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Langmuir Isotherm : In 1916, Irving Langmuir developed a model Isotherm for adsorption which is
based on four assumptions.
1. The surface of adsorbent is uniform; all the adsorption sites are equivalent.
2. Adsorbed molecules donot interact
3. All adsorption occurs through the same mechanism
4. Adsorption takes place only on the free surface of the adsorbent; monolayer adsorption
These conditions are very difficult to meet all the times. The mechanism of adsorption may differ
form first molecule to last one adsorbed and monolayer adsorption happens in rare cases. This
problems are eliminated in BET Isotherm.
Separation factor (𝑅𝐿 ), a dimensionless quantity determines the feasibility and favourability of
adsorption process for Langmuir isotherm model. It is given as:
1
𝑅𝐿 =
𝐾𝐿 𝐶𝑜
where,
𝐶𝑜 = intial concentration of solution
Freundlich Isotherm: This model is used to describe heterogeneous adsorption system. Freundlich
gave an empirical equation which is represented as:
𝑥
= 𝐾𝐹 𝐶𝑒 1⁄𝑛
𝑚
The linear form of the above empirical equation is given as:
𝑥 1
log ( ) = log(𝐾𝐹 ) + log(𝐶𝑒 )
𝑚 𝑛
where,
x=amount of dye adsorbed
m=weight of adsorbent used
𝐾𝐹 =adsorption capacity
1
=heterogeneity factor and n>1 shows favourable adsorption
𝑛