You are on page 1of 15

PAPER-1 (B.E./B. TECH.

JEE (Main) 2019


COMPUTER BASED TEST (CBT)
Questions & Solutions
Date: 8 April, 2019 (SHIFT-2) | TIME: 02.30 P.M. to 05.30 P.M.

Duration: 3 Hours | Max. Marks: 360


SUBJECT: CHEMISTRY

_______________________________________________________________________________________________________________

Resonance Eduventures Ltd.


Registered & Corporate Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Tel.No.: 0744-6607777, 3012100, 3012222, 6635555 | Toll Free: 1800 258 5555 | Fax: +91-022-39167222 | 08003 444 888
Website: www.resonance.ac.in | E-mail: contact@resonance.ac.in | CIN: U80302RJ2007PLC024029
| JEE (MAIN) 2019 | DATE : 08-04-2019 (SHIFT-2) | PAPER-2 | OFFICIAL | CHEMISTRY

PART : CHEMISTRY
Straight Objective Type (lh/ks oLrqfu"B izkj)
This section contains 30 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which Only One is correct.
bl [k.M esa 30 cgq&fodYih iz'u gSaA izR;sd iz'u ds 4 fodYi (1), (2), (3) rFkk (4) gSa] ftuesa ls flQZ ,d lgh gSA
1. The Mond process is used for the :
(1) purification of Zr and Ti (2) extraction of Mo
(3) extraction of Zn (4) purification of Ni
ekWUM izØe iz;qDr gksrk gS%
(1) Zr rFkk Ti ds 'kks/ku ds fy, (2) Mo ds fu"d"kZ.k ds fy,
(3) Zn ds fu"d"kZ.k ds fy, (4) Ni ds 'kks/ku ds fy,
Ans. (4)
50C
Sol. Ni(s) + 4CO(g)   [Ni(CO)4]
Impure (v'kq))
200   250 C
[Ni(CO)4]     Ni(s) + 4CO(g)
Pure ('kq))
2. The statement that is INCORRECT about the interstitial compounds is :
(1) they are chemically reactive. (2) they have metallic conductivity
(3) they are very hard. (4) they have high melting points
varjkyh ;kSfxdks ds ckjs esa tks dFku vlR; gksxk] og gS%
(1) os jklk;fud :i ls vfHkfØ;k'khy gks rs gS A (2) muesa /kkfRod pkydrk gksrh gSA
(3) os cgq r dBksj gks rs gSa A (4) muds xyukad mPp gks rs gSaA
Ans. (1)
Sol. Interstitial compound are almost inert so (A) is wrong statement
vUrjdk'kh ;kSfxd yxHkx vfØ; gksrs gSA blfy, (A) xyr dFku gSA
3. The covalent alkaline earth metal halide (X = Cl, Br, I) is :
lgla;ksth {kkjh; e`nk /kkrq gSykbM (X = Cl, Br, I) gS%
(1) CaX2 (2) SrX2 (3) BeX2 (4) MgX2
Ans. (3)
Sol. According to Fajan’s rule when size of cation decrease, then covalent character increase.
So BeX2 is covalent in nature.
Qktku fu;e ds vuqlkj tc /kuk;u dk vkdkj ?kVrk gS] rks lgla;kstd xq.k c<+rk gSA
vr% BeX2 lgla;kstd izd`fr dk gSA
4. The correct statement about ICl 5 and ICl –4 is :
(1) ICl 5 is trigonal bipyramidal and ICl 4– is tetrahedral.
(2) ICl 5 is square pyramidal and ICl –4 is square planar.
(3) both are isostructural.
(4) ICl 5 is square pyramidal and ICl –4 is tetrahedral.
ICl 5 rFkk ICl 4– ds fy, lR; dFku gS%
(1) ICl 5 f=kelurk{k f}fijkfeMh rFkk ICl 4– prq"Qydh; gSA
(2) ICl 5 oxZ fijkfeMh rFkk ICl 4– oxZ leryh; gS A
(3) nksuks gh lelajpukRed gSaA
(4) ICl 5 oxZ fijkfeMh ICl –4 prq"Qydh; gSA

Resonance Eduventures Ltd.


Corp. & Reg. Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph.No. : +91-744-3012222, 6635555 | FAX No. : +91-022-39167222
To Know more : sms RESO at 56677 | Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in | CIN : U80302RJ2007PLC024029

This solution was download from Resonance JEE (MAIN) 2019 Solution portal PAGE # 1
| JEE (MAIN) 2019 | DATE : 08-04-2019 (SHIFT-2) | PAPER-2 | OFFICIAL | CHEMISTRY
Ans. (2)
– Cl Cl
Cl Cl Cl

Sol.  

Cl Cl Cl Cl
Square planar Square pyramidal
– Cl Cl
Cl Cl Cl

Sol.  

Cl Cl Cl Cl
oxZ leryh; oxZ fijkfeMh;
5. The major product of the following reaction is :
fuEu vfHkfØ;k dk eq[; mRikn gS%
O
(1) t-BuOK
(2) Conc. H2SO4/
Cl

O O

(1) (2)

O O

(3) (4)

Ans. (1)
O O
(1) t-BuOK
Sol.
E2 elimination
Cl reaction

O
(2) Conc. H2SO4/
Electrophilic
subsitution

6. If p is the momentum of the fastest electron ejected from a metal surface after the irradiation of light
having wavelength , then for 1.5 p momentum of the photoelectron, the wavelength of the light should
be :
(Assume kinetic energy of ejected photoelectron to be very high in comparison to work function) :
;fn  rjaxnS/;Z ds izdk'k ls fdjf.kr gksus ij,d /kkrq dh lrg ls fudys gq, rhozre bysDVªkWu dk laosx p gS rks
izdkf'kd bysDVªkWu ds 1.5 p laosx ds fy, izdk'k dk rjaxnS/;Z gksxk%
¼eku yhft;s fd fu"dkflr izdkf'kd bysDVªkWu dh K.E. ¼xfrt ÅtkZ½ mlds dk;ZQyu dh rqy uk esa cgqr mPp gSa½
3 1 4 2
(1)  (2)  (3)  (4) 
4 2 9 3
Ans. (3)

Resonance Eduventures Ltd.


Corp. & Reg. Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph.No. : +91-744-3012222, 6635555 | FAX No. : +91-022-39167222
To Know more : sms RESO at 56677 | Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in | CIN : U80302RJ2007PLC024029

This solution was download from Resonance JEE (MAIN) 2019 Solution portal PAGE # 2
| JEE (MAIN) 2019 | DATE : 08-04-2019 (SHIFT-2) | PAPER-2 | OFFICIAL | CHEMISTRY
Sol. As kinetic energy is much higher than work function so
E = E0 + KE  KE
hc  P2 
As E = & kE =  
  2m 
 
2
2 P    1 
2
So =  1   2   
1  P2    1 .5 
4
2 = 
9

7. The major product obtained in the following reaction is :


fuEu vfHkfØ;k esa izkIr gksus okyk eq[; mRikn gS%
NH2
(i) CHCl3/KOH
(ii) Pd/C/H2

CN O
H H
NCH3 NCH3

(1) (2)

H2N OH CN O
H H
NCHCl2 NCH3

(3) (4)

CN OH CN OH
Ans. (1)
NH2 NC NH–CH3
1 CHCl .KOH 2  H2 , Pd, C
Sol.   3    

CN O CN O OH
CH2NH2
(Carbyalmine reaction) (Reduction)
¼dkfcZy ,ehu vfHkfØ;k½ ¼vip;u½

8. Fructose and glucose can be distinguished by :


(1) Seliwanoff's test (2) Benedict's test (3) Fehling's test (4) Barfoed's test
ÝDVkst rFkk Xyqdkst fuEu fdlds }kjk igpkus tk ldrs gSa\
(1) lfyokukWQ ijh{k.k (2) csfufMDV ijh{k.k (3) Qsgfyax ijh{k.k (4) ckQksZM ijh{k.k
Ans. (1)
Sol. Seliwanoff's test: Seliwanoff's reagent is (0.5%) resorcinol in 3N HCl. It gives red solution with
fructose and sucrose but no change in colour with glucose.
Sol. lsfyokukWQ ijh{k.k% lsfyokukWQ vfHkdeZd 3N HCl es (0.5%) fjlksflZukWy dk feJ.k gksrk gSA ;g ÝsDVkst ,oa
lqØkst ds lkFk yky foy;u nsrk gS tcfd Xywdkst ds lkFk dksbZ jax ifjorZu ugha nsrk gSA

Resonance Eduventures Ltd.


Corp. & Reg. Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph.No. : +91-744-3012222, 6635555 | FAX No. : +91-022-39167222
To Know more : sms RESO at 56677 | Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in | CIN : U80302RJ2007PLC024029

This solution was download from Resonance JEE (MAIN) 2019 Solution portal PAGE # 3
| JEE (MAIN) 2019 | DATE : 08-04-2019 (SHIFT-2) | PAPER-2 | OFFICIAL | CHEMISTRY
9. The major product obtained in the following reaction is :
fuEu vfHkfØ;k esa izkIr gksus okyk eq[; mRikn gS%
CH3 O
NaOH
OHC 
CH3

(1) (2)

O
CH3

H3C

(3) (4) H

O
O CH2
Ans. (1)
Sol. It is an example of intramolecular aldol condensation.
;g vUr% v.kqd ,YMksy la?kuu vfHkfØ;k dk mnkgj.k gSA
O O O
O


OH
– CH=O  
CH=O
OH

10. Among the following molecules/ions,


fuEu v.kqvksa@vk;uksa esa
C 22 – , N22– , O 22 – , O2
which one is diamagnetic and has the shortest bond length?
dkSu izf rpqEcdh; gS vkSj mldh vkcU/k yEckbZ lcls de gS\
(1) O2 (2) N22– (3) O 22 – (4) C 22 –
Ans. (4)
Sol. C2–2  1s2, 1s2,2s2,2s2, [2P x2 = 2Py2] 2Pz2
10  4
Bond Order = = 3 (diamagnetic)
2
10  4
cU/k Øe = = 3 (izfrpqEcdh;)
2
N2–2  1s 2 ,  * 1s2 , 2s 2 ,  * 2s2 , [ 2Px2  2Py2 ] 2Pz2 , [ * 2Px1   * 2Py1 ]
10 – 6
B.O   2 (Paramagnetic)
2
10 – 6
cU/k Øe   2 (vuqpqEcdh;)
2
O 2–2  1s 2 ,  * 1s 2 , 2s 2 ,  * 2s 2 , 2Pz2 [2Px2  2Py2 ] [ * 2Px2   * 2Py2 ]

Resonance Eduventures Ltd.


Corp. & Reg. Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph.No. : +91-744-3012222, 6635555 | FAX No. : +91-022-39167222
To Know more : sms RESO at 56677 | Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in | CIN : U80302RJ2007PLC024029

This solution was download from Resonance JEE (MAIN) 2019 Solution portal PAGE # 4
| JEE (MAIN) 2019 | DATE : 08-04-2019 (SHIFT-2) | PAPER-2 | OFFICIAL | CHEMISTRY

10 – 8
B.O   1(Diamagnetic) (izfrpqEcdh;)
2
O 2  1s 2 ,  * 1s 2 , 2s 2 ,  * 2s 2 , 2Pz2 [2Px2  2Py2 ] [  * 2Px1   * 2Py1 ]
10 – 6
B.O   2 (Paramagnetic)
2
10 – 6
cU/k Øe   2 (vuqpqEcdh;)
2
1
B.O 
B.L.
1
cU/k Øe
cU/k yEckbZ

11. The percentage composition of carbon by mole in methane is :


eksy ds vk/kkj ij feFksu esa dkcZu dh izfr'krrk la?kVu gS%
(1) 80% (2) 20% (3) 75% (4) 25%
Ans. (2)
Sol. CH4
nC = 1 mole eksy
nH = 4 mole eksy
nC 1
mole percentage of C ¼dkcZu ds eksy dk izfr'kr½ = × 100 = × 100 = 20%
nC  nH 1 4

12. For the solution of the gases w, x, y and z in water at 298 K, the Henrys law constants (KH) are 0.5, 2, 35
and 40 k bar, respectively. The correct plot for the given data is :

partial y
(1) (2) pressure x
w
(0,0) mole fraction
of water

z
partial z partial
(3) pressure (4) pressure y
y x
x
w w
(0,0) mole fraction (0,0) mole fraction
of water of water

Resonance Eduventures Ltd.


Corp. & Reg. Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph.No. : +91-744-3012222, 6635555 | FAX No. : +91-022-39167222
To Know more : sms RESO at 56677 | Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in | CIN : U80302RJ2007PLC024029

This solution was download from Resonance JEE (MAIN) 2019 Solution portal PAGE # 5
| JEE (MAIN) 2019 | DATE : 08-04-2019 (SHIFT-2) | PAPER-2 | OFFICIAL | CHEMISTRY
298 K ij ty esa xSl w, x, y rFkk z ds foy;u ds fy, gsujh fu;e fLFkjkad (KH) Øe'k% 0.5, 2, 35 rFkk 40 k bar,
gSaA fn;s vk¡dM+ksa ds fy;s lgh IykV gS %

partial y
(1) (2) pressure x
w
(0,0) mole fraction
of water

z
partial z partial
(3) pressure (4) pressure y
y x
x
w w
(0,0) mole fraction (0,0) mole fraction
of water of water
Ans. (3)
Sol. Pgas = KH. xgas

Pgas = KH. 1 – x H2O 
Pgas = KH – KH. x H2O
y = c + mx

13. The maximum prescribed concentration of copper in drinking water is :


ihus ds ty es dkWij ¼rkacs½ dh fu/kkZfjr vf/kdre lkUnzrk gS%
(1) 0.05 ppm (2) 3 ppm (3) 5 ppm (4) 0.5 ppm
Ans. (2)
The maximum prescribed concentration of copper in drinking water is 3 ppm
ihus ds ty es dkWij ¼rkacs½ dh fu/kkZfjr vf/kdre lkUnzrk 3 ppm gSA

14. The major product of the following reaction is.


fuEu vfHkfØ;k dk eq[; mRikn gS%
CH3

(1) Cl2/h
(2) H2O,

Cl
CHCl2 CO2H CHO CH2OH

(1) (2) (3) (4)

Cl Cl Cl Cl
Ans. (3)

Resonance Eduventures Ltd.


Corp. & Reg. Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph.No. : +91-744-3012222, 6635555 | FAX No. : +91-022-39167222
To Know more : sms RESO at 56677 | Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in | CIN : U80302RJ2007PLC024029

This solution was download from Resonance JEE (MAIN) 2019 Solution portal PAGE # 6
| JEE (MAIN) 2019 | DATE : 08-04-2019 (SHIFT-2) | PAPER-2 | OFFICIAL | CHEMISTRY

CH3 CH=O
CHCl2

1 Cl2 / h 2  H O, 
Sol.     2  

Cl Cl
Cl
(Free radical
(SN1)
Substitution)
¼eqDr ewy d izfrLFkkiu½

15. 0.27 g of a long chain fatty acid was dissolved in 100 cm3 of hexane. 10 mL of this solution was added
dropwise to the surface of water in a round watch glass. Hexane evaporates and a monolayer is
formed. The distance from edge to cenre of the watch glass is 10 cm. What is the height of the
monolayer?
[Density of fatty acid = 0.9 g cm–3,  = 3]
nh?kZ Ja`[kyk okys QSVh ,flM ds 0.27 g dks 100 cm3 gsDlsu esa ?kksyk x;kA bl foy;u ds 10 mL dks ,d xksykdkj
okp X;kl esa j[ks ty dh lrg ij cw¡n&cw¡n djds fxjk;k x;kA gsDlsu ok"ihÑr gks xbZ vkSj ,d ,dy irZ cu xbZA
okp Xykl ds fdjkus ls muds dsUnz rd dh nwjh 10 cm gSA ml ,dy ijr dh Å¡pkbZ D;k gksxh\
[QSVh ,flM dk ?kuRo = 0.9 g cm–3,  = 3]
(1) 10–2 m (2) 10–6 m (3) 10–8 m (4) 10–4 m
Ans. (2)
0.27  0.1
Sol. Mass of fatty acid which is added over watch glass = = 2.7 × 10–2
100
2.7  10 2
Volume of fatty acid = = 3 × 10–2
0 .9
Total Area of glass plate = r2 = 3 × [10]2 = 300 cm2
Volume = Area × hight
3×10–2 = 300 × hight
Hight of the layer = 10–4 cm = 10–6 m

16. The ion that has sp3d2 hybridization for the central atom, is :
fuEu esa ls fdl vk;u es dsfUnz; ijek.kq dk ladj.k sp3d2 gS\
(1) [ICl2]– (2) [IF6]– (3) [BrF2]– (4) [ICl 4]–
Ans. (4)

Cl Cl

Sol.  Sp3d2
Cl Cl
[BrF2]–  sp3d
[ICl 2]–  sp3d
[IF6]–  sp3d3

17. Which one of the following alkenes when treated with HCl yields majorly an anti Markovnikov product?
fuEufyf[kr ,sYdhuksa esa ls dkSu&lk ,d HCl ds lkFk vfHkfØ;k djds eq[;r% ,d izfr ekdksZuhdkWQ mRikn nsrk gS\
(1) CH3O–CH=CH2 (2) Cl–CH=CH2 (3) H2N–CH=CH2 (4) F3C–CH=CH2
Ans. (4)
Sol. CF3 is very strong -I group hence it will favour anti-Markownikov's product.
CF3–CH=CH2 
 CF3–CH2–CH2+  CF3–CH2–CH2X (anti-Markownikov's product)
HX

Resonance Eduventures Ltd.


Corp. & Reg. Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph.No. : +91-744-3012222, 6635555 | FAX No. : +91-022-39167222
To Know more : sms RESO at 56677 | Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in | CIN : U80302RJ2007PLC024029

This solution was download from Resonance JEE (MAIN) 2019 Solution portal PAGE # 7
| JEE (MAIN) 2019 | DATE : 08-04-2019 (SHIFT-2) | PAPER-2 | OFFICIAL | CHEMISTRY
Sol. CF3 izcyre -I lewg gS] vr% ;g ,UVh&ekjdksuhdkW o mRikn cuk;sxkA
HX
CF3–CH=CH2 
 CF3–CH2–CH2+  CF3–CH2–CH2X (,UVh&ekjdksuhdkW o mRikn)

18. 5 moles of an ideal gas at 100 K are allowed to undergo reversible compression till its temperature
becomes 200 K. If CV = 28 JK–1 mol–1 , calculate U and pV for this process, (R = 8.0 JK–1 mol –1)
100 K ij] ,d vkn'kZ xsl ds 5 eksy dk mRØe.kh; laihMu rc rd fd;k tkrk gS tc rd dh mldk rki 200 K
ugha gks tkrkA ;fn CV = 28 JK–1 mol–1 , rks bl izØe ds fy, U rFkk pV dh x.kuk dhft, (R = 8.0 JK–1 mol–
1)

(1) U = 14 kJ; (pV) = 4 kJ (2) U = 14 kJ; (pV) = 18 kJ


(3) U = 14 kJ; (pV) = 0.8 J (4) U = 2.8 kJ; (pV) = 0.8 kJ
Ans. (1)
5  28  100
Sol. U = nCvT = = 14 KJ
1000
5  8  100
(PV) = nRT = = 4 KJ
1000

19. Consider the bcc unit cells of the solid 1 and 2 with the position of atoms as shown below. The radius of
atoms as shown below. The radius of atom B is twice that of atom A. The unit cell edge length is 50%
more in solid 2 than in 1. What is the approximate packing efficiency in solid 2?
Bksl 1 rFkk 2 ijek.kqvks dh fLFkfr ds lkFk] tSlk fd uhps n'kkZ;k x;k gS] dh ch-lh-lh ¼dk-da-?k-½ ,dd dksf"Bdk ij
fopkj dhft,A ijek.kq B dh f=kT;k ijek.kq A dh f=kT;k dh nwuh gSA Bksl 1 dh ,dd dksf"Bdk dh dksj yEckbZ ls
Bksl 2 dh ,dd dksf"Bdk dh dksj yEckbZ 50% T;knk gSA Bksl 2 ls esa yxHkx lqladqyu n{krk D;k gS\
A A
A A
A A A A
A B
A A A A
A A A A
Solid 1 Solid 2
(1) 65% (2) 45% (3) 90% (4) 75%
Ans. (3)
Sol. 3a  2r  2(2r )  6r
6r
a= 2 3 r
3
4 3 4
r  (2r )3
P.F. = 3 3
a3
4 3
(r  8r 3 )
3 4  9r 3
= 
( 2 3r )3
3  8  3 3r 3

=  0.906
2 3
% of packing efficiency = 0.906 × 100 = 90.6%
ladqyu n{krk dk % = 0.906 × 100 = 90.6%

Resonance Eduventures Ltd.


Corp. & Reg. Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph.No. : +91-744-3012222, 6635555 | FAX No. : +91-022-39167222
To Know more : sms RESO at 56677 | Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in | CIN : U80302RJ2007PLC024029

This solution was download from Resonance JEE (MAIN) 2019 Solution portal PAGE # 8
| JEE (MAIN) 2019 | DATE : 08-04-2019 (SHIFT-2) | PAPER-2 | OFFICIAL | CHEMISTRY
20. The strength of 11.2 volume solution of H2O2 is : [Given that molar mass of H = 1 g mol –1 and O = 16 g
mol –1]
H2O2 ds 11.2 vk;ru foy;u dh lkeF;Z gS] ¼fn;k x;k gS% eksyj nzO;eku H = 1 g mol–1 rFkk O = 16 g mol–1½
(1) 3.4% (2) 34% (4) 13.6% (4) 1.7%
Ans. (1)
Volume strength vk;ru lkeF; Z
Sol. M=
11.2 11.2
%( w / v )  10
M=
GMM
%( w / v )  10
1=
34
w
So % = 3.4 %
v

21. The compound that inhibits the growth of tumors is :


(1) cis-[Pd(Cl)2(NH3)2] (2) cis-[Pt(Cl)2(NH3)2]
(3) trans-[Pt(Cl)2(NH3)2] (4) trans-[Pd(Cl)2(NH3)2]
og ;kSfxd tks V;wej dh o`f) dks jksdrk gS] gS%
(1) fll-[Pd(Cl)2(NH3)2] (2) fll-[Pt(Cl)2(NH3)2]
(3) Vªkal-[Pt(Cl)2(NH3)2] (4) Vªkal-[Pd(Cl)2(NH3)2]
Ans. (2)
Cl NH3
Sol. Pt

Cl NH3

22. Calculate the standard cell potential (in V) of the cell in which following reaction takes place :
ml lsy ds ekud lsy foHko (V esa) dh x.kuk dhft, ftlesa fuEu vfHkfØ;k gksrh gS%
Fe2+ (aq) + Ag+ (aq)  Fe3+ (aq) + Ag(s)
Given that ¼fn;k x;k gS%½
E0Ag / Ag  xV
0
EFe 2
/ Fe
 yV
0
EFe 3
/ Fe
 zV
(1) x – z (2) x – y (3) x + y – z (4) x + 2y – .3z
Ans. (4)
Sol. Fe2+ Fe G1  –2Fy
Fe3+ Fe G 2  –3Fz
Fe3+ Fe2+ Eº = 3z – 2y
E°cell = E 0Ag |Ag  EFe
0
3
| Fe2 
= x – [3z – 2y) = x + 2y – 3z
For given cell reaction
fn xbZ lSy vfHkfØ;k ds fy,
Ecell = x + 2y – 3z

Resonance Eduventures Ltd.


Corp. & Reg. Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph.No. : +91-744-3012222, 6635555 | FAX No. : +91-022-39167222
To Know more : sms RESO at 56677 | Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in | CIN : U80302RJ2007PLC024029

This solution was download from Resonance JEE (MAIN) 2019 Solution portal PAGE # 9
| JEE (MAIN) 2019 | DATE : 08-04-2019 (SHIFT-2) | PAPER-2 | OFFICIAL | CHEMISTRY
23. The calculated spin-only magnetic moments (BM) of the anionic and cationic species of [Fe(H2O)6]2 and
[Fe(CN)6],
(1) 0 and 5.92 (2) 4.9 and 0 (3) 0 and 4.9 (4) 2.84 and 5.92
[Fe(H2O)6]2 rFkk [Fe(CN)6] ds _.kk;fud rFkk /kuk;fud Lih'kht ds ifjdfyr izpØ.k&ek=k pqEcdh; vk?kw.kZ (BM
esa) Øe'k% gSa%
(1) 0 rFkk 5.92 (2) 4.9 rFkk 0 (3) 0 rFkk 4.9 (4) 2.84 rFkk 5.92
Ans. (3)
Sol. [Fe(CN)6]–4
Fe+2  3d6
CN–  S.F.L.
t2g2,2,2 eg0,0
No. of unpaired e– = 0
v;qfXer bysDVªkWuksa dh la[;k = 0
B.M. = 0
[Fe(H2O)6]+2
Fe+2  3d6
H2O  W.F.L.
t2g2,1,1 eg1,1
No. of unpaired e– = 4
v;qfXer bysDVªkWuksa dh la[;k = 4
= 46 = 24 B.M. = 4.9BM

k1 k2
24. For a reaction scheme A  B   C, if the rate of formation of B is set to be zero then the
concentration of B is given by :
k1 k2
vfHkfØ;k ;kstuk A  B   C ds fy,] ;fn B ds cuus dh nj 'kwU; dh nh tk; rks B dh lkUnz rk fuEu ds
}kjk nh tk;sxh%
k 
(1) (k1–k2) [A] (2) (k1 + k2) [A] (3)  1  [A] (4) k1k2 [A]
 k2 
Ans. (3)
d[B ]
Sol.  K 1 [ A ] – K 2 [B ]
dt
d[B ]
0
dt
K
[B] = 1 [ A ]
K2

25. Polysubsitution is a major drawback in :


(1) Friedel Craft's acylation (2) Reimer Tiemann reaction
(3) Friedel Craft's alkylation (4) Acetylation of aniline
fuEu es ls fdles cgqizfrLFkkiu ,d eq[; deh gS\
(1) ÝhMy&Øk¶V ,slkbys'ku ¼,flyhdj.k½ (2) jkbej Vheu vfHkfØ;k
(3) ÝhMy&Øk¶V ,sfYdys 'ku (4) ,sfuyhu ,slkbys'ku
Ans. (3)
Sol. In Friedel craft alkylation, the alkylated product obtained is more activated than reactant, hence
undergoes poly substitution.
fÝMy Øk¶V ,Ydyhdj.k es] ,YdyhÑr mRikn vfHkdeZd dh rqyuk es vf/kd lfØ; gksrk gS] vr% cgqizf rLFkkiu
gksrk gSA

Resonance Eduventures Ltd.


Corp. & Reg. Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph.No. : +91-744-3012222, 6635555 | FAX No. : +91-022-39167222
To Know more : sms RESO at 56677 | Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in | CIN : U80302RJ2007PLC024029

This solution was download from Resonance JEE (MAIN) 2019 Solution portal PAGE # 10
| JEE (MAIN) 2019 | DATE : 08-04-2019 (SHIFT-2) | PAPER-2 | OFFICIAL | CHEMISTRY
26. The major product in the following reaction is :
fuEu vfHkfØ;k esa eq[; mRikn gS%
NH2

N
N
base
+ CH3I  
N N
H
NH2 NH2
N +
NCH3 N
N
(1) (2)
N N +
N N
H H
CH3
NHCH3
NH2
N
N N
N
(3) (4)

N N N
N H
CH3
Ans. (3)
(e)
(a) NH2
N N(d)
Sol. (Adenine)
NH N
(b) (c)

Adenine is the purine base present in RNA and DNA. It reacts from nitrogen b with ribose sugar hence
according to this correct product is (3).

27. For the following reactions, equilibrium constants are given :


S(s) + O2(g) SO2(g); K1 = 1052
2S(s) + 3O2(g) 2SO3(g); K2 = 10129
The equilibrium constant for the reaction,
2SO2(g) + O2(g) 2SO3(g) is :
(1) 1077 (2) 10154 (4) 10181 (4) 1025
uhps nh xbZ vfHkfØ;kvksa ds fy;s lkE; fLFkjkad fn;s x;s gSa%
S(s) + O2(g) SO2(g); K1 = 1052
2S(s) + 3O2(g) 2SO3(g); K2 = 10129
vfHkfØ;k
2SO2(g) + O2(g) 2SO3(g) dk lkE; fLFkjkad gksxk%
(1) 1077 (2) 10154 (4) 10181 (4) 1025
Ans. (4)
[SO 3 ]2
Sol. Target equation y{; vfHkfØ;k Keq = ….(1)
[SO 2 ] 2 [O 2 ]
[SO2 ]
K1 = = 1052
[O 2 ]

Resonance Eduventures Ltd.


Corp. & Reg. Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph.No. : +91-744-3012222, 6635555 | FAX No. : +91-022-39167222
To Know more : sms RESO at 56677 | Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in | CIN : U80302RJ2007PLC024029

This solution was download from Resonance JEE (MAIN) 2019 Solution portal PAGE # 11
| JEE (MAIN) 2019 | DATE : 08-04-2019 (SHIFT-2) | PAPER-2 | OFFICIAL | CHEMISTRY

[SO 3 ] 2
K2 = = 10129 …(2)
[O 2 ] 3
[SO 2 ] 2
K12 = = 10104 …(3)
[O 2 ]2
K2 10 129
Keq = = = 1025
(K 1 ) 2 10 104

28. Which of the following compounds will show the maximum 'enol' content?
fuEu ;kSfxdksa es ls dkSu&lk ^bZukWy* dh vf/kdre ek=kk iznf'kZr djsxk\
(1) CH3COCH2CONH2 (2) CH3COCH2COOC2H5
(3) CH3COCH2COCH3 (4) CH3COCH3
Ans. (3)
O O
Sol. Enol content is maximum in CH3–C–CH2–C–CH3
O O
CH3–C–CH2–C–CH3 bZukWy ?kVd vf/kdre gS A

29. The structure of Nylon-6 is :


ukbykWu-6 dh lajpuk gS%
O H O H O H O H
(1) C–(CH2)6–N (2) (CH2)4–C–N (3) C–(CH2)5–N (4) (CH2)6–C–N
n n n n
Ans. (3)
Sol. Nylon 6 is prepared by caprolactamsss.

30. The IUPAC symbol for the element with atomic number 119 would be :
119 ijek.kq Øeka d okys rRo ds fy, vkbZ-;w-ih-,-lh izrhd gksxk%
(1) une (2) unh (3) uun (4) uue
Ans. (4)
Sol. 119  Ununenium (uue)

Resonance Eduventures Ltd.


Corp. & Reg. Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph.No. : +91-744-3012222, 6635555 | FAX No. : +91-022-39167222
To Know more : sms RESO at 56677 | Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in | CIN : U80302RJ2007PLC024029

This solution was download from Resonance JEE (MAIN) 2019 Solution portal PAGE # 12