐𝑚3
𝑘10 = 𝑃10 𝑉10 = 37,1𝑥105 𝑃𝑎. 0,25𝑐𝑚3 = 9,275𝑥105 𝑃𝑎. 𝑐𝑚3

(3+3,775+4,41+4,68+5,1+5,83+6,4+7,08+7,92+9,275)𝑥105 𝑃𝑎.𝑐𝑚3
𝑘𝑝𝑟𝑜𝑚𝑒𝑑𝑖𝑜 = 10

𝑘𝑝𝑟𝑜𝑚𝑒𝑑𝑖𝑜 = 5,7465𝑃𝑎. 𝑐𝑚3

 ECUACIÓN DE LOS GASES IDEALES

PVm  RT
Vm n  V
PV  k

𝑃𝑎. 𝑐𝑚3
𝑅 = 83,14𝑥105
𝑚𝑜𝑙. 𝑘

𝑇 = 298𝑘
Para el punto 1:
𝑃1 = 1𝑥105 𝑃𝑎 𝑉1 = 3𝑐𝑚3 𝑛 = 0,00012𝑚𝑜𝑙
𝑃1 𝑉𝑚1 = 𝑅𝑇

5
𝑃𝑎. 𝑐𝑚3
5
1𝑥10 𝑃𝑎𝑉𝑚1 = 83,14𝑥10 𝑥298𝑘
𝑚𝑜𝑙. 𝑘
𝑐𝑚3
𝑉𝑚1 = 24775,72
𝑚𝑜𝑙
𝑉1 = 𝑉𝑚1 𝑛 = 2,974𝑐𝑚3
𝑘1 = 𝑃1 𝑉1 = 1𝑥105 𝑃𝑎. 2,974𝑐𝑚3 = 297400𝑃𝑎. 𝑐𝑚3

Para el punto 2:
𝑃2 = 1,51𝑥105 𝑃𝑎 𝑉2 = 2.5𝑐𝑚3 𝑛 = 0,00015𝑚𝑜𝑙
𝑃2 𝑉𝑚2 = 𝑅𝑇
𝑃𝑎. 𝑐𝑚3
1,51𝑥105 𝑃𝑎𝑉𝑚2 = 83,14𝑥105 𝑥298𝑘
𝑚𝑜𝑙. 𝑘
𝑐𝑚3
𝑉𝑚2 = 16407,76
𝑚𝑜𝑙
𝑉2 = 𝑉𝑚2 𝑛 = 2,461164𝑐𝑚3
𝑘2 = 𝑃2 𝑉2 = 1,51𝑥105 𝑃𝑎. 2,461164𝑐𝑚3 = 371635,16𝑃𝑎. 𝑐𝑚3

Para el punto 3:
𝑃3 = 2,1𝑥105 𝑃𝑎 𝑉3 = 2,1𝑐𝑚3 𝑛 = 0,00017𝑚𝑜𝑙
𝑃3 𝑉𝑚3 = 𝑅𝑇
𝑃𝑎. 𝑐𝑚3
2,1𝑥105 𝑃𝑎𝑉𝑚3 = 83,14𝑥105 𝑥298𝑘
𝑚𝑜𝑙. 𝑘
𝑐𝑚3
𝑉𝑚3 = 11797,96
𝑚𝑜𝑙
𝑉3 = 𝑉𝑚3 𝑛 = 2,00565𝑐𝑚3
𝑘3 = 𝑃3 𝑉3 = 2.1𝑥105 𝑃𝑎. 2,0065𝑐𝑚3 = 421186,5𝑃𝑎. 𝑐𝑚3

Para el punto 4:
𝑃4 = 2,6𝑥105 𝑃𝑎 𝑉4 = 1.8𝑐𝑚3 𝑛 = 0,00018𝑚𝑜𝑙
𝑃4 𝑉𝑚4 = 𝑅𝑇
𝑃𝑎. 𝑐𝑚3
2,6𝑥105 𝑃𝑎𝑉𝑚4 = 83,14𝑥105 𝑥298𝑘
𝑚𝑜𝑙. 𝑘
𝑐𝑚3
𝑉𝑚4 = 9529,1231
𝑚𝑜𝑙
𝑉4 = 𝑉𝑚4 𝑛 = 1,71524𝑐𝑚3
𝑘4 = 𝑃4 𝑉4 = 2,6𝑥105 𝑃𝑎. 1,71524𝑐𝑚3 = 445962,4𝑃𝑎. 𝑐𝑚3

Para el punto 5:
𝑃5 = 3,4𝑥105 𝑃𝑎 𝑉5 = 1,5𝑐𝑚3 𝑛 = 0,00021𝑚𝑜𝑙
𝑃5 𝑉𝑚5 = 𝑅𝑇
𝑃𝑎. 𝑐𝑚3
3,4𝑥105 𝑃𝑎𝑉𝑚5 = 83,14𝑥105 𝑥298𝑘
𝑚𝑜𝑙. 𝑘
𝑐𝑚3
𝑉𝑚5 = 7286,9764
𝑚𝑜𝑙
𝑉5 = 𝑉𝑚5 𝑛 = 1,53026𝑐𝑚3
𝑘5 = 𝑃5 𝑉5 = 3,4𝑥105 𝑃𝑎. 1,53026𝑐𝑚3 = 520322,4𝑃𝑎. 𝑐𝑚3

Para el punto 6:
𝑃6 = 5,3𝑥105 𝑃𝑎 𝑉6 = 1,1𝑐𝑚3 𝑛 = 0,000235𝑚𝑜𝑙
𝑃6 𝑉𝑚6 = 𝑅𝑇
𝑃𝑎. 𝑐𝑚3
5,3𝑥105 𝑃𝑎𝑉𝑚6 = 83,14𝑥105 𝑥298𝑘
𝑚𝑜𝑙. 𝑘
𝑐𝑚3
𝑉𝑚6 = 4674,664
𝑚𝑜𝑙
𝑉6 = 𝑉𝑚6 𝑛 = 1,098𝑐𝑚3
𝑘6 = 𝑃6 𝑉6 = 5,3𝑥105 𝑃𝑎. 1,098𝑐𝑚3 = 581940𝑃𝑎. 𝑐𝑚3

Para el punto 7:
𝑃7 = 8𝑥105 𝑃𝑎 𝑉7 = 0,8𝑐𝑚3 𝑛 = 0,000258𝑚𝑜𝑙
𝑃7 𝑉𝑚7 = 𝑅𝑇
𝑃𝑎. 𝑐𝑚3
8𝑥105 𝑃𝑎𝑉𝑚7 = 83.14𝑥105 𝑥298𝑘
𝑚𝑜𝑙. 𝑘
𝑐𝑚3
𝑉𝑚7 = 3096,965
𝑚𝑜𝑙
𝑉7 = 𝑉𝑚7 𝑛 = 0,799𝑐𝑚3
𝑘7 = 𝑃7 𝑉7 = 8𝑥105 𝑃𝑎. 0,799𝑐𝑚3 = 639200𝑃𝑎. 𝑐𝑚3

Para el punto 8:
𝑃8 = 11,8𝑥105 𝑃𝑎 𝑉8 = 0,6𝑐𝑚3 𝑛 = 0,000285𝑚𝑜𝑙
𝑃8 𝑉𝑚8 = 𝑅𝑇
𝑃𝑎. 𝑐𝑚3
11,8𝑥105 𝑃𝑎𝑉𝑚8 = 83,14𝑥105 𝑥298𝑘
𝑚𝑜𝑙. 𝑘
𝑐𝑚3
𝑉𝑚8 = 2099,637
𝑚𝑜𝑙
𝑉8 = 𝑉𝑚8 𝑛 = 0,598𝑐𝑚3
𝑘8 = 𝑃8 𝑉8 = 11,8𝑥105 𝑃𝑎. 0,598𝑐𝑚3 = 705640𝑃𝑎. 𝑐𝑚3

Para el punto 9:
𝑃9 = 19,8𝑥105 𝑃𝑎 𝑉9 = 0,4𝑐𝑚3 𝑛 = 0,000319𝑚𝑜𝑙
𝑃9 𝑉𝑚9 = 𝑅𝑇
𝑃𝑎. 𝑐𝑚3
19,8𝑥105 𝑃𝑎𝑉𝑚9 = 83,14𝑥105 𝑥298𝑘
𝑚𝑜𝑙. 𝑘
𝑐𝑚3
𝑉𝑚9 = 1251,298
𝑚𝑜𝑙
𝑉9 = 𝑉𝑚9 𝑛 = 0,399𝑐𝑚3
𝑘9 = 𝑃9 𝑉9 = 19,8𝑥105 𝑃𝑎. 0,399𝑐𝑚3 = 790020𝑃𝑎. 𝑐𝑚3

Para el punto 10:

𝑃10 = 37,1𝑥105 𝑃𝑎 𝑉10 = 0,25𝑐𝑚3 𝑛 = 0,000374𝑚𝑜𝑙
𝑃10 𝑉𝑚10 = 𝑅𝑇
𝑃𝑎. 𝑐𝑚3
37,1𝑥105 𝑃𝑎𝑉𝑚10 = 83,14𝑥105 𝑥298𝑘
𝑚𝑜𝑙. 𝑘
𝑐𝑚3
𝑉𝑚10 = 667,809
𝑚𝑜𝑙
𝑉10 = 𝑉𝑚10 𝑛 = 0,249𝑐𝑚3
𝑘10 = 𝑃10 𝑉10 = 37,1𝑥105 𝑃𝑎. 0,249𝑐𝑚3 = 923790𝑃𝑎. 𝑐𝑚3

Hallando el k promedio:
𝑘1 + 𝑘2 + 𝑘3 + 𝑘4 + 𝑘5 + 𝑘6 + 𝑘7 + 𝑘8 + 𝑘9 + 𝑘10
𝑘𝑝𝑟𝑜𝑚𝑒𝑑𝑖𝑜 =
10

𝑘𝑝𝑟𝑜𝑚𝑒𝑑𝑖𝑜
(297400 + 371635,16 + 421186,5 + 445962,4 + 520322,4 + 581940 + 639200 + 705640 + 790020 + 923790)
=
10
 𝑘𝑝𝑟𝑜𝑚𝑒𝑑𝑖𝑜 = 569709,646𝑃𝑎. 𝑐𝑚3

a) Gráfico P vs V

Gráfico P vs V
40

35

30

25
PRESIÓN

20

15

10

0
0 0.5 1 1.5 2 2.5 3 3.5
VOLUMEN

b) Gráfico P vs 1/V

Gráfico P vs 1/V
40

35

30

25
Presión

20

15

10

0
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5
1/Volumen
 ECUACIÓN DE VAN DER WAALS

𝑹𝑻 𝟐 𝒂 𝒂𝒃
𝑽𝟑𝒎 − (𝒃 + ) 𝑽𝒎 + ( )𝑽𝒎 − =𝟎
𝑷 𝑷 𝑷

𝑃𝑎. 𝑐𝑚3
𝑅 = 83,14𝑥105
𝑚𝑜𝑙. 𝑘
𝑇 = 298𝑘

Cálculo del a y b para el aire, considerando que su composición es: 21% O 2 y 79%
N2

𝑎̅ = ∑ 𝑥𝑖 . 𝑎𝑖
𝑖

𝑎̅ = 𝑥𝑁2 . 𝑎𝑁2 + 𝑥𝑂2 . 𝑎𝑂2

De datos obtenidos en tablas:

𝑎𝑡𝑚.𝑑𝑚6 𝑎𝑡𝑚.𝑑𝑚6
𝑎𝑁2 = 1,39 𝑎𝑂2 = 1,36
𝑚𝑜𝑙2 𝑚𝑜𝑙2

Reemplazando:
𝑎𝑡𝑚. 𝑑𝑚6 𝑎𝑡𝑚. 𝑑𝑚6
𝑎̅ = (0,79) × (1,39 )+ (0,21) × (1,36 )
𝑚𝑜𝑙 2 𝑚𝑜𝑙 2

𝑎𝑡𝑚. 𝑑𝑚6
𝑎̅ = 1,38
𝑚𝑜𝑙 2
Realizamos el mismo procedimiento para hallar la otra constante:
 𝑏̅ = ∑ 𝑥𝑖 . 𝑏𝑖
𝑖

𝑏̅ = 𝑥𝑁2 . 𝑏𝑁2 + 𝑥𝑂2 . 𝑏𝑂2

De datos obtenidos en tablas:

𝑑𝑚3 𝑑𝑚3
𝑏𝑁2 = 3,913 × 10−2 𝑏𝑂2 = 3,183 × 10−2
𝑚𝑜𝑙 𝑚𝑜𝑙

Reemplazando:
𝑑𝑚3 𝑑𝑚3
𝑏̅ = (0,79) × (3,913 × 10−2 ) + (0.21) × (3,183 × 10−2 )
𝑚𝑜𝑙 𝑚𝑜𝑙

𝑑𝑚3
𝑏̅ = 0,0376
𝑚𝑜𝑙
Para un correcto trabajo, procedemos a hacer un cambio de unidades a las contantes a
y b del aire:
𝑎𝑡𝑚. 𝑑𝑚6 6
𝑃𝑎. 𝑐𝑚3
𝑎̅ = 1.38 = 1.38 × 101325 × 10
𝑚𝑜𝑙 2 𝑚𝑜𝑙 2

𝑃𝑎.𝑐𝑚3
𝑎̅ = 1.38 × 101325 × 106 𝑚𝑜𝑙2

𝑑𝑚3 𝑐𝑚3
𝑏̅ = 0.0376 = 37.6
𝑚𝑜𝑙 𝑚𝑜𝑙

𝑐𝑚3
𝑏̅ = 37.6
𝑚𝑜𝑙

 Para el punto 1:

𝑃1 = 1𝑥105 𝑃𝑎

𝑉1 = 3𝑐𝑚3
𝑐𝑚3 2 𝑐𝑚6 𝑐𝑚9
𝑉𝑚3 − (8258,57 ) 𝑉𝑚 + (4,66095𝑥105 ) 𝑉𝑚 − (17,525172𝑥10 6
)=0
𝑚𝑜𝑙 𝑚𝑜𝑙 2 𝑚𝑜𝑙 3
 𝐹 ′ (𝑉𝑚 ) = 3𝑉𝑚2 − 1651714𝑉𝑚 + 466095
𝑅𝑇 𝑐𝑚3
𝑉𝑚0 = = 24775,72
𝑃 𝑚𝑜𝑙
𝐹(24775,72 ) 𝑐𝑚3
𝑉𝑚1 = 24775,72 − ′ = 24763,563
𝐹 (24775,72 ) 𝑚𝑜𝑙
𝐹( 24763,563) 𝑐𝑚3
𝑉𝑚2 = 24763,563 − = 24757,513
𝐹 ′ (24763,563 ) 𝑚𝑜𝑙
𝐹(24757,513 ) 𝑐𝑚3
𝑉𝑚3 = 24757,513 − = 24754.499
𝐹 ′ (24757,513) 𝑚𝑜𝑙
𝐹( 24754.499) 𝑐𝑚3
𝑉𝑚4 = 24754.499 − = 24752.995
𝐹 ′ (24754.499 ) 𝑚𝑜𝑙
𝐹( 24752.995) 𝑐𝑚3
𝑉𝑚5 = 24752.995 − = 24752.995
𝐹 ′ (24752.995) 𝑚𝑜𝑙

𝑐𝑚3
𝑉𝑚 = 24752.995
𝑚𝑜𝑙
𝑛 = 0,00012𝑚𝑜𝑙
𝑐𝑚3
𝑉1 = 𝑉𝑚 𝑥𝑛 = 24752.995 𝑥 0,00012𝑚𝑜𝑙
𝑚𝑜𝑙
𝑉1 = 2.9703594𝑐𝑚3

𝐾1 = 𝑃1 𝑥𝑉1 = 1𝑥105 𝑃𝑎 𝑥 2.9703594𝑐𝑚3

𝐾1 = 297035.94𝑃𝑎. 𝑐𝑚3

 Para el punto 2:

𝑃2 = 1.5𝑥105 𝑃𝑎
𝑐𝑚3 2 𝑐𝑚9
𝑉2 = 2.5𝑐𝑚3 𝑉𝑚3 − (27721.94 ) 𝑉𝑚 + (9.32190𝑥105 𝑉𝑚 ) − (35.050344𝑥106 )=0
𝑚𝑜𝑙 𝑚𝑜𝑙 3

𝐹 ′ (𝑉𝑚 ) = 3𝑉𝑚2 − 55443.88𝑉𝑚 + 932190

𝑅𝑇 𝑐𝑚3
𝑉𝑚0 = = 16407.76
𝑃 𝑚𝑜𝑙
𝐹(16407.76 ) 𝑐𝑚3
𝑉𝑚1 = 16407.76 − = 16394.201
𝐹 ′ (16407.76 ) 𝑚𝑜𝑙
𝐹( 16394.201) 𝑐𝑚3
𝑉𝑚2 = 16394.201 − = 16378.768
𝐹 ′ (16394.201 ) 𝑚𝑜𝑙
 𝐹(16378.768 ) 𝑐𝑚3
𝑉𝑚3 = 16378.768 − = 16374.53
𝐹 ′ (16378.768) 𝑚𝑜𝑙
𝐹( 16374.53) 𝑐𝑚3
𝑉𝑚4 = 16374.53 − ′ = 16373.287
𝐹 (16374.53 ) 𝑚𝑜𝑙
𝐹( 16373.287) 𝑐𝑚3
𝑉𝑚5 = 16373.287 − = 16371.133
𝐹 ′ (16373.287) 𝑚𝑜𝑙

𝑐𝑚3
𝑉𝑚 = 16371.133
𝑚𝑜𝑙
𝑛 = 0,00015𝑚𝑜𝑙
𝑐𝑚3
𝑉2 = 𝑉𝑚 𝑥𝑛 = 16371.133 𝑥0,00015𝑚𝑜𝑙
𝑚𝑜𝑙
𝑉2 = 2.456𝑐𝑚3

𝐾2 = 𝑃2 𝑥𝑉2 = 1.5𝑥105 𝑃𝑎 𝑥 2.456𝑐𝑚3

𝐾2 = 322800𝑃𝑎. 𝑐𝑚3

 Para el punto 3:

𝑃3 = 2.1𝑥105 𝑃𝑎

𝑉3 = 2.1𝑐𝑚3

𝑐𝑚3 2 𝑐𝑚9
𝑉𝑚3 − (11835.56 ) 𝑉𝑚 + (6.65850𝑥105 𝑉𝑚 ) − (25.03596𝑥106 )=0
𝑚𝑜𝑙 𝑚𝑜𝑙 3

𝐹 ′ (𝑉𝑚 ) = 3𝑉𝑚2 − 23671.12𝑉𝑚 + 665850

𝑅𝑇 𝑐𝑚3
𝑉𝑚0 = = 11797.96
𝑃 𝑚𝑜𝑙
𝐹(11797.96 ) 𝑐𝑚3
𝑉𝑚1 = 11797.96 − = 11779.11
𝐹 ′ (11797.96 ) 𝑚𝑜𝑙
𝐹( 11779.11) 𝑐𝑚3
𝑉𝑚2 = 11779.11 − = 11779.04
𝐹 ′ (11779.11) 𝑚𝑜𝑙
𝐹(11779.04) 𝑐𝑚3
𝑉𝑚3 = 11779.04 − = 11779.04
𝐹 ′ (11779.04) 𝑚𝑜𝑙
𝑐𝑚3
𝑉𝑚 = 11779.04
𝑚𝑜𝑙
𝑛 = 0,00017𝑚𝑜𝑙
 𝑐𝑚3
𝑉3 = 𝑉𝑚 𝑥𝑛 = 11779.04 𝑥0,00017𝑚𝑜𝑙
𝑚𝑜𝑙
𝑉3 = 2.002𝑐𝑚3

𝐾3 = 𝑃3 𝑥𝑉3 = 2.1𝑥105 𝑃𝑎 𝑥 2.002𝑐𝑚3

𝐾3 = 420420𝑃𝑎. 𝑐𝑚3

 Para el punto 4:

𝑃4 = 2.6𝑥105 𝑃𝑎

𝑉4 = 1.8𝑐𝑚3

𝑐𝑚3 2 𝑐𝑚9
𝑉𝑚3 − (9566.72 ) 𝑉𝑚 + (5.378019𝑥105 𝑉𝑚 ) − (20.221352𝑥106 )=0
𝑚𝑜𝑙 𝑚𝑜𝑙 3

𝐹 ′ (𝑉𝑚 ) = 3𝑉𝑚2 − 19133.44𝑉𝑚 + 537801.9

𝑅𝑇 𝑐𝑚3
𝑉𝑚0 = = 9529.1231
𝑃 𝑚𝑜𝑙
𝐹(9529.1231 ) 𝑐𝑚3
𝑉𝑚1 = 9529.1231 − ′ = 9510.4682
𝐹 (9529.1231 ) 𝑚𝑜𝑙
𝐹(9510.4682) 𝑐𝑚3
𝑉𝑚2 = 9510.4682 − = 9510.3947
𝐹 ′ (9510.4682 ) 𝑚𝑜𝑙
𝐹(9510.3947 ) 𝑐𝑚3
𝑉𝑚3 = 9510.3947 − = 9510.3947
𝐹 ′ (9510.3947) 𝑚𝑜𝑙
𝑐𝑚3
𝑉𝑚 = 9510.3947
𝑚𝑜𝑙
𝑛 = 0,00018𝑚𝑜𝑙
𝑐𝑚3
𝑉4 = 𝑉𝑚 𝑥𝑛 = 9510.3947 𝑥0,00018𝑚𝑜𝑙
𝑚𝑜𝑙
𝑉2 = 1.7119𝑐𝑚3

𝐾4 = 𝑃4 𝑥𝑉4 = 2.6𝑥105 𝑃𝑎 𝑥 1.7119𝑐𝑚3

𝐾4 = 445094𝑃𝑎. 𝑐𝑚3

 Para el punto 5:

𝑃5 = 3.4𝑥105 𝑃𝑎

𝑉5 = 1.5𝑐𝑚3
𝑐𝑚3 2 𝑐𝑚9
𝑉𝑚3 − (7286.97 ) 𝑉𝑚 + (4.11260𝑥105 𝑉𝑚 ) − (15.463387𝑥106 )=0
𝑚𝑜𝑙 𝑚𝑜𝑙 3
 𝐹 ′ (𝑉𝑚 ) = 3𝑉𝑚2 − 14573.95𝑉𝑚 + 411260
𝑅𝑇 𝑐𝑚3
𝑉𝑚0 = = 7286.98
𝑃 𝑚𝑜𝑙
𝐹(7286.98 ) 𝑐𝑚3
𝑉𝑚1 = 7286.98 − ′ = 7231.255
𝐹 (7286.98 ) 𝑚𝑜𝑙
𝐹( 7231.255) 𝑐𝑚3
𝑉𝑚2 = 7231.255 − = 7230.386
𝐹 ′ (7231.255 ) 𝑚𝑜𝑙
𝐹(7230.386 ) 𝑐𝑚3
𝑉𝑚3 = 7230.386 − = 7230.386
𝐹 ′ (7230.386) 𝑚𝑜𝑙
𝑐𝑚3
𝑉𝑚 = 7230.386
𝑚𝑜𝑙
𝑛 = 0,00021𝑚𝑜𝑙
𝑐𝑚3
𝑉5 = 𝑉𝑚 𝑥𝑛 = 7230.386 𝑥0,00021𝑚𝑜𝑙
𝑚𝑜𝑙
𝑉5 = 1.5185𝑐𝑚3

𝐾5 = 𝑃5 𝑥𝑉5 = 3.4𝑥105 𝑃𝑎 𝑥1.5185𝑐𝑚3

𝐾5 = 516290𝑃𝑎. 𝑐𝑚3

 Para el punto 6:

𝑃6 = 5,3𝑥105 𝑃𝑎
𝑉6 = 1,1𝑐𝑚3

𝑐𝑚3 2 𝑐𝑚6 𝑐𝑚9

𝑉𝑚3 − (4312,264 ) 𝑉𝑚 + (2,638273𝑥105 ) 𝑉 − (9,9919𝑥10 6
)=0
𝑚𝑜𝑙 𝑚𝑜𝑙 2 𝑚 𝑚𝑜𝑙 3

𝐹 ′ (𝑉𝑚 ) = 3𝑉𝑚2 − 8624,528𝑉𝑚 + 263827,3

𝑅𝑇 𝑐𝑚3
𝑉𝑚0 = = 4674,6641
𝑃 𝑚𝑜𝑙
𝐹(4674,6641 ) 9142654657 𝑐𝑚3
𝑉𝑚1 = 4674,6641 − = 4674,6641 − = 4316,1920
𝐹 ′ (4674,6641 ) 25504509,22 𝑚𝑜𝑙
𝐹( 4316,1920) 1201914356 𝑐𝑚3
𝑉𝑚2 = 4316,1920 − = 4316,1920 − = 4252,6902
𝐹 ′ (4316,1920 ) 18927248,91 𝑚𝑜𝑙
𝐹(4252,6902 ) 34569423,34 𝑐𝑚3
𝑉𝑚3 = 4252,6902 − = 4252,6902 − = 4250,7527
𝐹 ′ (4252,6902) 17842503,41 𝑚𝑜𝑙
𝐹( 4250,7527) 31270.48721 𝑐𝑚3
𝑉𝑚4 = 4250,7527 − = 4250,7527 − = 4250,7527
𝐹 ′ (4250,7527 ) 17809787.17 𝑚𝑜𝑙
 𝑐𝑚3
𝑉𝑚 = 4250,7527
𝑚𝑜𝑙
𝑛 = 0,000235𝑚𝑜𝑙
𝑐𝑚3
𝑉6 = 𝑉𝑚 𝑥𝑛 = 4250,7527 𝑥 0,000235𝑚𝑜𝑙
𝑚𝑜𝑙
𝑉6 = 0,99893𝑐𝑚3

𝐾6 = 𝑃6 𝑥𝑉6 = 5,3𝑥105 𝑃𝑎 𝑥 0,99893𝑐𝑚3

𝐾6 = 529432,9𝑃𝑎. 𝑐𝑚3

 Para el punto 7:

𝑃7 = 8𝑥105 𝑃𝑎

𝑉7 = 0,8𝑐𝑚3
𝑐𝑚3 2 𝑐𝑚6 𝑐𝑚9
𝑉𝑚3 − (3134,565 ) 𝑉𝑚 + (1,747856𝑥105 ) 𝑉𝑚 − (6,5719𝑥10 6
)=0
𝑚𝑜𝑙 𝑚𝑜𝑙 2 𝑚𝑜𝑙 3

𝐹 ′ (𝑉𝑚 ) = 3𝑉𝑚2 − 6269,13𝑉𝑚 + 174785,6

𝑅𝑇 𝑐𝑚3
𝑉𝑚0 = = 3096,965
𝑃 𝑚𝑜𝑙
𝐹( 3096,965) 174104158,6 𝑐𝑚3
𝑉𝑚1 = 3096,965 − = 3096,965 − = 3078,7019
𝐹 ′ (3096,965 ) 9533086,043 𝑚𝑜𝑙
𝐹(3078,7019 ) 2047750,723 𝑐𝑚3
𝑉𝑚2 = 3078,7019 − = 3078,7019 − = 3078,4819
𝐹 ′ (3078,7019 ) 9309219,325 𝑚𝑜𝑙
𝐹(3078,4819 ) 17,77524 𝑐𝑚3
𝑉𝑚3 = 3078,4819 − ′ = 3078,4819 − = 3078,4819
𝐹 (3078,4819 ) 9306534,792 𝑚𝑜𝑙
𝐹(3078,4818 ) −912,87812 𝑐𝑚3
𝑉𝑚4 = 3078,4818 − = 3078,4818 − = 3078,4819
𝐹 ′ ( 3078,4818) 9306533,572 𝑚𝑜𝑙
𝑐𝑚3
𝑉𝑚 = 3078,4819
𝑚𝑜𝑙
𝑛 = 0,000258𝑚𝑜𝑙
𝑐𝑚3
𝑉7 = 𝑉𝑚 𝑥𝑛 = 3078,4819 𝑥 0,000258𝑚𝑜𝑙
𝑚𝑜𝑙
𝑉7 = 0,79425𝑐𝑚3

𝐾7 = 𝑃7 𝑥𝑉7 = 8𝑥105 𝑃𝑎 𝑥 0,79425𝑐𝑚3

𝐾7 = 635400𝑃𝑎. 𝑐𝑚3
  Para el punto 8:

𝑃8 = 11,8𝑥105 𝑃𝑎
𝑉8 = 0,6𝑐𝑚3

𝑐𝑚3 2 𝑐𝑚6 𝑐𝑚9

𝑉𝑚3 − (2137,237 ) 𝑉𝑚 + (1,184987𝑥105 ) 𝑉 − (4,4555𝑥10 6
)=0
𝑚𝑜𝑙 𝑚𝑜𝑙 2 𝑚 𝑚𝑜𝑙 3

𝐹 ′ (𝑉𝑚 ) = 3𝑉𝑚2 − 4274,474𝑉𝑚 + 118498,7

𝑅𝑇 𝑐𝑚3
𝑉𝑚0 = = 2099,6372
𝑃 𝑚𝑜𝑙
𝐹(2099,6372 ) 78590948,79 𝑐𝑚3
𝑉𝑚1 = 2099,6372 − = 2099,6372 − = 2081,6492
𝐹 ′ ( 2099,6372) 4369083,194 𝑚𝑜𝑙
𝐹(2081,6492 ) 1340645,282 𝑐𝑚3
𝑉𝑚2 = 2081,6492 − = 2081,6492 − = 2081,3315
𝐹 ′ (2081,6492) 4220333,493 𝑚𝑜𝑙
𝐹(2081,3315 ) 259,9039 𝑐𝑚3
𝑉𝑚3 = 2081,3315 − = 2081,3315 − = 2081,3314
𝐹 ′ (2081,3315 ) 4217723.757 𝑚𝑜𝑙
𝐹( 2081,3314) −161.86843 𝑐𝑚3
𝑉𝑚4 = 2081,3314 − = 2081,3314 − = 2081,3314
𝐹 ′ ( 2081,3314) 4217722.935 𝑚𝑜𝑙
𝑐𝑚3
𝑉𝑚 = 2081,3314
𝑚𝑜𝑙
𝑛 = 0,000285𝑚𝑜𝑙
𝑐𝑚3
𝑉8 = 𝑉𝑚 𝑥𝑛 = 2081,3314 𝑥 0,000285𝑚𝑜𝑙
𝑚𝑜𝑙
𝑉8 = 0,59318𝑐𝑚3

𝐾8 = 𝑃8 𝑥𝑉8 = 11,8𝑥105 𝑃𝑎 𝑥 0,59318𝑐𝑚3

𝐾8 = 699952,4𝑃𝑎. 𝑐𝑚3

 Para el punto 9:

𝑃9 = 19,8𝑥105 𝑃𝑎

𝑉9 = 0,4𝑐𝑚3

𝑐𝑚3 2 𝑐𝑚6 𝑐𝑚9

𝑉𝑚3 − (1288,898 ) 𝑉𝑚 + (0,706204𝑥105 ) 𝑉𝑚 − (2,6553𝑥10 6
)=0
𝑚𝑜𝑙 𝑚𝑜𝑙 2 𝑚𝑜𝑙 3

𝐹 ′ (𝑉𝑚 ) = 3𝑉𝑚2 − 2577,796𝑉𝑚 + 70620,4

 𝑅𝑇 𝑐𝑚3
𝑉𝑚0 = = 1251,2989
𝑃 𝑚𝑜𝑙
𝐹(1251,2989) 26841177,98 𝑐𝑚3
𝑉𝑚1 = 1251,2989 − = 1251,2989 − = 1233,8952
𝐹 ′ (1251,2989) 1542273,912 𝑚𝑜𝑙
𝐹(1233,8952 ) 741890,6834 𝑐𝑚3
𝑉𝑚2 = 1233,8952 − = 1233,8952 − = 1233,3861
𝐹 ′ (1233,8952 ) 1457382,383 𝑚𝑜𝑙
𝐹(1233,3861 ) −73,61255 𝑐𝑚3
𝑉𝑚3 = 1233,3861 − = 1233,3861 − = 1233,3862
𝐹 ′ (1233,3861 ) 1454926,46 𝑚𝑜𝑙
𝐹(1233,3862) 71,88011 𝑐𝑚3
𝑉𝑚4 = 1233,3862 − = 1233,3862 − = 1233,3862
𝐹 ′ (1233,3862) 1454926,942 𝑚𝑜𝑙
𝑐𝑚3
𝑉𝑚 = 1233,3862
𝑚𝑜𝑙
𝑛 = 0,000319𝑚𝑜𝑙
𝑐𝑚3
𝑉9 = 𝑉𝑚 𝑥𝑛 = 1233,3862 𝑥 0,000319𝑚𝑜𝑙
𝑚𝑜𝑙
𝑉9 = 0,39345𝑐𝑚3

𝐾9 = 𝑃9 𝑥𝑉9 = 19,8𝑥105 𝑃𝑎 𝑥 0,39345𝑐𝑚3

𝐾9 = 779031𝑃𝑎. 𝑐𝑚3

 Para el punto 10:

𝑃10 = 37,1𝑥105 𝑃𝑎

𝑉10 = 0,25𝑐𝑚3
𝑐𝑚3 2 𝑐𝑚6 𝑐𝑚9
𝑉𝑚3 − (705,409 ) 𝑉𝑚 + (0,376896𝑥105 ) 𝑉 − (1,4171𝑥106
)=0
𝑚𝑜𝑙 𝑚𝑜𝑙 2 𝑚 𝑚𝑜𝑙 3

𝐹 ′ (𝑉𝑚 ) = 3𝑉𝑚2 − 1410,818𝑉𝑚 + 37689,6

𝑅𝑇 𝑐𝑚3
𝑉𝑚0 = = 667,8091
𝑃 𝑚𝑜𝑙
𝐹( 667,8091) 6983968,276 𝑐𝑚3
𝑉𝑚1 = 667,8091 − = 667,8091 − = 651,6962
𝐹 ′ ( 667,8091) 433439,4833 𝑚𝑜𝑙
𝐹(651,6962 ) 332816,616 𝑐𝑚3
𝑉𝑚2 = 651,6962 − = 651,6962 − = 650,8480
𝐹 ′ (651,6962 ) 392388,6818 𝑚𝑜𝑙
𝐹(650,8480) 890,999367 𝑐𝑚3
𝑉𝑚3 = 650,8480 − = 650,8480 − = 650,8457
𝐹 ′ (650,8480) 390270,8836 𝑚𝑜𝑙
 𝐹(650,8457) 6,617068 𝑐𝑚3
𝑉𝑚4 = 650,8457 − = 650,8457 − = 650,8457
𝐹 ′ (650,8457) 390265,1468 𝑚𝑜𝑙
𝑐𝑚3
𝑉𝑚 = 650,8457
𝑚𝑜𝑙
𝑛 = 0,000374𝑚𝑜𝑙
𝑐𝑚3
𝑉10 = 𝑉𝑚 𝑥𝑛 = 650,8457 𝑥 0,000374𝑚𝑜𝑙
𝑚𝑜𝑙
𝑉10 = 0,24341𝑐𝑚3

𝐾10 = 𝑃10 𝑥𝑉10 = 37,1𝑥105 𝑃𝑎 𝑥 0,24341 𝑐𝑚3

𝐾10 = 903051,1𝑃𝑎. 𝑐𝑚3

𝑘𝑝𝑟𝑜𝑚𝑒𝑑𝑖𝑜
297035.94 + 322800 + 420420 + 445094 + 516290 + 529432,9 + 635400 + 699952,4 + 779031 + 903051,1
=
10

𝑘𝑝𝑟𝑜𝑚𝑒𝑑𝑖𝑜 = 554850.694𝑃𝑎. 𝑐𝑚3

a) Gráfica P vs V
 Gráfica P vs V
40

35

30

25
PRESIÓN

20

15

10

0
0 0.5 1 1.5 2 2.5 3 3.5
VOLUMEN

b) Grafica P vs 1/V

Gráfica P vs 1/V
40

35
E
C 30

U 25
Presión

A 20
C 15
I
10
Ó
5
N
0
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5
D 1/Volumen
E
REDLICH-KWONG
 RT 2 bRT a ab
Vm3  Vm  (b2   )Vm  0
P P T .P T .P

𝑐𝑚6
𝑎𝑎𝑖𝑟𝑒 = 16,07𝑥106 𝑥 101325
𝑚𝑜𝑙 2 𝑘 −0,5
𝑐𝑚3
𝑏𝑎𝑖𝑟𝑒 = 0,026𝑥103
𝑚𝑜𝑙

𝑃𝑎. 𝑐𝑚3
5
𝑅 = 83,14𝑥10
𝑚𝑜𝑙. 𝑘
𝑇 = 298𝑘

 Para el punto 1:

𝑃1 = 3𝑥105 𝑃𝑎
𝑉1 = 1𝑐𝑚3
𝑐𝑚3 2 𝑐𝑚6 𝑐𝑚9
𝑉𝑚3 − (24775,72 ) 𝑉𝑚 + (15339.01147 ) 𝑉 − (314414.881 )=0
𝑚𝑜𝑙 𝑚𝑜𝑙 2 𝑚 𝑚𝑜𝑙 3

𝐹 ′ (𝑉𝑚 ) = 3𝑉𝑚2 − 49551.44𝑉𝑚 + 15339.01147

- Hallamos el Vm según Redlich-Kwong:

𝑅𝑇 𝑐𝑚3
𝑉𝑚0 = = 24775,72
𝑃 𝑚𝑜𝑙
𝐹(24775,72 ) 379720638,4 𝑐𝑚3
𝑉𝑚1 = 24775,72 − = 24775,72 − = 24775.1014
𝐹 ′ (24775,72 ) 613851640.5 𝑚𝑜𝑙
𝐹(24775.1014) 18960,56 𝑐𝑚3
𝑉𝑚2 = 24775.1014 − = 24775.1014 − = 24775.1013
𝐹 ′ (24775.1014) 613790337,9 𝑚𝑜𝑙
𝐹(24775.1013) 0.089744 𝑐𝑚3
𝑉𝑚3 = 24775.1013 − = 24775.1013 − = 24775.1013
𝐹 ′ (24775.1013) 613790334 𝑚𝑜𝑙
𝑐𝑚3
𝑉𝑚 = 24775.1013
𝑚𝑜𝑙
  Para el punto 2:

𝑃2 = 1.5𝑥105 𝑃𝑎
𝑉2 = 2.5𝑐𝑚3
𝑐𝑚3 2 𝑐𝑚6 𝑐𝑚9
𝑉𝑚3 − (16407,76 ) 𝑉 + (1054755.536 ) 𝑉 − (16349574.18 )=0
𝑚𝑜𝑙 𝑚 𝑚𝑜𝑙 2 𝑚 𝑚𝑜𝑙 3

𝐹 ′ (𝑉𝑚 ) = 3𝑉𝑚2 − 32815.52𝑉𝑚 + 1054755.536

- Hallamos el Vm según Redlich-Kwong:

𝑅𝑇 𝑐𝑚3
𝑉𝑚0 = = 16407,76
𝑃 𝑚𝑜𝑙
𝐹(16407,76 ) 17289826120 𝑐𝑚3
𝑉𝑚1 = 16407,76 − = 16407,76 − = 16343.7874
𝐹 ′ (16407,76 ) 270269343.8 𝑚𝑜𝑙
𝐹(16343.7874) 134035395.8 𝑐𝑚3
𝑉𝑚2 = 16343.7874 − ′ = 16343.7874 − = 16343.2836
𝐹 (16343.7874) 266083034.5 𝑚𝑜𝑙
𝐹(16343.2836) 8278.1066 𝑐𝑚3
𝑉𝑚3 = 16343.2836 − = 16343.2836 − = 16343.2836
𝐹 ′ (16343.2836) 266050168 𝑚𝑜𝑙
𝐹(16343.2836) −0.012 𝑐𝑚3
𝑉𝑚4 = 16343.2836 − = 16343.2836 − = 16343.2836
𝐹 ′ (16343.2836) 266050168 𝑚𝑜𝑙

𝑐𝑚3
𝑉𝑚 = 16343.2836
𝑚𝑜𝑙
 Para el punto 3:

𝑃3 = 2.1𝑥105 𝑃𝑎
𝑉3 = 2.1𝑐𝑚3
𝑐𝑚3 2 𝑐𝑚6 𝑐𝑚9
𝑉𝑚3 − (11797,96 ) 𝑉 + (755235.0858 ) 𝑉 − (11678267.27 )=0
𝑚𝑜𝑙 𝑚 𝑚𝑜𝑙 2 𝑚 𝑚𝑜𝑙 3

𝐹 ′ (𝑉𝑚 ) = 3𝑉𝑚2 − 23595.92𝑉𝑚 + 755235.0858

- Hallamos el Vm según Redlich-Kwong:

𝑅𝑇 𝑐𝑚3
𝑉𝑚0 = = 11797,96
𝑃 𝑚𝑜𝑙
 𝐹(11797,96 ) 8898555066 𝑐𝑚3
𝑉𝑚1 = 11797,96 − ′ = 11797,96 − = 11734.37
𝐹 (11797,96 ) 139947095.2 𝑚𝑜𝑙
𝐹(11734.37) 95142865.41 𝑐𝑚3
𝑉𝑚2 = 11734.37 − ′ = 11734.37 − = 11733.68
𝐹 (11734.37) 136958524.9 𝑚𝑜𝑙
𝐹(11733.68) 11294.71039 𝑐𝑚3
𝑉𝑚3 = 11733.68 − ′ = 11733.68 − = 11733.68
𝐹 (11733.68) 136926008 𝑚𝑜𝑙
𝑐𝑚3
𝑉𝑚 = 11733.68
𝑚𝑜𝑙

 Para el punto 4:

𝑃4 = 2.6𝑥105 𝑃𝑎
𝑉4 = 1.8𝑐𝑚3
𝑐𝑚3 2 𝑐𝑚6 𝑐𝑚9
𝑉𝑚3 − (9529,1231 ) 𝑉𝑚 + (609867.6099 ) 𝑉 − (9432446.642 )=0
𝑚𝑜𝑙 𝑚𝑜𝑙 2 𝑚 𝑚𝑜𝑙 3

𝐹 ′ (𝑉𝑚 ) = 3𝑉𝑚2 − 19058.2462𝑉𝑚 + 609867.6099

- Hallamos el Vm según Redlich-Kwong:
𝑅𝑇 𝑐𝑚3
𝑉𝑚0 = = 9529,1231
𝑃 𝑚𝑜𝑙
𝐹(9529,1231 ) 5802071083 𝑐𝑚3
𝑉𝑚1 = 9529,1231 − = 9529,1231 − = 9465.65287
𝐹 ′ (9529,1231 ) 91414054.66 𝑚𝑜𝑙

𝐹(9465.65287) 76519887.2 𝑐𝑚3

𝑉𝑚2 = 9465.65287 − ′ = 9465.65287 − = 9464.7931
𝐹 (9465.65287) 89006877.53 𝑚𝑜𝑙
𝐹(9464.7931) 13944.5223 𝑐𝑚3
𝑉𝑚3 = 9464.7931 − ′ = 9464.7931 − = 9464.7930
𝐹 (9464.7931) 88974438.11 𝑚𝑜𝑙
𝑐𝑚3
𝑉𝑚 = 9464.7930
𝑚𝑜𝑙

 Para el punto 5:

𝑃5 = 3.4𝑥105 𝑃𝑎
𝑉5 = 1.5𝑐𝑚3
 𝑐𝑚3 2 𝑐𝑚6 𝑐𝑚9
𝑉𝑚3 − (7286,9764 ) 𝑉 + (466210.2876 ) 𝑉 − (7213047.432 )=0
𝑚𝑜𝑙 𝑚 𝑚𝑜𝑙 2 𝑚 𝑚𝑜𝑙 3

𝐹 ′ (𝑉𝑚 ) = 3𝑉𝑚2 − 14573.9528𝑉𝑚 + 466210.2876

- Hallamos el Vm según Redlich-Kwong:
𝑅𝑇 𝑐𝑚3
𝑉𝑚0 = = 7286,9764
𝑃 𝑚𝑜𝑙
𝐹(7286,9764 ) 3390050316 𝑐𝑚3
𝑉𝑚1 = 7286,9764 − = 7286,9764 − = 7223.6893
𝐹 ′ (7286,9764 ) 53566235.34 𝑚𝑜𝑙

𝐹(7223.6893) 58118898 𝑐𝑚3

𝑉𝑚2 = 7223.6893 − = 7223.6893 − = 7222.5658
𝐹 ′ (7223.6893) 51733565.44 𝑚𝑜𝑙
𝐹(7222.5658) 18152.58547 𝑐𝑚3
𝑉𝑚3 = 7222.5658 − = 7222.5658 − = 7222.5655
𝐹 ′ (7222.5658) 51701250.26 𝑚𝑜𝑙
𝑐𝑚3
𝑉𝑚 = 7222.5655
𝑚𝑜𝑙

 Para el punto 6:

𝑃6 = 5,3𝑥105 𝑃𝑎

𝑉6 = 1,1𝑐𝑚3

𝑐𝑚3 2 𝑐𝑚6 𝑐𝑚9

𝑉𝑚3 − (4674,6642 ) 𝑉𝑚 + (55753,4 ) 𝑉𝑚 − (4627237,98 )=0
𝑚𝑜𝑙 𝑚𝑜𝑙 2 𝑚𝑜𝑙 3

𝐹 ′ (𝑉𝑚 ) = 3𝑉𝑚2 − 9349,3284𝑉𝑚 + 55753,4

- Hallamos el Vm según Redlich-Kwong:

𝑅𝑇 𝑐𝑚3
𝑉𝑚0 = = 4674,6642
𝑃 𝑚𝑜𝑙
𝐹(4674,6642 ) 256001185 𝑐𝑚3
𝑉𝑚1 = 4674,6642 − ′ = 4674,6642 − = 4662,9790
𝐹 (4674,6642 ) 21908238,78 𝑚𝑜𝑙
𝐹(4662,9790) 1274031,415 𝑐𝑚3
𝑉𝑚2 = 4662,9790 − = 4662,9790 − = 4662,9203
𝐹 ′ (4662,9790) 21690150,87 𝑚𝑜𝑙
𝐹(4662,9203) 851,65202 𝑐𝑚3
𝑉𝑚3 = 4662,9203 − = 4662,9203 − = 4662,9203
𝐹 ′ (4662,9203) 21689057,38 𝑚𝑜𝑙
 𝑐𝑚3
𝑉𝑚 = 4662,9203
𝑚𝑜𝑙

 Para el punto 7:

𝑃7 = 8𝑥105 𝑃𝑎

𝑉7 = 0,8𝑐𝑚3
𝑐𝑚3 2 𝑐𝑚6 𝑐𝑚9
𝑉𝑚3 − (3096,965 ) 𝑉𝑚 + (36708,493 ) 𝑉𝑚 − (3065545,16 )=0
𝑚𝑜𝑙 𝑚𝑜𝑙 2 𝑚𝑜𝑙 3

𝐹 ′ (𝑉𝑚 ) = 3𝑉𝑚2 − 6193,93𝑉𝑚 + 36708,493

- Hallamos el Vm según Redlich-Kwong:

𝑅𝑇 𝑐𝑚3
𝑉𝑚0 = = 3096,965
𝑃 𝑚𝑜𝑙
𝐹(3096,965) 110619372,9 𝑐𝑚3
𝑉𝑚1 = 3096,965 − = 3096,965 − = 3085,476
𝐹 ′ (3096,965) 9627900,704 𝑚𝑜𝑙
𝐹(3085,476) 820486,0857 𝑐𝑚3
𝑉𝑚2 = 3085,476 − = 3085,476 − = 3085,389
𝐹 ′ (3085,476) 9485972,572 𝑚𝑜𝑙
𝐹(3085,389) 3097506,745 𝑐𝑚3
𝑉𝑚3 = 3085,389 − = 3085,389 − = 3085,062
𝐹 ′ (3085,389) 9484900.848 𝑚𝑜𝑙

𝑐𝑚3
𝑉𝑚 = 3085,062
𝑚𝑜𝑙

 Para el punto 8:

𝑃8 = 11,8𝑥105 𝑃𝑎

𝑉8 = 0,6𝑐𝑚3
𝑐𝑚3 2 𝑐𝑚6 𝑐𝑚9
𝑉𝑚3 − (2099,6373 ) 𝑉 + (24669,419 ) 𝑉 − (2078335,701 )=0
𝑚𝑜𝑙 𝑚 𝑚𝑜𝑙 2 𝑚 𝑚𝑜𝑙 3

𝐹 ′ (𝑉𝑚 ) = 3𝑉𝑚2 − 4199,2746𝑉𝑚 + 24669,419

- Hallamos el Vm según Redlich-Kwong:

𝑅𝑇 𝑐𝑚3
𝑉𝑚0 = = 2099,6373
𝑃 𝑚𝑜𝑙
 𝐹(2099,637) 49718496,6 𝑐𝑚3
𝑉𝑚1 = 2099,637 − = 2099,637 − = 2088,422
𝐹 ′ (2099,637) 4433146,211 𝑚𝑜𝑙
𝐹(2088,422) 526218,3762 𝑐𝑚3
𝑉𝑚2 = 2088,422 − ′ = 2088,422 − = 2088,301
𝐹 (2088,422) 4339331,311 𝑚𝑜𝑙
𝐹(2088,301) 1220,274809 𝑐𝑚3
𝑉𝑚3 = 2088,301 − = 2088,301 − = 2088,301
𝐹 ′ (2088,301) 4338323,272 𝑚𝑜𝑙
𝑐𝑚3
𝑉𝑚 = 2088,301
𝑚𝑜𝑙
 Para el punto 9:

𝑃9 = 19,8𝑥105 𝑃𝑎
𝑉9 = 0,4𝑐𝑚3

𝑐𝑚3 2 𝑐𝑚6 𝑐𝑚9

𝑉𝑚3 − (1251,2989 ) 𝑉𝑚 + (14428,8457 ) 𝑉𝑚 − (1238604,105 )=0
𝑚𝑜𝑙 𝑚𝑜𝑙 2 𝑚𝑜𝑙 3

𝐹 ′ (𝑉𝑚 ) = 3𝑉𝑚2 − 2502,5978𝑉𝑚 + 14428,8457

- Hallamos el Vm según Redlich-Kwong:

𝑅𝑇 𝑐𝑚3
𝑉𝑚0 = = 1251,298
𝑃 𝑚𝑜𝑙
𝐹(1251,298) 16816194,65 𝑐𝑚3
𝑉𝑚1 = 1251,298 − ′ = 1251,298 − = 1240,657
𝐹 (1251,298) 1580177,783 𝑚𝑜𝑙
𝐹(1240,657) 282314,7949 𝑐𝑚3
𝑉𝑚2 = 1240,657 − = 1240,657 − = 1240,472
𝐹 ′ (1240,657) 1527252,742 𝑚𝑜𝑙
𝐹(1240,472) −142,4099496 𝑐𝑚3
𝑉𝑚3 = 1240,472 − = 1240,472 − = 1240,472
𝐹 ′ (1240,472) 1526338,696 𝑚𝑜𝑙
𝑐𝑚3
𝑉𝑚 = 1240,472
𝑚𝑜𝑙

 Para el punto 10:

𝑃10 = 37,1𝑥105 𝑃𝑎

𝑉10 = 0,25𝑐𝑚3

𝑐𝑚3 2 𝑐𝑚6 𝑐𝑚9

𝑉𝑚3 − (667,8092 ) 𝑉𝑚 + (7454,0608 ) 𝑉 − (661033,9965 )=0
𝑚𝑜𝑙 𝑚𝑜𝑙 2 𝑚 𝑚𝑜𝑙 3
 𝐹 ′ (𝑉𝑚 ) = 3𝑉𝑚2 − 1335,6184𝑉𝑚 + 7454,0608

- Hallamos el Vm según Redlich-Kwong:

𝑅𝑇 𝑐𝑚3
𝑉𝑚0 = = 667,8092
𝑃 𝑚𝑜𝑙
𝐹(667,809) 4316856,383 𝑐𝑚3
𝑉𝑚1 = 667,809 − ′ = 667,809 − = 658,289
𝐹 (667,809) 453423,1884 𝑚𝑜𝑙
𝐹(658,289) 120366,805 𝑐𝑚3
𝑉𝑚2 = 658,289 − = 658,289 − = 658,001
𝐹 ′ (658,289) 428264,3824 𝑚𝑜𝑙
𝐹(658,001) −2864,94844 𝑐𝑚3
𝑉𝑚3 = 658,001 − = 658,001 − = 658,001
𝐹 ′ (658,001) 427511,766 𝑚𝑜𝑙

𝑐𝑚3
𝑉𝑚 = 658,001
𝑚𝑜𝑙

El volumen molar fue hallado por el método de Newton- Raphson:

𝐹(𝑉𝑛+1 )
𝑉𝑛 = 𝑉𝑛+1 −
𝐹′(𝑉𝑛+1 )

 Hallando el k para Redlick- Kwong

𝑐𝑚3
−𝑉1 = 𝑉𝑚1 𝑛 = 24775,1013 𝑥 0,00012𝑚𝑜𝑙 = 2,97305𝑐𝑚3
𝑚𝑜𝑙
𝑘1 = 𝑃1 𝑉1 = 1𝑥105 𝑃𝑎. 2.9730𝑐𝑚3 = 297305𝑃𝑎. 𝑐𝑚3
𝑐𝑚3
−𝑉2 = 𝑉𝑚2 𝑛 = 16432.836 𝑥0.00015 𝑚𝑜𝑙 = 2,4649𝑐𝑚3
𝑚𝑜𝑙
𝑘2 = 𝑃2 𝑉2 = 1.5𝑥105 𝑃𝑎. 2,4649𝑐𝑚3 = 369746𝑃𝑎. 𝑐𝑚3
𝑐𝑚3
−𝑉3 = 𝑉𝑚3 𝑛 = 11733,68 𝑥 0.00017𝑚𝑜𝑙 = 1,9947𝑐𝑚3
𝑚𝑜𝑙
𝑘3 = 𝑃3 𝑉3 = 2.1𝑥105 𝑃𝑎. 1,9947𝑐𝑚3 = 418894𝑃𝑎. 𝑐𝑚3
𝑐𝑚3
−𝑉4 = 𝑉𝑚4 𝑛 = 9464,7930 𝑥 0.00018𝑚𝑜𝑙 = 1,7037𝑐𝑚3
𝑚𝑜𝑙
𝑘4 = 𝑃4 𝑉4 = 2.6𝑥105 𝑃𝑎. 1,7037𝑐𝑚3 = 442953𝑃𝑎. 𝑐𝑚3
 𝑐𝑚3
−𝑉5 = 𝑉𝑚5 𝑛 = 7222,5655 𝑥 0,00021𝑚𝑜𝑙 = 1,5167𝑐𝑚3
𝑚𝑜𝑙
𝑘5 = 𝑃5 𝑉5 = 3,4𝑥105 𝑃𝑎. 1,5167𝑐𝑚3 = 515691𝑃𝑎. 𝑐𝑚3
𝑐𝑚3
−𝑉6 = 𝑉𝑚6 𝑛 = 4662,9203 𝑥 0,000235𝑚𝑜𝑙 = 1,09579𝑐𝑚3
𝑚𝑜𝑙
𝑘6 = 𝑃6 𝑉6 = 5,3𝑥105 𝑃𝑎. 1,09579𝑐𝑚3 = 580768,7 𝑃𝑎. 𝑐𝑚3
𝑐𝑚3
−𝑉7 = 𝑉𝑚7 𝑛 = 3085,062 𝑥 0,000258𝑚𝑜𝑙 = 0,79595𝑐𝑚3
𝑚𝑜𝑙
𝑘7 = 𝑃7 𝑉7 = 8𝑥105 𝑃𝑎. 0,79595𝑐𝑚3 = 636760 𝑃𝑎. 𝑐𝑚3
𝑐𝑚3
−𝑉8 = 𝑉𝑚8 𝑛 = 2088,301 𝑥 0,000285𝑚𝑜𝑙 = 0,59517𝑐𝑚3
𝑚𝑜𝑙
𝑘8 = 𝑃8 𝑉8 = 11,8𝑥105 𝑃𝑎. 0,59517𝑐𝑚3 = 702300,6 𝑃𝑎. 𝑐𝑚3
𝑐𝑚3
−𝑉9 = 𝑉𝑚9 𝑛 = 1240,472 𝑥 0,000319𝑚𝑜𝑙 = 0,39571𝑐𝑚3
𝑚𝑜𝑙
𝑘9 = 𝑃9 𝑉9 = 19,8𝑥105 𝑃𝑎. 0,39571𝑐𝑚3 = 783505,8 𝑃𝑎. 𝑐𝑚3
𝑐𝑚3
−𝑉10 = 𝑉𝑚10 𝑛 = 658,001 𝑥 0,000374𝑚𝑜𝑙 = 0,24609𝑐𝑚3
𝑚𝑜𝑙
𝑘10 = 𝑃10 𝑉10 = 37,1𝑥105 𝑃𝑎. 0,24609𝑐𝑚3 = 912993,9 𝑃𝑎. 𝑐𝑚3

𝑘𝑝𝑟𝑜𝑚𝑒𝑑𝑖𝑜 =
(297305 + 369746 + 418894 + 442953 + 515691 + 580768,7 + 636760 + 702300,6 + 783505,8 + 912993,9)
𝑃𝑎. 𝑐𝑚3
10

𝑘𝑝𝑟𝑜𝑚𝑒𝑑𝑖𝑜 = 566091.8𝑃𝑎. 𝑐𝑚3

a) Gráfico P vs V

b) G
Gráfico P vs V ráfica P
40 vs 1/V
35

30

25 Gráfico P vs 1/V
Presión

20 40

15 35
10
30
5
25
PRESIÓN

0
0 0.5 20 1 1.5 2 2.5 3 3.5
Volumen
15

10

0
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5
1/VOLUMEN
ECUACI
ÓN DE VIRIAL
(BEATTIE-BRIDGEMAN)

𝑅𝑇 𝐶𝑃
𝑉𝑚 = + 𝐵 +
𝑃 𝑅𝑇

𝑃𝑎. 𝑐𝑚3 6
𝑎̅ = 1.38 × 101325 × 10
𝑚𝑜𝑙 2
𝑐𝑚3
𝑏̅ = 37.6
𝑚𝑜𝑙
Reemplazando:
𝑎 𝑐𝑚3
𝐵=𝑏− = 𝑏̅ = 37.6
𝑅𝑇 𝑚𝑜𝑙
𝑃𝑎. 𝑐𝑚3
1.38 × 101325 × 106 3
− 𝑚𝑜𝑙2 = −18.8377 𝑐𝑚
𝑃𝑎. 𝑐𝑚3 𝑚𝑜𝑙
83,14 × 105 × 298𝐾
𝑚𝑜𝑙. 𝐾

2
2
𝑐𝑚3 𝑐𝑚6
𝐶 = 𝑏 = (37.6 ) = 1413.76
𝑚𝑜𝑙 𝑚𝑜𝑙 2

Trabajando con los puntos escogidos:

 Para el punto 1:

𝑃1 = 1x105 𝑃𝑎

𝑉1 = 3𝑐𝑚3
𝑃𝑎.𝑐𝑚3 𝑐𝑚6
83,14×105 × ×298𝐾 𝑐𝑚3 1413.76 ×1×105 𝑃𝑎 𝑐𝑚3
𝑚𝑜𝑙.𝐾 𝑚𝑜𝑙2
𝑉𝑚 = − 18.8377 + 𝑃𝑎.𝑐𝑚3
=24756.939 𝑚𝑜𝑙
1×105 𝑃𝑎 𝑚𝑜𝑙 83,14×105 × ×298𝐾
𝑚𝑜𝑙.𝐾

𝑐𝑚3
𝑃𝑉𝑚 1𝑥105 𝑃𝑎 × 24756.939
𝑍= = 𝑚𝑜𝑙 = 0.9992
𝑅𝑇 𝑃𝑎. 𝑐𝑚3
83.14 × 105 × × 298𝐾
𝑚𝑜𝑙. 𝐾
 Dónde:
𝑃. 𝑉 = 𝑍. 𝑛. 𝑅. 𝑇

𝑛. 𝑅. 𝑇 = 𝐾1

𝑃. 𝑉 105 𝑃𝑎(3𝑐𝑚3 )
𝐾1 = = = 300240.19𝑃𝑎. 𝑐𝑚3
𝑍 0.9992
  Para el punto 2:

𝑃2 = 1.51𝑥105 𝑃𝑎
𝑉2 = 2.5𝑐𝑚3
𝑃𝑎.𝑐𝑚3 𝑐𝑚6
83,14×105 × ×298𝐾 𝑐𝑚3 1413.76 ×1.51×105 𝑃𝑎 𝑐𝑚3
𝑚𝑜𝑙.𝐾 𝑚𝑜𝑙2
𝑉𝑚 = − 18.8377 + 𝑃𝑎.𝑐𝑚3
=16389.0100𝑚𝑜𝑙
1.51×105 𝑃𝑎 𝑚𝑜𝑙 83,14×105 × ×298𝐾
𝑚𝑜𝑙.𝐾

𝑐𝑚3
𝑃𝑉𝑚 1.51𝑥105 𝑃𝑎 × 16389.0100
𝑍= = 𝑚𝑜𝑙 = 0.9988
𝑅𝑇 𝑃𝑎. 𝑐𝑚 3
83,14 × 105 × × 298𝐾
𝑚𝑜𝑙. 𝐾
 Dónde:
𝑃. 𝑉 = 𝑍. 𝑛. 𝑅. 𝑇

𝑛. 𝑅. 𝑇 = 𝐾2

𝑃. 𝑉 1.51𝑥105 𝑃𝑎 × 2.5𝑐𝑚3
𝐾2 = = = 377953.5442𝑃𝑎. 𝑐𝑚3
𝑍 0.9988
 Para el punto 3:

𝑃3 = 2.1𝑥105 𝑃𝑎

𝑉3 = 2.1𝑐𝑚3
𝑃𝑎.𝑐𝑚3 𝑐𝑚6
83,14×105 × ×298𝐾 𝑐𝑚3 1413.76 ×2.1×105 𝑃𝑎 𝑐𝑚3
𝑚𝑜𝑙.𝐾 𝑚𝑜𝑙2
𝑉𝑚 = − 18.8377 + 𝑃𝑎.𝑐𝑚3
=7268.33𝑚𝑜𝑙
3.4×105 𝑃𝑎 𝑚𝑜𝑙 83,14×105 × ×298𝐾
𝑚𝑜𝑙.𝐾

𝑐𝑚3
𝑃𝑉𝑚 2.1𝑥105 𝑃𝑎 × 7268.33
𝑍= = 𝑚𝑜𝑙 = 0.9974
𝑅𝑇 𝑃𝑎. 𝑐𝑚3
83,14 × 105 × × 298𝐾
𝑚𝑜𝑙. 𝐾
 Dónde:
𝑃. 𝑉 = 𝑍. 𝑛. 𝑅. 𝑇

𝑛. 𝑅. 𝑇 = 𝐾5

𝑃. 𝑉 2.1𝑥105 𝑃𝑎 × 2.1𝑐𝑚3
𝐾3 = = = 441706.73𝑃𝑎. 𝑐𝑚3
𝑍 0.9974
  Para el punto 4:

𝑃4 = 2.6𝑥105 𝑃𝑎
𝑉4 = 1.8𝑐𝑚3
𝑃𝑎.𝑐𝑚3 𝑐𝑚6
83,14×105 × ×298𝐾 𝑐𝑚3 1413.76 ×2.6×105 𝑃𝑎 𝑐𝑚3
𝑚𝑜𝑙.𝐾 𝑚𝑜𝑙2
𝑉𝑚 = − 18.8377 + 𝑃𝑎.𝑐𝑚3
=9510.4337𝑚𝑜𝑙
2.6×105 𝑃𝑎 𝑚𝑜𝑙 83,14×105 × ×298𝐾
𝑚𝑜𝑙.𝐾

𝑐𝑚3
𝑃𝑉𝑚 2.6𝑥105 𝑃𝑎 × 9510.4337
𝑍= = 𝑚𝑜𝑙 = 0.9980
𝑅𝑇 𝑃𝑎. 𝑐𝑚3
83,14 × 105 × × 298𝐾
𝑚𝑜𝑙. 𝐾
 Dónde:
𝑃. 𝑉 = 𝑍. 𝑛. 𝑅. 𝑇

𝑛. 𝑅. 𝑇 = 𝐾5

𝑃. 𝑉 2.6𝑥105 𝑃𝑎 × 1.8𝑐𝑚3
𝐾4 = = = 511329.46𝑃𝑎. 𝑐𝑚3
𝑍 0.9980

 Para el punto 5:

𝑃5 = 3.4𝑥105 𝑃𝑎
𝑉5 = 1.5𝑐𝑚3
𝑃𝑎.𝑐𝑚3 𝑐𝑚6
83,14×105 × ×298𝐾 𝑐𝑚3 1413.76 ×3.4×105 𝑃𝑎 𝑐𝑚3
𝑚𝑜𝑙.𝐾 𝑚𝑜𝑙2
𝑉𝑚 = − 18.8377 + 𝑃𝑎.𝑐𝑚3
=7268.33𝑚𝑜𝑙
3.4×105 𝑃𝑎 𝑚𝑜𝑙 83,14×105 × ×298𝐾
𝑚𝑜𝑙.𝐾

𝑐𝑚3
𝑃𝑉𝑚 3.4𝑥105 𝑃𝑎 × 7268.33
𝑍= = 𝑚𝑜𝑙 = 0.9974
𝑅𝑇 𝑃𝑎. 𝑐𝑚3
83,14 × 105 × × 298𝐾
𝑚𝑜𝑙. 𝐾
 Dónde:
𝑃. 𝑉 = 𝑍. 𝑛. 𝑅. 𝑇

𝑛. 𝑅. 𝑇 = 𝐾5
 𝑃. 𝑉 3.4𝑥105 𝑃𝑎 × 1.5𝑐𝑚3
𝐾5 = = = 511329.46𝑃𝑎. 𝑐𝑚3
𝑍 0.9974

 Para el punto 6:

𝑃6 = 5,3𝑥105 𝑃𝑎

𝑉6 = 1,1𝑐𝑚3
𝑃𝑎.𝑐𝑚3 𝑐𝑚6
83,14×105 × ×298𝐾 𝑐𝑚3 1413.76 ×5.3×105 𝑃𝑎 𝑐𝑚3
𝑚𝑜𝑙.𝐾 𝑚𝑜𝑙2
𝑉𝑚 = − 18.8377 𝑚𝑜𝑙 + 𝑃𝑎.𝑐𝑚3
=4656.1288 𝑚𝑜𝑙
5.3×105 𝑃𝑎 83,14×105 × ×298𝐾
𝑚𝑜𝑙.𝐾

𝑐𝑚3
𝑃𝑉𝑚 5.3𝑥105 𝑃𝑎 × 4656.1288
𝑍= = 𝑚𝑜𝑙 = 0.9960
𝑅𝑇 𝑃𝑎. 𝑐𝑚 3
83,14 × 105 × × 298𝐾
𝑚𝑜𝑙. 𝐾
 Dónde:
𝑃. 𝑉 = 𝑍. 𝑛. 𝑅. 𝑇
𝑛. 𝑅. 𝑇 = 𝐾6

𝑃. 𝑉 5.3𝑥105 𝑃𝑎 × 1.1𝑐𝑚3
𝐾6 = = = 585341.37𝑃𝑎. 𝑐𝑚3
𝑍 0.9960

 Para el punto 7:

𝑃7 = 8𝑥105 𝑃𝑎
𝑉7 = 0,8𝑐𝑚3
𝑃𝑎.𝑐𝑚3 𝑐𝑚6
83,14×105 × ×298𝐾 𝑐𝑚3 1413.76 ×8×105 𝑃𝑎 𝑐𝑚3
𝑚𝑜𝑙.𝐾 𝑚𝑜𝑙2
𝑉𝑚 = 5
− 18.8377 𝑚𝑜𝑙 + 𝑃𝑎.𝑐𝑚3
=3078.58 𝑚𝑜𝑙
8×10 𝑃𝑎 83,14×105 × ×298𝐾
𝑚𝑜𝑙.𝐾

𝑐𝑚3
𝑃𝑉𝑚 8𝑥105 𝑃𝑎 × 3078.58
𝑍= = 𝑚𝑜𝑙 = 0.9941
𝑅𝑇 𝑃𝑎. 𝑐𝑚3
83,14 × 105 × × 298𝐾
𝑚𝑜𝑙. 𝐾
  Dónde:
𝑃. 𝑉 = 𝑍. 𝑛. 𝑅. 𝑇
𝑛. 𝑅. 𝑇 = 𝐾7

𝑃. 𝑉 8𝑥105 𝑃𝑎 × 0.8 𝑐𝑚3

𝐾7 = = = 643822.02𝑃𝑎. 𝑐𝑚3
𝑍 0.9941

 Para el punto 8:

𝑃8 = 11,8𝑥105 𝑃𝑎

𝑉8 = 0,6𝑐𝑚3
𝑃𝑎.𝑐𝑚3 𝑐𝑚6
83,14×105 × ×298𝐾 𝑐𝑚3 1413.76 ×11.8×105 𝑃𝑎 𝑐𝑚3
𝑚𝑜𝑙.𝐾 𝑚𝑜𝑙2
𝑉𝑚 = 5 − 18.8377 𝑚𝑜𝑙 + 𝑃𝑎.𝑐𝑚3
=2081.47 𝑚𝑜𝑙
11.8×10 𝑃𝑎 83,14×105 × ×298𝐾
𝑚𝑜𝑙.𝐾

𝑐𝑚3
𝑃𝑉𝑚 11.8𝑥105 𝑃𝑎 × 2081.47
𝑍= = 𝑚𝑜𝑙 = 0.9913
𝑅𝑇 𝑃𝑎. 𝑐𝑚3
83,14 × 105 × × 298𝐾
𝑚𝑜𝑙. 𝐾
 Dónde:
𝑃. 𝑉 = 𝑍. 𝑛. 𝑅. 𝑇
𝑛. 𝑅. 𝑇 = 𝐾8

𝑃. 𝑉 11.8𝑥105 𝑃𝑎 × 0.6 𝑐𝑚3

𝐾8 = = = 714213.66𝑃𝑎. 𝑐𝑚3
𝑍 0.9913

 Para el punto 9:

𝑃8 = 19,8𝑥105 𝑃𝑎

𝑉8 = 0,4𝑐𝑚3
𝑃𝑎.𝑐𝑚3 𝑐𝑚6
83,14×105 × ×298𝐾 𝑐𝑚3 1413.76 ×19.8×105 𝑃𝑎 𝑐𝑚3
𝑚𝑜𝑙.𝐾 𝑚𝑜𝑙2
𝑉𝑚 = − 18.8377 𝑚𝑜𝑙 + 𝑃𝑎.𝑐𝑚3
=1233.5911 𝑚𝑜𝑙
19.8×105 𝑃𝑎 83,14×105 × ×298𝐾
𝑚𝑜𝑙.𝐾
 𝑐𝑚3
𝑃𝑉𝑚 19.8𝑥105 𝑃𝑎 × 1233.5911
𝑍= = 𝑚𝑜𝑙 = 0.9858
𝑅𝑇 𝑃𝑎. 𝑐𝑚 3
83,14 × 105 × × 298𝐾
𝑚𝑜𝑙. 𝐾
 Dónde:
𝑃. 𝑉 = 𝑍. 𝑛. 𝑅. 𝑇
𝑛. 𝑅. 𝑇 = 𝐾8

𝑃. 𝑉 19.8𝑥105 𝑃𝑎 × 0.4 𝑐𝑚3

𝐾8 = = = 803408.39𝑃𝑎. 𝑐𝑚3
𝑍 0.9858
 Para el punto 10:

𝑃10 = 37,1𝑥105 𝑃𝑎

𝑉10 = 0,25𝑐𝑚3

𝑃𝑎. 𝑐𝑚3 𝑐𝑚6 5

83,14 × 105 × × 298𝐾 𝑐𝑚3 1413.76 2 × 37.1 × 10 𝑃𝑎
𝑉𝑚 = 𝑚𝑜𝑙. 𝐾 − 18.8377 + 𝑚𝑜𝑙
37.1 × 105 𝑃𝑎 𝑚𝑜𝑙 𝑃𝑎. 𝑐𝑚3
83,14 × 105 × × 298𝐾
𝑚𝑜𝑙. 𝐾
𝑐𝑚3
= 651.0884
𝑚𝑜𝑙

𝑐𝑚3
𝑃𝑉𝑚 37.1𝑥105 𝑃𝑎 × 651.0884
𝑍= = 𝑚𝑜𝑙 = 0.9749
𝑅𝑇 𝑃𝑎. 𝑐𝑚 3
83,14 × 105 × × 298𝐾
𝑚𝑜𝑙. 𝐾
 Dónde:
𝑃. 𝑉 = 𝑍. 𝑛. 𝑅. 𝑇
𝑛. 𝑅. 𝑇 = 𝐾8

𝑃. 𝑉 37.1𝑥105 𝑃𝑎 × 0.25 𝑐𝑚3

𝐾10 = = = 714213.66𝑃𝑎. 𝑐𝑚3
𝑍 0.9749

K prom (Virial) = 579823.5296

a) Gráfica P vs Vm

Gráfico P vs V
14

12
P
10
R
E 8
S
I 6
O
4
N
2

0
0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08
Volumen molar

b) Gráfica P vs 1/Vm

Gráfica P vs 1/Vm
14

12
P
10
r
e 8
s
i 6
ó
4
n
2

0
0 10 20 30 40 50 60
1/Volumen molar
 RESULTADOS:

P V 𝑽𝒎 Gas Ideal 𝑽𝒎 Van der 𝑽𝒎 de 𝑽𝒎 de la Factor

Waals Redlich-Kwon ecuación de de
(𝟏𝟎𝟓 𝑷𝒂) (𝒄𝒎𝟑 ) 𝒄𝒎𝟑
( ) Virial compres
𝒎𝒐𝒍 𝒄𝒎𝟑 𝒄𝒎𝟑
( ) ( ) ibilidad
𝒎𝒐𝒍 𝒎𝒐𝒍 𝒄𝒎𝟑
( )
𝒎𝒐𝒍

𝑷𝟏 1 3 24775,72 24752.995 24775.1013 24756.939 0.9992

𝑷𝟐 1.51 2.5 16407,76 16371.133 16343.2836 16389.0100 0.9988

𝑷𝟑 2.1 2.1 11797,96 11779.04 11733.68 11779.2440 0.9984

𝑷𝟒 2.6 1.8 9529,1231 9510.3947 9464.7930 9510.4337 0.9980

𝑷𝟓 3.4 1.5 7286,9764 7230.386 7222.5655 7268.33 0.9974

𝑷𝟔 5.3 1.1 4674,664 4250,7527 4662,9203 4656.1288 0.9960

𝑷𝟕 8 0.8 3096,965 3078,4819 3085,062 3078.58 0.9941
𝑷𝟖 11.8 0.6 2099,637 2081,3314 2088,301 2081.47 0.9913
𝑷𝟗 19,8𝑥105 0.4 1251,298 1233,3862 1240,472 1233.5911 0.9858

𝑷𝟏𝟎 37,1𝑥105 0.25 667,809 650,8457 658,001 651.0884 0.9750

 P V 𝑲 Gas Ideal 𝑲 Van der 𝑲 de Redlich- 𝑲 de la
Waals Kwon ecuación de
(𝟏𝟎𝟓 𝑷𝒂) (𝒄𝒎𝟑 ) 𝑷𝒂. 𝒄𝒎𝟑 Virial
𝑷𝒂. 𝒄𝒎𝟑 𝑷𝒂. 𝒄𝒎𝟑
𝑷𝒂. 𝒄𝒎𝟑

𝑷𝟏 1 3 297400 297035.94 297305 300240.19

𝑷𝟐 1,51 2.5 371635,16 322800 369746 377953.54

𝑷𝟑 2.1 2.1 421186,5 420420 418894 441706.73

𝑷𝟒 2.6 1.8 445962,4 445094 442953 468937.8757

𝑷𝟓 3.4 1.5 520322,4 516290 515691 511329.46

𝑷𝟔 5.3 1.1 581940 529432.9 580768.7 585341.37

𝑷𝟕 8 0.8 639200 635400 636760 643822.02

𝑷𝟖 11.8 0.6 705640 699952.4 702300.6 714213.66

𝑷𝟗 19,8 0.4 790020 779031 783505,8 803408.40

𝑷𝟏𝟎 37,1 0.25 92379 903051,1 912993,9 951282.05